TWI633125B - 具有半結晶嵌段之嵌段共聚物及得自其之組合物與由其製造之物件 - Google Patents
具有半結晶嵌段之嵌段共聚物及得自其之組合物與由其製造之物件 Download PDFInfo
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- TWI633125B TWI633125B TW106109663A TW106109663A TWI633125B TW I633125 B TWI633125 B TW I633125B TW 106109663 A TW106109663 A TW 106109663A TW 106109663 A TW106109663 A TW 106109663A TW I633125 B TWI633125 B TW I633125B
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- block
- block copolymer
- mol
- selectively hydrogenated
- semi
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
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| US201662312743P | 2016-03-24 | 2016-03-24 | |
| US62/312,743 | 2016-03-24 |
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| TW201736419A TW201736419A (zh) | 2017-10-16 |
| TWI633125B true TWI633125B (zh) | 2018-08-21 |
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| EP (1) | EP3436490B1 (enExample) |
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| TW (1) | TWI633125B (enExample) |
| WO (1) | WO2017165521A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019183302A1 (en) * | 2018-03-23 | 2019-09-26 | Kraton Polymers Llc | Ultrahigh melt flow styrenic block copolymers |
| US11279821B2 (en) | 2018-03-23 | 2022-03-22 | Kraton Polymers Llc | Ultrahigh melt flow styrenic block copolymers |
| JP7232822B2 (ja) * | 2018-04-13 | 2023-03-03 | 株式会社クラレ | 多層フィルムおよびそれを備える成形体 |
| JP7264672B2 (ja) * | 2019-03-08 | 2023-04-25 | 株式会社Eneosマテリアル | エラストマー |
| CN114786742B (zh) * | 2019-10-14 | 2025-08-26 | 英力士苯领集团股份公司 | 适于医疗器械的苯乙烯丁二烯嵌段共聚物组合物 |
| EP3819315B1 (en) | 2019-11-08 | 2023-01-18 | TSRC Corporation | Polymer composition and pressure sensitive adhesives or films made therefrom |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62112640A (ja) * | 1985-11-09 | 1987-05-23 | Toyo Tire & Rubber Co Ltd | タイヤトレツド用ゴム組成物 |
| WO2004003027A1 (ja) * | 2002-06-27 | 2004-01-08 | Asahi Kasei Chemicals Corporation | 水添共重合体及びその組成物 |
Family Cites Families (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA716645A (en) | 1965-08-24 | Shell Oil Company | Block polymers and process for preparing them | |
| GB1044068A (en) * | 1962-10-24 | 1966-09-28 | Union Carbide Corp | Production of coated biaxially oriented linear highly crystalline polyolefin films |
| US3595942A (en) | 1968-12-24 | 1971-07-27 | Shell Oil Co | Partially hydrogenated block copolymers |
| USRE27145E (en) | 1969-05-20 | 1971-06-22 | Side-chain | |
| US3634549A (en) | 1969-08-04 | 1972-01-11 | Shell Oil Co | Conjugated diene block copolymers having a random copolymer elastomeric block and their hydrogenated counterparts |
| US3670054A (en) | 1969-10-29 | 1972-06-13 | Shell Oil Co | Block copolymers having reduced solvent sensitivity |
| US3700633A (en) | 1971-05-05 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
| US4039593A (en) | 1973-05-18 | 1977-08-02 | Lithium Corporation Of America | Preparation of hydroxy-terminated conjugated diene polymers |
| US4089913A (en) | 1974-01-10 | 1978-05-16 | Sumitomo Chemical Company, Limited | Process for producing transparent block copolymer resin |
| US4122134A (en) | 1974-02-13 | 1978-10-24 | Sumitomo Chemical Company, Limited | Method for producing transparent block copolymer resin |
| US3936365A (en) * | 1974-05-28 | 1976-02-03 | The Dow Chemical Company | Radiation crosslinked block copolymer blends with improved impact resistance |
| US3985830B1 (en) | 1974-07-15 | 1998-03-03 | Univ Akron | Star polymers and process for the preparation thereof |
| US4107236A (en) | 1976-02-09 | 1978-08-15 | Phillips Petroleum Company | Hydrogenated block copolymers containing a block derived from low vinyl polybutadiene and a block derived from medium vinyl polybutadiene |
