TW399156B - Radiation-curable ink composition, radiation-curable matrix forming composition, coated optical glass fiber, and ribbon assembly - Google Patents

Abstract

Provided is a ribbon assembly having the functional capability of providing mid-span access without the use of additives, monomers or oligomers containing fluorine or silicone. The ribbon assembly is formulated from an oligomer which reduces the surface energy of the ink coating and/or the matrix material. Also provided are ink coating compositions and matrix forming compositions which are suitable for forming the ribbon assembly.

Description

Λ7 M7 V. Description of the invention (1) 1. Scope of the invention The present invention relates to a glass optical fiber ribbon module used for forming a ribbon module, and a composition for forming a substrate and an ink coating composition. 2. Description of related arts Glass fiber is usually coated with two overlapping radiation-curable coatings, which together form a basic coating. The coating that is in direct contact with the glass is called the basic coating on the inside, and the coating on the outside is called the basic coating on the outside. Internal basic coatings are generally relatively soft coatings that provide optical fibers with regard to environmental protection and, in particular, resistance to the well-known microbending phenomenon. The micro-bend phenomenon in the coated optical fiber will cause the signal transmission capacity of the coated optical fiber to be attenuated, and therefore it is undesirable. The outer covering on the exposed surface of the coated optical fiber is typically designed to provide resistance to physical manipulation forces, such as those encountered when an optical fiber is made into a cable, rather than a relatively hard coating. For the purpose of multi-band transmission, we use glass fiber optic assemblies containing numerous coated optical fibers. Examples of glass fiber optic components include ribbon components and cables. A typical ribbon component is made by binding a number of parallel-oriented, individually coated glass optical fibers to a matrix material. This matrix material has the function of maintaining the individual glass fibers in a straight line, and it can protect the glass fibers from being damaged during operation and in the installation environment. Often, optical fibers are arranged in a ribbon structure, which has a generally flat, strand-like structure. A typical strand contains about 2 to 24 fibers. According to this ΐ /, read the first note and note the total market item is to fill in the wooden page) ir- wood paper recognition standards apply '丨' 囤 燕 家 行 窣 (CNS) Λ4 八 ', ½ (2Ι〇Χ? 97. »/ ί > -4- ΑΊ __ 117… _ 丨 ·· ———----— —-____ Five 'Description of the Invention (2) Application, which can combine many of the obtained belt-shaped components into one with several to An individual coated glass fiber optic cable is left and right. An example of a ribbon component is described in the published European Patent Application No. 198 8 91. In general, a large number of The ribbon components are joined together into a cable 'as described in U.S. Patent No. 4'906,06.07. Coated glass fibers used in glass fiber optic components are generally coated with an external colored layer. Called ink coating, or adding a colorant to the exterior basic coating 'promotes the identification of individual coated glass fibers. Therefore, the substrate material that binds the coated glass fibers together with the external ink layer (if (If any), or in contact with a colored outer cover. The coating usually has a thickness of about 3 to 10 microns and is formed by dispersing the pigment in a UV-curable carrier system. The UV-curable carrier system contains a UV-curable homopolymer or monomer of uniform molecular weight. The molecular weight polymer or monomer is liquid before curing to promote the application of the ink composition of glass fiber, and is solid after being exposed to ultraviolet radiation. In this way, when the inner basic coating and the outer basic coating are applied, The UV curable ink composition can be applied to the coated glass fiber in the same way. We usually need to implement the branching of the fiber link at the terminal positioning intermediates of the specified length of the ribbon component in the application. .This method of accessing each fiber is generally called " mid-span access method ", and there are special problems in it. General methods and tools for accessing the end or end of a ribbon component, generally It is not completely suitable, or impossible to implement (the "first read" "-" parameters ", ντ ^ π). π A7 ΙΪ7 V. Description of the invention (3) Mid-span access method. Many attempts have been made to provide a ribbon-shaped unit, and the matrix substance in the unit can be easily coated from the colored fiber on the glass fiber at any position on the ribbon-shaped unit. Detachment without removing the colored coating from the coated glass fiber. However, if the separation of the matrix material also removes the colored coating on the fiber, it will invalidate the purpose of identifying each fiber. A common method of distance access is to contact the matrix substance with a solvent, such as ethanol or isopropanol. Such a solvent must have the ability to swell or soften the matrix substance. At the same time, the solvent should be selected so as not to make each The coating on the glass fiber expands. Swelling of the matrix material weakens the matrix material and can then be removed mechanically using intermediate brushing or similar mechanical methods to provide individual glass fiber access that is still coated and can be considered the same color. An example of this solvent peeling method is described in AT & T brochure 'D-182355 Accuribbon ™ Single Fliber Access " (March 3, 1991). Published European Application No. 06 1 409 9A2, which discloses the optical fiber ribbon unit, in which the adhesion between the colored layer and the matrix layer of each glass optical fiber is based on the use of a release agent with a weight percentage of less than 5% Into each layer to suppress. The purpose of adding the release agent is that when the glass optical fiber is separated from the matrix substance, the colored layer is not removed thereby. Examples of these release agents include silicone-based release agents or fluorine-based release agents. Published Japanese Patent Application No. 6 4 _ 2 2 9 7 6 discloses a radiation-curable ink composition which contains a special radiation-curable ink. The ink composition, which provides a wood paper scale suitable for use with a matrix material in a band-shaped component, is explained in detail:?:; 'V- (cf) Λ4 圯 imi (~ 2 \ 〇κνη ^ Γ) Tfi-. ™ " Behind the scenes: vx Italian matters ", Α · 8 this s) --5 Λ7 H7 V. Description of the invention (4) The outer coating that is detached has a viscous ink coating. The published Japanese Patent Application No. Η 1-15 2 4 0 5 discloses that the Shank composition which is curable by irradiation contains an organic polysiloxane compound. The polysiloxane compound, which provides Ink coating that is easily detached from the matrix substance in the belt-like module. U.S. Patent No. 4,900,126 (Jackson) discloses glass fiber ribbon units in which each individually coated glass fiber has a colored outer layer. Each glass optical fiber is further coated with a release agent, which has a low binding affinity or a low colorant substance affinity. An example of the release agent is polytetrafluoroethylene. The release agent forms a weak boundary layer at the interface between the colorant substance and the matrix substance, thereby separating the matrix and the glass fiber without removing the colored abrasion on each glass fiber. U.S. Patent No. 5,5 2,4,164, discloses a cable assembly containing numerous ribbon assemblies. Common coverings that bind strip components together contain ingredients that have poor compatibility with the main ingredients in general coatings. Examples of such poorly compatible ingredients include hydrocarbons having 10 to 20 carbon atoms, silicone oils and fluorine oils. Poorly compatible components reduce friction between ribbon components to prevent damage to the fiber when the cable is bent. Poorly compatible ingredients provide " ocean " and " discontinuous layers of island salamanders' on the common coating. There is no disclosure or teaching related to the mid-span access method for the individual coated glass fibers contained in the ribbon module. U.S. Patent No. 5,561,730 discloses a cable comprising a plurality of ribbon-shaped units. A common covering that binds the band-shaped components together. Its wood-paper if scale describes Chuan '丨' same cause elephant generation (CNS > ΛΊ (2Ι0Χ29 ·) ^ ίί) .J. History of the Ministry of Economic Affairs? ί · ^; Η4 消 f Cooperative printed in Λ7 _ I! 7 V. Description of the invention (5) Contains release agent. Examples of such release agents are silicone oils and fluorine oils. The release agent composition reduces friction between the ribbon components to prevent damage to the fiber when the cable is bent. There is no disclosure or teaching related to giving mid-span access to the individual coated glass fibers contained in the ribbon assembly. US Patent No. 5,62,8,8,8 discloses that A coated glass fiber unit composed of a plurality of coated glass optical fibers bound together by a binding layer. The ink coated on the glass fiber and the common bundling layer are treated to suppress the adhesion between the layers so that the bundling layer can be removed from the ink layer. A silicone release agent or a fluorine release agent is added to the ink coating and the common binding layer. If silicone-based release agent and fluorine-based release agent take too long, it will cause unfavorable degradation of the internal basic coating and the external basic coating. When the release agent is bound by the coating, they can adhere tightly to the coating. Release agents are often incompatible with the desired coating composition. Therefore, traditional silicone release agents and fluorine release agents can only be used in small amounts, such as less than 5% by weight. "If the traditional release agent is used in an amount of more than 5%, it will cause matrix substances and The swelling of the ink coating will gather between the substrate and the ink coating layer, causing the substrate to be inevitably peeled off by the glass fiber, thereby reducing the protective function of the substrate substance. In the coating of glass optical fibers, it is also inappropriate to use a release agent mainly composed of acrylated silicone and a release agent mainly composed of fluorine. For example, these types of release agents are often incompatible with the ingredients in the ink coating. The use of these types of release agents can also cause unsuitable changes in the properties of the ink coating. Wood and paper scales of the national valve (CNS) Λ4'ΐΰΓϊΊϊοχΙ ^ ΐ ^ ~~ Τβ-. (ΪΑ first wlift in the back: · / .τ. &Amp; city items · ίΓ} · ίΛscript π} Order Λ 7 in five 'invention description (6) As the demand for coated glass fiber increases, manufacturers must respond by adding more fiber drawing lines and trying to increase the speed of existing fiber drawing lines. Later In the example, a factor that determines the upper limit of the line speed is the curing rate characteristics of the curable ink composition under the specified irradiation source and intensity. AI ▲ • ft Fire in the warp section? Ί , · Ακ 工 消 ". If the speed of the production line is increased to a speed that does not provide the time required for the curing of the radiation-curable ink composition, the radiation-curable ink composition will not receive enough The amount of radiation to cure the curable ink composition is completely cured or crosslinked. The speed of the production line is usually inversely proportional to the amount of radiation to the glass fiber. In other words, when the speed of the production line is increased, it is constant. As for the source, the amount of radiation that is irradiated to the curable ink composition during the production process will inevitably decrease. The insufficient curing of the curable ink composition is not desirable, and must be avoided, Because the incompletely cured ink coating does not meet our required properties, and / or the incompletely cured ink coating still has stickiness (which will cause problems in subsequent processing), or there is a foul odor, and The extractables (which we do not want) that are considered to be cured by the ink coating will also increase, and the coated glass fiber will have insufficient adhesion. Although the ink composition must have a very fast curing speed to ensure The ink coating on the high-speed wire drawing tower is completely cured, but other important properties of the ink coating cannot be sacrificed in order to improve the curing speed. For example, when the ink coating is used in a ribbon component, it will give appropriate mid-span access. The curable ink composition must exhibit adaptable adhesion properties to provide a coating that is more resistant than ink coatings and substrates. The adhesion between substances is even greater

Wood paper scale Shizhou 屮 Four Valves 枣 Pillow Jujube (CNS) 2KVX2V7; JI ;:) Q A7 H7 V. Description of the invention (7) Adhesion between the basic coating on the outside and the coating on the ink 'for mid-span access . In addition, the ink composition should not contain ingredients that would migrate to the surface of the glass fiber and cause corrosion. The ink composition should also not contain ingredients that cause instability in protective coatings. The ink coating of glass optical fiber should be able to be colored quickly for ten years, without causing attenuation of signal transmission, not penetrated by cable glue and chemicals, and allow a sufficient amount of penetration into the center of the optical fiber. From the above, we understand that glass fiber technology places many unique needs on irradiating curable ink compositions, while more traditional technologies, such as printing inks, do not. Irradiation curable ink compositions need to provide mid-span access and avoid the problems associated with traditional fluorine-based release agents and silicone-based release agents. Generally, the ink composition to be cured must be in an inert atmosphere, that is, in an oxygen-depleted state. Providing an inert atmosphere on a glass fiber drawing tower is quite expensive. Therefore, a radiation curable Shan ink composition that exhibits a high curing speed in the presence of air must provide significant benefits over the ink composition that can be cured in an inert atmosphere. Summary of the invention The object of the present invention is to provide a glass fiber optic ribbon module, which has the functionality of imparting mid-span access without using fluorine-containing or silicone-containing additives, monomers, or polymers of homogeneous molecular weight. Efficacy "Another object of the present invention is to provide a suitable paper and paper scale suitable for forming a belt-shaped component. / TROHm (CNS) Λ4 now 怙 (2 丨 77n ~ (ΐ Λ ^ read between the back notes " V term (Notes for this article) • -β H7 ____ V. Description of the invention (8) Irradiation-curable substrate-forming composition. A further purpose is to provide radiation-curable ink composition 'when it is in a ribbon component When properly cured and used, imparts mid-span access to individual coated glass optical fibers. Another object of the present invention is to provide radiation curable which can be cured in the presence of air and still impart mid-span access. Ink composition.-• so By formulating the radiation-curable ink composition to contain the homogeneous molecular weight polymer for viscosity adjustment according to the present invention, we have surprisingly found that an ink coating can be formed on a coated glass fiber It imparts the functional performance of mid-span access to tape components without the use of fluorine or silicone-containing release agent additives. In particular, the polymer matrix formed by the novel ink coating composition according to the present invention It is essentially suitable for giving mid-span access. The invention provides a novel radiation-curable ink coating composition, which is suitable for forming an ink coating on a glass optical fiber. Functional group that can be cured by irradiation, and is not substantially a viscosity adjustment of silicone and fluorine, which is formulated with a composition of a homogeneous molecular weight polymer. It contains: a plurality of coated glass optical fibers; and a matrix substance that binds the aforementioned plurality of coated glass optical fibers together, wherein at least one of the aforementioned coated glass optical fibers contains a coated optical glass, It also includes: glass fiber; there is more than one layer of coating on the aforementioned glass fiber; wood paper size is applicable to the 'I' valve S house m · (CNS) (2Ι 〇 × 2Μ7; > ν). 1: Λ7 H7 V. Description of the invention (9) The above-mentioned one or more coated ink coatings are prepared by a composition containing: a homogeneous molecular weight for adjusting adhesion Polymer, which has more than one type of radiation-curable functional groups connected to the backbone with low surface energy, and is substantially not silicone and fluorine. The present invention further provides a radiation-curable matrix prepared by the || A composition for formation, which comprises: an oligomeric molecular weight polymer for adhesion adjustment, which has more than one type of radiation-curable functional group connected to a low surface energy backbone, and is substantially not silicone and fluorine. The invention also provides a novel ribbon-shaped module, which exhibits the property of giving span access in individual glass optical fibers without using silicone release agent and fluorine release agent in the ink coating or matrix substance. The ribbon components include: 'Many coated glass optical fibers; Ten clips of the furnace department: ΪΝίΓΛPrinted by a consumer cooperative (near nine back-notes & matters-pi-fill rtT 本 τί) Many glass optical fibers are bound together by a matrix substance formed by a composition that contains more than one type of radiation-curable functional group attached to a low surface energy backbone and is substantially non-adhesive of silicone and fluorine A homogeneous molecular weight polymer is used for force regulation. Detailed description of suitable examples According to the improved radiation-curable ink coating composition of the present invention, it is possible to provide mid-span access without using additives. In particular, the ink composition is suitable for providing a three-dimensional cured ink coating 'cross-linked polymer paper recognition standard. Shizhou Zhongshou Valve House Pillow (CNS) (210X 297 * / *.). 12-A7 H7 V. Description of the Invention (10) (ΪΛRead First. Weeping Back to the Market Item- / 1- * ¥!.: '5 本 Jr) The matrix exhibits the inherent properties that confer mid-span access. Giving mid-span access in this way is very different from the way additives are used. However, if desired, a conventional release agent can be added to adjust the properties of the desired ink composition. The improved ink composition of the present invention may be any ink composition known for coating and identifying coated glass optical fibers. Generally, the radiation-curable ink composition contains more than one pigment dispersed in a radiation-curable carrier system. However, a pigment-free, clear ink coating can be formed as desired. The use of a novel radiation-curable carrier-adjustable homogeneous molecular weight polymer in a radiation-curable carrier system can transform a conventional ink composition into an improved ink composition according to the present invention. Surprisingly, the homopolymer of the molecular weight used for the adhesion adjustment can even be used as the main homopolymer of the radiation-curable carrier system. Alternatively, the improved ink composition according to the present invention may be prepared by mixing a homogeneous molecular weight polymer and a pigment, a diluent monomer, and other homogeneous molecular weight polymers for adhering force adjustment. The ink coating composition is doped with fluorine and silicone to impart mid-span access. It has been found that fluorine and silicone reduce the surface energy of the resulting ink coating. I am convinced that this low surface energy will reduce the adhesion strength between the ink coating and the matrix material in the following methods. When using liquid matrix materials, low surface energy often results in poor wetting. Poor wettability results in a reduction in surface area contact, which reduces the adhesion between the matrix material and the ink coating. The present invention provides reduced surface energy without the use of fluorine and silicone. In this paper, the standard ten-valve valve (CNS) AWt (2IOx 297 * i ;: > _ 13-Λ7 Η7 V. Description of the invention (11) The homogeneous molecular weight polymer for adhesive force adjustment is used. Low surface energy backbones can reduce surface energy. Low surface energy backbones have prominent hydrocarbon side chains that reduce surface energy. Examples of suitable low surface energy backbones include hydrocarbon backbones and polyester backbones. More suitable Low molecular weight polymer of low molecular weight polymer for adhesion adjustment. Low molecular weight polymer of high molecular weight polymer for adhesion adjustment. Exists in the amount of ink coating that can provide the surface energy of the top contact angle with the following degree: 65 ° The above is suitable, more suitable is about 70 ° or more, more suitable is 75 ° or more, and more than about 80 ° is most suitable, and the traditional silicone-containing compound and fluorine-containing compound do not need to be used. It can be used to formulate the ink coating composition, which substantially avoids silicone release agents and fluorine release agents, and avoids other traditional release agents, which is given in proper curing. It is even more surprising when accessing from a distance, that even if the ink composition is cured in air, it can provide such properties. Representative examples of homogeneous molecular weight polymers for adhesion adjustment include including more than one type of low surface energy backbone Irradiation-curable functional groups are homogeneous molecular weight polymers. Irradiation-curable functional groups can be ethylenically unsaturated, which can be polymerized by free radical polymerization or cationic polymerization. Special examples of suitable ethylenically unsaturated, Contains acrylate, formamidine acrylate, styrene, vinyl ether, vinyl ester, N-substituted acrylamide, N-vinylamine, maleate, and fumarate. Suitable ethylenically unsaturated systems Contains acrylate, methacrylate, and N-vinyl functional providers. Wood paper ift scales (?) (CNS) and Chuan Ming (2l0x2 < i7. ^] F. T ~. 14 ~-~ (771 first reading from the back ^ Sun fill ^ this ^)

