RU2224746C2 - Фитопатогенный фунгицид, производное 2-пиридилметиламина, фунгицидная композиция, способ борьбы с фитопатогенными грибами - Google Patents

Фитопатогенный фунгицид, производное 2-пиридилметиламина, фунгицидная композиция, способ борьбы с фитопатогенными грибами Download PDF

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RU2224746C2
RU2224746C2 RU2000124062/04A RU2000124062A RU2224746C2 RU 2224746 C2 RU2224746 C2 RU 2224746C2 RU 2000124062/04 A RU2000124062/04 A RU 2000124062/04A RU 2000124062 A RU2000124062 A RU 2000124062A RU 2224746 C2 RU2224746 C2 RU 2224746C2
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Брайан Энтони МОЛОНИ (GB)
Брайан Энтони МОЛОНИ
Дэвид ХАРДИ (GB)
Дэвид ХАРДИ
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Элизабет Энн САВИЛЛЬ-СТОУНЗ
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Abstract

Описывается фитопатогенный фунгицид, содержащий соединение формулы (I)
Figure 00000001

где А1 - 2-пиридил, имеющий до 2 заместителей, которые могут быть одинаковыми или различными и выбраны из галогена, алкила, состоящего из 1-5 атомов углерода, замещенного галогеном; группы -OSO2R5а, где R5а - алкил, состоящий из 1-5 атомов углерода; циано, -СООR5а, А2 - фенил, необязательно замещенный до 5 заместителями, одинаковыми или различными, выбранными из группы, включающей галоген, циано, гидрокси, нитро; радикалы Е, ОЕ, SE, где Е - алкил, состоящий из 1-5 атомов углерода, фенил или пирролил, причем каждый из них может быть замещен галогеном или цианогруппой; 2-фталимидо, и -СООR5а, аминогруппа, замещенная двумя алкильными группами, состоящими из 1-5 атомов углерода, L - группы, включающие -(С=О)-, -(С=S)-, -(SO2)-; R1 - водород, алкил, состоящий из 1-5 атомов углерода, необязательно замещенный цианогруппой или фенилом, СООR5а; R2 - водород, алкил, состоящий из 1-5 атомов углерода, или его соль. Описываются производное 2-пиридилметиламина формулы (I) или его соль, его R1 и R2 - водород, А1, А2, L имеют значения, указанные выше, фунгицидная композиция и способ борьбы с фитопатогенными грибами, использующие указанные выше соединения. Технический результат - высокая фунгицидная активность заявленных соединений. 4 с.п. ф-лы, 4 табл.

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Claims (6)

