TW392079B - Coated optical fibers having strippable primary coatings and processes for making and using same - Google Patents
Coated optical fibers having strippable primary coatings and processes for making and using same Download PDFInfo
- Publication number
- TW392079B TW392079B TW087107936A TW87107936A TW392079B TW 392079 B TW392079 B TW 392079B TW 087107936 A TW087107936 A TW 087107936A TW 87107936 A TW87107936 A TW 87107936A TW 392079 B TW392079 B TW 392079B
- Authority
- TW
- Taiwan
- Prior art keywords
- optical fiber
- acrylate
- coating
- patent application
- item
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 230
- 239000013307 optical fiber Substances 0.000 title claims abstract description 123
- 238000000034 method Methods 0.000 title claims abstract description 31
- 230000008569 process Effects 0.000 title claims abstract description 10
- 239000000178 monomer Substances 0.000 claims abstract description 70
- 239000000463 material Substances 0.000 claims abstract description 41
- 239000003381 stabilizer Substances 0.000 claims abstract description 38
- 239000003085 diluting agent Substances 0.000 claims abstract description 37
- 239000011521 glass Substances 0.000 claims abstract description 31
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910000077 silane Inorganic materials 0.000 claims abstract description 17
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims description 212
- 229920000642 polymer Polymers 0.000 claims description 124
- 239000000203 mixture Substances 0.000 claims description 116
- -1 alkane acrylate Chemical class 0.000 claims description 64
- 239000000126 substance Substances 0.000 claims description 58
- 238000011049 filling Methods 0.000 claims description 51
- 239000000835 fiber Substances 0.000 claims description 45
- 239000003504 photosensitizing agent Substances 0.000 claims description 38
- 239000010410 layer Substances 0.000 claims description 35
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 34
- 229920000570 polyether Polymers 0.000 claims description 30
- 125000001931 aliphatic group Chemical group 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 150000004756 silanes Chemical class 0.000 claims description 24
- 230000002079 cooperative effect Effects 0.000 claims description 23
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 22
- 238000012360 testing method Methods 0.000 claims description 20
- 229930195733 hydrocarbon Natural products 0.000 claims description 19
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical class C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 claims description 17
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims description 16
- 239000008199 coating composition Substances 0.000 claims description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 14
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 13
- 239000003365 glass fiber Substances 0.000 claims description 13
- 239000005056 polyisocyanate Substances 0.000 claims description 13
- 229920001228 polyisocyanate Polymers 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 12
- 238000012546 transfer Methods 0.000 claims description 10
- 230000005855 radiation Effects 0.000 claims description 9
- 239000011247 coating layer Substances 0.000 claims description 8
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 5
- 239000000376 reactant Substances 0.000 claims description 5
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 4
- XMIIGOLPHOKFCH-UHFFFAOYSA-N 3-phenylpropionic acid Chemical compound OC(=O)CCC1=CC=CC=C1 XMIIGOLPHOKFCH-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 238000009434 installation Methods 0.000 claims description 4