Λ7 Η7 V. Description of the Invention (12) First, a polymer of a homogeneous molecular weight for the adjustment of adhesive strength mainly composed of polyester will be described. The radiation-curable functional group may be directly bonded to the polyester backbone 'or may be connected to the polyester via a linking group. Examples of suitable linking groups include urethane, urea, and ester groups. Polyesters, which are mainly homopolymers for adjusting adhesion, usually have a number average molecular weight of about 500 to 10,000, and preferably a number of about 10,000 to 8,000. Polyesters generally have about 2 to 40, preferably about 3 to 20, and most preferably about 5 to 15 equivalents of ester groups. Polyesters contain hydrocarbon side chains that protrude from the backbone of the polyester. Without being bound by any theory, I believe that the prominent hydrocarbon side chains give the cured ink coating the ability to detach from the surface of the matrix material to provide a matrix substance adhesion layer. In particular, we believe that the hydrocarbon side chains are entangled with non-chemical compounds to achieve sufficient adhesion between the ink coating and the matrix material to reduce the surface energy of the ink coating to avoid undesired peeling. When the combination of entanglement and non-composite property can provide adhesion, the combination of entanglement and non-composite property is destroyed during mid-span access, which can provide a clean, bare ink-coated glass fiber and matrix substance adhesion layer. It is that the position of the hydrocarbon side chain is close enough to the ester group, and it can hinder the chemical attack of the ester functional group. For example, the hydrocarbon side chain may be located on the alpha carbon of the ester functional group to cause steric hindrance. Therefore, surprisingly, we have found that hydrocarbon side chains can be applied for two purposes: (1) reducing the surface energy of ink coatings, and (2) providing the hydrolytic stability of the coated polyester backbone. Wooden paper scales are applicable to the Chinese government officials (('NS) 4 况 况 (2Ι0χ? 97 疔). 15-(诮 reading vj & 肀 4 items, !!:? Π) * 1Τ Λ7)) Ί 5. Description of the invention (13) 读 Read memorandum and note * 氺 ## This page) The hydrocarbon side chain should be a homogeneous molecular weight polymer to reduce adhesion The amount of surface energy capability of the ink coating exists. It is desirable that the number of homogeneous molecular weight polymers used for adhesion adjustment is at least about 5%, more preferably at least about 10%, and at least about 15% is more suitable, which is composed of hydrocarbon side chains. The method of using hydrocarbon side chains to reduce surface energy is generally applied to all polymerized backbone types, and is not limited to polyester. The amount of hydrocarbon side chains should not be so large as to produce undesirable properties such as the viscosity of the uncured ink coating composition is too high, or the strength and / or tensile strength of the cured ink coating is too low. Therefore, the part of the average molecular weight of the homogeneous molecular weight polymer for adjusting the adhesion of the hydrocarbon side chain should be less than 40%, more preferably less than 30%, and most preferably less than 20%. A suitable hydrocarbon side chain is substantially uniformly dispersed on the polyester backbone. "A particularly suitable structure is a comb-like structure, in which the hydrocarbon side chains are like comb teeth protruding from the comb trunk. However, the hydrocarbon side chains can protrude from the polyester backbone in different directions, as opposed to the comb teeth of the two-dimensional comb. A suitable hydrocarbon side chain is a lower alkyl group or an alkyl-substituted aryl group, which has 3 to 30 carbon atoms, preferably 5 to 20 carbon atoms, and more preferably 5 to 15 carbon atoms. Alkyl and / or alkyl-substituted aryl groups can be linear, branched or cyclic as desired. Therefore, the following groups are suitable: propyl, n-butyl, isobutyl, 2-ethylbutyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, Dodecyl, tetradecyl, propylphenol, butylphenol, pentylphenol, hexylphenol, heptylphenol, octylphenol, nonylphenol. A linear alkyl group or a branched alkyl group is preferred. When using an aryl group substituted by an alkyl group, the basic paper size of the alkyl group is suitable for Zhongzhou Valves <:? Net (CNS) Λ4 叱 彳 Μ 2 丨 〇 X 2V7 male film ~) ~ Λ7 H7 V. Invention It is indicated that the (14) group is preferably in the para position of the aryl group bonded to the polyester backbone. The hydrocarbon side chain is preferably a lower alkyl group. The ester functional group in the polyester backbone is preferably at least about 50%, more preferably at least about 70%, more preferably at least about 90%, and substantially all of the ester functional groups are hindered by the hydrocarbon side chain. Obstacles are most appropriate. The polyester backbone of a homopolymer of adhesive strength can be formed by any suitable method. As disclosed in this article, those skilled in the art can make the required polyester backbone. For example, the following method is suitable for producing a polyester backbone having a hydrocarbon side chain. (1) A hydroxycarboxylic acid is reacted with a polyol to obtain a polyester having a hydrocarbon side chain. Branching the polyol and / or hydroxycarboxylic acid to obtain a hydrocarbon side chain protruding from the polyester backbone. Alternatively, the hydroxycarboxylic acid and / or polyol may contain non-terminal hydroxy-functional groups. Based on the principle that they can react with carboxylic acids to form ester groups, side chains are also formed during the formation of the polyester backbone. (2) A polycarboxylic acid is reacted with a polyol to obtain a polyester having a hydrocarbon side chain. Branching the polyol and / or branching the polycarboxylic acid to obtain a hydrocarbon side chain protruding from the polyester backbone. Alternatively, the polyhydric alcohol may contain a non-terminal hydroxyl functional group. Based on the principle that it can react with a carboxylic acid to form an ester group, a side chain is formed in the polyester backbone. Adhesiveness is adjusted by using a polyester backbone of a homogeneous molecular weight polymer, which is formed by reacting a suitable hydroxycarboxylic acid with a suitable glycol. As used herein, the term hydroxycarboxylic acid includes hydroxycarboxylic acid fatty acids. The hydroxy-functional carboxylic acid preferably has about 4 to 30 carbon atoms, and more preferably has about 8 to 24 carbon atoms. Examples of suitable hydroxycarboxylic acid fatty acids include hydroxyoctanoic acid, wood-paper scale Tongchuan '丨' valve 阂 home 栉-; V- U'NS) (2Ι0 × 297.:. ≫) 1) _ 17 _ adjacent (You especially read the city item 4 ^ .¾ page)

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R3 1 I-1 CI _ • TC 1 .R4 y L r5 I 〇II C- OH ⑴ u Λ7 H7 V. Description of the invention (15) Hydrodecanoic acid, dodecanoic acid, hexadecanoic acid, hexadecanoic acid , Hydroxystearyl carbonate, hydroxyoleic acid, linoleic acid, and hydroxylinolenic acid. Specific examples of suitable hydroxycarboxylic acids include 12-hydroxyoctadecanoic acid, 2-hydroxy_4-methylvaleric acid, 12-carboxy-4-octyl-dodecanoic acid, 5-dodecyllactone, 19- Hydroxyl-10-hexyl-nineteen carbon number, and 16-hydroxy-4_nonyl-1 1-butyl-hexadecyl carbon number. Examples of commercially available suitable paracarboxylic acids include P-10 acid from Cas Chem Inc. The hydroxycarboxylic acid suitably possesses a structure that results in a polyester having a hydrocarbon side chain when a hydroxyl functional group is reacted to form an ester group. If a branched hydrocarbyl functional hydroxy acid is used, the hydroxy function will be at the end. However, if a linear hydroxycarboxylic acid is used, non-terminal hydroxy functional groups should be present so that when the hydroxy functional group reacts to form an ester bond, a hydrocarbon side chain bonded to the polyester backbone is formed. The hydroxycarboxylic acid fatty acid may contain more than one hydroxy group. It is preferred that the hydroxycarboxylic acid fatty acid contains only one unsaturated bond. The hydroxycarboxylic acid preferably contains more than one hydrocarbon side chain, as represented by the following chemical formula (1):

Ri I

HO-C I ί r2 where: Η = hydrogen atom; 〇 = oxygen atom: R 1, R 2, R 3, R 4, R 5 and R 6 = Η or hydrocarbon side chain. Elephant (CNS) (210X297 * — 'ίΛ first read 诮 t and jiang * water item # fill.rcr 本 H) Order A7 Η 7 V. Description of the invention (16) However, at least one of R 至 to R 6 is For the hydrocarbon side chain, it is not necessary that both R ^ and R 2 are Η; and 3 of X + Υ + Z is preferably 5 and 10 is more suitable. The hydrocarbon side chain is preferably close enough to the ester group formed by the reaction of the hydroxyl group and the carboxylic acid group, so that the hydrocarbon side chain can hinder the chemical reaction of the ester functional group. For example, ester groups are easily hydrolyzed in the presence of moisture. However, we found that if the hydrocarbon side chain is placed at a critical position, it can hinder the hydrolysis reaction. Therefore, ink coatings based on polyesters with sterically hindered ester groups are more resistant to chemical reactions in nature. An example of a polymer of homogeneous molecular weight suitable for adhesion adjustment can be represented by the following non-limiting chemical formula. The components listed in the formula react with P-(BHCA) m -1-R (2) P-(( BHCA) mA- (BHCA) ml) nR (3) Rl-((BHCA) mA- (BHCA) ml) nR (4) where BHCA is a branched hydroxycarboxylic acid and / or contains non-terminal hydroxyl functional groups Hydroxycarboxylic acid, which is bonded when a hydroxy-functional reaction occurs

* 1T A hydrocarbon side chain on a polyester backbone to form an ester group; I is a polyisocyanate compound: A is a polyol; P is a compound containing more than one hydroxyl functional group; R is a functional group containing curable radiation Zhixiang functional compound; The paper size is appropriate / 丨] in the national valve; V · (CNS) Λ4 ^, (210X297 ^ /;) 7 ^ 9 _ M7 V. Description of the invention (17) n = l to 20 About 1 to 10 (on average): and m = about 1 to 50, about 1 to 30 (on average) 〇 The homogeneous molecular weight polymer for adjusting adhesion according to the present invention, Not limited by Chemical Formulas 2 to 4. For example, using a polyhydric alcohol having two or more hydroxyl functional groups, the homogeneous molecular weight polymer for adhesion adjustment may contain a branched polyester backbone. However, a linear polyester backbone having carbon-containing side chains as shown in Chemical Formulas 2 to 4 is desirable. ^ Branched polyesters excluding linear polyester A with carbon-containing side chains. Only polyesters containing side chains composed of complete monomer units are considered to be a branched polyester A. '" The use of branched chains and side chains is described in Odian, Principles of Polymerization, third edition, pgs 17-19. These pages are incorporated herein by reference. In the Ministry of Economic Affairs, Chemical Engineering Co., Ltd. is printed. In Chemical Formulas 2 to 4, isocyanate groups react with hydroxyl groups to form urethane bonds, which is a well-known reaction. The hydroxycarboxylic acid is polymerized to form a polyester backbone of a polymer having a homogeneous molecular weight polymer for adjusting adhesion. The use of a hydroxycarboxylic acid mixture can be used to modulate the properties of the polyester as required. The water formed during the formation of the ester groups can be removed by any suitable method, such as distillation.之后 After the polyester backbone is formed, the terminal hydroxycarboxylic acid group of the resulting polyester is reacted with the polyisocyanate and hydroxyl-functional radiation-curable functional groups to generate urethane between the polyester backbone and the radiation-curable functional groups key. Functional groups that can be cured by irradiation can also be bonded to positions other than the terminal position of the polyester backbone. -20- ----II ----I (" 'Nine readings back to note & market items " " 本本 乃) Wooden paper scale through; 0, 丨 '囡 prisoner (CNS) (2IOX2W Public Office) Λ7 Λ7 Μ: Ministry k if i? · Eliminate i · Cooperative Du Yin v. V. Description of the invention ( 18) Place it on. These reaction patterns are well known in the art, and those skilled in the art can easily make the desired polymers according to the disclosure. The radiation-curable functional group may be attached to the polyester backbone via any suitable. For example, a polyester backbone that retains carboxylic acid functional groups can be formed. The carboxylic acid functional groups can react with the hydroxyl groups of a curable compound that is irradiated to form an ester bond between the polyester curable compounds. In the first example, " A " may be an alkyl polyol having about carbon atoms, preferably about 5 to 30. The polyol may be linear, or an alcohol as desired. Suitable polyols have a hydrocarbon side chain that protrudes from the alpha carbon atom to the hydroxyl functional group. Suitable hydrocarbon side chains include the hydrocarbon side diols described earlier herein. Where appropriate, polyols can be used to provide the required levels. Examples of suitable diols include the following structure (5) R; Re

I I HO-0¾-C2 -I I R9 Ri〇 where Η = hydrogen atom; 〇 = oxygen atom;

