US20080038636A1 - Method for Manufacturing Polyradical Compound and Battery - Google Patents
Method for Manufacturing Polyradical Compound and Battery Download PDFInfo
- Publication number
- US20080038636A1 US20080038636A1 US11/791,652 US79165205A US2008038636A1 US 20080038636 A1 US20080038636 A1 US 20080038636A1 US 79165205 A US79165205 A US 79165205A US 2008038636 A1 US2008038636 A1 US 2008038636A1
- Authority
- US
- United States
- Prior art keywords
- battery
- active material
- polyradical compound
- electrode active
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
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- 238000000034 method Methods 0.000 title claims description 31
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- 239000003792 electrolyte Substances 0.000 claims abstract description 24
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- -1 vinyl ether compound Chemical class 0.000 claims description 29
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 16
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/137—Electrodes based on electro-active polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
- H01M4/602—Polymers
- H01M4/606—Polymers containing aromatic main chain polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/043—Processes of manufacture in general involving compressing or compaction
- H01M4/0433—Molding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/109—Primary casings; Jackets or wrappings characterised by their shape or physical structure of button or coin shape
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to an electrode active material that has a high capacity density and from which a large current can be extracted; a battery that has a high energy density and produces a large output; and a polyradical compound that can be the electrode active material having the above-mentioned properties.
- a lithium ion battery As a battery having a high energy density, a lithium ion battery has been developed and widely used since the 1990s.
- a lithium ion battery as an electrode active material, for example, a lithium-containing transition metal oxide such as lithium manganate or lithium cobaltate is used for a cathode, and carbon is used for an anode.
- the lithium ion battery uses an insertion reaction of lithium ions into the electrode active material and an elimination reaction of lithium ions from the electrode active material to charge and discharge.
- Such a lithium ion battery has a high energy density and exhibits excellent cycle performance, and thus the lithium ion battery is used in various kinds of electronic devices represented by cellular phones.
- the lithium ion battery has a low reaction rate of the electrode reaction, and thus extracting a large current seriously deteriorates battery properties. Therefore, the lithium ion battery has drawbacks of having difficulties to produce a large output and also requiring many hours to recharge.
- an electric double layer capacitor As a storage device that produces a large output, an electric double layer capacitor is known.
- the electric double layer capacitor can discharge a large current at one time and thereby producing a large output.
- the electric double layer capacitor also exhibits excellent cycle performance, and has been developed as a backup power supply.
- the electric double layer capacitor is not suitable for a power supply of portable electronic devices because the capacitor has a very low energy density and downsizing of the capacitor is difficult.
- Patent Document 1 U.S. Pat. No. 4,833,048
- Patent Document 2 Japanese Patent No. 2,715,778 disclose a battery using an organic compound having a disulfide bond for a cathode.
- This battery uses an electrochemical oxidation-reduction reaction that involves forming and dissociating disulfide bonds as the principle on which the battery operates.
- the battery is composed of an electrode material containing sulfur or carbon as its main component, both of which are elements of low specific gravity, thereby achieving some effects as a large capacity battery having a high energy density.
- the battery has a drawback that its capacity tends to decrease through charging and discharging cycles because the dissociated bonds have a low efficiency to form the bonds again and the electrode active material diffuses into an electrolyte solution.
- a battery using an organic compound there is proposed a battery using a conductive polymer as an electrode material.
- This battery uses doping and undoping reactions of electrolyte ions for the conductive polymer as the principle on which the battery operates.
- the doping reaction is defined as a reaction of stabilizing charged radicals generated by oxidation or reduction of the conductive polymer by counter ions.
- Patent Document 3 U.S. Pat. No. 4,442,187 discloses a battery using such a conductive polymer as a cathode or anode material. This battery consists of only sulfur and carbon both of which are elements of low specific gravity, and was expected as a large capacity battery.
- the conductive polymer has a property that charged radicals generated by oxidation or reduction of the conductive polymer are delocalized over a wide region of ⁇ -electron conjugated system and the charged radicals interact each other to cause electrostatic repulsion or elimination of the radicals.
- This property restricts the generation of charged radicals, namely the concentration of doping, and thus limits the capacity of a battery.
- a battery using polyaniline as a cathode has a doping ratio of 50% or less
- a battery using polyacetylene as a cathode has a doping ratio of 7%.