| US4237245A (en) | 1979-08-20 | 1980-12-02 | The Firestone Tire & Rubber Company | Hydrogenated block copolymers of butadiene containing a block of 1,4 and a block of 1,2-microstructure |
| US4252914A (en) | 1979-08-20 | 1981-02-24 | The Firestone Tire & Rubber Company | Thermoplastic elastomer blends of hydrogenated polybutadiene block copolymers with alpha-olefin polymers and copolymers |
| JPS5792014A (en) | 1980-11-27 | 1982-06-08 | Sumitomo Rubber Ind Ltd | Conjugated diene block polymer |
| US4391949A (en) | 1981-11-12 | 1983-07-05 | Shell Oil Company | Asymmetric block copolymers and corresponding adhesive formulations |
| US4444953A (en) | 1981-11-12 | 1984-04-24 | Shell Oil Company | Assymetric block copolymers and corresponding adhesive formulations |
| JPS59140240A (ja) | 1983-01-31 | 1984-08-11 | Japan Synthetic Rubber Co Ltd | ゴム組成物 |
| US4578429A (en) | 1984-08-31 | 1986-03-25 | Shell Oil Company | Selectively hydrogenated block copolymers modified with acid compounds or derivatives |
| US5371141A (en) | 1985-07-31 | 1994-12-06 | Shell Oil Company | High impact resistant blends of thermoplastic polyamides and modified block copolymers |
| JPS6241213A (ja) | 1985-08-16 | 1987-02-23 | シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ | 変性ブロツクコポリマ−、該コポリマ−を含有する耐衝撃性組成物、及び該コポリマ−の製造法 |
| US4882384A (en) | 1988-02-01 | 1989-11-21 | Shell Oil Company | Modified block copolymers |
| US4970265A (en) | 1989-03-27 | 1990-11-13 | Shell Oil Company | Functionalized polymers and process for modifying unsaturated polymers |
| US5191024A (en) | 1989-05-19 | 1993-03-02 | Japan Synthetic Rubber Co., Ltd. | Hydrogenated diene block copolymer and composition comprising the same |
| US5216074A (en) | 1989-07-17 | 1993-06-01 | Japan Synthetic Rubber Co., Ltd. | Thermoplastic elastomer composition |
| US5276100A (en) | 1990-01-16 | 1994-01-04 | Mobil Oil Corporation | Solid elastomeric block copolymers |
| US5206300A (en) | 1990-03-30 | 1993-04-27 | Shell Oil Company | Functionalized elastomeric polymers |
| KR0185671B1 (ko) | 1990-08-23 | 1999-05-15 | 요하네스 아르트 반 주트펜 | 블록 공중합체의 용융 금속화 방법 |
| US5132355A (en) | 1990-11-26 | 1992-07-21 | Boris Nahlovsky | Gels of polyethylene block copolymers and liquid hydrocarbons |
| US5665822A (en) | 1991-10-07 | 1997-09-09 | Landec Corporation | Thermoplastic Elastomers |
| US5516831A (en) * | 1991-01-30 | 1996-05-14 | Shell Oil Company | Selectively sulfonated block copolymers/extender oils |
| JPH0532836A (ja) * | 1991-07-29 | 1993-02-09 | Japan Synthetic Rubber Co Ltd | シート、フイルム用重合体組成物 |
| US5395471A (en) * | 1991-10-15 | 1995-03-07 | The Dow Chemical Company | High drawdown extrusion process with greater resistance to draw resonance |
| JP2988080B2 (ja) * | 1991-11-13 | 1999-12-06 | ジェイエスアール株式会社 | 熱可塑性重合体組成物 |
| US5202387A (en) | 1992-05-08 | 1993-04-13 | The Goodyear Tire & Rubber Company | Elastomer with outstanding characteristics for use in making tire tread compounds |
| JP3349772B2 (ja) * | 1993-06-25 | 2002-11-25 | ダイセル化学工業株式会社 | エポキシ変性水添ブロック重合体およびその組成物 |
| US5596041A (en) * | 1994-04-04 | 1997-01-21 | Japan Synthetic Rubber Co., Ltd. | Hydrogenated block copolymer and hydrogenated block copolymer compositon |
| JP3282364B2 (ja) * | 1994-04-04 | 2002-05-13 | ジェイエスアール株式会社 | 水添ブロック共重合体 |
| KR960008405A (ko) * | 1994-08-10 | 1996-03-22 | 알베르투스 빌헬무스·요아네스 째스트라텐 | 광경화가능한 탄성중합체 조성물로부터의 플렉서 인쇄판 |
| WO1996018660A1 (en) * | 1994-12-12 | 1996-06-20 | The Dow Chemical Company | Hydrogenation of unsaturated polymers using divalent non-aromatic anionic dienyl-containing group iv metal catalysts |
| US5885908A (en) | 1996-10-04 | 1999-03-23 | Minnesota Mining And Manufacturing Co. | Anisotropic elastic films |
| US6100334A (en) * | 1999-01-05 | 2000-08-08 | Advanced Elastomer Systems, L.P. | Thermoplastic vulcanizates from a cyclic olefin rubber, a polyolefin, and a compatiblizer |