Ci = hydroxy-functional α-carbon atom (5) Therefore, it is a homogeneous molecular weight linking group that is good at this. The ester-based trunk is still a hydroxyl-functional trunk and the branch is a multivalent or positional chain with 2 to 50 carbon atoms Included. When branching is included: I! ----- I _ I ::-/ -I: I ---- I-Τ--n I ---- I-ί ϋ- (ΪΛ1 间 1Α Back note & ^-item # > /ι·.ν* This book) Wood paper thick scale suitable / Π, 丨, country home; (tv. (CNS > Λ4 悦 你 (2Ι〇χ2 ( ) ·; * Ίί >. 21

Ο ο CH-, 2 c IR c— H o H 7 Λ7 B7 V. Description of the invention (19) C 2 = carbon atom of hydroxyl functional group; and R 7, R 8, R 9 and R 1 〇 = each is Η or smoke part 'but R7, R8, R9 and Ri. Not all Η and R7, R8, only 9 or R1. At least one is preferably a hydrocarbon side chain as described in this specification. The hydrocarbon moiety, R 7, R 8 'R 9 and R 1. 'Can hinder the chemical reaction of the polyester formed by the reaction between the hydrocarbon functional group and the carboxylic acid. As previously discussed, ester groups are easily hydrolyzed in the presence of moisture. However, a portion of the hydrocarbon may hinder the hydrolysis reaction. Therefore, ink coatings based on polyesters with this structure are essentially more resistant to chemical reactions. Particularly suitable diols are represented by the following chemistry (6): where Η = hydrogen atom; 〇 = oxygen atom; C = carbon atom; and R 1 1 and R! 2 are each fluorene or a hydrocarbon side chain , But R 1 1 and R〗 2 are not all Η. Conveniently, Rii and Ru are all alkyl groups having about 1 to 12 carbon atoms, and alkyl groups having about 2 to 6 carbon atoms are most suitable. It is expedient that at least one of R 1 1 or R: 2 is a hydrocarbon side chain described in this specification. Special examples of suitable polyols include: 2-methyl-1,3-propanediol; 2,2-bis Methyl-l, 3-propanediol; ---------- 乂 ------ iT ·-^ ---- r 丨 ϋ (171 先 读 ####埃 s 本 s) The paper ift octave / 0 屮 valve mm. (CN! 5 > 44 叹 was inferior (2ΙΟΧ 297, »ίί). _ 22-Λ7 Λ7 Τ; Elimination of cooperative printing— ^ ________ V. Description of the invention (2〇) 2 ~ ethyl-1'3-propanediol; 2,2-diethyl-1'3-propanediol; 2-propyl-1 2-methyl-1,3-propanediol; 2-propyl-2__ethyl-1,3-propanediol; 2-butyl-2-ethyl-1,3-propanediol; 2-cyclohexyl 2-methyl-1'3-propanediol; 2-phenyl-2-methyl-1,3-propanediol; 1,2-propanediol; 1,4-butanediol; '1,6-hexane Diols; 1,2-cyclohexanediol; 1,3-cyclohexanediol; 1,4-cyclohexanediol; Cyclohexanedimethanol: 2,2-dimethyl-4 4 Dimethyl-1,5-pentanediol t Ethylene glycol: diethylene glycol; dipropylene glycol; 1,9-nonanediol, etc. and mixtures thereof. If necessary, they can be used together Molecular weight polymer polyol. A suitable homogeneous molecular weight polymer polyol is a diol. If homogeneous molecular weight polymer diol is used, on average it is preferred to have at least about two hydroxyl groups. The homogeneous molecular weight polymer averages Say, you can have more than 2 kinds of basic paper sizes for diameter basis. Applicable to the national government (CNS) Λ4 ^ ((210X2 ^ 7 ^ /; --------- (-{»? 前 间Note from the bottom of the page * The market item scarcely fills the VCT book KK) * 1T Λ7 ___________137 ___________ V. Description of the invention (21) (" Please read the back note of f item 4: This S) group. Polyols have more than two types of hydroxyl groups, which can form branched molecular weight polymers for adjusting the adhesion. Examples of suitable glycol molecular polymers include polyether diols, polyolefin diols, and polyesters Diols, polycarbonate diols, and mixtures thereof. Polyester diols are preferred. If polyether diols are used, the polyethers are A suitable non-microcrystalline polyether contains more than one of the following monomer groups: -〇-ch2-ch2-〇-; -〇-ch2-ch-o-; -o-ch2-ch2-ch2-o- ; Ch3 -o-ch2-ch2-ch2-ch2-〇-; -o-ch2-ch-ch2-ch2-〇- · I 'ch3 -0-CH-CH2-CH2-CH2-0-; -0- CH-CH2-0-; and suitable polyethers are repeating units I CH.-CH, furan, treated as polyether dimethyl-tetramethylated products, branched and non-0 0 0 (poly Hodogaya used

, 1T

I ch3 ch3

I -0-CH2-C-0- ·

Ich3 polyether glycol can be made of ethylene oxide, propylene oxide, tetrahydromethyl-substituted tetrahydrofuran, butylene oxide, and the like. An example of a polyether that can be used as an alcohol is the polymerization of 3% by weight of 3% hydrogen furan and 80% by weight of tetrahydrofuran. Both of them are ring-opening polymerization. This polyether copolymer contains branched oxyalkylene repeating units and is sold as PTG — L 1 Hodgaya Chemical Company of Japan). Another example of ether ether diol is PTG — L 2 0 0 0 (wooden paper hate scale / 丨] '丨' inner circumference 丨 Du Zhun ([~ 5) eight 4 叱 诂 (2 丨 0 '乂 297 male; !;.) _24 Λ7 _________ »7 ____ ____ 5. Description of the invention (22)

Chemical Company). If a polyolefin diol is used, the polyolefin is preferably a linear or branched hydrocarbon containing many hydroxyl terminal groups. A suitable hydrocarbon is a non-aromatic compound containing most of the methylene groups (-CH2-), and it may contain internal unsaturation and / or prominent unsaturation. Fully saturated. For example, argonized hydrocarbons are preferred because the decrease in unsaturation increases the long-term stability of the cured optical fiber coating. Examples of hydrocarbon diols include, for example, hydroxyl-terminated, fully or partially hydrogenated 1,2-polybutadiene; 1,4-1-1, 2-polybutadiene copolymer, 1,2-poly Butadiene-ethylene or propylene copolymers, polyisobutylene polyols, mixtures thereof, and the like. The hydrocarbon diol is preferably a substantially, fully hydrogenated 1,2-polybutadiene or a 1,2-polybutadiene-ethylene copolymer. Examples of polycarbonate diols are conventionally prepared by glycol alcoholysis of diethylene carbonate. The diol may be, for example, an alkylene glycol having about 2 to 12 carbon atoms, such as 1,4-butanediol, 1,6-hexanediol, 1,12-dodecanediol, and the like. We can also make mixtures of these diols. In addition to carbonate groups, the backbone of polycarbonate diols may contain ether bonds. So, for example, we can use polycarbonate copolymers of alkylene oxide monomers and the alkylene glycols previously described. The alkylene oxide monomer includes, for example, ethylene oxide, tetraoxetane, and the like. These copolymers produce a cured coating, which exhibits lower strength than a polycarbonate diol homopolymer and suppresses the crystallinity of the coating composition in a liquid state. We can also use blends of polycarbonate diols and polycarbonate copolymers.

Polycarbonate-alcohols include, for example, Duracarb 122 (PPG -25 (571 readings and notes 4¾¾'benda)

* 1T Λ7 Λ7 -26- Β7 V. Description of the invention (23)

Industries) and Permanol KM 1-1 7 3 3 (Permuthane Inc., Ma.). Duracarb 122 is produced by the hydrolysis of diethyl carbonate with hexanediol. Examples of polyester diols include: saturated polycarboxylic acids, or their anhydrides, and reaction products of diols. Saturated polycarboxylic acids and anhydrides include: for example, phthalic acid, isophthalic acid, terephthalic acid, trimellitic acid, tetrahydrophthalic acid, hexahydrophthalic acid, tetrachlorophthalic acid, adipic acid Acid, azelaic acid, sebacic acid, succinic acid, glutaric acid, malonic acid, pimelic acid, suberic acid, 2, -dimethylsuccinic acid, 3,3-dimethylglutaric acid , 2,2-dimethylglutaric acid, etc., their anhydrides, and mixtures thereof. Diols include, for example, 1,4-butanediol, 1,8-octanediol, diethylene glycol, 1,6-hexanediol, dimethylolcyclohexane, and the like. Included in this classification are polycaprolactones, commercially available from Union Carbide under the trade name Tone Polyol, such as Tone 0200, 0221, 0301, 0310, 2201, and 2221. Tone Polyol 〇 3 0 1 and 03 10 are trifunctional. The polyhydric alcohol is preferably present in a smaller amount than that of the hydroxycarboxylic acid. Polyol " A 〃 is preferably present in a weight percentage of about 10% or less, and more preferably in a weight percentage of about 7% or less. It is based on the reaction used to produce a homogeneous molecular weight polymer for adhesion adjustment Total weight. Any organic polyisocyanate, either alone or in combination, can be used as a polyisocyanate. Examples of suitable diisocyanates include isophorone diisofluoroate (IPDI), toluene diisocyanate ( Tiger (cns) 圯 彳 f, (210x2 ^ 7 ---------: κ ------ IT one-: ^ I (read first. Note to the back Please read the booklet for the matter) -27- Λ7 ____ _ til ___________________ V. Description of the Invention (24) TDl), Tetramethylene xylene diisocyanate (TMXDI), Diphenylmethylene diisocyanate, Hexamethyl diisocyanate, Cyclohexylene diisocyanate, methylenedicyclohexane diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, m-phenylene diisocyanate, 4-chloro-1, 3-phenylene diisocyanate, 4, 4 > -phenylene diisocyanate, 1,5-naphthalene diisocyanate, 1,4-tetramethylene diisocyanate, 1 '6-hexamethylene diisocyanate, 1, 10-decamethyl diisocyanate, 1, 4 ~ Cyclohexylene diisocyanate, with polyalkoxide and polyester glycol diisocyanate, such as TD I as terminal Polytetramethylene ether glycol and TD I-terminated polyethylene adipate. Polyisocyanate is preferably TDI, TPDI or TM XDI. We can use any suitable hydroxyl-functional radiation curable Compounds. Such compounds with (meth) acrylate functional groups include, for example, hydroxy-functional acrylates such as 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, etc. Compounds with vinyl ether functional groups include: For example, 4-hydroxybutyl vinyl ether and triethylene glycol monovinyl ether. Compounds having maleate functional groups include, for example, maleic acid and hydroxy functional maleate. 0 hydroxyl groups capable of providing epoxy functional groups. A functional compound is, for example, a chloromethoxypropane ring that can react with the hydroxyl group of a homopolymer, a diol, or a compound with more than one epoxy group, and the hydroxyl group can react with a polyisocyanate, such as bisphenol A. The homopolymer of double epoxy resins can provide hydroxyl-functional compounds of the amine or thioene system, and it can be used on wood paper (CNS) (210 × 297 ^ '] ί ~ --------- ^ ------ ir —— ^ -----. 4- (邙 read first note and note- & events ^ 衿 本(Order) ___B7 V. Description of the invention (25) Contains, for example, allyl unsaturated, or tertiary amine or sulfur driving groups. Therefore, the reaction of isocyanate with trimethylolpropane allyl ether can impart adhesion adjustment The use of homopolymers with allylic unsaturation, or the reaction of isocyanates with amine-gathering compounds can impart amine functional groups to homopolymers with homopolymers for adjusting adhesion. Such compounds include, for example, trimethylolpropane, an adduct of isoflurane diisocyanate and diethyl (methyl) ethanolamine, an adduct of hexanediol, isoflurane diisocyanate and dipropylethanolamine And adducts of diethylethanolamine, dimethylethanolamine, or dipropylethanolamine. Polyols, polyisocyanates, and hydroxyl-functional radiation-curable compounds are based on the use of 1 equivalent of the hydroxyl functional group of the polyol. The ratio of the isocyanate functional group contained in the polyisocyanate of about 1.1 to 1.3 equivalents and the hydroxyl functional group contained in the hydroxyl-functional radiation-curable compound of about 0.2 to 1.5 equivalents is suitable for the reaction. My hope is that the equivalent of the hydroxyl functional group in the polyol and the hydroxyl functional radiation-curable compound is almost equivalent to the equivalent of the isocyanate group in the polyisocyanate. In the reaction of these compounds, a catalyst can be used for the urethane formation reaction. Examples of suitable catalysts include: copper naphthenate; cobalt naphthenate; zinc naphthenate; n-butyltin dodecanoate; triethylamine; 1,4-diazobicyclo (2,2'2) octane Alkanes; and 2,6,7-trimethyl-1,4-diazobicyclo (2,2,2) octane. The catalyst is usually used in an amount of about 0.01 to 1 part by weight per 100 parts by weight of the reaction raw material. The reaction temperature is generally in the range of about 10 t to 90 ° C. A suitable range is about 20T: to about 80 ° C. General Secretary General CNS (210X297. ^ 处 ~) — ~ 2Q ~. II--I--I---1--II- < I Hi HI-: I --- m Ding --1 nnn _,-Λ '^, Tn (¾ read it first. Remember the city and then fill out this page) Λ7 1Π From the entropy ministry: 屮 Industry and Consumers Cooperatives Explanation (26) 1 I Particularly suitable adhesive force adjustment is represented by the following molecular formula polymer 1 1 | (7): 1 1 R _ I-. ((BHCA) s--A-(BHCA) V — 1 1 I ν '1 I) WR (7) λ 1¾ 1 | The homogeneous molecular weight polymer (7) is prepared by reacting the following components if 1 1 1 | Italian IR = hydroxyl-functional, curable by irradiation Compound; Minor item 1 1 I == polyisocyanate compound; 4 f% of the unit B Η CA = branched or containing a non-terminal hydroxy-functional hydroxycarboxylic acid T \ V_ ^ 1 1 acid > reaction at the hydroxy-functional group Carbon is attached to the polyester backbone Chain 1 | y to form an ester group; 1 IA = polyol; 1 order 1 W = about 1 to 2 0, preferably about 1 to 10, and about 1 to · 15 is most suitable: and 1 1 S + V = about 4 to 20, preferably about 5 to 15) 1 1, and about 1 2 is most suitable (on average) ° Or, according to the body; f curable. Water I functional group R // Because the hydroxyl function of 1 R " reacts with the carboxylic acid function of 1 1 on the polyester backbone to form an ester bond, and it is directly bonded to the polyester backbone 0 1 1 This way t can avoid the use of polyisocyanate Ethyl cyanate · 1 1 A particularly suitable release-molecular-weight homopolymer is poly (hydroxyoctadecanoic acid) 1 I urethane acrylate, which is represented by the following homopolymer (8) instead of 1 I 1 1 Η A 1 I —P 〇1 y (HSA)--I Η A (8) 1 1 The homogeneous molecular weight polymer (8) is made of the following ingredients: 1 1 1 This paper is suitable for China / China榡 4 .. (CMS) (2 丨 〇χ29λ 公 ^). 29-137 ______ Λ7 V. Description of the invention (27) Η A = ethyl propionate vinegar I = isophorone diisocyanate vinegar; and P 〇1 y (HSA), which is represented by the following (9) .. • one by one —----. ··· ----------- CH “CH2) 5 pH5 HO- ( CH- (CH2) 10.C02) b-CH2-C-CH2. (O2C- (CH2) 10-CH) c-〇H (9) C4Hg (CH2) 5-CH3 where B + c = 2 to 2 0 About 5 to about 15 is suitable, and about 12 is the most suitable (on average) ° Another suitable method for modulating the release agent homopolymer is to react the polycarboxylic acid with a polyol. The following chemical formula is a representative example of this type of reaction: R ~ I-(A-(PAC-A) t)-I- R (1〇) R-(PAC-A) t-1-R (11) R- (PAC-(A-PAC).)-R (12) where PAC is a polycarboxylic acid compound; I = poly.isocyanate compound; R = hydroxyl-functional radiation-curable compound; A = polyol; and t = l To about 20, preferably about 1 to 15 (on average) ° At least one of the carboxylic acid or polyol is branched to provide a polyester backbone with carbon-containing side chains' or the polyol contains non-terminal The hydroxy-functional group 'the hydroxy-functional group provides a polyester backbone with a carbon-containing side chain when a hydroxy-glyceryl group reacts with a carboxylic acid to form an ester-functional group. The mold release homogeneous molecular weight polywood paper scale is suitable for Chinese valve home treatment winter ^ yang ^ 枋 枋 (7; 〇χ 297 · ^ iij -30- through the drop section t clip sample " local labor consumption 0 ^ India? ;!. Λ7 _____________ H7 __ 5. Explanation of the invention (28) The structure of the compound is not restricted by the chemical formulas 10 to 12. I, R and A may be any of the compounds described earlier in this specification. PAC It can be any polycarboxylic acid compound. Suitable dicarboxylic acids include: oxalic acid; malonic acid; succinic acid; glutaric acid; adipic acid: pimelic acid: suberic acid; azelaic acid; sebacic acid Acid; maleic acid; fumaric acid; phthalic acid; isophthalic acid; terephthalic acid; terephthalic acid; trimellitic acid; and trimellitic acid. We can also use two or more carboxylic acids Carboxylic acids with homogeneous molecular weight polymers for adjusting the adhesion of polyester backbones, which can be used in larger amounts than traditional silicone-containing release agents and fluorine-containing release agents. In particular, this type of adhesion The homogeneous molecular weight polymer for adjustment may be about 1 to 90 wt%, preferably about 5 to 80 wt%, and a suitable amount of about 10 to 7 wt%. For use, the percentage is based on the total weight of the ink-curable composition that is curable by irradiation. A further suitable example of a polymer having a homogeneous molecular weight for adhesion adjustment is a hydrocarbon compound containing at least one functional group that is curable by irradiation and protruding hydrocarbon side chains. This type of adhesion-adjusting compound contains a number average molecular weight of about 1,000 to 10,000, preferably about 2, ◦ 00 to 8, 0 0 0, and the upper bond is followed by at least one functional group that can be cured by irradiation. Hydrocarbon backbone. Radiation-curable functional groups can be bonded to the hydrocarbon in any suitable manner, such as the polyester backbone described herein. Examples of suitable hydrocarbons include polyethylene, polybutene, polypropylene, and ethylene, Copolymer of butene and propylene. When we can also use chloroprene rubber and polybutadiene polymer, polychloroprene rubber and polybutadiene are completely ordered by -------- 'ϋ (to first Read the back and remember the contention and struggle to fill out the fight) >, the paper music standard Shizhou, 丨 'National National Standards (CNS) 8 4 rules (2Ι〇ΧΝ7' :, > >)-31 -A7 ____ H7 V. Description of the invention (29) Hydrogen A suitable homopolymer with a molecular weight of about 4 500 is a polybutene acrylate having a number average molecular weight of about 4. A commercially available example of such a homopolymer is Kraton L 1203 ( Shell Chemical Co.). The oligomeric polymer for adhesion adjustment with a hydrocarbon backbone can be used in larger portions than conventional silicone-containing release agents and fluorine-containing release agents. In particular, this type of adhesive Efforts to adjust the homogeneous molecular weight polymer can be about 1 to 90 wt%, preferably about 5 to 8 wt%, and a suitable amount of about 10 to 70 wt%, based on the total weight of the curable ink coating composition. To use. The homogeneous molecular weight polymer for adjusting adhesion can be used as a major homogeneous molecular weight polymer in the ink coating composition. However, other radiation-curable homo-molecular-weight polymers are generally mixed with the monomers to adjust the adhesion-generating homo-molecular-weight polymers to customize the ink coating properties as required. Conveniently, the irradiation-curable monomers and homopolymers present in the irradiation-curable carrier system are selected to be compatible with the homopolymers for adhesion adjustment, so that the homopolymers for adhesion adjustment are polymerized. The substance remains dissolved or dispersed in the liquid irradiation-curable carrier system. We can easily measure the compatibility of monomers with oligomeric polymers and oligomeric polymers for adhesion adjustment, as shown in the examples below. In particular, we can mix the homopolymer of the molecular weight for adhesion adjustment with the required monomers and homopolymers of the same molecular weight. If we observe a vague mixture, the monomer or homogeneous molecular weight polymer may be compatible with the adhesion adjustment and adjustment of wood and paper. 7 Π China National Standards (CNS) ΛΊ / ΜΜ 210X297) _ 32-浐 部 中 夹Bid ^^ $ Industrial and Consumer Cooperatives Seal 褽 Λ7 — H7---------- 一 ··. .1 丨 丨 — ........ ... 5. Description of the invention (30) Incompatible polymers with homogeneous molecular weight. However, if desired, we can also use a mixture of the monomer 'homo-molecular weight polymer incompatible with the homo-molecular weight polymer for adhesion adjustment. However, before use, we must stir the ink composition to disperse the adhesion-adjusting homogeneous molecular weight polymer. Examples of commercially available ink compositions that can be reconstituted to contain the homogeneous molecular weight polymer for adhesion adjustment according to the present invention include ultraviolet curable inks available from DSM Desotech, Inc., which are multifunctional Acrylate monomers are predominant. The ink coating is typically about 3 to 10 microns thick and is concentric to prevent attenuation of signal transmission. However, if desired, the ink coating can be used in any form suitable to provide the distinct color identification of individual coated glass fibers. Examples of suitable coverings include: long stroke (-), dotted lines and circles. It is advisable that the ink is coated with a substantially concentric shape. The ink coating composition according to the present invention is capable of substantially providing concentric ink coating, as well as discontinuous coatings such as long strokes, dots, lines, and rings. When it is not concentric and can be coated, it can be used to adjust the matrix molecular weight polymer to separate the matrix material from dots, long strokes, or other ink coatings. The ink coating generally also has a glass transition temperature (T g) of at least about 50 ° C, and at least about 70 ° C. Those skilled in formulating radiation-curable ink compositions know how to adjust the radiation-curable composition to provide the desired cured coating properties. Therefore, the radiation-curable composition that generally forms the outer basic coating composition can be reconstituted and can be used as a radiation-curable carrier system in the ink coating according to the present invention. Appropriate irradiated wood and paper scales that can be reassorted in various ways are applicable to the National Valve House Standard (CNS). (2 丨 〇 > &297; 297) -33 ~ / -ί (对 先 间Read. Behind the note of the city item #fill * " 本 \ = 0