- the battery using a conductive polymer as an electrode material achieves some effects in weight reduction, however, a battery having a high energy density has not been obtained.
- Patent Document 4 Japanese Patent Application Laid-Open No. 2002-1510844 discloses an organic radical compound such as a nitroxide radical compound, an aryloxy radical compound, and a polymer having a specific amino triazine structure as an active material; and a battery using the organic radical compound as a positive or anode material.
- Patent Document 5 Japanese Patent Application Laid-Open No. 2002-304996 discloses a storage device that uses particularly a compound having a cyclic nitroxide structure among nitroxide compounds as an electrode active material.
- Patent Document 6 Japanese Patent Application Laid-Open No. 2002-313344 discloses a battery using a nitroxyl radical polymer, which is a polyradical compound, as a binder for an electrode.
- Non-Patent Document 1 W. Reppe et al, Annalen der Chemie (Ann.), vol. 601 (1956), p. 81-111
- Non-Patent Document 2 Warren H. et al, Journal of The American Chemical Society, vol.
- Non-Patent Document 3 Yasutaka Ishii et al, Journal of The American Chemical Society, vol. 124 (2002), p. 1590-1591; and Patent Document 7: Japanese Patent Application Laid-Open No. 2003-73321).
- Patent Document 1 U.S. Pat. No. 4,833,048
- Patent Document 2 Japanese Patent No. 2,715,778
- Patent Document 3 U.S. Pat. No. 4,442,187
- Patent Document 4 Japanese Patent Application Laid-Open No. 2002-151084
- Patent Document 5 Japanese Patent Application Laid-Open No. 2002-304996
- Patent Document 6 Japanese Patent Application Laid-Open No. 2002-313344
- Patent Document 7 Japanese Patent Application Laid-Open No. 2003-73321
- Non-Patent Document 1 W. Reppe et al, Annalen der Chemie (Ann.), vol. 601, p. 81-111 (1956)
- Non-Patent Document 2 Warren H. et al, Journal of The American Chemical Society, vol. 79, p. 2828-2833 (1957)
- Non-Patent Document 3 Yasutaka Ishii et al, Journal of The American Chemical Society, vol. 124, p. 1590-1591 (2002)
- An object of the present invention is to provide an electrode active material that has a high capacity density and from which a large current can be extracted; and a battery that has a high energy density and produces a large output.
- another object of the present invention is to provide a method for manufacturing a polyradical compound that can be used as an electrode active material.
- the inventors of the present invention have thoroughly examined. As a result, the inventors have found that the above-mentioned problems can be solved when a specific organic compound that have not been used as electrode active materials, that is, a polyradical compound having a partial structure represented by the following general formula (2) in a molecule, is used as an electrode active material.
- a specific organic compound that have not been used as electrode active materials that is, a polyradical compound having a partial structure represented by the following general formula (2) in a molecule
- the present invention provides a novel battery that has a high energy density and produces a large output (more specifically that can discharge a large current) by using a polyradical compound having a partial structure represented by the following general formula (2) in a molecule as an electrode active material and by utilizing an oxidation-reduction reaction of the partial structure.
- the present invention is an electrode active material, comprising a polyradical compound having a partial structure represented by the following general formula (2): wherein, in the general formula (2), R 1 to R 3 independently represent a hydrogen atom or a methyl group; and R 4 to R 7 independently represent an alkyl group having 1 to 3 carbon atoms.
- the polyradical compound having a partial structure represented by the general formula (2) performs an oxidation-reduction reaction shown in the following scheme (I) or (II) in the course of charging and discharging.
- the oxidation-reduction reaction of the scheme (I) in the case of using the polyradical compound having a partial structure represented by the general formula (2) as a cathode, the structure in the state of (A) changes to the state of (B) with emitting electrons by charging. By discharging, the structure in the state of (B) changes to the state of (A) with accepting electrons.
- the structure in the state of (C) changes to the state of (A) with emitting electrons by charging.
- the structure in the state of (A) changes to the state of (C) with accepting electrons.
- Charging and discharging are preferably conducted by using the oxidation-reduction of the scheme (I) in view of stability of the oxidation-reduction reaction of the polymer.
- an electrode active material in a battery is oxidized or reduced by charging and discharging, and thus the electrode active material is in either starting state or reduced state.