| JP3949110B2 (ja) | 2001-10-23 | 2007-07-25 | 旭化成ケミカルズ株式会社 | 水添共重合体 |
| JP4090998B2 (ja) | 2002-01-31 | 2008-05-28 | クレイトン・ポリマーズ・リサーチ・ベー・ベー | 機械的特性と加工性が改善されたブロック共重合体組成物 |
| US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
| US6987142B2 (en) | 2002-02-07 | 2006-01-17 | Kraton Polymers U.S. Llc | Adhesives and sealants from controlled distribution block copolymers |
| US6703449B1 (en) | 2002-12-20 | 2004-03-09 | Kraton Polymers U.S. Llc | Block copolymers containing both polystyrene and low vinyl content polydiene hard blocks |
| JPWO2005003227A1 (ja) | 2003-07-04 | 2007-10-04 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
| JP4259295B2 (ja) * | 2003-09-29 | 2009-04-30 | Jsr株式会社 | 水添ジエン系共重合体、重合体組成物、及び該重合体組成物を用いた成形体 |
| US20050215724A1 (en) * | 2004-03-25 | 2005-09-29 | Kraton Polymers U.S. Llc | Thermoplastic gel compositions that can be converted into thermoset gel compositions by exposure to radiation |
| ATE389691T1 (de) | 2004-03-29 | 2008-04-15 | Pirelli & C Spa | Thermoplastisches elastomer enthaltend in verteilter form vulkanisierten kautschuk |
| JP4421547B2 (ja) | 2005-02-10 | 2010-02-24 | 住友ゴム工業株式会社 | ゴム組成物およびそれを用いたトレッドを有するタイヤ |
| EP1702957A1 (en) | 2005-03-14 | 2006-09-20 | Kraton Polymers Research B.V. | Hydrogenated block copolymer composition for overmoulding onto thermoplastics |
| EP1707596A1 (en) | 2005-03-14 | 2006-10-04 | Kraton Polymers Research B.V. | Hydrogenated block copolymer composition for overmoulding onto thermoplastics |
| CN101875824B (zh) * | 2005-03-29 | 2014-07-23 | 大科能树脂有限公司 | 抗静电树脂组合物、抗静电/压敏粘合性树脂组合物、压敏粘合膜和它们的制备方法 |
| TWI326691B (en) * | 2005-07-22 | 2010-07-01 | Kraton Polymers Res Bv | Sulfonated block copolymers, method for making same, and various uses for such block copolymers |
| US7576148B2 (en) | 2005-11-09 | 2009-08-18 | Kraton Polymers U.S. Llc | Blown asphalt compositions |
| US7582702B2 (en) * | 2006-03-24 | 2009-09-01 | Kraton Polymers U.S. Llc | Block copolymer compositons |
| JP4984759B2 (ja) * | 2006-09-05 | 2012-07-25 | 富士通セミコンダクター株式会社 | 半導体記憶装置 |
| JP5058764B2 (ja) * | 2007-10-23 | 2012-10-24 | 電気化学工業株式会社 | クロス共重合体の製造方法及び得られるクロス共重合体、その用途 |
| JP4733232B2 (ja) * | 2008-03-31 | 2011-07-27 | 旭化成イーマテリアルズ株式会社 | ポリオレフィン製微多孔膜、及び捲回物 |
| JP5620815B2 (ja) * | 2008-04-15 | 2014-11-05 | 電気化学工業株式会社 | 熱可塑性樹脂組成物 |
| GB201403454D0 (en) * | 2014-02-27 | 2014-04-16 | Cambridge Entpr Ltd | Heart valve |
| EP3320027B1 (en) * | 2015-06-12 | 2020-08-12 | Kraton Polymers U.S. LLC | Styrenic block copolymers as thermally-activated viscosifiers for oilfield applications |
-
2017
- 2017-03-22 CN CN201780018978.2A patent/CN108779221B/zh active Active
- 2017-03-22 EP EP17771060.5A patent/EP3436490B1/en active Active
- 2017-03-22 US US15/466,207 patent/US10633465B2/en active Active
- 2017-03-22 WO PCT/US2017/023595 patent/WO2017165521A1/en not_active Ceased
- 2017-03-22 JP JP2018549941A patent/JP2019510858A/ja active Pending
- 2017-03-23 TW TW106109663A patent/TWI633125B/zh active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62112640A (ja) * | 1985-11-09 | 1987-05-23 | Toyo Tire & Rubber Co Ltd | タイヤトレツド用ゴム組成物 |
| WO2004003027A1 (ja) * | 2002-06-27 | 2004-01-08 | Asahi Kasei Chemicals Corporation | 水添共重合体及びその組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2019510858A (ja) | 2019-04-18 |
| CN108779221A (zh) | 2018-11-09 |
| US10633465B2 (en) | 2020-04-28 |
| EP3436490C0 (en) | 2023-08-16 |
| US20170275392A1 (en) | 2017-09-28 |
| CN108779221B (zh) | 2022-07-05 |
| EP3436490A1 (en) | 2019-02-06 |
| TW201736419A (zh) | 2017-10-16 |
| WO2017165521A1 (en) | 2017-09-28 |
| EP3436490B1 (en) | 2023-08-16 |
| EP3436490A4 (en) | 2020-01-22 |
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