1. Фитопатогенный фунгицид, содержащий соединение формулы (I)
Figure 00000044
где А1 представляет 2-пиридил, имеющий до 2 заместителей, которые могут быть одинаковыми или различными и выбраны из галогена; алкила, состоящего из от 1 до 5 атомов углерода, замещенного галогеном; группы -OSO2R5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода; циано; и -COOR5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода;
А2 представляет фенил, необязательно замещенный до 5 заместителями, которые могут быть одинаковыми или различными и выбраны из группы, включающей галоген, циано, гидрокси, нитро, радикалы Е, ОЕ, SE, где Е является алкилом, состоящим из от 1 до 5 атомов углерода, фенилом или пирролилом, причем каждый из них может быть замещен галогеном или цианогруппой, 2-фталимидо и -COOR5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода, и аминогруппу, замещенную двумя алкильными группами, состоящими из от 1 до 5 атомов углерода;
L выбирают из группы, включающей -(С=O)-, -(C=S)-, -(SO2)-;
R1 является водородом; алкилом, состоящим из от 1 до 5 атомов углерода, необязательно замещенным цианогруппой или фенилом; и -COOR5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода;
R2 является водородом или алкилом, состоящим из от 1 до 5 атомов углерода;
или его соль.
2. Производное 2-пиридилметиламина формулы (I)
Figure 00000045
A1 представляет 2-пиридил, имеющий заместители в положении 3 и/или 5, а не в другом положении, причем заместители выбраны из группы, включающей галоген, алкил, состоящий из от 1 до 5 атомов углерода, замещенный галогеном, группу –SO2OR5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода, циано, и -COOR5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода;
А2 представляет фенил, необязательно замещенный до 5 заместителями, которые могут быть одинаковыми или различными и выбраны из группы, включающей галоген, циано, гидрокси, нитро, радикалы Е, ОЕ, SE, где Е является алкилом, состоящим из от 1 до 5 атомов углерода, фенилом или пирролилом, причем каждый из них может быть замещен галогеном или цианогруппой, 2-фталимидо и -COOR5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода, и аминогруппу, замещенную дзумя алкильными группами, состоящими из от 1 до 5 атомов углерода,
L выбирают из группы, включающей -(С=O)-, -(C=S)-, -(SO2)-;
R1 и R2 являются водородом;
или его соль.
3. Фунгицидная композиция, включающая производные 2-пиридилметиламина по п.2 в смеси с приемлемым для сельского хозяйства разбавителем или носителем.
4. Способ борьбы с фитопатогенными грибами в зараженном или подверженном заражению ими очаге, который включает нанесение в очаг соединения формулы (I) по п.1 или 2.
Приоритет по пунктам и признакам:
19.02.1998 при А1 - 2-пиридил, замещенный хлором, СF3; А2 - фенил, необязательно, замещенный до 5 заместителями, которые могут быть одинаковыми или различными и выбраны из группы, включающей галоген, циано, гидрокси, нитро, радикалы Е, ОЕ, SE, где Е является алкилом, состоящим из от 1 до 5 атомов углерода, фенилом или пирролилом, причем каждый из них может быть замещен галогеном или цианогруппой, 2-фталимидо и -COOR5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода, и аминогруппу, замещенную двумя алкильными группами, состоящими из от 1 до 5 атомов углерода; L = -(C=O)-; R1 является водородом; R2 является водородом.
Фунгицидная композиция и способ борьбы с фитопатогенными грибами. 30.06.1998 при А1 - 2-пиридил, замещенный СF3, R2 является алкилом, состоящим из от 1 до 5 атомов углерода.
Фунгицидная композиция и способ борьбы с фитопатогенными грибами. 11.08.1998 - уточняет признаки А1 и А2.
16.02.1999 при А1 - 2-пиридил, замещенный алкилом, состоящим из от 1 до 5 атомов углерода, группы –OSO2R5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода; циано; и -COOR5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода; L выбирают из группы, включающей -(С=S)-, -(SO2)-; R1 является алкилом, состоящим из от 1 до 5 атомов углерода, необязательно замещенным цианогруппой или фенилом; и –COOR5a, где R5a является алкилом, состоящим из от 1 до 5 атомов углерода, фунгицидная композиция и способ борьбы с фитопатогенными грибами.
RU2000124062/04A 1998-02-19 1999-02-16 Фитопатогенный фунгицид, производное 2-пиридилметиламина, фунгицидная композиция, способ борьбы с фитопатогенными грибами RU2224746C2 (ru)

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GBGB9803413.5A GB9803413D0 (en) 1998-02-19 1998-02-19 Fungicides
GB9803413.5 1998-02-19
GBGB9813998.3A GB9813998D0 (en) 1998-06-30 1998-06-30 Fungicides
GB9813998.3 1998-06-30
GBGB9817353.7A GB9817353D0 (en) 1998-08-11 1998-08-11 Fungicides
GB9817353.7 1998-08-11

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SI20356A (sl) 2001-04-30
AU751032B2 (en) 2002-08-08
TW575562B (en) 2004-02-11
TR200101071T2 (tr) 2002-06-21
WO1999042447A1 (en) 1999-08-26
US6828441B2 (en) 2004-12-07
HUP0100817A2 (hu) 2001-07-30
NO20004159D0 (no) 2000-08-18
EP1056723B1 (en) 2007-11-28
CA2319005A1 (en) 1999-08-26
SK12392000A3 (sk) 2001-03-12
KR20010034505A (ko) 2001-04-25
JP4749542B2 (ja) 2011-08-17

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