- the electrode active material has the structure represented by the general formula (2) in either charged state or discharged state.
- the present invention has been accomplished by finding that the polyradical compound having a partial structure represented by the general formula (2) is excellent as an electrode active material. This is because the polyradical compound having a partial structure represented by the general formula (2) almost does not cause side reactions and performs an oxidation-reduction reaction that is reversible with almost 100% ratio stability. Thus, a battery that uses the polyradical compound having a partial structure represented by the general formula (2) as an electrode active material can charge and discharge stably, and such a battery has an excellent cycle property. In addition, a battery that uses the polyradical compound having a partial structure represented by the general formula (2) as an electrode active material has a more excellent high-output property than a conventional lithium ion battery.
- the polyradical compound having a partial structure represented by the general formula (2) has a substituent group that exhibits a high electrode reaction rate, thereby discharging a large current at one time. Furthermore, the polyradical compound having a partial structure represented by the general formula (2) can be consisted of small mass elements of carbon, nitrogen, hydrogen, and oxygen. Therefore, the weight of an electrode active material can be reduced, and an electrode manufactured with the electrode active material has a high capacity density per unit weight. As a result, manufacturing a battery with the electrode active material provides a battery that has a high energy density per weight.
- a battery according to the present invention is preferably a lithium battery, particularly preferably a lithium secondary battery, which has a carbon anode into which metallic lithium or lithium ions can be inserted and eliminated.
- the polyradical compound that is used in the present invention as an electrode active material can be preferably manufactured according to the following methods. That is, the present invention is a method for manufacturing a polyradical compound, polymerizing at least a radical substituted vinyl ether compound represented by the following general formula (1) in the presence of a cationic polymerization catalyst to obtain a polyradical compound having a partial structure represented by the following general formula (2), wherein, in the general formula (1), R 1 to R 3 independently represent a hydrogen atom or a methyl group; and R 4 to R 7 independently represent an alkyl group having 1 to 3 carbon atoms, wherein, in the general formula (2), R 1 to R 3 independently represent a hydrogen atom or a methyl group; and R 4 to R 7 independently represent an alkyl group having 1 to 3 carbon atoms.
- the present invention has proposed an electrode active material containing a polyradical compound having a partial structure represented by the general formula (2) and a novel battery using the electrode active material.
- the present invention provides an electrode active material that has a high capacity density and from which a large current can be extracted; and a battery that has a high energy density and produces a large output. Therefore, the present invention makes it possible to manufacture a battery composed of an electrode active material that contains light and safe elements and does not contain heavy metals.
- the present invention also realizes a battery that has a large capacity (per weight), exhibits excellent stability in charging and discharging cycles, and further produces a large output.
- the present invention provides a method for manufacturing the polyradical compound.
- FIG. 1 is a schematic view showing an embodiment of the structure of a battery according to the present invention.
- FIG. 1 shows the structure of an embodiment of a battery according to the present invention.
- the battery shown in FIG. 1 has the structure in which a cathode 6 is laminated, via a separator 5 containing an electrolyte, with an anode 4 which is placed on an anode collector 3 to oppose each other; and a cathode collector 7 is laminated on the cathode 6 .
- This structure is packed with an aluminum exterior housing 1 on the anode side and an aluminum exterior housing 1 on the cathode side. Between the aluminum exterior housings is placed an insulating gasket 2 made of an insulating material such as plastic resins for the purpose of avoiding electrical contact between the aluminum exterior housings.
- such an electrolyte instead of the separator 5 may lie between the electrodes may be laminated via such an electrolyte instead of the separator 5 .
- an electrode active material that is used for the anode 4 or the cathode 6 or both electrodes is characterized by containing a polyradical compound having a partial structure represented by the general formula (2) that will be described later.
- the battery according to the present invention is preferably a lithium battery or particularly a lithium secondary battery using the electrode active material as a cathode active material in view of battery capacity.
- An electrode active material for an electrode in the present invention denotes a material that directly contributes to an electrode reaction such as a charging reaction and a discharging reaction, and plays a key role in a battery system.
- an electrode active material that contains a polyradical compound having a partial structure represented by the general formula (2) is used as an electrode active material, wherein, in the general formula (2), R 1 to R 3 independently represent a hydrogen atom or a methyl group; and R 4 to R 7 independently represent an alkyl group having 1 to 3 carbon atoms.