- 239000005304 optical glass Substances 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 4
- 238000007711 solidification Methods 0.000 claims description 4
- 230000008023 solidification Effects 0.000 claims description 4
- KBQVDAIIQCXKPI-UHFFFAOYSA-N 3-trimethoxysilylpropyl prop-2-enoate Chemical group CO[Si](OC)(OC)CCCOC(=O)C=C KBQVDAIIQCXKPI-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 125000000524 functional group Chemical group 0.000 claims description 3
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 claims description 3
- 229940065472 octyl acrylate Drugs 0.000 claims description 3
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 claims description 2
- NQSLZEHVGKWKAY-UHFFFAOYSA-N 6-methylheptyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C(C)=C NQSLZEHVGKWKAY-UHFFFAOYSA-N 0.000 claims description 2
- COCLLEMEIJQBAG-UHFFFAOYSA-N 8-methylnonyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C(C)=C COCLLEMEIJQBAG-UHFFFAOYSA-N 0.000 claims description 2
- LVGFPWDANALGOY-UHFFFAOYSA-N 8-methylnonyl prop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C=C LVGFPWDANALGOY-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- LCXXNKZQVOXMEH-UHFFFAOYSA-N Tetrahydrofurfuryl methacrylate Chemical compound CC(=C)C(=O)OCC1CCCO1 LCXXNKZQVOXMEH-UHFFFAOYSA-N 0.000 claims description 2
- GTBGXKPAKVYEKJ-UHFFFAOYSA-N decyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C(C)=C GTBGXKPAKVYEKJ-UHFFFAOYSA-N 0.000 claims description 2
- ZNAOFAIBVOMLPV-UHFFFAOYSA-N hexadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(C)=C ZNAOFAIBVOMLPV-UHFFFAOYSA-N 0.000 claims description 2
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 claims description 2
- LUCXVPAZUDVVBT-UHFFFAOYSA-N methyl-[3-(2-methylphenoxy)-3-phenylpropyl]azanium;chloride Chemical compound Cl.C=1C=CC=CC=1C(CCNC)OC1=CC=CC=C1C LUCXVPAZUDVVBT-UHFFFAOYSA-N 0.000 claims description 2
- KCAMXZBMXVIIQN-UHFFFAOYSA-N octan-3-yl 2-methylprop-2-enoate Chemical compound CCCCCC(CC)OC(=O)C(C)=C KCAMXZBMXVIIQN-UHFFFAOYSA-N 0.000 claims description 2
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 claims description 2
- KEROTHRUZYBWCY-UHFFFAOYSA-N tridecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCOC(=O)C(C)=C KEROTHRUZYBWCY-UHFFFAOYSA-N 0.000 claims description 2
- XOALFFJGWSCQEO-UHFFFAOYSA-N tridecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCOC(=O)C=C XOALFFJGWSCQEO-UHFFFAOYSA-N 0.000 claims description 2
- 150000003673 urethanes Chemical class 0.000 claims description 2
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 2
- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical compound CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 claims 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims 2
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical compound CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 claims 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 1
- VCSYXZQBBCIQCJ-UHFFFAOYSA-N 2-phenyl-4-propan-2-ylphenol Chemical class CC(C)C1=CC=C(O)C(C=2C=CC=CC=2)=C1 VCSYXZQBBCIQCJ-UHFFFAOYSA-N 0.000 claims 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- 239000006087 Silane Coupling Agent Substances 0.000 claims 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- CGUUOQGBKYXSHJ-UHFFFAOYSA-N carbonic acid;2-methylprop-2-enoic acid Chemical compound OC(O)=O.CC(=C)C(O)=O CGUUOQGBKYXSHJ-UHFFFAOYSA-N 0.000 claims 1
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 claims 1
- AQNSVANSEBPSMK-UHFFFAOYSA-N dicyclopentenyl methacrylate Chemical compound C12CC=CC2C2CC(OC(=O)C(=C)C)C1C2.C12C=CCC2C2CC(OC(=O)C(=C)C)C1C2 AQNSVANSEBPSMK-UHFFFAOYSA-N 0.000 claims 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims 1