.¾¾- 部 部 桴 桴 '· 局 · ΛIndustrial price reduction cooperation ¾ Λ7 ______— 137 V. Description of the invention (31) Examples of curable compositions, including US Patent No. 4' 624,994: 4 , 682,851; 4 > 782'129: 4 >794'133;4,806'574;4,849,462; 5 '2 1 9, 8 9 6 and 5, 3 3 6, 5 6 3 All of the disclosed compositions are incorporated herein by reference. A radiation-curable carrier system suitable for forming the ink composition contains at least one radiation-curable homogeneous molecular weight polymer or monomer having at least one functional group capable of polymerizing upon exposure to actinic radiation. Suitable radiation-curable, homogeneous molecular weight polymers or monomers are now widely known and within the skill of the art. Generally, the radiation-curable functional group used is ethylenically unsaturated 'and it can be polymerized by radical polymerization or cationic polymerization. Specific examples of suitable ethylenic unsaturation include acrylate, methacrylate, styrene, vinyl ether, vinyl ester, N-substituted acrylamide, N-vinylamine, maleate, and fumaric acid. ester. Conveniently, the ethylenic unsaturation is provided with a group containing an acrylate, methacrylate or N-vinyl functional group. Another type of functional group generally used is an epoxy group, or a thioalkene or amine ene system. Epoxy groups can be polymerized by cationic polymerization. On the other hand, thioalkene and amine ene can be polymerized by radical polymerization. The epoxy groups are homopolymerizable. For example, in the thiophene and amine systems, polymerization occurs between groups containing allylic unsaturation and groups containing tertiary amines or thiophenes. This paper is of suitable size; fl China S-house-; V- (c NS) Λ 4 Yue 梠 (210 X 2 9 7. Public i) _ 34-a-~ ----------I-- I τ ____ I _ -¾ * vi-(" Read the note of the first note " Matters | 衿 本 w) --1_K _______ A7 H7 V. Description of the invention (32) The radiation-curable function in the polymer of homogeneous molecular weight It is better to have at least 8 Om 0%, and it is more appropriate to have at least 9 ◦ --------- install-(Note to the nine reading & market items. 丨 copybook Page) Around m0, it is acrylate, methacrylate and N-vinyl. Using a mixture of mono-, di-, tri-, tetra- and high-functionality homogeneous molecular weight polymers can achieve the required property balance, in which functionalization Refers to the number of radiation-curable functional groups present in a homogeneous molecular weight polymer. The homogeneous molecular weight polymer generally contains a carbon-containing backbone structure, and functional groups which are irradiated by radiation are bonded thereto. Examples of suitable carbon-containing backbones include polyethers, polyolefins, polyesters, polyamides, and polycarbonates. The size of the carbon-containing backbone can be selected to provide the desired molecular weight. The number-average molecular weight of the homogeneous molecular weight polymer is generally between about 500 to 10,000 ', preferably between about 500 to 7,000', and between about 1,000 to 5, For example, the carbon-containing backbone of a homogeneous molecular weight polymer may contain aromatic groups, and ring-opened epoxy or alkoxy groups. The homogeneous molecular weight polymer can be represented by, for example: R-A r-R; or

R-L-Ar-L-R where r is a radiation-curable functional group, A r is a moiety containing an aromatic group, and L is a linking group. Examples of suitable linking groups include alkoxy groups or ring-opened epoxy groups, wood-paper scale suitable for China® Home Pillow Standard (CNS), Λ4 stats (210x2 (mWi> -35 · Λ7 U / V. Invention) Note (33) Such as ethoxy, propoxy, butoxy, and repeating units. L may also be a urethane or urea linking group. The aromatic group may be derived from a bisphenol unit, such as bisphenol A A suitable homopolymer of homogeneous molecular weight is a glycidyl ether derivative of bisphenol A, which has an acrylate functional group bonded thereto. An example of such a homopolymer of commercially available homogeneous molecular weight is CN—120 (Sartomer), which It has a molecular weight of about 1 300 and a glass transition temperature of about 6 5 ° C when cured. Another example of a suitable molecular weight polymer is a trifunctional polyether or molecular weight having a molecular weight of about 500 to 500 Polyester. A suitable example of a trifunctional, homogeneous molecular weight polymer is the commercially available polyurethane triacrylate Ebecryl 264, which has a molecular weight of about 2000 and a glass transition temperature of about 4 2 t when cured. Curable carrier systems can also contain Reactive diluent is used to adjust viscosity. Reactive diluents can be low-viscosity monomers, which contain more than one functional group that can polymerize under exposure to actinic radiation. Usually below 25 ° C The viscosity of the low-viscosity diluent monomer is about 50 to 500 centipoise. An example of a suitable glass fiber coating composition viscosity is about 500 to 50,000 centipoise at 25 ° C. This functionality The radical may be of the same nature as the functional group used in the radiation-curable monomer or the homo-molecular-weight polymer. It is desirable that the functional group present in the reactive diluent is capable of interacting with the radiation-curable monomer or Irradiation-curable functional groups copolymerize on homogeneous molecular weight polymers. For example, the reactive diluent can be a monomer or a monomer mixture having acrylate g or vinyl ether functional groups, and a C4-C2O alkyl or poly Heart paper scale is suitable for Sichuan, 丨, China National Humble (CNS) ΛΊ on-site (2 丨 〇Χ297 »/ ί). 36---------- Installation ------ Order I ：- ---- Line (? /. Please refer to the following ii & Matters · ίΓ} · Fill in this Η) The Ministry of Economic Affairs quot; Industrial Consumer Cooperative Cooperative Seal Λ7 ______H7 5. Description of the invention (34) Ether part. Specific examples of such reactive diluents include: hexyl acrylate, 2-ethylhexyl acrylate, isobornyl acrylate, acrylic acid Decyl ester, dodecyl acrylate, stearyl acrylate, 2-ethoxyethoxy monoethyl acrylate, dodecyl vinyl ether, 2 ~~ ethylhexyl vinyl ether, N-vinylformamide, Isodecyl acrylate, isooctyl acrylate, vinyl-caprolactam, vinylpyrrolidone and the like. Another type of reactive diluent that can be used is a compound having an aromatic group. Specific examples of reactive diluents with aromatic groups include: ethylene glycol phenyl ether monoacrylate, polyethylene glycol phenyl ether acrylate, polypropylene glycol phenyl ether-acrylic acid ester, and alkyl groups with the above monomers. A substituted phenyl derivative such as polyethylene glycol nonylphenyl ether monoacrylate. The reactive diluent may include a diluent having two or more polymerizable functional groups. Specific examples of such monomers include: C 2-C 18 hydrocarbon diacrylate diesters, c4-c8 hydrocarbon divinyl ethers, c3-c18 hydrocarbon triacrylates, and their polyether analogs, such as 1, 6-2 Adipic acid acrylate, trimethylolpropane triacrylate, hexanediol divinyl ether, triethylene glycol diacrylate, pentaerythryl triacrylate, hydroxyethylated bisphenol A diacrylate, and two Tripropylene Acrylate. If the radiation-curable functional group of the radiation-curable monomer or homopolymer is an epoxy group, for example, one or more of the following compounds can be used as a reactive diluent: epioxycyclohexane Alkane, phenylethylene oxide, 1 '2-epoxy-4_vinylcyclohexane, glycidyl acrylate' 1 '2-epoxy-4 -epoxyethyl-cyclohexane, Diglycidyl ether of polyethylene glycol, diglycidyl ether of bisphenol A, etc. -------- ^ -------- order ----- ^ VI .. (Please read first Note on the back Sun fills this page) The paper size is applicable to the Chinese Standard (CNS) Λ4 gauge (2IOX297i ^) -37- Ministry of Fire Safety Standards Bureau I ::; Industry Consumers Cooperatives A7 H7 V. Description of the invention (35) 0 If the radiation-curable monomer or the polymer having a homogeneous molecular weight has an amine or thioalkene system, a reaction having allylic unsaturation can be used. Examples of alkaline diluents include diallylphthalate, triallyltrimelate, triallyl cyanurate, triallyl isocyanurate , Iso-diallyl phthalate. For amine-ene systems, amine-functional diluents that can be used include, for example, trimethylolpropane, adducts of isophorone diisocyanate and bis (methyl) ethylethanolamine, hexanediol, isophor Adduct of ketene diisocyanate and dipropylethanolamine, adduct with triamine methylolpropane, trimethylhexamethylene diisocyanate and bis (methyl) ethylethanolamine. The radiation-curable ink composition ' may contain a light-sensitive starter which generates radicals. Examples of suitable free-radical type photoinitiators include, but are not limited to, isobutylbenzoin ether; 2,4,6-trimethylbenzidinediphenylphosphine oxide; 1- Hydroxycyclohexyl phenone; 2-benzyl-2-dimethylamino-1 1- (4-morpholinophenyl) -butane-1 ketone; 2,2-dimethoxy-2-2-phenylacetamidine Benzene; perfluorinated diphenylbiscyclopentadienyl titanium; 2-methyl_1- (4- (methylthio) phenyl)-2-(4-morpholinyl) -1 1-acetone; 2 —Hydroxy-2—methyl-1-phenylpropan-1-one; 4- (2-Ethylethoxy) phenyl—2—Hydroxy-2—propylmethanone dimethoxyphenylacetophenone ; 1- (4-cumenyl)-2-hydroxy- 2-methylpropan-1 ketone; 1- (4-dodecyl-phenyl)-2-hydroxy- 2-methylpropan-1 ketone; 4— (2 -Hydroxyethoxy) phenyl-2 1 (2 1 -Hydroxy 2 -propyl) _ Zhang scale is applicable to the Chinese National Standard (CNS) octagonal (210 × 297 male) -38-(pair (Read this first, and pay attention to $)