- R 4 to R 7 independently represent a methyl group or an ethyl group.
- the electrode active material may be fixed to an electrode, or dissolved or dispersed in an electrolyte.
- the electrode active material in the case of using the electrode active material being fixed to an electrode, for the purpose of preventing decrease of capacity by dissolution of the electrode active material to an electrolyte solution, the electrode active material is preferably solid and insoluble or has a low degree of solubility in the electrolyte solution. In this case, the electrode active material may swell as long as the material is insoluble or has a low degree of solubility in the electrolyte solution.
- the electrode active material has a high degree of solubility in the electrolyte solution, elution of the material from the electrode to the electrolyte solution may decrease capacity through charging and discharging cycles.
- the polyradical compound having a partial structure represented by the general formula (2) preferably has a number average molecular weight of 500 or higher, more preferably 5000 or higher, still more preferably 10,000 or higher, particularly preferably 40,000 or higher and most preferably 70,000 or higher. This is because the polyradical compound having a number average molecular weight of 500 or higher is less prone to dissolve in an electrolyte solution for batteries, and the polyradical compound having a number average molecular weight of 5000 or higher is almost insoluble in an electrolyte solution for batteries.
- the polyradical compound may have either a linear, branched or network structure.
- the number average molecular weight there is not particularly the upper limit of the number average molecular weight, but in view of convenience for synthesis, it is suitable to use a polyradical compound preferably having a number average molecular weight of 5,000,000 or less, more preferably 1,000,000 or less, still more preferably 200,000 or less, and-particularly preferably 100,000 or less.
- the polyradical compound may have a crosslinked structure obtained by using a crosslinker.
- the number average molecular weight denotes a value obtained by using GPC in which dimethyl formamide (DMF) is used as an eluant to measure soluble matter in DMF of the sample.
- the polyradical compound having a partial structure represented by the general formula (2) preferably has a glass transition temperature of 80° C. or higher, more preferably 100° C. or higher, and still more preferably 130° C. or higher, in view of convenience for electrode manufacturing processes, conditions for use, and the like.
- the glass transition temperature is preferably 250° C. or less, more preferably 200° C. or less, still more preferably 180° C. or less, and particularly preferably 150° C. or less.
- the polymer As the polymer, a homopolymer having only a partial structure represented by the general formula (2) may be used, or a copolymer further having another partial structure may be used. In view of convenience for synthesis, the homopolymer is preferably used. In the case of using the copolymer, the copolymer preferably contains 70 to 99 mol % of the partial structure represented by the general formula (2) to the total of the polymer, and more preferably 80 to 95 mol %.
- polyradical compound having a partial structure represented by the general formula (2) examples include polyradical compounds having partial structures represented by the following general formulae (4) to (13):
- the polyradical compound having a partial structure represented by the above formula (4) can be synthesized, for example, by the route shown in the following synthetic scheme (14). More specifically, the polyradical compound can be synthesized by a method of polymerizing a radical substituted vinyl ether compound in the presence of a cationic polymerization catalyst to conduct cationic polymerization. The polyradical compound can be synthesized by polymerizing 2,2,6,6-tetramethyl piperidine-4-vinyloxy-1-oxyl, using, for example, boron trifluoride diethyl ether complex as the cationic polymerization catalyst. Furthermore, the polyradical compounds represented by the formulae (5) to (13) can be synthesized by similar methods.
- cationic polymerization catalyst that is used for the polymerization
- catalysts that are generally used for cationic polymerization may be used other than those mentioned above, but a Lewis acid is preferably used. It is also possible to use a protonic acid as the cationic polymerization catalyst, but in that case, the polymerization is preferably conducted under the condition where the protonic acid does not cause a side reaction with a monomer containing a radical.
- the Lewis acid aluminum chloride, tin tetrachloride, iron chloride, and the like may be used.
- a transition-metal compound such as tin tetrachloride, titanium tetrachloride, titanium trichloride, vanadium tetrachloride, or vanadium oxide trichloride
- an organometallic compound having a typical metal such as triethyl aluminum, ethyl aluminum dichloride, triethyl oxonium, or hexafluoro borate.
- the target polyradical compound can be synthesized by properly changing synthetic scheme, materials to be used, reaction conditions, and the like, and combining known synthetic techniques.