- 239000011152 fibreglass Substances 0.000 claims 1
- PZDUWXKXFAIFOR-UHFFFAOYSA-N hexadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C=C PZDUWXKXFAIFOR-UHFFFAOYSA-N 0.000 claims 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 claims 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims 1
- 229940119545 isobornyl methacrylate Drugs 0.000 claims 1
- 229920000847 nonoxynol Polymers 0.000 claims 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims 1
- ATZHWSYYKQKSSY-UHFFFAOYSA-N tetradecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)=C ATZHWSYYKQKSSY-UHFFFAOYSA-N 0.000 claims 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical class CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 claims 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 239000000976 ink Substances 0.000 description 32
- 239000004615 ingredient Substances 0.000 description 24
- 150000001875 compounds Chemical class 0.000 description 19
- VFBJXXJYHWLXRM-UHFFFAOYSA-N 2-[2-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]ethylsulfanyl]ethyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCSCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 VFBJXXJYHWLXRM-UHFFFAOYSA-N 0.000 description 16
- 235000015170 shellfish Nutrition 0.000 description 16
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- 239000007788 liquid Substances 0.000 description 13
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 238000001723 curing Methods 0.000 description 8
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- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 230000003287 optical effect Effects 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 125000005442 diisocyanate group Chemical group 0.000 description 5
- 238000010894 electron beam technology Methods 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 4
- 108091092920 SmY RNA Proteins 0.000 description 4
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- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- UTPYTEWRMXITIN-YDWXAUTNSA-N 1-methyl-3-[(e)-[(3e)-3-(methylcarbamothioylhydrazinylidene)butan-2-ylidene]amino]thiourea Chemical compound CNC(=S)N\N=C(/C)\C(\C)=N\NC(=S)NC UTPYTEWRMXITIN-YDWXAUTNSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 244000147568 Laurus nobilis Species 0.000 description 3
- 235000017858 Laurus nobilis Nutrition 0.000 description 3
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- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
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- 238000007710 freezing Methods 0.000 description 3
- 230000002496 gastric effect Effects 0.000 description 3
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- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
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- NHOWREQLQRFDRW-UHFFFAOYSA-N (methoxyamino)oxymethane Chemical compound CONOC NHOWREQLQRFDRW-UHFFFAOYSA-N 0.000 description 2
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- ACHUKAXRNNEFMX-UHFFFAOYSA-N 2,3,4-trimethylbenzenecarboximidamide Chemical compound CC1=CC=C(C(N)=N)C(C)=C1C ACHUKAXRNNEFMX-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LKOKKQDYMZUSCG-UHFFFAOYSA-N 3,5,5-Trimethyl-3-cyclohexen-1-one Chemical compound CC1=CC(C)(C)CC(=O)C1 LKOKKQDYMZUSCG-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- UOMQXZZZJAOFCI-UHFFFAOYSA-N CCCCCCCCCCCC.C(C(=C)C)(=O)O Chemical compound CCCCCCCCCCCC.C(C(=C)C)(=O)O UOMQXZZZJAOFCI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
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- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 description 2