、 1T Λ7 ___117 V. Description of the invention (36) ketone; diethoxyphenylacetophenone; (2,6_dimethoxybenzidine)-2 '4,4 trimethylpentylphosphine oxide And a mixture of 2-hydroxy-2-methyl-1, 1-phenyl-propan-1, ketone; benzophenone; 1-acetone, 2-methyl-1, 1- (4- (methylthio) phenyl )., 2- (4-morpholinyl); and mixtures thereof. Other additives used in radiation-curable carrier systems include, but are not limited to, catalysts, lubricants, wetting agents, antioxidants, and stabilizers. The selection and use of such additives is within the skill of this art. 'In ribbon assemblies, coated optical fibers are often used. Due to the versatility of the ink coating composition of the present invention, the composition is very suitable for use in coated glass optical fibers in a ribbon-shaped module. Surprisingly, the ink coatings made according to the present invention can provide mid-span access without the use of a release agent. Although not suitable, release agents can be used if needed. Suitable release agents include silicone, silicone acrylate, fluorocarbon oil, or resin. Because the ink coating according to the present invention can originally provide mid-span access, the amount of release agent added is significantly reduced compared to conventional ink coatings. The release agent may be present in an amount of about 0.1 to 5 wt% based on the total weight of the ink composition. In the present invention, inorganic and organic pigments suitable for producing a radiation-curable ink composition can be used. The pigment 〃 used refers to both inorganic pigments and organic pigments. Using 12 or less coated glass fiber ribbon components, only 12 colors are needed to properly distinguish each coated fiber. However, in large band-shaped components, more than 12 colors can be used, --------- install -------- order ------ line- 'This paper size is suitable for towels National sample (c NS Μ 4 (21 OX 2 9 7 film). 39-Jing Yi Ministry Central # 5ί- ^ Only workers eliminate cooperation. Social printing ^ A7 1) 7 V. Description of the invention (37) Appropriate Differentiate each coated glass fiber. Examples of twelve colors commonly used to make ribbon components include: black, white, yellow, blue, red, green, orange, brown, pink, aqua, purple, and gray. Specific examples of suitable black pigments include: carbon black. Specific examples of suitable white pigments include: titanium dioxide. Specific examples of suitable yellow pigments include diaryl yellow and pigments based on diazonium. Specific examples of suitable blue pigments include phthalocyanine blue, basic dye pigments, and phthalocyanine. Specific examples of suitable red pigments include: anthraquinone (red), naphthol red, monoazo-based pigments, quinacridine pigments, anthraquinone, and perylene. Specific examples of suitable green pigments include: phthalocyanine green and nitroso-based pigments. Specific examples of suitable orange pigments include: monoazo- and diazo-based pigments, quinacridine pigments, anthraquinones, and camels. Specific examples of suitable purple pigments include quinacridine violet, basic dye pigments, and carbazole dioxazine-based pigments. Appropriate aqua, brown, gray and pink pigments can be easily blended by mixing other colors. Those skilled in the art can make any color they want by mixing different pigments. The pigment contained in the ink composition can provide a color that is visible to the naked eye without the presence of an enlarged portion to facilitate the identification of individual colored glass optical fibers. The amount of pigment should not be so large that it will significantly reduce the curing speed of the ink composition or cause other undesired effects. "We have found that the appropriate pigmented wood size is suitable for the China National Standards (CNS) Λ4 (2 丨 OX 297) ) -40---------- Correcting clothes-(I read the notes from the back and notice the matter # 丨? J 本 打)

， 1T Line Ward and Decoration Department t- * if · 肀 工 消 资 合 社 社 印 34 Λ7 ___ 137 V. Description of the Invention (38) Examples of the amount of materials are based on the total weight of the ink composition about 1 to 20 W t% 'It is preferable to be about 1 to 15 wt%' and about] to 10 wt% is more suitable. According to the above, a suitable radiation-curable ink composition can be formulated from a composition that contains: about 1 to 20 wt% of one or more pigments; about 1 to 9 O w t% of adhesion Adjust the polymer with homogeneous molecular weight. • A suitable ink composition can be formulated from a composition containing: one or more pigments of about 1 to 2 Ow t%; a homogeneous molecular weight polymer for adjusting adhesion of about 1 to 9 O w t%; Other radiation curable homogeneous molecular weight polymers of about 1 to 8 Ow t% at random; one or more radiation curable diluent monomers of about 1 to 8 Ow t. A suitable amount of other radiation-curable homogeneous molecular weight polymers includes about 10 to 70 wt% based on the total weight of the ink composition, and preferably about 20 to 60 wt%. A suitable amount of the radiation-curable diluent monomer includes about 5 to 70 wt% based on the total weight of the ink composition, and preferably about 10 to 60 wt%. The ink composition contains a photosensitive starter, in order to apply the valve national pillow standard (CNS) Λ4 / 兄 格 (210X297- »«! ^ 衣, 1τ ------ ^-< (Take note of the f term π Μ 本 ΪΓ) > wn_ 浐 部 -5- 爽 标 ^^ ·· Η 工 消 贽 社 印 印 印 Bi7 Λ7 H7 V. Description of the invention (39) Weight about 1 A portion of about 20 wt% is preferable, and a portion of about 1 to 10 wt% is more suitable. The ink composition can be applied to coated optical glass and cured by any suitable method. Suitable method Examples are disclosed in U.S. Patent Nos. 4,62,285, and the complete disclosure is incorporated herein by reference. The ink composition can also be substantially coated with the glass fiber drawing and the outside of the coating tower. Apply a similar method to apply. In terms of application, the colored outer basic coating is used instead of or in combination with the ink coating. If the concentric ink coating is used, the adhesion can be adjusted. Molecular weight polymer is incorporated into a pigmented exterior basic coating, providing The outer base of coloring; the level of adhesion required between the coating and the base substance. Based on the disclosure in this specification, those skilled in the art can formulate the colored pigments required for the use of homogeneous molecular weight polymers for adhesion adjustment. Exterior basic coating. For example, the radiation-curable substrate of the exterior basic coating is similar to the ink-curable radiation-curable carrier system. Therefore, the viscosity of the exterior basic coating can be the same as that of the ink coating described in this specification. The adjustment is performed in the same way as the polymer of the homogeneous molecular weight. By using the polymer of the homogeneous molecular weight of the adhesion adjustment, the conventional colored outer basic coating can be changed to an improved colored outer basic coating according to the present invention. An example of the outer basic coating is disclosed in published PCT application WO 90/13579, the complete disclosure of which is incorporated herein by reference. The polymer of homogeneous molecular weight for adhesion adjustment is used to impart a colored outer basic The coating has a top contact angle (the outer basic coating is related to the matrix material. Country store house: ν · (CNS) / Copy it like this (210X297 public y). 42 ~ (Read first to read the back ;!-Yishi Xiangsun fill ^ · Ben 玎) Pack. Shanghai Department t Times ίέ-ν-ΆΜΤ; printed by Xiaoling Cooperative ¾ A7 in V. The interface of the description of invention (4〇) is more than 65 °, more than about 70 ° is more suitable, and about 7 5 ° C is more suitable, about It is advisable to have the most suitable surface energy above 80 ° C, instead of using traditional silicone and fluorine-containing compounds. Tough molecular weight polymers for adhesion adjustment can also be injected into the composition for curing and curing the substrate. Materials, providing the ability of the formed substrate to escape from the ink coating. The radiation-curable matrix-forming composition is mainly composed of radiation-curable monomers and oligomeric polymers, which are similar to those used in the ink coating composition described above. The ratio of the homogeneous molecular weight polymer for adjusting the adhesion of the oil-and-ink coating composition described above can be used to formulate the improved matrix-forming composition according to the present invention. Therefore, those skilled in the art can easily produce an improved matrix-forming composition capable of providing a matrix substance that can be used in a belt-shaped module to impart mid-span access. A suitable matrix-forming composition that can be formulated to include a homogeneous molecular weight polymer for adjusting adhesion is disclosed in U.S. Patent No. 4,8,4,64,04, the complete disclosure of which is incorporated herein by reference. Reference. The homogeneous molecular weight polymer for adjusting the adhesive strength is preferably capable of imparting a matrix substance having a temperature of about 65 ° C or more, more preferably about 70 ° C or more, and more preferably about 75 ° C or more. The most suitable is about 80 ° C or more. The amount of surface energy at the top contact angle is preferably present instead of using conventional silicone-containing compounds and fluorine-containing compounds. The polymer of homogeneous molecular weight for adhesive force adjustment can be used in the ink coating or matrix material, or both of the tape-like components, to customize the required viscosity of the ink coating and the matrix material. Wood paper scale suitable / 丨 H, _home d: (CNS) Λ4 anxious (2IOxT〇7Tj > ^ ~ j ~ _ 43-'' .— ^ _------- * 0 .-V (r -5/1 first Mf-Jf and then remember fJfi.-iH fill in ΪΪ this book) Μ Η 7 •. ······· -------- _. _.-, Ιρ ^ ι ·, · · Μ · ·---_______ V. Description of the Invention (41) 'Installation · The ribbon components are now widely known in this art, and those skilled in this art can easily use what is disclosed herein to Novel ribbon assemblies containing more than one improved ink-coated glass optical fiber are prepared for the desired application. The novel ribbon assemblies made in accordance with the present invention can be used in telecommunication systems. Such telecommunication systems generally include Receiver and switch for ribbon-type components containing glass fiber. Transmitters and switches containing coated glass fiber are basic connection units for telecommunication systems. For long-distance connection (such as the connection between cities) The purpose can be to bury the strip module underground or underwater. It can also use the strip module to directly connect the residential houses.

, 1T The novel ribbon module made according to the present invention can also be applied to a cable television system. This type of cable television system typically includes ribbon components containing glass fiber optics, transmitters, receivers, and switches. A ribbon module containing coated glass fiber is the basic connection unit for this type of cable television system. For the purpose of long-distance links (such as links between cities), the strip-shaped components can be buried underground or underwater. It is also possible to use ribbon modules to directly connect houses in residential areas. The following examples are provided to further explain the present invention, without limiting the present invention. &Quot; • 部 中 夹 ^ " ^ π-τ- 消 贽 Cooperation.

Examples 1 to 13 and Comparative Example A When used in a belt-like device, the ink composition formed the ability to exhibit the ink coverage of a mid-span access, without using a silicone release agent or a fluorocarbon release agent. In this case, the test is as follows. First, a substantially radiation-curable carrier composition is prepared by mixing the ingredients shown in Table 1. Basic paper size standard / fl 屮 valve valve home standard (CNS) (2 丨 〇 X 2men's Square) -44- Λ7 H7 V. Description of the invention (42) ^ ~ The invention is used for adjusting the adhesion of homopolymers (B-1 and B-2). The curable ink coating composition was produced by mixing the basic composition shown in Table 2 and a pigment. The ink coating compositions are tested to determine if they can provide mid-span access. The test results are shown in Table 2 ---: ------ 1¾ .------ ^ 1T --'----- like. ^ $ '(ϊτ 本本) Classic "' Qiu 屮 folder 栉 杓 工 工 消 消 消 论 合 合 .. The paper printed by the agency is suitable for ffl, 丨 'Valve National Pillow (CNS>' Μ 叱 枋 (2 | 〇χ297. ^ 筇) -45- Λ7 Η 7 V. Description of the invention (43) Economic & Trademarks of the Ministry of Central and Central Bureau of Commerce and Industry Cooperation &Cooperation; Table 1 Composition (wt%, based on the total weight of the carrier system) Basic carrier system B-1 Basic carrier system B-2 Basic carrier system B-3 Poly (12-hydroxyoctadecanoic acid) urethane acrylate 22.72 76.7 0 Epoxy acrylate 2.84 0 38.6 Six-functional aromatic urinal acrylic 9.17 0 0 Aliphatic urethane triacrylate is released 15% with hexanediol diacrylate 10.56 0 32.4 Pentaerythritol tetraacrylate 11.59 0 10 Hexylene glycol diacrylate 18.29 17.04 1.51 Troysol 98C Surfactant (Troy) 0.57 0 0 2,6-di-tert-butyl-methylphenol 0.57 0.57 0 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl'T-ΐ · 1.14 1.14 0 2-methyl -1-(4- (methylthio) phenyl) 2- (4-morpholinyl) 1-acetone 4.55 4 .55 0 silicone diacrylate 0 0 1.21 50% phosphinized oxygen, diphenyl (2,4,6-trimethylphenylhydrazone) and 50% 2-meryl-2-methyl-1-phenyl -1-acetone 0 0 10 isobornene acrylate 0 0 3 phenoxyethyl acrylate 0 0 3 terephthalimide monomethyl ether 0 0 0.14 phenothiazine 0 0 0.14 pack, 1T ----- -# '(Besides reading the following and paying attention to the items " -Fill in ^: this page) Wood paper scales are applicable 屮 囡 家 # 准 （C'NS） / \ 4 悦 乾 （210X297 公 / ;.) 46-V. Description of the invention (44 Central Government Bureau of the Ministry of Economic Affairs only eliminates bismuth Λ7 B7 CN from the cooperative Example 13 Orange 〇S3 oo P: 1- < Example 12 Red 〇78.14 21.86 Via S: 1 < Example 11 Blue! 1_ 〇OO oo OJ Pass 0: 1- ^ Example 10 Aqua 1_ J i 84.68 o 15.32 Pass 〇: Γ -'- < Example 9 i Brown 82.15 o 17.85 -1 Pass 〇: If Example 8 Green I 1_un 〇〇〇〇Factory H Pass 〇: I- < Example 7 Orange cs 〇〇o OO Pass 5: Example 6 Rose color CO oo o Pass 5: t-―ί Example I5! Yellow 79.8 o 20.2 P: Example! 4 | Purple 83.77 o 16.23 Pass: Example 3 Blue OO oo o cs Pass 5: TH Example 1 2 Dark blue gray m oo oo o vn t- * r- Pass f- ^ Example I1 White 86.37 o 13.63 Passed 0: r1 1 im ^ _ | m X-Μ kanchain basic carrier system Bl basic carrier system B-2 pigment test results 1 middle span access to the outer basic coating! matrix material! ------- --Install ------ 1T-^ -----. 4 // HS. (Note for the first reading * Note 4 fill in 1- :? Ben 玎) m 5. Description of the invention (45) The results shown in Table 2 demonstrate that the homogeneous molecular weight polymer for adhesion adjustment according to the present invention can give the ink coating the inherent properties of mid-span access. "Matrix substances M 1-M 5 The effect of taking is tested below. The radiation-curable matrix-forming composition was prepared by mixing the ingredients shown in Table 4. The ability of the matrix material to impart mid-span access is recognized in Example 1 and tested using the ink composition method shown in Table 3. The test results are shown in Table 4. Printed by the Ministry of Economic Affairs, Central Laboratories and Consumers 'Association *' J? I This paper is moderately suitable / Π 屮 因 榡 因 因 因 因 因 因 八 八 忧 CN CN 八 CN CN 八 CN CN CN CN CN CN 21 (21 (> x2V7, > > C)-48 -V. Description of the invention (46 — ^ 1 «

