TWI342044B - Process for forming dual metal gate structures - Google Patents
Process for forming dual metal gate structures Download PDFInfo
- Publication number
- TWI342044B TWI342044B TW093110018A TW93110018A TWI342044B TW I342044 B TWI342044 B TW I342044B TW 093110018 A TW093110018 A TW 093110018A TW 93110018 A TW93110018 A TW 93110018A TW I342044 B TWI342044 B TW I342044B
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- metal
- region
- gate
- covering
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 44
- 239000002184 metal Substances 0.000 title claims description 44
- 238000000034 method Methods 0.000 title claims description 14
- 230000009977 dual effect Effects 0.000 title 1
- 239000000758 substrate Substances 0.000 claims description 23
- 239000004065 semiconductor Substances 0.000 claims description 14
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 10
- 239000006117 anti-reflective coating Substances 0.000 claims description 7
- 125000006850 spacer group Chemical group 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- 238000001312 dry etching Methods 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229910004200 TaSiN Inorganic materials 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 238000005530 etching Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 229920002120 photoresistant polymer Polymers 0.000 description 10
- 229910052736 halogen Inorganic materials 0.000 description 6
- 150000002367 halogens Chemical class 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 5
- 241000252506 Characiformes Species 0.000 description 4
- 229910052732 germanium Inorganic materials 0.000 description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 4
- 239000012212 insulator Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229920005591 polysilicon Polymers 0.000 description 4
- 150000004772 tellurides Chemical group 0.000 description 4
- 229910052797 bismuth Inorganic materials 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 3
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 2
- 238000001039 wet etching Methods 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0135—Manufacturing their gate conductors
- H10D84/014—Manufacturing their gate conductors the gate conductors having different materials or different implants
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0144—Manufacturing their gate insulating layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0147—Manufacturing their gate sidewall spacers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0165—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices
- H10D84/0172—Manufacturing their gate conductors
- H10D84/0177—Manufacturing their gate conductors the gate conductors having different materials or different implants
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/02—Manufacture or treatment characterised by using material-based technologies
- H10D84/03—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
- H10D84/038—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
Landscapes
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
- Electrodes Of Semiconductors (AREA)
- Thin Film Transistor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/410,043 US6790719B1 (en) | 2003-04-09 | 2003-04-09 | Process for forming dual metal gate structures |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200507099A TW200507099A (en) | 2005-02-16 |
| TWI342044B true TWI342044B (en) | 2011-05-11 |
Family
ID=32927360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW093110018A TWI342044B (en) | 2003-04-09 | 2004-04-09 | Process for forming dual metal gate structures |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6790719B1 (enExample) |
| JP (1) | JP4653735B2 (enExample) |
| KR (1) | KR101159339B1 (enExample) |
| CN (1) | CN100487880C (enExample) |
| TW (1) | TWI342044B (enExample) |
| WO (1) | WO2004093182A1 (enExample) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3790237B2 (ja) * | 2003-08-26 | 2006-06-28 | 株式会社東芝 | 半導体装置の製造方法 |