- the polymerization is preferably conducted in an organic solvent.
- the polymerization is preferably conducted in a halogenated organic solvent.
- dichloromethane or chloroform is preferably used.
- a vinyl ether monomer that is used for synthesizing the polyradical compound can be synthesized by the following methods.
- the vinyl ether monomer can be synthesized by reacting acetylene with an corresponding alcohol at a high temperature (180 to 200° C.) under increased pressure (about 20 to 50 atm) in the presence of catalytic amounts of potassium hydroxide and sodium hydroxide.
- a high temperature 180 to 200° C.
- pressure about 20 to 50 atm
- the vinyl ether monomer can be synthesized by heating and refluxing an corresponding alcohol and alkyl vinyl ether in the presence of mercuric acetate catalyst. Furthermore, as disclosed in Ishii Yasutaka et al, Journal of The American Chemical. Society, vol. 124 (2002), p. 1590-1591; and Japanese Patent Application Laid-Open No. 2003-73321, the vinyl ether monomer can also be synthesized by heating and refluxing an corresponding alcohol and vinyl acetate in the presence of iridium catalyst.
- the polyradical compound having a partial structure represented by the general formula (2) may be used alone or in combination of two or more of the polyradical compounds. Furthermore, the polyradical compound may be used in combination with another electrode active material. In this case, the electrode active material preferably contains 10 to 90 wt % of the polyradical compound having a partial structure represented by the general formula (2), and more preferably 20 to 80 wt %.
- examples which can be combined as another electrode active material may include metallic oxides, disulfide compounds, other stable radical compounds, and conductive polymers.
- the metallic oxides may include: lithium manganates such as LiMnO 2 and Li x Mn 2 O 4 (0 ⁇ x ⁇ 2), lithium manganates having Spinel structure, MnO 2 , LiCoO 2 , LiNiO 2 , Li y V 2 O 5 (0 ⁇ y ⁇ 2), olivine materials LiFePO 4 , and materials in which a part of Mns in Spinel structure are substituted with another transition metal such as LiNi 0.5 Mn 1.5 O 4 , LiCr 0.5 Mn1.5O 4 , LiCo 0.5 Mn 1.5 O 4 , LiCoMnO 4 , LiNi 0.5 Mn 0.5 O 2 , LiNi 0.33 Mn 0.33 Co 0.33 O 2 , LiNi 0.8 Co 0.2 O 2
- Examples of the disulfide compounds may include: dithioglycol, 2,5-dimercapto-1,3,4-thiadiazole, and S-triazine-2,4,6-trithiol.
- Examples of the other stable radical compounds may include poly(2,2,6,6-tetramethyl piperidinoxyl-4-yl methacrylate).
- Examples of the conductive polymers may include: polyacetylene, polyphenylene, polyaniline, and polypyrrole.
- lithium manganates or LiCoO 2 is particularly preferably combined. In the present invention, these other electrode active materials may be used alone or in combination of two or more of the materials.
- examples which can be combined as another electrode active material may include graphite, amorphous carbon, metallic lithium, lithium alloy, lithium ion absorbed carbon, metallic sodium, and conductive polymers.
- other stable radical compounds may also be used.
- the other stable radical compounds may include poly(2,2,6,6-tetramethyl piperidinoxyl-4-yl methacrylate).
- the shapes of the above materials are not particularly limited.
- metallic lithium is not limited to have the shape of a thin film, and may be a bulk material, a compressed powder, a fiber, a flake, and the like.
- metallic lithium or graphite is particularly preferably combined.
- these other electrode active materials may be used alone or in combination of two or more of the materials.
- the battery according to the present invention uses the polyradical compound having a partial structure represented by the general formula (2) as an electrode active material in an electrode reaction either in a cathode or an anode, or in electrode reactions in both of a cathode and an anode.
- the polyradical compound is used as an electrode active material in an electrode reaction in one electrode, as an electrode active material in the other electrode, a conventionally known electrode active material such as the above materials can be used.
- These electrode active materials may be used alone or in combination of two or more of the materials. And at least one of these electrode active materials and the polyradical compound having a partial structure represented by the general formula (2) may be combined and used.
- the polyradical compound having a partial structure represented by the general formula (2) may also be used alone.
- the polyradical compound having a partial structure represented by the general formula (2) directly contributes to an electrode reaction either in a cathode or an anode.