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OOSOI inch /; 001 ΟΟΓΟΈΙ A7 B7 (you especially read 1Ϊ-and the notes for this s). Outfit. 80 ^ inchΌ inchΌ 000 ι · ί 9.6

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Distilling si! SiE (!?! &+; 涵 翻 -Π) step on S (_ # i, Ds, s («揪 (« ME-), inch), 1.1. «Frc \ ®M—I wire wood The paper size is suitable for China and Fujian countries;?: 肀 (CNS) (210X297 male Af:) -49- Λ7 H7 Central Government Ministry of Economic Affairs ^ '· Bureau ljl Industry and Consumer Cooperation System 5. Description of Invention (47) Table 4 Ingredients (Wt%, based on the total weight of the composition) Ml M2 M3 M4 M5 Agent molecular weight polymer HT- (Pluraco 12010) 0.9- (SynFAC801 7) mTH 55 61.1 68.24 55 55 Isobornene acrylate 3.9 4.3 0 5 3.9 Propoxylated hexanediol diacrylate 3.9 4.3 0 5 3.9 Ethoxylated bisphenol A diacrylate 23 25.5 11 29.7 23 1-Hydroxycyclohexylphenyl ketone 4 4.4 3 4 4 Thio Diethylenebis (3,5-di-tert-butyl-4-hydroxyphenylpropionic acid) 3 0.4 0.3. 0.3 3 Epoxidized soybean oil acrylate 10 0 0 0 0 Polyethylene glycol (Carbowax PEG300) 0 0 0 0 10 Vinylhexylpropanamine 0 0 10 1 1 Phenoxyethyl acrylate 0 0 6.46 0 0 Dimethylpolysiloxane 0 0 0,3 0.3 0 Dimethylpolysiloxane (Interfacial activator ) 0 0 0.7 0.7 0 The test results basically cover the outside P1 P1 P1 P1 P1 Midspan Distance access (4 hours after formulating the ink composition IN-2) is made by reacting the following components by passing through the homogeneous molecular weight polymer system: hydroxyethyl acrylate T = toluene diisocyanate polyoxypropylene-alcohol-alcohol ' With a molecular weight (BASF) of about 2000 Syn FAC 8 0 1 7 = ethoxylated bisphenol a glycol (Milliken --------- t-- (for the first reading (Note on this item on this page) “-丁 • = 5 Soulwood paper wave scale suitable for Sichuan China m ;: 今-(CNS) 8 4 Now Gu (2 丨 〇 XW cm> -50- Λ7 Μ 7 5 4. Description of the invention (48) The results in Table 4 illustrate the use of homopolymers for adjusting the adhesion to give the belt-shaped components the ability to access in mid-span. Example 1 4 1 15 Different additive pairs in the matrix material The effect of the substrate's ability to impart mid-span access is tested below. The additives shown in Table 5 are combined with a radiation-curable substrate-forming substance. The ability to impart mid-span access is given in Example 1 The method is determined, and the test results are shown in Table 5. Table 5 Ingredients (wt%, based on the total weight of the composition) Example 1 4 Example 1 5 Matrix composition M4 9 0 9 0 Kemester 6000 10 0 Epoxidized soybean oil acrylate 0 1 0 The test results are basically covered with P 1 on the outside P 1 Ink coating composition IN-1 IN-1 Mid-span access (immediately after the ink composition IN-1 is prepared) The polymer of uniform molecular weight for adhesion adjustment was added through Example 1 6-1 7 The ink composition of the ingredients shown in Table 6. The ink composition does not use a fluorine-containing mold release agent and a silicone-containing mold release agent to impart mid-span access capabilities. It is based on Example 1 This paper is suitable for paper size !!] China Valve® Home. 1 '?: (CNS) ΛΊ 悦 枯 (2 丨 0X297 公 尨) -51-Λ7 _________ |! 7 V. The method of invention description (49) is tested. The test results are shown in Table 6. Table 6 Ingredients (wt%, based on the total weight of the composition) Example I 4 Example I 5 Ink composition IN-1 8 0 8 0 Polyethylene butylene acrylate 2 0 0 Cardolite NC-547 0 2 0 Test As a result, the PI PI I matrix material M I-I Μ I-I was used for medium-span access (the formulation of the ink composition was performed immediately after passing IN-1) ^ (" 'Please read it first. Please note the back Matter Sun fills this page) Order 1 The results in Table 6 illustrate that the molecular weight polymer for forming a release layer according to the present invention can unexpectedly impart mid-span access without the need for silicone-containing release. Agent and fluorine-containing release agent. Examples and Comparative Examples of Surface Energy The surface energy of a substantially irradiated and curable support system for ink coatings and conventional ink coatings made according to the present invention was tested. The test results are shown in Table 7. Wood paper scale suitable for China National Sweeping Apple (CNS) (210 X 297 ^^ ") ~~ Z ~ ζ2 Λ7 137 V. Description of the invention (50) Table 7 Sample average contact angle top (°) Basic carrier system B 2 8 0 + /-2 (76.7wt% 12HSA) Basic Carrier System B 1 7 8 +/- 2 (22.72wt% 12HSA) Basic Carrier System B 1 6 5 +/- 2 (without 12HSA) Commercially available inks The basic carrier 62 +/- 1 (silicone has been removed) (please read it first and pay attention to the entry to save Emei ranunculus)-loaded if The results in Table 7 show that the present invention is surprisingly capable of substantial Reduce the surface energy of the ink coating without using silicone release agent or fluorine release agent. The larger the contact angle, the smaller the surface energy. * Span access during the test procedure. A commercially available, 75-micron-thick, radiation-curable external basic coating composition rolled flat was applied to polyethylene terephthalate flakes ( Mylar sheet) and cured under exposure to nitrogen at 1 Joule / cm 2 generated by the Fusion D lamp under a nitrogen atmosphere to form a cured outer base film. A 5 to 10 micron thick slab sample of the radiation-curable ink composition was formed on the cured outer base film. The ink composition was cured in the air by exposure to ultraviolet rays of 1 J u 1 e / cm 2 produced by Fusi i n n D 1 a m p. Yumu paper scale suitable valve due to domestic standard Xin (CNS) 210X2 «^ 公 犮） -53-4 < standard ^-/ 0h industrial and consumer cooperation in the Ministry of Economics. Du Yin on Λ7 ΙΪ7 V. Description of the invention (51) Ink The coating forms a 75-micron-thick, commercially available, radiation-curable matrix composition slab. The matrix composition was cured in a nitrogen atmosphere by exposure to ultraviolet rays of 1 ule / cm 2 generated by the Fusson D lamp, and a cured matrix substance was formed on the ink coating. The resulting multilayer film was cut into strips about 1/4 to 1/2 inch wide. At one end of each strip, use a knife to separate the portion of the matrix material from the ink coating. A force is applied to the separated portion of the matrix material, and the matrix material remaining on the ink coating is peeled off. If the remaining gelatinous material is separated from the ink coating, and the ink coating remains intact, and the p-matrix material is not peeled off, the ink coating passes the mid-span access test. Surface energy Contact angle measurement was performed using a fixed droplet method using a Rame-Hart contact angle goniometer. Use water as a test solution. Using a Gilmont micro-syringe equipped with a stainless steel needle, a droplet (4- 8 β 1) was placed on the surface of the sample.接触 Measure the contact angle after 1 minute. Measure the contact angle on both sides of the droplet to determine symmetry. Five measurements were performed on each film. A total of 10 drops were used for each sample. The results are averaged and the standard deviation is calculated. In each case, a progressive contact angle was measured. Measure the contact angle of the film's air / ink interface. The top is a series of air / ink-coated interfaces, and the bottom is series of polyethylene terephthalate / ink-coated interfaces. The air / ink interface represents the general matrix material applied to the ink-coated surface. The sample ink film was flattened using a three-thousandth-inch Tosu stick to --------- frame-Chiyou read the back note " 事 孙 填 # 本 Ή) Paper according to scale / Π 中 因 Country of China (CNS) A4 / .US (2 丨 () X2 (; 7 ^ 0). 54-A 7 137

_ I ---- ..-·-·-II II----I _ · _ || ^ Μ · ~ ^ ~ J ---------—— · I V. Description of the invention (52 ) Pure ink base on polyethylene terephthalate. The flats were cured using a D bulb under a nitrogen atmosphere with 2 J / cm 2 UV. The top and bottom of each ~ sample are cured. Remove the film from the polyethylene terephthalate sheet and place the film on a microscope slide for measurement. The same method was used to make the matrix film, except that the curing was different at 1j. (" You read please refer to the note # 姑 、 " 本 ί) Download it. This paper ί / ί standard Tongchuan Middle Valve House sample standard (CNS) AdMfi (210X2974 / ;,)-55-

Claims (1)