| US7125775B1 (en) * | 2004-03-18 | 2006-10-24 | Integrated Device Technology, Inc. | Method for forming hybrid device gates |
| US7030001B2 (en) * | 2004-04-19 | 2006-04-18 | Freescale Semiconductor, Inc. | Method for forming a gate electrode having a metal |
| DE102004026232B4 (de) * | 2004-05-28 | 2006-05-04 | Infineon Technologies Ag | Verfahren zum Ausbilden einer integrierten Halbleiterschaltungsanordnung |
| KR100602122B1 (ko) * | 2004-12-03 | 2006-07-19 | 동부일렉트로닉스 주식회사 | 반도체 소자의 제조방법 |
| US7109079B2 (en) * | 2005-01-26 | 2006-09-19 | Freescale Semiconductor, Inc. | Metal gate transistor CMOS process and method for making |
| JP4764030B2 (ja) | 2005-03-03 | 2011-08-31 | 株式会社東芝 | 半導体装置及びその製造方法 |
| JP4626411B2 (ja) * | 2005-06-13 | 2011-02-09 | ソニー株式会社 | 半導体装置および半導体装置の製造方法 |
| US20070048920A1 (en) * | 2005-08-25 | 2007-03-01 | Sematech | Methods for dual metal gate CMOS integration |
| US7332433B2 (en) * | 2005-09-22 | 2008-02-19 | Sematech Inc. | Methods of modulating the work functions of film layers |
| JP4723975B2 (ja) * | 2005-10-25 | 2011-07-13 | 株式会社東芝 | 半導体装置およびその製造方法 |
| JP2007123548A (ja) * | 2005-10-28 | 2007-05-17 | Renesas Technology Corp | 半導体装置の製造方法 |
| US20070178634A1 (en) * | 2006-01-31 | 2007-08-02 | Hyung Suk Jung | Cmos semiconductor devices having dual work function metal gate stacks |
| KR100827435B1 (ko) * | 2006-01-31 | 2008-05-06 | 삼성전자주식회사 | 반도체 소자에서 무산소 애싱 공정을 적용한 게이트 형성방법 |
| JP4929867B2 (ja) * | 2006-06-19 | 2012-05-09 | 富士通セミコンダクター株式会社 | 半導体装置の製造方法 |
| KR100835430B1 (ko) * | 2007-05-21 | 2008-06-04 | 주식회사 동부하이텍 | 반도체 소자의 듀얼 게이트 전극 형성 방법 |
| US7696036B2 (en) * | 2007-06-14 | 2010-04-13 | International Business Machines Corporation | CMOS transistors with differential oxygen content high-k dielectrics |
| US7666730B2 (en) * | 2007-06-29 | 2010-02-23 | Freescale Semiconductor, Inc. | Method for forming a dual metal gate structure |
| KR100903383B1 (ko) * | 2007-07-31 | 2009-06-23 | 주식회사 하이닉스반도체 | 일함수가 조절된 게이트전극을 구비한 트랜지스터 및 그를구비하는 메모리소자 |
| JP2009044051A (ja) * | 2007-08-10 | 2009-02-26 | Panasonic Corp | 半導体装置及びその製造方法 |
| US20090206416A1 (en) * | 2008-02-19 | 2009-08-20 | International Business Machines Corporation | Dual metal gate structures and methods |
| US7691701B1 (en) * | 2009-01-05 | 2010-04-06 | International Business Machines Corporation | Method of forming gate stack and structure thereof |
| DE102009039418B4 (de) * | 2009-08-31 | 2013-08-22 | GLOBALFOUNDRIES Dresden Module One Ltd. Liability Company & Co. KG | Einstellung der Austrittsarbeit in Gate-Stapeln mit großem ε, die Gatedielektrika mit unterschiedlicher Dicke enthalten |
| US8435878B2 (en) | 2010-04-06 | 2013-05-07 | International Business Machines Corporation | Field effect transistor device and fabrication |
| US8211775B1 (en) | 2011-03-09 | 2012-07-03 | United Microelectronics Corp. | Method of making transistor having metal gate |
| US8519487B2 (en) | 2011-03-21 | 2013-08-27 | United Microelectronics Corp. | Semiconductor device |
| US9384962B2 (en) | 2011-04-07 | 2016-07-05 | United Microelectronics Corp. | Oxygen treatment of replacement work-function metals in CMOS transistor gates |
| US8530980B2 (en) | 2011-04-27 | 2013-09-10 | United Microelectronics Corp. | Gate stack structure with etch stop layer and manufacturing process thereof |
| US9490342B2 (en) | 2011-06-16 | 2016-11-08 | United Microelectronics Corp. | Method for fabricating semiconductor device |
| US8673758B2 (en) | 2011-06-16 | 2014-03-18 | United Microelectronics Corp. | Structure of metal gate and fabrication method thereof |
| US8536038B2 (en) | 2011-06-21 | 2013-09-17 | United Microelectronics Corp. | Manufacturing method for metal gate using ion implantation |
| US8486790B2 (en) | 2011-07-18 | 2013-07-16 | United Microelectronics Corp. | Manufacturing method for metal gate |
| US8551876B2 (en) | 2011-08-18 | 2013-10-08 | United Microelectronics Corp. | Manufacturing method for semiconductor device having metal gate |