- an electrode in which the polyradical compound is used as an electrode active material is not limited to a cathode or an anode.
- the polyradical compound having a partial structure represented by the general formula (2) in view of energy density, it is particularly preferable to use the polyradical compound having a partial structure represented by the general formula (2) as a cathode active material.
- the cathode active material it is preferable to use the polyradical compound having a partial structure represented by the general formula (2) alone.
- the polyradical compound may be combined with another cathode active material and used.
- the other cathode active material is preferably lithium manganates or LiCoO 2 .
- metallic lithium or graphite is preferably used as the anode active material.
- a conductivity imparting agent (auxiliary conductive material) or an ionic conduction auxiliary material may be mixed with the polyradical compound.
- auxiliary conductive material may include: carbonaceous particulates such as graphite, carbon black, and acetylene black; carbon fibers such as Vapor Grown Carbon Fiber (VGCF) or carbon nanotube; and conductive polymers such as polyaniline, polypyrrole, polythiophene, polyacetylene, and polyacenes.
- the ionic conduction auxiliary material may include polymer gel electrolytes and polymer solid electrolytes.
- a carbon fiber is preferable mixed.
- Mixing a carbon fiber further increases the tensile strength of an electrode, which reduces the possibility that cracking occurs in the electrode or the electrode comes off.
- Vapor Grown Carbon Fiber is mixed.
- These materials may be used alone or in combination of two or more of the materials. Preferred ratio of the materials in an electrode is 10 to 80 wt %.
- binders may be used.
- the binders may include resin binders such as polytetrafluoroethylene, polyvinylidene fluoride, vinylidene fluoride-hexafluoropropylene copolymer, vinylidene fluoride-tetrafluoroethylene copolymer, styrene butadiene copolymer rubber, polypropylene, polyethylene, polyimide, and various kinds of polyurethanes.
- resin binders may be used alone or in combination of two or more of the resin binders. Preferred ratio of the resin binders in an electrode is 5 to 30 wt %.
- catalysts that promote an oxidation reduction reaction may be used.
- the catalysts may include: conductive polymers such as polyaniline, polypyrrole, polythiophene, polyacetylene, polyacenes; basic compounds such as pyridine derivatives, pyrrolidone derivatives, benzimidazole derivatives, benzthiazole derivatives, and acridine derivatives; and metallic ion complexes.
- conductive polymers such as polyaniline, polypyrrole, polythiophene, polyacetylene, polyacenes
- basic compounds such as pyridine derivatives, pyrrolidone derivatives, benzimidazole derivatives, benzthiazole derivatives, and acridine derivatives
- metallic ion complexes metallic ion complexes.
- anode collector and a cathode collector there may be used a collector having a shape of foil, metallic flat plate, mesh, or the like that is made of nickel, aluminum, copper, gold, silver, aluminum alloy, stainless, carbon or the like.
- the collector may have catalytic effect, or an electrode active material and the collector may be chemically bonded.
- a separator such as porous films made of polyethylene, polypropylene, or the like, or a nonwoven fabric.
- the electrolyte transports charged carriers between an anode and a cathode, and generally it is preferable that the electrolyte has an ionic conductivity of 10 ⁇ 5 to 10 ⁇ 1 S/cm at 20° C.
- the electrolyte for example, there may be used an electrolyte solution in which an electrolyte salt is dissolved in a solvent.
- electrolyte salt there may be used a conventionally known material such as LiPF 6 , LiClO 4 , LiBF 4 , LiCF 3 SO 3 , Li(CF 3 SO 2 ) 2 N, Li(C 2 F 5 SO 2 ) 2 N, Li(CF 3 SO 2 ) 3 C, or Li(C 2 F 5 SO 2 ) 3 C.
- electrolyte salts may be used alone or in combination of two or more of the electrolyte salts.
- an organic solvent such as ethylene carbonate, propylene carbonate, dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate, ⁇ -butyrolactone, tetrahydrofuran, dioxolane, sulfolane, dimethylformamide, dimethylacetamide, or N-methyl-2-pyrrolidone.
- organic solvent such as ethylene carbonate, propylene carbonate, dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate, ⁇ -butyrolactone, tetrahydrofuran, dioxolane, sulfolane, dimethylformamide, dimethylacetamide, or N-methyl-2-pyrrolidone.