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- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000003848 UV Light-Curing Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- ZNAAXKXXDQLJIX-UHFFFAOYSA-N bis(2-cyclohexyl-3-hydroxyphenyl)methanone Chemical compound C1CCCCC1C=1C(O)=CC=CC=1C(=O)C1=CC=CC(O)=C1C1CCCCC1 ZNAAXKXXDQLJIX-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/245—Removing protective coverings of light guides before coupling
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/106—Single coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/1065—Multiple coatings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02395—Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Light Guides In General And Applications Therefor (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3583897P | 1997-01-24 | 1997-01-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW392079B true TW392079B (en) | 2000-06-01 |
Family
ID=21885084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW087107936A TW392079B (en) | 1997-01-24 | 1998-05-22 | Coated optical fibers having strippable primary coatings and processes for making and using same |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6014488A (enExample) |
| EP (1) | EP0894277A4 (enExample) |
| JP (1) | JP2000507369A (enExample) |
| KR (1) | KR100325883B1 (enExample) |
| CN (1) | CN1105925C (enExample) |
| AU (1) | AU6037398A (enExample) |
| BR (1) | BR9805953B1 (enExample) |
| CA (1) | CA2248356A1 (enExample) |
| IL (1) | IL125898A (enExample) |
| NO (1) | NO984140L (enExample) |
| TW (1) | TW392079B (enExample) |
| WO (1) | WO1998033081A1 (enExample) |
Families Citing this family (63)
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| US5664041A (en) * | 1993-12-07 | 1997-09-02 | Dsm Desotech, Inc. | Coating system for glass adhesion retention |
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| JP4003838B2 (ja) * | 1997-03-18 | 2007-11-07 | ディーエスエム アイピー アセッツ ビー． ブイ | 低出力電子ビーム照射により光ファイバーコーテイングとインキを硬化する方法 |
| US6211262B1 (en) * | 1998-04-20 | 2001-04-03 | Spectra Group Limited, Inc. | Corrosion resistant, radiation curable coating |
| US6110593A (en) | 1998-05-21 | 2000-08-29 | Dsm N.V. | Radiation-curable optical fiber primary coating system |
| US6376018B1 (en) * | 1998-06-17 | 2002-04-23 | Wilfred C. Kittler, Jr. | Method for the production of unsupported thin film particles |
| US6215934B1 (en) * | 1998-10-01 | 2001-04-10 | Lucent Technologies, Inc. | Coated optical fiber with improved strippability |
| US6366722B1 (en) | 1999-03-04 | 2002-04-02 | Luna Innovations, Inc. | Optical waveguide sensors having high refractive index sensitivity |
| US6428204B1 (en) * | 1999-06-29 | 2002-08-06 | Fitel Usa Corp. | Method of making a coated optical fiber comprising measuring the delamination resistance of the coating at two different temperatures |
| US6243523B1 (en) * | 1999-06-29 | 2001-06-05 | Lucent Technologies Inc. | Coated optical fiber with increased modulus and thermally enhanced strippability |
| AU6627600A (en) * | 1999-08-09 | 2001-03-05 | Borden Chemical, Inc. | Heat strippable optical fiber ribbons |
| EP1268357B1 (en) * | 1999-12-30 | 2008-01-09 | Corning Incorporated | Optical fibers prepared with a primary coating composition including a monomer with a pendant hydroxyl functional group |
| US6775451B1 (en) | 1999-12-30 | 2004-08-10 | Corning Incorporated | Secondary coating composition for optical fibers |
| US6584263B2 (en) | 2000-07-26 | 2003-06-24 | Corning Incorporated | Optical fiber coating compositions and coated optical fibers |
| EP1209132A1 (en) | 2000-11-22 | 2002-05-29 | Dsm N.V. | Coated optical fibers, primary coating composition, method for curing, as well as an assembly and a method for measuring |
