RU2405793C2 - Стабилизация фотохромных систем - Google Patents
Стабилизация фотохромных систем Download PDFInfo
- Publication number
- RU2405793C2 RU2405793C2 RU2006114602/05A RU2006114602A RU2405793C2 RU 2405793 C2 RU2405793 C2 RU 2405793C2 RU 2006114602/05 A RU2006114602/05 A RU 2006114602/05A RU 2006114602 A RU2006114602 A RU 2006114602A RU 2405793 C2 RU2405793 C2 RU 2405793C2
- Authority
- RU
- Russia
- Prior art keywords
- composition according
- photochromic
- alkyl
- group
- hydrogen
- Prior art date
Links
- 230000006641 stabilisation Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract 10
- 150000001412 amines Chemical class 0.000 claims abstract 8
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000004611 light stabiliser Substances 0.000 claims abstract 3
- 239000002861 polymer material Substances 0.000 claims abstract 3
- 239000000126 substance Substances 0.000 claims abstract 2
- 239000000975 dye Substances 0.000 claims 8
- 229910052739 hydrogen Inorganic materials 0.000 claims 8
- -1 C 1 -C 4 alkyl Substances 0.000 claims 6
- 239000006096 absorbing agent Substances 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 229920000642 polymer Polymers 0.000 claims 6
- 150000002431 hydrogen Chemical class 0.000 claims 4
- 239000011159 matrix material Substances 0.000 claims 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 4
- 125000002947 alkylene group Chemical group 0.000 claims 3
- 230000000087 stabilizing effect Effects 0.000 claims 3
- 125000001424 substituent group Chemical group 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 239000012634 fragment Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- 229920000515 polycarbonate Polymers 0.000 claims 2
- 239000004417 polycarbonate Substances 0.000 claims 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims 2
- 239000003381 stabilizer Substances 0.000 claims 2
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims 1
- MJPPGVVIDGQOQT-UHFFFAOYSA-N 2-bromo-5-(2-bromo-2-nitroethenyl)furan Chemical compound [O-][N+](=O)C(Br)=CC1=CC=C(Br)O1 MJPPGVVIDGQOQT-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 claims 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims 1
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000004450 alkenylene group Chemical group 0.000 claims 1
- 125000003302 alkenyloxy group Chemical group 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000005037 alkyl phenyl group Chemical group 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- LCIYFINKFGDAHD-UHFFFAOYSA-N azepane;3-nitrobenzoic acid Chemical compound C1CCCNCC1.OC(=O)C1=CC=CC([N+]([O-])=O)=C1 LCIYFINKFGDAHD-UHFFFAOYSA-N 0.000 claims 1
- 150000001562 benzopyrans Chemical class 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 229920003086 cellulose ether Polymers 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000000000 cycloalkoxy group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000002993 cycloalkylene group Chemical group 0.000 claims 1
- 238000002845 discoloration Methods 0.000 claims 1
- 125000003073 divalent carboacyl group Chemical group 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 239000003063 flame retardant Substances 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 229920005669 high impact polystyrene Polymers 0.000 claims 1
- 239000004797 high-impact polystyrene Substances 0.000 claims 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 1
- 230000003287 optical effect Effects 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 claims 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract 2
- 239000006100 radiation absorber Substances 0.000 abstract 1
- 230000002441 reversible effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03103587 | 2003-09-29 | ||
| EP03103587.6 | 2003-09-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006114602A RU2006114602A (ru) | 2007-11-20 |
| RU2405793C2 true RU2405793C2 (ru) | 2010-12-10 |
Family
ID=34384662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006114602/05A RU2405793C2 (ru) | 2003-09-29 | 2004-09-20 | Стабилизация фотохромных систем |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US20070064195A1 (enExample) |