- the electrolyte may be used a solid electrolyte.
- polymers used for the solid electrolyte may include: vinylidene fluoride polymers such as polyvinylidene fluoride, vinylidene fluoride-hexafluoropropylene copolymer, vinylidene fluoride-ethylene copolymer, vinylidene fluoride-monofluoroethylene copolymer, vinylidene fluoride-trifluoroethylene copolymer, vinylidene fluoride-tetrafluoroethylene copolymer, and vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene terpolymer; acrylonitrile polymers such as acrylonitrile-methyl methacrylate copolymer, acrylonitrile-methyl acrylate copolymer, acrylonitrile-ethyl methacrylate copolymer, acrylonitrile-ethyl
- battery form is not particularly limited, and conventionally known form may be used.
- the battery forms may include a form in which an electrode stack and a form in which a rolled electrode is sealed with a metallic case, a resin case, or a laminated film made of a metallic foil such as an aluminum foil and a synthetic resin film, which is manufactured in the form of a cylinder, a rectangle, a coin, a sheet, or the like.
- the present invention is not limited thereto.
- a method for manufacturing a battery is not particularly limited, and a properly selected method may be used depending on materials.
- the method may be used, in which a solvent is added to an electrode active material, a conductivity imparting agent, and the like, to make a slurry; the slurry is applied to an electrode collector, and the solvent is evaporated by heating or in a room temperature to manufacture an electrode; furthermore, the electrodes are opposed each other via a separator by laminating or rolling the electrodes which are packed with exterior housings; an electrolyte solution is poured thereto; and the battery is sealed.
- Examples of the solvents to make the slurry may include: ether solvents such as tetrahydrofuran, diethyl ether, and ethylene glycol dimethyl ether; amine solvents such as N,N-dimethylformamide, and N-methyl pyrrolidone; aromatic hydrocarbon solvents such as benzene, toluene, and xylene; aliphatic hydrocarbon solvents such as hexane and heptane; halogenated hydrocarbon solvents such as chloroform, dichloromethane, dichloroethane, trichloroethane, and carbon tetrachloride; alkyl ketone solvents such as acetone and methyl ethyl ketone; alcohol solvents such as methanol, ethanol, and isopropyl alcohol; and dimethylsulfoxide.
- ether solvents such as tetrahydrofuran, diethyl ether, and ethylene glycol dimethyl ether
- an electrode active material, a conductivity imparting agent, and the like are subjected to dry kneading and processed into a thin film and the thin film is laminated on an electrode collector.
- a method for manufacturing an electrode particularly in the case of employing a method in which a solvent is added to an organic electrode active material, a conductivity imparting agent, and the like, to make a slurry; the slurry is applied to an electrode collector, and the solvent is evaporated by heating or in a room temperature to manufacture an electrode, the electrode tends to come off, become cracked or the like.
- an electrode preferably having a thickness of from 80 ⁇ m to 500 ⁇ m by using the polyradical compound having a partial structure represented by the general formula (2) according to the present invention has an advantages that the electrode is less prone to come off, become cracked or the like, and an uniform electrode is manufactured.
- the polymer that is changed into the polyradical compound represented by the general formula (2) by an electrode reaction may include: lithium salts or sodium salts composed of an anion obtained by reducing the polyradical compound represented by the general formula (2) and an electrolyte cation such as lithium ion or sodium ion; and salts composed of a cation obtained by oxidizing the compound represented by the general formula (2) and an electrolyte anion such as PF 6 ⁇ or BF 4 ⁇ .
- other manufacturing conditions such as taking out a lead from the electrode and packing may be conducted according to a conventionally known method as a method for manufacturing a battery.
- a polyradical compound having a partial structure represented by the following formula (14) was synthesized by the following synthetic scheme (15).
- the spin density of the polyradical compound (a-1) measured with ESR spectrum was 3.05 ⁇ 10 21 spin/g. This value is in close agreement with the spin concentration based on the assumption that all radicals in the polymer are not deactivated by polymerization and exist as radicals. And the glass transition temperature of the polyradical compound (a-1) was measured to be 132° C.
- a polyradical compound having a partial structure represented by the above formula (14) was synthesized by the following synthetic scheme (16).
- a polyradical compound having a partial structure represented by the above formula (14) was synthesized by the following synthetic scheme (17).