| US6553169B2 (en) * | 2000-11-29 | 2003-04-22 | Corning Incorporated | Optical fiber coating compositions and coated optical fibers |
| KR20030066762A (ko) | 2000-12-29 | 2003-08-09 | 디에스엠 아이피 어셋츠 비.브이. | 방사선-경화 가능 섬유 광학 코팅재에 사용하기 위한비결정-형성 올리고머 |
| US6775443B2 (en) * | 2001-01-29 | 2004-08-10 | Corning Cable Systems Llc | Tight buffered optical cables with release layers |
| US6596787B1 (en) | 2001-02-02 | 2003-07-22 | Henkel Loctite Corporation | Non-yellowing fast cure speed UV\visible curable liquid acrylic ester adhesives for glass bonding |
| US20030077059A1 (en) | 2001-03-13 | 2003-04-24 | Ching-Kee Chien | Optical fiber coating compositions |
| WO2002072498A1 (en) * | 2001-03-13 | 2002-09-19 | Corning Incorporated | Optical fiber coating compositions |
| KR100405004B1 (ko) * | 2001-03-22 | 2003-11-10 | 주식회사 루밴틱스 | 광섬유 리본 코팅용 수지 조성물 |
| TW536640B (en) * | 2001-04-13 | 2003-06-11 | Furukawa Electric Co Ltd | Coated optical fiber |
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| JP5106730B2 (ja) * | 2001-09-27 | 2012-12-26 | Ｄｉｃ株式会社 | 光硬化型樹脂組成物及び該組成物を用いた光ファイバ素線及び光ファイバテープ心線 |
| US6628886B2 (en) * | 2002-01-04 | 2003-09-30 | Iphotonics, Inc. | Integrated processing system for optical devices |
| US6714713B2 (en) * | 2002-03-15 | 2004-03-30 | Corning Cable Systems Llc | Optical fiber having a low-shrink buffer layer and methods of manufacturing the same |
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| WO2003091346A1 (en) | 2002-04-24 | 2003-11-06 | Dsm Ip Assets B.V. | Radiation curable coating composition for optical fiber with reduced attenuation loss |
| US7238386B2 (en) * | 2002-05-09 | 2007-07-03 | Hexion Specialty Chemicals, Inc. | Methods for making and using point lump-free compositions and products coated with point lump-free compositions |
| US20040037521A1 (en) * | 2002-08-22 | 2004-02-26 | Shunhe Xiong | Methods and apparatus for coloring optical fibers during draw |
| US6862392B2 (en) * | 2003-06-04 | 2005-03-01 | Corning Incorporated | Coated optical fiber and curable compositions suitable for coating optical fiber |
| US7207732B2 (en) * | 2003-06-04 | 2007-04-24 | Corning Incorporated | Coated optical fiber and curable compositions suitable for coating optical fiber |
| US7050688B2 (en) * | 2003-07-18 | 2006-05-23 | Corning Cable Systems Llc | Fiber optic articles, assemblies, and cables having optical waveguides |
| US7715675B2 (en) * | 2003-07-18 | 2010-05-11 | Corning Incorporated | Optical fiber coating system and coated optical fiber |
| JP4618479B2 (ja) * | 2004-01-29 | 2011-01-26 | Ｄｉｃ株式会社 | 光ファイバー被覆用樹脂組成物及びそれを用いた光ファイバーユニット |
| EP1738208B1 (de) * | 2004-04-22 | 2013-10-02 | Reichle & De-Massari AG | Kunststoff-ferrule |
| US20070218290A1 (en) * | 2004-06-24 | 2007-09-20 | Beneq Oy | Method for Doping Material and Doped Material |
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| KR100789617B1 (ko) * | 2005-09-13 | 2007-12-27 | 주식회사 엘지화학 | 네가티브 ｃ 타입의 보상 필름 및 이의 제조 방법 |
| ATE498595T1 (de) | 2006-12-14 | 2011-03-15 | Dsm Ip Assets Bv | D1364 bt-sekundärbeschichtung für optische fasern |
| RU2436822C2 (ru) * | 2006-12-14 | 2011-12-20 | ДСМ Ай Пи ЭССЕТС Б.В. | Отверждаемое излучением вторичное покрытие d 1370 r для оптического волокна |
| RU2434914C2 (ru) * | 2006-12-14 | 2011-11-27 | ДСМ Ай Пи ЭССЕТС Б.В. | Отверждаемое излучением первичное покрытие d 1368 cr для оптического волокна |
| ATE514728T1 (de) * | 2006-12-14 | 2011-07-15 | Dsm Ip Assets Bv | D1381-superbeschichtungen für optische fasern |
| KR101155014B1 (ko) * | 2006-12-14 | 2012-06-11 | 디에스엠 아이피 어셋츠 비.브이. | 광섬유에 대한 ｄ1378 ｃａ 선 경화성 1차 코팅 |
| DE602007012575D1 (de) * | 2006-12-14 | 2011-03-31 | Dsm Ip Assets Bv | Strahlungshärtbare d1363 bt-grundierbeschichtung für optische fasern |
