TWI455908B - 烯烴之製造方法 - Google Patents

烯烴之製造方法 Download PDF

Info

Publication number
TWI455908B
TWI455908B TW098140805A TW98140805A TWI455908B TW I455908 B TWI455908 B TW I455908B TW 098140805 A TW098140805 A TW 098140805A TW 98140805 A TW98140805 A TW 98140805A TW I455908 B TWI455908 B TW I455908B
Authority
TW
Taiwan
Prior art keywords
olefin
producing
ketone
hydrogen
solid acid
Prior art date
Application number
TW098140805A
Other languages
English (en)
Other versions
TW201022184A (en
Inventor
Tsuneyuki Ohkubo
Kenji Fujiwara
Terunori Fujita
Original Assignee
Mitsui Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2009204474A external-priority patent/JP5410888B2/ja
Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Publication of TW201022184A publication Critical patent/TW201022184A/zh
Application granted granted Critical
Publication of TWI455908B publication Critical patent/TWI455908B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7615—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/76—Iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Claims (5)

  1. 一種烯烴之製造方法，係在含Cu之氫化觸媒及固態酸物質的存在下，依反應溫度50~300℃範圍使酮與氫進行反應的烯烴之製造方法；其中，上述含Cu之氫化觸媒係進一步含有IIIA族及IIB族中之至少一個元素；上述固態酸物質係β-沸石。
  2. 如申請專利範圍第1項之烯烴之製造方法，其中，上述反應係在固定床反應器中實施，在該反應器的入口側填充含Cu氫化觸媒，並在出口側填充固態酸物質。
  3. 如申請專利範圍第1項之烯烴之製造方法，其中，上述酮係丙酮，上述烯烴係丙烯。
  4. 一種烯烴之製造方法，係在已填充含Cu之氫化觸媒與固態酸物質的反應器中，供應酮、氫、及水，並使酮與氫進行反應的烯烴之製造方法；其中，上述含Cu之氫化觸媒係進一步含有IIIA族及IIB族中之至少一個元素；上述固態酸物質係β-沸石；上述反應的反應溫度係50~300℃範圍內；上述水與酮的供應量莫耳比(水/酮)係0.01~1.0。
  5. 如申請專利範圍第1項之烯烴之製造方法，其中，上述酮係從源自植物的原料，利用能生成異丙醇與丙酮的異丙醇 生成細菌而獲得的丙酮；上述烯烴係丙烯。
TW098140805A 2008-12-01 2009-11-30 烯烴之製造方法 TWI455908B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008306735 2008-12-01
JP2009204474A JP5410888B2 (ja) 2009-09-04 2009-09-04 オレフィンの製造方法

Publications (2)

Publication Number Publication Date
TW201022184A TW201022184A (en) 2010-06-16
TWI455908B true TWI455908B (zh) 2014-10-11

Family

ID=42233154

Family Applications (1)

Application Number Title Priority Date Filing Date
TW098140805A TWI455908B (zh) 2008-12-01 2009-11-30 烯烴之製造方法

Country Status (11)

Country Link
US (1) US8680355B2 (zh)
EP (1) EP2364963B1 (zh)
KR (1) KR101325457B1 (zh)
CN (1) CN102227393B (zh)
BR (1) BRPI0922145B1 (zh)
CA (1) CA2744991C (zh)
RU (1) RU2469998C1 (zh)
SA (1) SA109300686B1 (zh)
SG (1) SG171867A1 (zh)
TW (1) TWI455908B (zh)
WO (1) WO2010064500A1 (zh)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8552239B2 (en) * 2009-03-16 2013-10-08 Mitsui Chemicals, Inc. Olefin production process
JP5580668B2 (ja) * 2010-06-17 2014-08-27 三井化学株式会社 オレフィンの製造方法
ES2668457T3 (es) * 2010-08-12 2018-05-18 Mitsui Chemicals, Inc. Bacteria productora de alcohol isopropílico que tiene una productividad mejorada por destrucción de GntR
JP5831925B2 (ja) * 2011-05-13 2015-12-09 国立大学法人東京工業大学 プロピレンの製造方法
JP5738439B2 (ja) 2012-01-20 2015-06-24 三井化学株式会社 オレフィンの製造方法
IT201700074911A1 (it) * 2017-07-04 2019-01-04 Versalis Spa Procedimento per la produzione di olefine da alcoli
CN110152716B (zh) * 2018-02-13 2021-10-08 中国科学院大连化学物理研究所 一种选择性脱去MOR12圆环Al的催化剂及一氧化碳加氢反应制乙烯的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6167493A (ja) * 1984-09-10 1986-04-07 Res Assoc Petroleum Alternat Dev<Rapad> イソプロピルアルコ−ルの製造法
JPH0341038A (ja) * 1989-07-10 1991-02-21 Mitsui Toatsu Chem Inc イソプロピルアルコールの製造方法
JPH0341035A (ja) * 1989-07-10 1991-02-21 Mitsui Toatsu Chem Inc プロピレンの製造方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE84378C (zh) *
DD84378A (zh) *
US4554260A (en) * 1984-07-13 1985-11-19 Exxon Research & Engineering Co. Two stage process for improving the catalyst life of zeolites in the synthesis of lower olefins from alcohols and their ether derivatives
US5017729A (en) * 1988-09-30 1991-05-21 Mitsui Petrochemical Industries, Ltd. Phenol preparation process and propylene recovery therefrom
JP2774607B2 (ja) 1988-09-30 1998-07-09 三井化学株式会社 フェノールの製造方法およびその製造時の副生アセトンからプロピレンを得る方法
CN1043956A (zh) 1988-12-31 1990-07-18 孙书敏 用植物废料生产有机溶剂的工艺方法
JPH0691171A (ja) 1992-09-10 1994-04-05 Tokuyama Soda Co Ltd ヘテロポリ酸塩担持触媒
JPH06167493A (ja) 1992-11-30 1994-06-14 Kyowa Medex Co Ltd 免疫測定方法
AU2001293057A1 (en) * 2000-09-25 2002-04-08 Exxonmobil Chemical Patents Inc Hydrogenation of cleavage effluents in phenol production
US6518475B2 (en) * 2001-02-16 2003-02-11 Exxonmobil Chemical Patents Inc. Process for making ethylene and propylene
US7238846B2 (en) * 2002-08-14 2007-07-03 Exxonmobil Chemical Patents Inc. Conversion process
US6737556B2 (en) * 2002-10-21 2004-05-18 Exxonmobil Chemical Patents Inc. Method and system for reducing decomposition byproducts in a methanol to olefin reactor system
US6984761B2 (en) * 2002-12-16 2006-01-10 Exxonmobil Chemical Patents Inc. Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor
US7405337B2 (en) 2004-09-21 2008-07-29 Uop Llc Conversion of oxygenate to propylene with selective hydrogen treatment of heavy olefin recycle stream
JPWO2007083684A1 (ja) 2006-01-21 2009-06-11 国立大学法人東京工業大学 触媒およびそれを用いるオレフィンの製造方法
CA2693467C (en) * 2007-07-11 2015-05-26 Mitsui Chemicals, Inc. Isopropyl alcohol-producing bacterium and method of producing isopropyl alcohol using the same
CN101244971A (zh) * 2008-02-27 2008-08-20 大连理工大学 一种生物乙醇高效脱水制乙烯的合成方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6167493A (ja) * 1984-09-10 1986-04-07 Res Assoc Petroleum Alternat Dev<Rapad> イソプロピルアルコ−ルの製造法
JPH0341038A (ja) * 1989-07-10 1991-02-21 Mitsui Toatsu Chem Inc イソプロピルアルコールの製造方法
JPH0341035A (ja) * 1989-07-10 1991-02-21 Mitsui Toatsu Chem Inc プロピレンの製造方法