Patent Application Scope October Modification 1. A glass fiber optic ribbon module having functional properties for giving span access in individual coated glass optical fibers, the aforementioned ribbon module comprising: a large number of coated glass optical fibers; and A matrix substance that binds the aforementioned numerous coated glass optical fibers together, at least one of the aforementioned coated glass optical fibers, which includes glass optical fibers; there is more than one coating on the aforementioned glass optical fibers; At least one layer of the coated ink coating is formulated with a composition containing ingredients printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs; the adhesion adjustment can be performed by irradiation of a low molecular weight polymer with a homopolymer of low molecular weight It is not silicone and fluorine. The aforementioned adhesive force is adjusted so that the surface energy of the aforementioned ink coating is at this level, which makes the adhesive force between the aforementioned matrix substances of the aforementioned glass fiber relatively low. The adhesion between at least one layer of coating is still poor < 2. The ink coating is formed by irradiating the curable ink coating group optical fiber, which is composed of: adhesion adjustment is connected to the low surface energy trunk with homogeneous molecular weight polymerization Irradiation can fix it with more than one kind of functional groups that are bonded, and it is substantially coated with homogeneous molecular weight polymer, which is reduced to a level. The ink is covered and coated with the foregoing. The foregoing ink product is suitable for use. The composition formulation of the following ingredients, which has more than one functional group that is bonded, and is substantial (please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) Α4 specification (210X297 mm) Patent application scope || -----· —-»·. # Ι · * 4 # ib Α8 Appendix 1: No. 8 7 1 1 Chinese Patent Application No. 2 8 4 9 Amendments to the scope of the Republic of China October 10, 1988 Amendment 1. Glass fiber ribbon assembly, which has the functional properties of giving span access to individual coated glass fibers, as described above The ribbon assembly includes: a plurality of coated glass optical fibers; and a matrix substance binding the aforementioned plurality of coated glass optical fibers together, at least one of the aforementioned coated glass optical fibers, which is characterized by It includes glass optical fiber; there is more than one coating on the aforementioned glass optical fiber; the ink coating on the aforementioned at least one coating is prepared from a composition containing ingredients printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs; Adhesiveness adjustment uses a molecular weight polymer with a low surface energy to irradiate on the backbone with low surface energy. Silicone and fluorine can be fixed. The aforementioned adhesiveness adjustment can adjust the surface energy of the ink coating. It is flat so that the adhesion between the aforementioned matrix substances of the aforementioned glass optical fiber is worse than the adhesion between the at least one layer of the coating < 2. The ink coating is formed by irradiating the curable ink coating group optical fiber, which is composed of Made: Irradiation of homogeneous molecular weight polymerization on the low surface energy trunk can be used to adjust the adhesive force. It can fix more than one kind of functional groups bonded, and it is essentially covered with ink of homogeneous molecular weight polymer, which is reduced to a level. With the coating and the above, the aforementioned ink product is suitable for the composition formulation of the components below the glass, it has more than one functional group that is bonded, and the essence (please read the precautions on the back before filling (This page) This paper size is applicable to China National Standard (CNS) A4 (210X297 mm), patent application scope (please read the precautions on the back before filling this page) Not for the adjustment of the adhesion of the ketone and fluorine. The molecular weight polymer exists in an amount that can reduce the surface energy of the ink coating formed by the aforementioned ink coating composition. 3 · Irradiation-curable ink coating composition, which is suitable for forming an ink coating on glass fiber, is formulated from a composition containing the following components: A homogeneous molecular weight polymer for adhesion adjustment, which has more than one type of bonding The functional group which can be cured by irradiation on a low surface energy trunk and is substantially free of ketones and fluorine (the homogeneous molecular weight polymer for adhesion adjustment described in the present invention is characterized in that it has a molecular weight of 1,000 to 8.0 The number average molecular weight of 0 0, and 5% to 40% of the number average molecular weight of the homo-molecular weight polymer are composed of hydrocarbon side chains. 4 · Irradiation-curable matrix substance composition, which is suitable for forming The coated glass fiber is a matrix substance bound together. The aforementioned matrix substance composition is prepared from a composition containing the following components: The homogeneous molecular weight polymer for adhesion adjustment printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. It has more than one type of radiation-curable group bonded to the low surface energy backbone, and is not substantially silicone and fluorine. The aforementioned adhesive force adjustment is required. The molecular weight polymer exists in a quantity that can reduce the surface energy of the matrix substance formed by the aforementioned matrix substance composition. 5. The radiation-curable matrix substance composition is suitable for forming coated glass The matrix substance bound together by optical fibers. The aforementioned matrix substance composition is prepared from a composition containing the following components: A homogeneous molecular weight polymer for adhesion adjustment, which has more than one type of bond. This paper is suitable for China National Standards (CNS) ) A4 specification (210X297 mm) .. A8 B8 C8 D8 VI. Patent application: Curable functional groups can be irradiated on the low surface energy trunk, and are not substantially silicone and fluorine. The molecular weight polymer is characterized in that it has a number average molecular weight of 1,000 to 8,000, and 5% to 4% of the number average molecular weight of the homogeneous molecular weight polymer is composed of a hydrocarbon side chain. Cured colored outer basic coating composition, which is suitable for forming colored outer basic coatings on glass optical fibers. The composition of the ingredients is formulated as follows: A homogeneous molecular weight polymer for adjusting adhesion, which has more than one type of radiation-curable functional group bonded to a low surface energy backbone, and is not substantially silicone and fluorine. The aforementioned adhesion The homogeneous molecular weight polymer for adjustment exists in a portion that can reduce the surface energy of the colored outer basic coating formed by the aforementioned colored outer basic coating composition. 7. Irradiation-curable colored outer basic coating composition, which is suitable It is used to form a colored outer basic coating on glass fiber. It is formulated from a composition containing the following components: A homogeneous molecular weight polymer for adhesion adjustment, which has more than one type of radiation-curable function bonded to a low surface backbone. Group, and is not substantially ketone and fluorine, the aforementioned molecular weight polymer for adhesion adjustment is characterized in that it has a number average molecular weight of 1,000 to 8,000, and 5% to 40% are composed of hydrocarbon side chains. 8 If the belt-shaped component of item 1 of the patent application scope is characterized in that the aforementioned molecular weight polymer for adjusting adhesive force contains the following chemical formula (please read the precautions on the back before filling this page), 11 intellectual property of the Ministry of Economic Affairs Bureau of the Consumer Cooperatives printed the paper scales applicable to China National Standards (CNS) A4 specifications (210X297 mm) -3- 6. At least one of the scope of patent applications, the ingredients listed in the formula reacted: p-( BHCA) m -1-R (2); P-((BHCA) m-A-(BHCA) n,-1) 0, R (3); and R -1-((BHCA) m-A-( BHCA) m -1) n-R. (4), where BHCA is a branched and / or hydroxycarboxylic acid containing a non-terminal hydroxyl functional group, which provides a bond to the polyester backbone when the hydroxyl functional group reacts A hydrocarbon side chain to form an ester group; I is a polyisocyanate compound; A is a polyol; P is a compound containing more than one hydroxyl functional group; R is a hydroxyl functional compound containing a functional group that can be cured by irradiation; η average It is from about 1 to 20; and m is from about 1 to 50 on average. 9 · If the ink coating composition of the second or third item of the patent application scope is characterized by the aforementioned molecular weight polymer for adjusting the adhesion, including (please read the precautions on the back before filling this page) Wisdom of the Ministry of Economic Affairs Employees of the Property Bureau cooperate with each other to print at least one of the following chemical formulas, which should be: The ingredients listed in the formula are anti-P ^ BHCA ^ -Ir "(2); P-((BHCA) m-A -(BHCA) m- l) n-R (3):: and R -1-((8HCA) m-a-(BHCA) m -1) n-R .Η). This paper size applies Chinese national standards (CNS) A4 specifications (21 ×; 297 mm) A8 B8 C8 D8 6. Application scope of patent where BHCA is a branched and / or hydroxycarboxylic acid containing non-terminal hydroxyl functional group, when the hydroxyl functional group reacts Provide a hydrocarbon side chain bonded to the polyester backbone to form an ester group; I is a polyisocyanate compound; A is a polyol; P is a compound containing more than one hydroxyl functional group; R is a functional group containing radiation curable Hydroxy-functional compounds; η is on average from 1 to 20; and m is on average from 1 50 or so. 10. The matrix substance composition according to item 4 or item 5 of the scope of patent application, characterized in that the above-mentioned homogeneous molecular weight polymer for adjusting adhesive force contains at least one of the following chemical formulas. Reaction · P-(BHCA) n, -1-R • (2); P-((BHCA) m-A-(BHCA) m-|) n-R (3); and R-f-(( BHCA) m-A-(BHCA) m-1) n-R. ⑷. Where BHCA is a branched and / or hydroxycarboxylic acid containing a non-terminal hydroxyl functional group, which provides a bond during the reaction of the hydroxyl functional group. Hydrocarbon side chains on the polyester backbone to form ester groups; I is a polyisocyanate compound; A is a polyol; P is a compound containing more than one hydroxyl functional group; (Please read the precautions on the back before filling this page ) Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 5-A8 B8 C8 D8 VII. The scope of patent application R is a functional group that contains curable radiation Hydroxy-functional compounds; η is on average from 1 to 20; and nl is on average From about 1 to 5 zero. 1 1. The colored outer basic coating composition according to item 6 or item 7 of the scope of the patent application is characterized in that the above-mentioned homogeneous molecular weight polymer for adjusting adhesive force contains at least one represented by the following chemical formula: Reacts: P-(BHCA) m -1-R '(2); P-((BHCA) m-A-(BHCA) m- l) n-R (3); and R-1 -((BHCA) m-A-(BHCA) m-1) n-R. ⑷. Where BHC A is a branched and / or hydroxycarboxylic acid containing a non-terminal hydroxyl functional group, the functional group is in the hydroxyl function Provides a hydrocarbon side chain bonded to the polyester backbone during the radical reaction to form an ester group; I is a polyisocyanate compound: A is a polyol; P is a compound containing more than one hydroxyl functional group; R is a compound containing radiation. The hydroxy-functional compound of the cured functional group; η is from about 1 to about 20 on average; and m is from about 1 to about 50 on average. 12. The belt-shaped component according to item 1 of the scope of patent application, characterized in that the above-mentioned homogeneous molecular weight polymer for adjusting adhesive force contains at least one represented by the following chemical formula, and the components listed in the formula react: Please read the notes on the back before filling out this page), 1T + Consumer cooperation with the Intellectual Property Bureau of the Ministry of Economic Affairs, printed on this paper, applicable to China National Standards (CNS) Α4 size (210 × 297 mm) -6- A8 B8 C8 ______ D8 VI. Scope of patent application R-I-((BHCA),-A-(BHCA) „-l) w-R ⑺ (Please read the precautions on the back before filling out this page) where R = hydroxyl functional, irradiation Curable compounds: I = polyisocyanate compound; BHCA = branched, and / or hydroxycarboxylic acid containing non-terminal hydroxy-functional groups, which functional groups provide a polymer attached to the polyester backbone when the hydroxy-functional groups react. Carbon side chains to form ester groups; A is a polyhydric alcohol; W = 1 to 20 or so (on average): and S + V = 4 to 20 (on average). 1 3. If a patent is applied for Composition of Ink Coatings in Scope 2 or 3 , Which is characterized in that the aforementioned molecular weight polymer for adjusting adhesive force contains at least one represented by the following chemical formula, and the components listed in the chemical formula react: R -1-((BHCA) S-A-(BHCA ) V- |) w-R ⑺ where R = hydroxyl-functional, radiation-curable compounds; printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs I = polyisocyanate compounds; BHCA = branched and / or non-terminal A hydroxycarboxylic acid of a hydroxy-functional group, which provides a carbon-containing side chain attached to the polyester backbone when the hydroxy-functional group reacts to form an ester group; A is a polyhydric alcohol: w = 1 to about 20 ( (On average); and S + V = 4 to 20 (on average). This paper size is applicable to China National Standards (CNS) A4 Washing (2 丨 0X297 mm) A8 B8 C8 D8 6. Scope of patent application (Please read the precautions on the reverse side before filling out this page) 1 4. If the matrix substance composition of item 4 or item 5 of the patent application scope is characterized by the aforementioned homogeneous molecular weight polymer for adhesion adjustment, it contains the following The chemical formula represents at least The components listed in the formula react: RI-((BHCA) sA- (8HCA) vI) w -R (7) where R = hydroxyl-functional, radiation-curable compound; I = polyisocyanate compound; BHCA = a branched and / or hydroxycarboxylic acid containing a non-terminal hydroxy-functional group that provides a carbon-containing side chain attached to the polyester backbone when the hydroxy-functional group reacts to form an ester group; A Is a polyol; W = 1 to 20 (on average): and S + V = 4 to 20 (on average). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 15. If the colored external basic coating composition of the patent application scope item 6 or item 7 is characterized by the aforementioned molecular weight polymer for adjusting adhesion, it contains the following chemical formula At least one of the components represented in the formula reacts: RI-((BHCA) SA- (BHCA) V- |) W.r (7) where R = hydroxyl-functional, radiation-curable compound; I = Polyisocyanate compound; BHCA = Branched and / or non-terminal hydroxycarboxylic acid-containing hydroxycarboxylic acid. This functional group is provided on the polyester backbone when the hydroxyfunctional group reacts. 8- This paper is applicable to China Standard (CNS) A4 specification (210X297 mm) A8 B8 C8 D8 VI. Carbon-containing side chains on the scope of patent application to form ester groups; A is a polyol; W = 1 to 20 (on average ): And S + V = 4 to 20 (on average). ] [6. The belt-shaped component according to item 1 of the scope of patent application, characterized in that the aforementioned molecular weight polymer for adjusting adhesive force contains at least one represented by the following chemical formula, and the components listed in the formula react: HA— I-Poly (HSA)-I-HA (8) where HA = hydroxyethyl acrylate, I = isophora diisocyanate; and Poly (HSA) is the following formula (9) to represent CH3. (CH2 ) s C2Hs, IIH- (CH- (CH2) I0.C02) 0-CH2-C-CH2. (O2C- (CH2) I0-CH) c-〇H (9) II C4H9 (CH2) s. CH3 is characterized by B + C = 2 to 20 (on average) ° 1 7. If the ink coating composition of the second or third item of the patent application scope is characterized by the aforementioned molecular weight for adhesion adjustment The 'polymer' contains at least one of the following chemical formulae, the ingredients listed in the formula react: HA-I-Poly (HSA)-I- HA (8) where HA = hydroxyethyl acrylate, I = Isophorone diisocyanate; and P 〇 y (HSA) is represented by the following formula (9) (please read the precautions on the back before filling this page). This paper uses China National Standard (CNS) A4 specification (210X297 mm) -9-A8 B8 C8 D8 patent application scope c2hs CH3; (CH2) s I / ru) 0-CH) c-〇H. (CH ^ o-CO ^ -CHrC-CH.XO ^ CH ^ o, '(CH2kCH3 (9), HO- (Ch' is characterized by B + C = 2 to 20 (on average) ° work 8. The matrix substance composition in the scope of the patent application No. 4 or No. 5 is characterized in that the aforementioned homogeneous molecular weight polymer for adjusting adhesive force contains at least one represented by the following chemical formula, and the components listed in the formula react with HA-I 1 y (HSA)-I-HA 8 (please read the notes on the back before filling out this page) where HA = hydroxyethyl acrylate 'I = isophorone diisocyanate; and Poly (HSA) is below Formula (9) to represent CH3. (CH2) s C2Hs II HO- (CH- (CH2), 0C02) b-CH2-C-CH2. (O2C- (CH2), 0-CH) c-OH IIC, H9 (CH2) ^ CH3 (9) Order printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, which is characterized by B + C = 2 to 20 (on average) ° 1 9. If the scope of patent application is the 6th or 7th The colored outer basic covering composition is characterized by the aforementioned adhesion A homogeneous molecular weight polymer for regulation, which contains at least one of the components represented by the formula below: HA-I y (HSA)-I-HA 8 where HA = hydroxyethyl acrylate, I = Isophorone diisocyanate; and Poly (HSA) is the following formula (9) to represent the paper size, using the Chinese National Standard (CNS) A4 specification (210X297 mm) _ _ A8 B8 C8 D8 VI. Patent application Range CH3. (CH2) 5 pHs h0- (L- (ch2wc〇2) b-ch2-c-ch2. (Q2c- (chqiaoH) c-〇H (9) C4H9 (CH2) s.CH3 Features It is B + C = about 2 to 20 (on average) ° 2 ◦. For example, the band component of item 16 of the patent application scope is characterized by b + C = about 5 to 15 (on average) ° 2 1. If the ink coating composition of item 17 in the patent application scope is characterized by B + C = 5 to 15 (on average) ° 2 2. If the matrix material composition of the item 18 of the patent application scope, It is characterized by B + C = 5 to 15 (on average) ° 2 3. As the colored external basic coating composition of item 19 in the scope of patent application, it is characterized by B + C = 5 to 15 (average) Say) ° (Please read the precautions on the back before filling out this page} Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 2 4. If the belt-shaped component of the first scope of patent application: 'It is characterized by the aforementioned adhesion adjustment A homogeneous molecular weight polymer containing at least one of the components represented by the following formula was reacted: R-1-(A-(PAC-A) J -1-R (1〇); R- (PAC-A),-I-R (11): and R-(PAC-(A-PAC) ()-R (12). Where PAC is a polycarboxylic acid compound; I = polyisocyanate compound; R = hydroxyl Functional radiation-curable compounds; A = polyol; and t = 1 to about 20 (on average), which is characterized by polycarboxylic acid or the size of this paper applicable + National Standards (CNS) A4 (210X297) Mm) _ '] _ A8 B8 C8 D8 VI. Patent application scope At least one of the polyols is a branched' provide polyester backbone ', which has a carbon-containing side chain, or the polyol contains non-terminal functional groups The base 'provides a polyester backbone with carbon-containing side chains' for radical functionality With carboxylic acids to form ester functional groups. 2 5. The ink coating composition according to item 2 or item 3 of the scope of patent application, characterized in that the above-mentioned homogeneous molecular weight polymer for adjusting adhesive force contains at least one of the ingredients listed in the following formula: Reacted: (1〇): (11); and (12), (Please read the notes on the back before filling in this card) R-I-(A-(PAC-A) ()-I-RR- (PAC-Λ), -1-RR-(PAC-(A-PAC) t)-R where PAC is a polycarboxylic acid compound; 1 = polyisocyanate compound; R = hydroxyl-functional radiation-curable compound; A = Polyols; and printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs at t = 1 to 20 (on average), characterized by at least one of a polycarboxylic acid or a polyhydric alcohol being branched, providing carbon-containing side chains The polyester backbone, or the polyol containing non-terminal hydroxyl functional groups, provides a polyester backbone with a carbon-containing side chain, and the hydroxyl functional group reacts with the residual acid to form an ester functional group. The matrix substance composition according to item 4 or item 5, characterized in that the aforementioned adhesive force is adjusted Sub-quantity polymer, containing at least one of the following chemical formulas, the ingredients listed in the formula are anti--12- This paper size applies to China National Standards (CNS) A4 specifications (210X297 mm) A8 B8 C8 D8 Six, The scope of patent application should be: R-i-(A-(PAC-A),)-I-R (1〇); R-(PAC-A),-|-R (11): and R-(PAC- (A-PAC),)-R (12), where PAC is a polycarboxylic acid compound; I = polyisocyanate; R = hydroxyl-functional radiation-curable compound; A = polyol; and t = 1 to Around 20 (on average) 'characterized by at least one of a polycarboxylic acid or a polyol being branched' providing a polyester backbone with a carbon-containing side chain, or a polyol containing a non-terminal hydroxyl functional group, Provide a polyester backbone with a carbon-containing side chain for the hydroxyl functional group to react with osmic acid to form an ester functional group. 