| EP (1) | EP1709114A1 (enExample) |
| JP (1) | JP4764822B2 (enExample) |
| KR (1) | KR101099452B1 (enExample) |
| CN (1) | CN1860167B (enExample) |
| AU (1) | AU2004275997B2 (enExample) |
| BR (1) | BRPI0414852A (enExample) |
| CA (1) | CA2538031C (enExample) |
| MY (1) | MY149850A (enExample) |
| RU (1) | RU2405793C2 (enExample) |
| TW (1) | TWI385204B (enExample) |
| WO (1) | WO2005030856A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005041952A1 (de) * | 2005-09-03 | 2007-03-08 | Bayer Materialscience Ag | Zusammensetzungen enthaltend Polycarbonat und neuartige UV-Absorber |
| ATE406413T1 (de) * | 2006-01-27 | 2008-09-15 | Ems Chemie Ag | Photochrome formmassen und daraus hergestellte gegenstände |
| CN100389168C (zh) * | 2006-04-04 | 2008-05-21 | 吉林大学 | 基底诱导同一染料分子发不同颜色荧光的方法 |
| US7667285B2 (en) | 2006-12-14 | 2010-02-23 | Motorola, Inc. | Printed electronic substrate havine photochromic barrier layer |
| BRPI0807143A2 (pt) * | 2007-02-06 | 2014-04-15 | Basell Polyolefine Gmbh | Itens fotocrômicos flexíveis e/ou rígidos para embalar itens sensíveis à luz |
| DE102007011069A1 (de) | 2007-03-07 | 2008-09-11 | Bayer Materialscience Ag | Polycarbonatzusammensetzung enthaltend UV-Absorber |
| EP2022820B1 (de) | 2007-07-25 | 2016-08-24 | Ems-Patent Ag | Photochrome formmassen und daraus hergestellte gegenstände |
| US8609300B2 (en) * | 2009-06-25 | 2013-12-17 | Sabic Innovative Plastics Ip B.V. | Method of making holographic recording materials and articles formed thereby |
| JP2013035877A (ja) * | 2009-12-10 | 2013-02-21 | Tokuyama Corp | フォトクロミック組成物 |
| WO2011139319A1 (en) * | 2010-05-03 | 2011-11-10 | Kent State University | Smart photochromic chiral nematic liquid crystal window |
| US8715887B2 (en) | 2010-07-30 | 2014-05-06 | Sabic Innovative Plastics Ip B.V. | Complex holograms, method of making and using complex holograms |
| EP2447236A1 (de) | 2010-10-12 | 2012-05-02 | Bayer MaterialScience AG | Spezielle UV-Absorber für härtbare UV-Schutz Beschichtungen |
| US9187668B2 (en) | 2011-10-27 | 2015-11-17 | Chromatic Technologies, Inc. | Photochromic inks |
| US8871424B2 (en) * | 2012-01-20 | 2014-10-28 | Cryovac, Inc. | Laser imageable polyolefin film |
| CN102898791A (zh) * | 2012-09-21 | 2013-01-30 | 江西科为薄膜新型材料有限公司 | 具有变色功能的pet薄膜 |
| JP5693689B2 (ja) * | 2012-09-24 | 2015-04-01 | 富士フイルム株式会社 | セルロースアシレートフィルム、それを用いた偏光板および液晶表示装置 |
| CN103275509A (zh) * | 2013-06-21 | 2013-09-04 | 苏州新区特氟龙塑料制品厂 | 一种变色塑料 |
| CN103911877B (zh) * | 2014-04-17 | 2016-01-13 | 傅科杰 | 一种用于纺织面料的变色剂 |
| US10253164B2 (en) * | 2014-05-15 | 2019-04-09 | Basf Se | Highly effective stabilizer |
| WO2017008974A1 (en) | 2015-07-14 | 2017-01-19 | Unilever Plc | Antimicrobial composition |
| WO2017047745A1 (ja) * | 2015-09-16 | 2017-03-23 | 三井化学株式会社 | 光学材料用重合性組成物、該組成物から得られる光学材料およびプラスチックレンズ |
| KR102063056B1 (ko) * | 2016-02-01 | 2020-01-07 | 주식회사 엘지화학 | 점착제 조성물, 그 조성물의 경화물을 포함하는 봉지층을 포함하는 태양전지용 봉지재 시트 및 상기 봉지재 시트를 포함하는 태양전지 모듈 |
| CN107828407A (zh) * | 2017-11-30 | 2018-03-23 | 天津工业大学 | 一种固态囊芯的变色微纳胶囊及其制备方法 |
| TWI754807B (zh) * | 2019-04-10 | 2022-02-11 | 財團法人紡織產業綜合研究所 | 聚酯光變色組成物以及聚酯光變色纖維的製備方法 |
| TWI754918B (zh) * | 2020-04-20 | 2022-02-11 | 財團法人紡織產業綜合研究所 | 光變色聚丙烯纖維及其製備方法 |
| TWI798707B (zh) | 2021-05-28 | 2023-04-11 | 財團法人紡織產業綜合研究所 | 光變色阻熱纖維和其製備方法 |
| CN113416516B (zh) * | 2021-06-18 | 2022-11-11 | 北京天山新材料技术有限公司 | 丙烯酸酯厌氧胶、用于形成其的组合物及应用 |
| WO2025225708A1 (ja) * | 2024-04-26 | 2025-10-30 | 株式会社クラレ | フォトクロミックフィルム、樹脂膜、及び積層体 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2125049C1 (ru) * | 1991-02-21 | 1999-01-20 | Циба Спешиалти Кемикэлс Холдинг Инк. | Гидроксифенилтриазины |
| US6060543A (en) * | 1996-09-13 | 2000-05-09 | Ciba Specialty Chemicals Corporation | Stabilizer combination |
| US6255483B1 (en) * | 1995-03-15 | 2001-07-03 | Ciba Specialty Chemicals Corporation | Biphenyl-substituted triazines |