Also Published As

Publication number Publication date
CA2744991C (en) 2013-07-16
US20110230696A1 (en) 2011-09-22
KR20110086124A (ko) 2011-07-27
SG171867A1 (en) 2011-07-28
TW201022184A (en) 2010-06-16
EP2364963B1 (en) 2015-02-25
KR101325457B1 (ko) 2013-11-04
EP2364963A4 (en) 2012-08-15
CN102227393A (zh) 2011-10-26
SA109300686B1 (ar) 2014-03-13
EP2364963A1 (en) 2011-09-14
CN102227393B (zh) 2015-02-18
BRPI0922145B1 (pt) 2017-12-05
CA2744991A1 (en) 2010-06-10
BRPI0922145A2 (pt) 2016-01-05
US8680355B2 (en) 2014-03-25
WO2010064500A1 (ja) 2010-06-10
RU2469998C1 (ru) 2012-12-20

Similar Documents

Publication Publication Date Title
TWI455908B (zh) 烯烴之製造方法
He et al. Synthesis of 1, 6-hexanediol from cellulose derived tetrahydrofuran-dimethanol with Pt-WO x/TiO2 catalysts
WO2010098798A3 (en) Process for producing cyclohexylbenzene
CN101939277A (zh) 醇在结晶硅酸盐上的脱水
Wang et al. Synthesis of light olefins from CO2 hydrogenation over (CuO-ZnO)-kaolin/SAPO-34 molecular sieves
Wang et al. Microstructured fiber@ HZSM-5 core–shell catalysts with dramatic selectivity and stability improvement for the methanol-to-propylene process
MX2014000293A (es) Sistema de membrana de transporte de oxigeno y metodo de transferencia de calor a reactores cataliticos/de proceso.
CN101939275A (zh) 醇在惰性组分存在下的脱水
ES2693529T3 (es) Reacción de dióxido de carbono con hidrógeno usando una membrana permselectiva
JP2011524368A5 (zh)
WO2009039948A3 (de) Verfahren und anlage zur herstellung von kohlenwasserstoffen
CN101808741A (zh) 磷改性分子筛和它们在有机物向烯烃的转化中的用途
JP2012510445A (ja) 酸触媒存在下で使用前にアルコールを精製する方法
JP2017537773A5 (zh)
BR112013003336B1 (pt) bactéria produtora de álcool isopropílico e método de produção de álcool isopropílico
TW201441189A (zh) 羰基化方法（二）
RU2015153807A (ru) Способ и система для производства метанола с использованием частичного окисления
Yu et al. Rhodium-catalyzed alkylation of ketones and alcohols with alcohols
MY150056A (en) Method for producing hydrogenolysis product of polyhydric alcohol
JP2008106056A (ja) プロピレンの製造方法
JP2006517957A5 (zh)
Dalena et al. Steam reforming of bioethanol using metallic catalysts on zeolitic supports: An overview
WO2009099291A3 (ko) 포타슘 오가노트리플로로보레이트 유도체 및 그 제조 방법
HRP20150407T1 (hr) Postupak proäśišä†avanja struje vode koja dolazi iz fischer-tropschove reakcije
JP2009143853A5 (zh)