27. For example, a colored external basic coating composition in the scope of patent application item 6 or item 7, which It is characterized in that the aforementioned molecular weight polymer for adjusting adhesive force contains at least one of the following formulas: Reacted: R-Ί-(A-(PAC-A),)-I-R (1〇); and R-(PAC-A),-I-R (11) R-(PAC -(A-PAC),)-R (12), where PAC is a polycarboxylic acid compound; I = polyisocyanate compound; R = hydroxyl-functional radiation-curable compound; (Please read the precautions on the back before filling in this Pages), 1T. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, this paper is printed in accordance with China National Standards (CNS) A4 specifications (210X297 mm) _ 13 _ A8 B8 C8 D8 6. Application scope of patents A = polyol; And t = 1 to about 20 (on average), which is characterized by at least one of a polycarboxylic acid or a polyol being branched to provide a polyester backbone with a carbon-containing side chain, or a polyol containing a non-terminal hydroxyl group A functional group that provides a polyester backbone with carbon-containing side chains for the hydroxyl functional group to react with a carboxylic acid to form an ester functional group. 28. The belt-shaped module according to item 1 of the scope of the patent application, characterized in that the aforementioned molecular weight polymer for adjusting adhesive force contains poly (12-hydroxyoctadecanoic acid) urethane acrylate. 2 9. The ink coating composition according to item 2 or item 3 of the scope of patent application, which is characterized in that the aforementioned molecular weight polymer for adjusting adhesion is a poly (1 2 -hydroxyoctadecanoic acid) urethane acrylate . 30. The matrix substance composition according to item 4 or item 5 of the scope of the patent application, characterized in that the aforementioned molecular weight polymer for adjusting adhesion is a poly (1 2_hydroxyoctadecanoic acid) urethane acrylate . 31. The colored external basic coating composition according to item 6 or item 7 of the patent application scope, which is characterized in that the aforementioned molecular weight polymer for adjusting adhesive force contains poly (12-hydroxyoctadecanoic acid) urine Alkyl acrylate. 32. The belt-shaped component according to item 1 of the patent application range, characterized in that the aforementioned ink coating has a surface energy of an average top contact angle of about 65 ° or more. 3 3 · The belt-shaped component ′ of the first item of patent application is characterized by the aforementioned ink coating, which has a surface energy with an average top contact angle of about 70 ° or more. This paper size applies to China National Standards (CNS) A4 specification (210X297 mm) (please read the precautions on the back before filling this page), vs. consumer cooperation with the Intellectual Property Bureau of the Ministry of Economic Affairs, printed -14- A8 B8 C8 D8 6. Scope of patent application (please read the precautions on the back before filling out this page) 3 4. If the ribbon component of the scope of patent application item 1 is characterized by the aforementioned ink coating, it has an average top contact angle of about 7 Surface energy above 5 °. 35. The belt-shaped component according to item 1 of the patent application range, characterized in that the aforementioned ink coating 'has a surface energy with an average top contact angle of about 80 ° or more. 36. The belt-shaped component according to item 1 of the scope of patent application, characterized in that the above-mentioned homogeneous molecular weight polymer for adjusting adhesive force 'has at least a radiation-curable functional group attached to a hydrocarbon trunk. '37. The ink coating composition according to item 2 or item 3 of the scope of patent application, characterized in that the above-mentioned homogeneous molecular weight polymer for adjusting adhesive force contains at least a radiation-curable functional group attached to a hydrocarbon trunk. . 38. The matrix substance composition according to item 4 or item 5 of the scope of patent application, which is characterized in that the aforementioned molecular weight polymer for adjusting adhesive force contains at least a radiation-curable functional group attached to the hydrocarbon trunk. 39. The colored external basic coating composition as claimed in item 6 or 7 of the scope of patent application, characterized in that the aforementioned adhesion adjustment polymer is printed by a polymer co-worker of the Intellectual Property Office of the Ministry of Economic Affairs and Intellectual Property Bureau, which contains at least a polymer The radiation-curable functional group on the hydrocarbon backbone is 040. For example, the belt-shaped component 'in the scope of patent application No. 1 is characterized by the aforementioned homogeneous molecular weight polymer for adhesion adjustment, which contains at least the hydrocarbon backbone Irradiating a curable functional group, the hydrocarbon backbone comprises a homopolymer or copolymer of ethylene, butene, or propylene. 4 1 · If the Ink Covering Group of item 2 or item 3 of the scope of patent application is applied -15- The size of this paper applies the Chinese National Standard (CNS) Λ4 specification (210X297mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 __ 成, a patent-applied product, characterized in that the aforementioned molecular weight polymer for adjusting the adhesive force 'it contains at least a radiation-curable functional group attached to the hydrocarbon trunk' The hydrocarbon. The trunk contains ethylene, butene Or homopolymer or copolymer of propylene. 4 2 · The matrix material composition according to item 4 or item 5 of the patent application, characterized in that the above-mentioned homogeneous molecular weight polymer for adjusting adhesive force contains at least a radiation-curable functional group attached to a hydrocarbon trunk 'The hydrocarbon backbone comprises a homopolymer or copolymer of ethylene, butene or propylene. 43. The colored outer basic coating composition as claimed in item 6 or 7 of the scope of patent application, which is characterized by the aforementioned homogeneous molecular weight polymer for adhesion adjustment, which contains at least a radiation-curable function attached to the hydrocarbon trunk Based, the hydrocarbon backbone comprises homopolymers or copolymers of ethylene, butene or propylene. 4 4. The belt-shaped component according to item 1 of the patent application scope, characterized in that the aforementioned ink coating composition is cured in an air environment. 4 5. The belt-shaped component according to item 1 of the scope of patent application, characterized in that the aforementioned molecular weight polymer for adjusting adhesive force is based on the aforementioned composition that can be cured by irradiation with a total weight of about 1 to 90%. The weight is there. 4 6 · If the ink coating composition of the second or third item of the patent application scope is characterized in that the aforementioned molecular weight polymer for adjusting the adhesive force is based on the total weight of the curable composition of about 1 to about 1 to A quantity of about 90% exists. "4 7. For example, the matrix substance composition of item 4 or item 5 of the patent application scope is characterized by the aforementioned homogeneous molecular weight polymer for adjusting adhesive force, which is based on the aforementioned irradiation. About 1 to 90% of the total weight of the cured composition is present. (Please read the precautions on the back before filling this page), -a * m It This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) -16- Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 Βδ C8 ____ D8 _ VI. Application for patent scope 48. If the colored external basic coating composition of the patent application scope item 6 or 7 is characterized by the aforementioned homogeneous molecular weight polymer for adjusting adhesion, it is based on An amount of about 1 to 90% of the total weight of the curable composition according to the aforementioned irradiation exists. 49. The belt-shaped component according to item 1 of the scope of patent application, characterized in that the aforementioned homogeneous molecular weight polymer for adjusting adhesive force is based on a total weight of the composition that can be cured according to the foregoing irradiation of about 5 to 80%. The weight is there. 50. If the ink coating composition of item 2 or item 3 of the scope of the patent application is characterized by the aforementioned homogeneous molecular weight polymer for tackiness adjustment, the total weight of the curable composition is about 5 to about 5 to About 80% of the amount is present. 5 1 · If the matrix substance composition of item 4 or item 5 of the scope of the patent application is characterized by the aforementioned homogeneous molecular weight polymer for adhesion adjustment, the total weight of the composition which can be cured according to the aforementioned irradiation is about 5 to About 80% of the amount is present. 5 2. If the colored external basic coating composition 'item 6 or 7 of the scope of patent application' is characterized by the aforementioned homogeneous molecular weight polymer for adjusting adhesive force, the total weight of the composition which can be cured according to the aforementioned irradiation Portions of about 5 to 80% are present. 53. The belt-shaped component according to item 1 of the patent application scope, characterized in that the aforementioned molecular weight polymer for adjusting adhesive force is based on the total weight of the composition which can be cured according to the aforementioned irradiation, from about 10 to 70%. There are 0 5 4 of the weight. · If the ink coating set of the second or third item of the patent application scope, the paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) -17- (Please read the back (Please fill in this page again) A8 B8 C8 D8 VI. The patent-applied product is characterized in that the aforementioned molecular weight polymer for adjusting adhesive force is in a quantity of about 10 to 70% of the total weight of the curable composition based on the aforementioned irradiation. With. 5 5 · The matrix substance composition according to item 4 or item 5 of the scope of the patent application, characterized in that the aforementioned molecular weight polymer for adjusting adhesive force is a polymer having a total weight of about 10, which can be cured by the aforementioned irradiation. A serving size of around 70% is present. 56. The colored outer basic coating composition as claimed in item 6 or 7 of the scope of patent application, characterized in that the aforementioned molecular weight polymer for adjusting adhesive force is based on the total weight of the composition that can be cured according to the aforementioned irradiation. Portions of about 10 to 70% are present. 5 7 · If the ink coating composition of the second or third item of the patent application scope is characterized in that the aforementioned molecular weight polymer for adjusting the adhesive force is coated with the ink capable of imparting the aforementioned, the aforementioned matrix substance, or The aforementioned colored exterior is basically covered with a portion of the surface energy presenting an average top contact angle of 65 ° or more. 58. The matrix substance composition according to item 4 or 5 of the scope of the patent application, characterized in that the aforementioned molecular weight polymer for adjusting adhesion is coated with the aforementioned ink, the aforementioned matrix substance, or the aforementioned The amount of surface energy that is substantially covered by the colored outer portion presenting an average top contact angle of 65 ° or more exists. 59. If the colored external basic coating composition of item 6 or 7 of the scope of patent application is characterized by the aforementioned adhesion-adjusting homogeneous molecular weight polymer 'system capable of imparting the aforementioned ink coating, the aforementioned matrix substance, or This paper uses the Chinese National Standard (CNS) A4 specification (210X297 mm) (please read the precautions on the back before filling out this page), 11 Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs-18- A8 B8 C8 D8 Sixth, the scope of patent application The aforementioned colored exterior is basically covered with a surface energy amount that exhibits an average top contact angle of more than 65 °. (Please read the precautions on the reverse side before filling out this page) 6 0. If the ink coating composition of item 2 or item 3 of the patent application scope is characterized by the aforementioned molecular weight polymer for adhesion adjustment, The amount of surface energy imparted to the aforementioned ink coating, the aforementioned matrix substance, or the aforementioned colored exterior coating substantially to exhibit an average top contact angle of at least 70 ° is present. 61. The matrix substance composition according to item 4 or 5 of the scope of application for a patent, characterized in that the aforementioned molecular weight polymer for adjusting adhesive force is a system capable of imparting coating to the aforementioned ink, the aforementioned matrix substance, or the aforementioned The colored exterior is substantially covered to exhibit at least 70. The amount of surface energy present for the average top contact angle of. 62. If the colored external basic coating composition of item 6 or 7 of the scope of patent application is characterized by the aforementioned molecular weight polymer for adjusting the adhesion, it is coated with the aforementioned ink, the aforementioned matrix substance 'or The aforementioned colored exterior is substantially covered with a portion of the surface energy presenting an average top contact angle of at least 70 ° or more. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 63. If the ink coating composition of the second or third item of the patent application scope is characterized by the aforementioned homogeneous molecular weight polymer for adjusting adhesion, it is capable of imparting the aforementioned The ink coating, the aforementioned substrate substance 'or the aforementioned colored exterior is substantially coated with a surface energy amount presenting an average top contact angle of at least 75 °. 64. If the matrix substance composition of item 4 or item 5 of the scope of patent application is characterized by the aforementioned homogeneous molecular weight polymer for adjusting adhesion, the paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). ^. A8 B8 C8 D8 39 ^ 156 6. Scope of patent application (please read the precautions on the back before filling this page) to be able to give the aforementioned ink coating, the aforementioned matrix substance, or the aforementioned colored The portion of the surface energy that is substantially coated to exhibit an average top contact angle of at least 75 ° is present. 65. If the colored outer basic covering composition of the patent application scope item 6 or item 7, is characterized in that the aforementioned adhesion-adjusting homogeneous molecular weight polymer is used to give the aforementioned ink coating, the aforementioned matrix substance, Or the aforementioned colored exterior is substantially covered with a surface energy fraction presenting an average top contact angle of at least 75 °. 6 6. The ink coating composition according to item 2 or 3 of the patent application scope, characterized in that the aforementioned molecular weight polymer for adjusting the adhesive force is coated with the aforementioned ink, the aforementioned matrix substance, or the aforementioned The amount of surface energy that is substantially covered by the colored exterior is present to exhibit an average top contact angle of at least 80 °. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 67. If the matrix substance composition in the scope of patent application No. 4 or No. 5 is characterized in that the aforementioned molecular weight polymer for adjusting adhesion is used to impart the aforementioned ink The coating, the aforementioned matrix material, or the aforementioned colored exterior is substantially coated in a quantity of surface energy presenting an average top contact angle of at least 80 °. 6 8. If the colored external basic coating composition of item 6 or 7 of the scope of patent application is characterized by the aforementioned homogeneous molecular weight polymer for adjusting adhesion, it is coated with the aforementioned ink and the aforementioned matrix substance, Or the aforementioned colored exterior is substantially covered with a portion of the surface energy presenting an average top contact angle of at least 80 °. 6 9 · If the ink coating composition in item 3 of the patent application scope, its -20- This paper size is applicable to China National Standard (CNS) A4 specifications (210X297 mm) B8 C8 D8 399156 The number of homogeneous molecular weight polymers for adjusting adhesion is at least 10% and the average molecular weight is composed of hydrocarbon side chains. (Please read the precautions on the back before filling in this page) 7 0 · If the matrix substance composition in the scope of patent application No. 5 is characterized by the number of the aforementioned molecular weight polymers for adjusting the adhesion, the average molecular weight is at least 10% It consists of hydrocarbon side chains. 71. The colored outer basic coating composition according to item 7 of the scope of patent application, characterized in that the number of the aforementioned molecular weight polymers for adjusting the adhesive force is at least 10%, and the average molecular weight is composed of hydrocarbon side chains. 72. The ink coating composition according to item 3 of the scope of patent application, characterized in that the average molecular weight of the number-average molecular weight polymer of the aforementioned adhesion adjusting homogeneous molecular weight of at least 15% is composed of a hydrocarbon side chain. 73. The matrix substance composition according to item 5 of the scope of patent application, characterized in that the number-average molecular weight of the aforementioned homogeneous molecular weight polymer for adhesion adjustment is at least 15%, which is composed of hydrocarbon side chains. 74. The colored outer basic coating composition according to item 7 of the scope of the patent application, characterized in that the number-average molecular weight of the above-mentioned homogeneous molecular weight polymer for adhesion adjustment is at least 15% and is composed of a hydrocarbon side chain. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 75. For example, the ink coating composition of the third patent application scope is characterized in that the above-mentioned number of homogeneous molecular weight polymers for adjusting adhesion is less than 30% of the average molecular weight. Hydrocarbon side chain composition. 7 6 · The ink coating composition according to item 5 of the scope of patent application, characterized in that the above-mentioned average molecular weight of the number of homogeneous molecular weight polymers for adjusting adhesion is less than 30%, which is composed of hydrocarbon side chains. 77. If the colored external basic covering group of the scope of the patent application is No. 7, the paper size is applicable to the Chinese National Slope (CNS) A4 specification (210 > < 297 Publication 1 〇1-" A8 B8 C8 D8 399156 々, The patent application product is characterized by the fact that the number of the aforementioned molecular weight polymers for adjusting the adhesion is equal to or less than 30% of the average molecular weight and is composed of hydrocarbon side chains. 7 8. The ink coating composition as described in item 3 of the patent application scope It is characterized in that the above-mentioned number of homogeneous molecular weight polymers for adjusting adhesive force is less than 20% of the average molecular weight and is composed of hydrocarbon side chains. 79. The matrix substance composition according to item 5 of the patent application scope is characterized in that The number of homogeneous molecular weight polymers for adjusting adhesion is less than 20% of the average molecular weight, and is composed of hydrocarbon side chains. 8 〇 The colored outer basic coating composition according to item 7 of the patent application scope, which is characterized by the aforementioned adjustment of adhesion The number of homogeneous molecular weight polymers is less than 20% of the average molecular weight, which is composed of hydrocarbon side chains. 8 1 · The ink coating composition according to item 3 of the patent application scope, which is characterized by the aforementioned hydrocarbon Chain, which contains a low alkyl group or an aryl group having 3 to 30 carbon atoms substituted with an alkyl group "8 2 · The matrix substance composition according to item 5 of the patent application scope, which is characterized by the aforementioned hydrocarbon side chain It contains a lower alkyl group, or an aryl group having 3 to 30 carbon atoms substituted with an alkyl group. 8 3. The colored outer basic coating composition as claimed in item 7 of the patent application scope, which is characterized by the aforementioned hydrocarbon side Chain, which contains a lower alkyl group, or an aryl group having 3 to 30 carbon atoms substituted with an alkyl group. 8 4. The ink coating composition according to item 3 of the patent application, which is characterized by the aforementioned hydrocarbon side chain. It contains a low alkyl group or an aryl group having 5 to 20 carbon atoms substituted by an alkyl group. 8 5. If the matrix substance composition of the scope of patent application No. 5 is applied, the paper size is applicable to the Chinese national standard (CNS) Λ4 specification (210X297 mm) (Please read the precautions on the back before filling this page),-° Printed by the Consumer Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -22- A8 399156 A hydrocarbon side chain that contains a low alkyl 'or alkyl group Substituted aryl groups having 5 to 20 carbon atoms 86. The colored outer basic coating composition as claimed in item 7 of the scope of patent application, characterized by the aforementioned hydrocarbon side chain, which contains a low alkyl group or is substituted by an alkyl group Aryl group having 5 to 20 carbon atoms ° 8 7. The ink coating composition according to item 3 of the patent application scope, characterized in that the aforementioned hydrocarbon side chain is separated along the trunk of the aforementioned comb-like structure 〇8. If the matrix substance composition of the scope of the patent application item 5 is characterized in that the aforementioned hydrocarbon side chain is separated along the trunk of the aforementioned comb-like structure 0 8 9 The material composition is characterized in that the aforementioned hydrocarbon side chains are separated along the trunk of the aforementioned comb-like structure (please read the precautions on the back before filling in this page). Standards apply to China National Standard (CNS) A4 (210X297 mm) -23-