| RU2191178C2 (ru) * | 1996-11-20 | 2002-10-20 | Циба Спешиалти Кемикалс Холдинг Инк. | Симметричные производные триазина и способ их получения (варианты) |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3485764A (en) * | 1964-05-22 | 1969-12-23 | American Cyanamid Co | Polymeric photochromic compositions stabilized with ultraviolet light absorbers |
| US5200116A (en) * | 1990-07-23 | 1993-04-06 | Ppg Industries, Inc. | Photochromic chromene compounds |
| JPH06184355A (ja) * | 1992-12-16 | 1994-07-05 | Sumitomo Chem Co Ltd | フォトクロミック性能を有する樹脂組成物 |
| US5556973A (en) * | 1994-07-27 | 1996-09-17 | Ciba-Geigy Corporation | Red-shifted tris-aryl-s-triazines and compositions stabilized therewith |
| EP1213283B1 (en) * | 1995-03-15 | 2009-04-29 | Ciba Holding Inc. | Biphenyl-substituted triazines as light stabilisers |
| US5770115A (en) * | 1996-04-19 | 1998-06-23 | Ppg Industries, Inc. | Photochromic naphthopyran compositions of improved fatigue resistance |
| IT1292461B1 (it) * | 1997-07-03 | 1999-02-08 | Great Lakes Chemical Italia | Composti fotocromatici,procedimento per la loro preparazione e loro utilizzo in materiali polimerici |
| ITMI980366A1 (it) * | 1998-02-25 | 1999-08-25 | Ciba Spec Chem Spa | Preparazione di eteri amminici stericamente impediti |
| GB2382348B (en) | 2000-07-26 | 2004-04-21 | Ciba Sc Holding Ag | Polyolefin film for protected environment |
| CO5231248A1 (es) * | 2000-07-26 | 2002-12-27 | Ciba Sc Holding Ag | Articulos transparentes de polimero de baja consistencia |
| US6547390B1 (en) * | 2000-09-11 | 2003-04-15 | Exxene Corporation | Top stabilized photochromic lens system |
| JP3922873B2 (ja) * | 2000-09-29 | 2007-05-30 | 株式会社トクヤマ | 硬化性組成物 |
| ZA200301683B (en) * | 2002-03-04 | 2004-09-06 | Ciba Sc Holding Ag | Synergistic combinations of UV absorbers for pigmented polyolefins. |
-
2004
- 2004-09-17 MY MYPI20043803A patent/MY149850A/en unknown
- 2004-09-20 US US10/572,154 patent/US20070064195A1/en not_active Abandoned
- 2004-09-20 CN CN2004800282267A patent/CN1860167B/zh not_active Expired - Fee Related
- 2004-09-20 KR KR1020067005755A patent/KR101099452B1/ko not_active Expired - Fee Related
- 2004-09-20 RU RU2006114602/05A patent/RU2405793C2/ru not_active IP Right Cessation
- 2004-09-20 JP JP2006530247A patent/JP4764822B2/ja not_active Expired - Fee Related
- 2004-09-20 BR BRPI0414852-5A patent/BRPI0414852A/pt not_active Application Discontinuation
- 2004-09-20 CA CA2538031A patent/CA2538031C/en not_active Expired - Fee Related
- 2004-09-20 EP EP04787170A patent/EP1709114A1/en not_active Withdrawn
- 2004-09-20 WO PCT/EP2004/052238 patent/WO2005030856A1/en not_active Ceased
- 2004-09-20 AU AU2004275997A patent/AU2004275997B2/en not_active Ceased
- 2004-09-27 TW TW093129170A patent/TWI385204B/zh not_active IP Right Cessation
-
2009
- 2009-07-24 US US12/508,641 patent/US8262945B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2125049C1 (ru) * | 1991-02-21 | 1999-01-20 | Циба Спешиалти Кемикэлс Холдинг Инк. | Гидроксифенилтриазины |
| US6255483B1 (en) * | 1995-03-15 | 2001-07-03 | Ciba Specialty Chemicals Corporation | Biphenyl-substituted triazines |
| US6060543A (en) * | 1996-09-13 | 2000-05-09 | Ciba Specialty Chemicals Corporation | Stabilizer combination |
| RU2191178C2 (ru) * | 1996-11-20 | 2002-10-20 | Циба Спешиалти Кемикалс Холдинг Инк. | Симметричные производные триазина и способ их получения (варианты) |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2538031A1 (en) | 2005-04-07 |
| JP2007507569A (ja) | 2007-03-29 |
| US8262945B2 (en) | 2012-09-11 |
| KR20060090811A (ko) | 2006-08-16 |
| MY149850A (en) | 2013-10-31 |
| WO2005030856A8 (en) | 2006-08-03 |
| US20090289236A1 (en) | 2009-11-26 |
| BRPI0414852A (pt) | 2006-11-21 |
| RU2006114602A (ru) | 2007-11-20 |
| AU2004275997A1 (en) | 2005-04-07 |
| WO2005030856A1 (en) | 2005-04-07 |
| CN1860167B (zh) | 2011-01-26 |
| AU2004275997B2 (en) | 2010-07-22 |
| TW200512281A (en) | 2005-04-01 |
| CA2538031C (en) | 2015-03-17 |
| TWI385204B (zh) | 2013-02-11 |
| JP4764822B2 (ja) | 2011-09-07 |
| CN1860167A (zh) | 2006-11-08 |
| EP1709114A1 (en) | 2006-10-11 |
| US20070064195A1 (en) | 2007-03-22 |
| KR101099452B1 (ko) | 2011-12-28 |
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