| CN101535200B (zh) * | 2006-12-14 | 2011-10-26 | 帝斯曼知识产权资产管理有限公司 | 光纤上的d1364bt次级涂层 |
| RU2504522C2 (ru) | 2009-10-09 | 2014-01-20 | ДСМ Ай Пи ЭССЕТС Б.В. | D1451 способы составления отверждаемых облучением суперпокрытий для оптического волокна |
| RU2604227C2 (ru) | 2009-10-09 | 2016-12-10 | ДСМ Ай Пи ЭССЕТС Б.В. | D1452 gb отверждаемое излучением покрытие для оптического волокна |
| KR101362615B1 (ko) | 2009-12-17 | 2014-02-12 | 디에스엠 아이피 어셋츠 비.브이. | 복사선 경화성 광섬유 코팅 조성물의 ｌｅｄ 경화 |
| JP5702951B2 (ja) * | 2010-06-02 | 2015-04-15 | 株式会社フジクラ | 光ファイバ心線 |
| CN103570255B (zh) * | 2012-08-07 | 2016-08-10 | 重庆国际复合材料有限公司 | 一种玻璃纤维浸润剂组合物、制备方法及应用 |
| JP6123444B2 (ja) * | 2013-04-10 | 2017-05-10 | 住友電気工業株式会社 | 光ファイバ素線およびその製造方法 |
| JP6459215B2 (ja) * | 2014-05-14 | 2019-01-30 | 住友電気工業株式会社 | 光ファイバ及び光ファイバの評価方法 |
| JP6106253B1 (ja) | 2015-12-04 | 2017-03-29 | 株式会社フジクラ | 光ファイバテープ、光ファイバテープの製造方法、及び間欠固定型光ファイバテープの連結部の形成に用いられる紫外線硬化樹脂組成物 |
| KR102363099B1 (ko) | 2016-02-19 | 2022-02-15 | 애버리 데니슨 코포레이션 | 접착제를 제조하는 2단계 방법 및 관련 조성물 |
| CN110099939B (zh) | 2016-10-25 | 2022-09-06 | 艾利丹尼森公司 | 在主链中具有光引发剂基团的嵌段聚合物及其用于粘合剂组合物中的用途 |
| PL3586179T3 (pl) * | 2017-02-27 | 2022-01-10 | Prysmian S.P.A. | Wdmuchiwana jednostka światłowodowa i powiązany sposób wytwarzania |
| JP2019045517A (ja) | 2017-08-29 | 2019-03-22 | 住友電気工業株式会社 | 光ファイバ |
| JP7507088B2 (ja) | 2017-12-19 | 2024-06-27 | エイブリィ・デニソン・コーポレイション | ペンダント官能基の後重合官能化 |
| WO2021020588A1 (en) * | 2019-07-31 | 2021-02-04 | Japan Fine Coatings Co. Ltd. | Radiation-curable resin composition and its cured product, and optical fiber |
| CN114829444A (zh) * | 2019-10-14 | 2022-07-29 | 康宁股份有限公司 | 聚合物基部分、粘合剂、可折叠设备及其制造方法 |
| CN115612327B (zh) * | 2022-10-27 | 2023-11-10 | 中昊北方涂料工业研究设计院有限公司 | 一种低气味易剥离光纤内层涂料的制备方法 |
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| JPS56117204A (en) * | 1980-02-21 | 1981-09-14 | Nippon Telegr & Teleph Corp <Ntt> | Manufacture of optical fiber |
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| JPS6052801A (ja) * | 1983-09-02 | 1985-03-26 | Mitsubishi Petrochem Co Ltd | 光フアイバ−被覆体 |
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-
1998
- 1998-01-23 EP EP98903664A patent/EP0894277A4/en not_active Withdrawn
- 1998-01-23 US US09/142,102 patent/US6014488A/en not_active Expired - Lifetime
- 1998-01-23 KR KR1019980707543A patent/KR100325883B1/ko not_active Expired - Lifetime
- 1998-01-23 CA CA002248356A patent/CA2248356A1/en not_active Abandoned
- 1998-01-23 IL IL12589898A patent/IL125898A/xx not_active IP Right Cessation
- 1998-01-23 WO PCT/US1998/001289 patent/WO1998033081A1/en not_active Ceased
- 1998-01-23 JP JP10532136A patent/JP2000507369A/ja not_active Withdrawn
- 1998-01-23 CN CN98800286A patent/CN1105925C/zh not_active Expired - Lifetime
- 1998-01-23 AU AU60373/98A patent/AU6037398A/en not_active Abandoned
- 1998-01-23 BR BRPI9805953-0A patent/BR9805953B1/pt not_active IP Right Cessation
- 1998-05-22 TW TW087107936A patent/TW392079B/zh not_active IP Right Cessation
- 1998-09-08 NO NO984140A patent/NO984140L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0894277A4 (en) | 2002-07-31 |
| US6014488A (en) | 2000-01-11 |
| KR20000064769A (ko) | 2000-11-06 |
| BR9805953B1 (pt) | 2008-11-18 |
| AU6037398A (en) | 1998-08-18 |
| IL125898A (en) | 2000-11-21 |
| CA2248356A1 (en) | 1998-07-30 |
| CN1105925C (zh) | 2003-04-16 |
| KR100325883B1 (ko) | 2002-09-26 |
| CN1219245A (zh) | 1999-06-09 |
| NO984140L (no) | 1998-11-20 |
| IL125898A0 (en) | 1999-04-11 |
| EP0894277A1 (en) | 1999-02-03 |
| JP2000507369A (ja) | 2000-06-13 |
| NO984140D0 (no) | 1998-09-08 |
| BR9805953A (pt) | 1999-08-31 |
| WO1998033081A1 (en) | 1998-07-30 |
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