- a polyradical compound having a partial structure represented by the above formula (14) was synthesized by the following synthetic scheme (18).
- a polyradical compound having a partial structure represented by the following formula (19) was synthesized by the following synthetic scheme (20).
- electrolyte solution a mixed solution of ethylene carbonate/diethyl carbonate (in a mixed volume ratio of 3:7) containing 1.0 mol/L of LiPF 6 electrolyte salt.
- the electrolyte solution-impregnated electrode was placed on a cathode collector, and thereon was laminated a polypropylene porous film separator which was impregnated with the electrolyte solution. Furthermore, a lithium-clad copper foil to be an anode was laminated.
- the electrode was stamped into the disk shape having a diameter of 12 mm to form an electrode for a coin battery. Incidentally, the electrode had a weight 10 of 15.6 mg.
- electrolyte solution a mixed solution of ethylene carbonate/diethyl carbonate (in a mixed volume ratio of 3:7) containing 1.0 mol/L of LiPF 6 electrolyte salt.
- the electrolyte solution-impregnated electrode was placed on a cathode collector (an aluminum foil), and thereon was a laminated polypropylene porous film separator which was impregnated with the electrolyte solution by a similar way. Furthermore, a copper foil that had a graphite layer on one side to be an anode was laminated.
- a coin battery was manufactured as with Example 2 except that the polyradical compound (a-2) synthesized in Synthetic Example 2 was used instead of the polyradical compound (a-1). No coming off, cracks or the like was observed in the formed electrode, and the surface of the electrode was uniform.
- the cathode of the coin battery had a weight of 13.2 mg.
- a coin battery was manufactured as with Example 2 except that the polyradical compound (a-3) synthesized in Synthetic Example 3 was used instead of the polyradical compound (a-1). No coming off, cracks or the like was observed in the formed electrode, and the surface of the electrode was uniform.
- the cathode of the coin battery had a weight of 11.7 mg.
- a coin battery was manufactured as with Example 2 except that the polyradical compound (a-4) synthesized in Synthetic Example 4 was used instead of the polyradical compound (a-1). No coming off, cracks or the like was observed in the formed electrode, and the surface of the electrode was uniform.
- the cathode of the coin battery had a weight of 10.7 mg.
- a coin battery was manufactured as with Example 2 except that the polyradical compound (b-1) synthesized in Synthetic Example 5 was used instead of the polyradical compound (a-1). No coming off, cracks or the like was observed in the formed electrode, and the surface of the electrode was uniform.
- the cathode of the coin battery had a weight of 13.2 mg.
- a coin battery was manufactured by the method as with Example 1 except that the used amount of graphite powder was increased to 900 mg instead of using the polyradical compound (a-1).
- a coin battery was manufactured by the method as with Example 1 except that LiCoO 2 was used instead of the polyradical compound (a-1).
- a coin battery was manufactured by the method as with Example 1 except that 2,2,6,6-tetramethyl piperidinoxyl (TEMPO) was used instead of the polyradical compound (a-1).
- TEMPO 2,2,6,6-tetramethyl piperidinoxyl
- the discharged capacity per the electrode active material was 35.2 mAh/g.
- An electrode was manufactured by the method as with Example 2—except that 1.0 g of poly(2,2,6,6-tetramethyl piperidinoxyl-4-yl methacrylate) (Mn: 127,000, Mw/Mn: 3.0) was used instead of the polyradical compound (a-1).
- Poly(2,2,6,6-tetramethyl piperidinoxyl-4-yl methacrylate) used here had a glass transition temperature of 153° C.
- the manufactured cathode layer had a thickness of 130 ⁇ m. Many coming offs and fine cracks were observed in the surface of the electrode.
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- Engineering & Computer Science (AREA)
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US20100255372A1 (en) * | 2006-06-06 | 2010-10-07 | Nec Corporation | Process for producing polyradical compound and battery cell |
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Also Published As
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CN101069307A (zh) | 2007-11-07 |
US8242213B2 (en) | 2012-08-14 |
CN100499226C (zh) | 2009-06-10 |
JP5239160B2 (ja) | 2013-07-17 |
JPWO2006061948A1 (ja) | 2008-06-05 |
US20110172378A1 (en) | 2011-07-14 |
WO2006061948A1 (ja) | 2006-06-15 |
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