| US8872286B2 (en) | 2011-08-22 | 2014-10-28 | United Microelectronics Corp. | Metal gate structure and fabrication method thereof |
| US8691681B2 (en) | 2012-01-04 | 2014-04-08 | United Microelectronics Corp. | Semiconductor device having a metal gate and fabricating method thereof |
| US8860181B2 (en) | 2012-03-07 | 2014-10-14 | United Microelectronics Corp. | Thin film resistor structure |
| US9105623B2 (en) | 2012-05-25 | 2015-08-11 | United Microelectronics Corp. | Semiconductor device having metal gate and manufacturing method thereof |
| US8975666B2 (en) | 2012-08-22 | 2015-03-10 | United Microelectronics Corp. | MOS transistor and process thereof |
| US9054172B2 (en) | 2012-12-05 | 2015-06-09 | United Microelectrnics Corp. | Semiconductor structure having contact plug and method of making the same |
| US8735269B1 (en) | 2013-01-15 | 2014-05-27 | United Microelectronics Corp. | Method for forming semiconductor structure having TiN layer |
| US9653300B2 (en) | 2013-04-16 | 2017-05-16 | United Microelectronics Corp. | Structure of metal gate structure and manufacturing method of the same |
| US9159798B2 (en) | 2013-05-03 | 2015-10-13 | United Microelectronics Corp. | Replacement gate process and device manufactured using the same |
| US9196542B2 (en) | 2013-05-22 | 2015-11-24 | United Microelectronics Corp. | Method for manufacturing semiconductor devices |
| US8921947B1 (en) | 2013-06-10 | 2014-12-30 | United Microelectronics Corp. | Multi-metal gate semiconductor device having triple diameter metal opening |
| US20150069534A1 (en) | 2013-09-11 | 2015-03-12 | United Microelectronics Corp. | Semiconductor device and method for fabricating the same |
| US9105720B2 (en) | 2013-09-11 | 2015-08-11 | United Microelectronics Corp. | Semiconductor device having metal gate and manufacturing method thereof |
| US9196546B2 (en) | 2013-09-13 | 2015-11-24 | United Microelectronics Corp. | Metal gate transistor |
| US9231071B2 (en) | 2014-02-24 | 2016-01-05 | United Microelectronics Corp. | Semiconductor structure and manufacturing method of the same |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6004869A (en) | 1997-04-25 | 1999-12-21 | Micron Technology, Inc. | Method for making a low resistivity electrode having a near noble metal |
| US6171959B1 (en) * | 1998-01-20 | 2001-01-09 | Motorola, Inc. | Method for making a semiconductor device |
| CN1123917C (zh) * | 1998-02-27 | 2003-10-08 | 联华电子股份有限公司 | 制作双电压金属氧化物半导体晶体管的方法 |
| US6166417A (en) * | 1998-06-30 | 2000-12-26 | Intel Corporation | Complementary metal gates and a process for implementation |
| JP2002083812A (ja) * | 1999-06-29 | 2002-03-22 | Semiconductor Energy Lab Co Ltd | 配線材料およびこれを用いた配線を備えた半導体装置およびその作製方法 |
| US6171910B1 (en) * | 1999-07-21 | 2001-01-09 | Motorola Inc. | Method for forming a semiconductor device |
| US6214681B1 (en) * | 2000-01-26 | 2001-04-10 | Advanced Micro Devices, Inc. | Process for forming polysilicon/germanium thin films without germanium outgassing |
| US6444512B1 (en) | 2000-06-12 | 2002-09-03 | Motorola, Inc. | Dual metal gate transistors for CMOS process |
| KR100399356B1 (ko) * | 2001-04-11 | 2003-09-26 | 삼성전자주식회사 | 듀얼 게이트를 가지는 씨모스형 반도체 장치 형성 방법 |
-
2003
- 2003-04-09 US US10/410,043 patent/US6790719B1/en not_active Expired - Lifetime
-
2004
- 2004-04-08 KR KR1020057019065A patent/KR101159339B1/ko not_active Expired - Fee Related
- 2004-04-08 WO PCT/US2004/010814 patent/WO2004093182A1/en not_active Ceased
- 2004-04-08 JP JP2006509809A patent/JP4653735B2/ja not_active Expired - Fee Related
- 2004-04-08 CN CNB2004800094963A patent/CN100487880C/zh not_active Expired - Fee Related
- 2004-04-09 TW TW093110018A patent/TWI342044B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TW200507099A (en) | 2005-02-16 |
| KR20050120785A (ko) | 2005-12-23 |
| US6790719B1 (en) | 2004-09-14 |
| JP2006523037A (ja) | 2006-10-05 |
| CN1771590A (zh) | 2006-05-10 |
| JP4653735B2 (ja) | 2011-03-16 |
| CN100487880C (zh) | 2009-05-13 |
| WO2004093182A1 (en) | 2004-10-28 |
| KR101159339B1 (ko) | 2012-06-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |