RU2016149802A - Связующие - Google Patents
Связующие Download PDFInfo
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- RU2016149802A RU2016149802A RU2016149802A RU2016149802A RU2016149802A RU 2016149802 A RU2016149802 A RU 2016149802A RU 2016149802 A RU2016149802 A RU 2016149802A RU 2016149802 A RU2016149802 A RU 2016149802A RU 2016149802 A RU2016149802 A RU 2016149802A
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- Prior art keywords
- binder composition
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- polyamino acid
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- 239000011230 binding agent Substances 0.000 title claims 47
- 239000000203 mixture Substances 0.000 claims 41
- 150000001720 carbohydrates Chemical class 0.000 claims 17
- 235000014633 carbohydrates Nutrition 0.000 claims 17
- 238000000034 method Methods 0.000 claims 16
- 239000002253 acid Substances 0.000 claims 15
- 239000000126 substance Substances 0.000 claims 11
- 239000006185 dispersion Substances 0.000 claims 8
- 239000000243 solution Substances 0.000 claims 8
- 239000000047 product Substances 0.000 claims 6
- 239000000835 fiber Substances 0.000 claims 5
- 239000002245 particle Substances 0.000 claims 5
- AIJULSRZWUXGPQ-UHFFFAOYSA-N Methylglyoxal Chemical compound CC(=O)C=O AIJULSRZWUXGPQ-UHFFFAOYSA-N 0.000 claims 4
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 claims 4
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical compound CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 claims 3
- 239000003431 cross linking reagent Substances 0.000 claims 3
- 239000002904 solvent Substances 0.000 claims 3
- NOEGNKMFWQHSLB-UHFFFAOYSA-N 5-hydroxymethylfurfural Chemical compound OCC1=CC=C(C=O)O1 NOEGNKMFWQHSLB-UHFFFAOYSA-N 0.000 claims 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims 2
- ROWKJAVDOGWPAT-UHFFFAOYSA-N Acetoin Chemical compound CC(O)C(C)=O ROWKJAVDOGWPAT-UHFFFAOYSA-N 0.000 claims 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 claims 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N Glycolaldehyde Chemical compound OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 claims 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 claims 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 229940120503 dihydroxyacetone Drugs 0.000 claims 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims 2
- 150000003384 small molecules Chemical class 0.000 claims 2
- WQZGKKKJIJFFOK-CBPJZXOFSA-N D-Gulose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O WQZGKKKJIJFFOK-CBPJZXOFSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-WHZQZERISA-N D-aldose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-WHZQZERISA-N 0.000 claims 1
- DCNMIDLYWOTSGK-HSUXUTPPSA-N D-glucosone Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C(=O)C=O DCNMIDLYWOTSGK-HSUXUTPPSA-N 0.000 claims 1
- MNQZXJOMYWMBOU-VKHMYHEASA-N D-glyceraldehyde Chemical compound OC[C@@H](O)C=O MNQZXJOMYWMBOU-VKHMYHEASA-N 0.000 claims 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims 1
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 claims 1
- 229930091371 Fructose Natural products 0.000 claims 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims 1
- 239000005715 Fructose Substances 0.000 claims 1
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-VSOAQEOCSA-N L-altropyranose Chemical compound OC[C@@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-VSOAQEOCSA-N 0.000 claims 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims 1
- 239000004472 Lysine Substances 0.000 claims 1
- 208000028017 Psychotic disease Diseases 0.000 claims 1
- PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 claims 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims 1
- 229930006000 Sucrose Natural products 0.000 claims 1
- 150000001366 alloses Chemical class 0.000 claims 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 claims 1
- SRBFZHDQGSBBOR-STGXQOJASA-N alpha-D-lyxopyranose Chemical compound O[C@@H]1CO[C@H](O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-STGXQOJASA-N 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000008121 dextrose Substances 0.000 claims 1
- 150000002016 disaccharides Chemical class 0.000 claims 1
- 229930182830 galactose Natural products 0.000 claims 1
- 239000008103 glucose Substances 0.000 claims 1
- 150000004676 glycans Chemical class 0.000 claims 1
- 229940015043 glyoxal Drugs 0.000 claims 1
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 claims 1
- GFAZHVHNLUBROE-UHFFFAOYSA-N hydroxymethyl propionaldehyde Natural products CCC(=O)CO GFAZHVHNLUBROE-UHFFFAOYSA-N 0.000 claims 1
- 150000002454 idoses Chemical class 0.000 claims 1
- BJHIKXHVCXFQLS-PQLUHFTBSA-N keto-D-tagatose Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)C(=O)CO BJHIKXHVCXFQLS-PQLUHFTBSA-N 0.000 claims 1
- 125000003588 lysine group Chemical group [H]N([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 claims 1
- 150000002772 monosaccharides Chemical class 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 229920001282 polysaccharide Polymers 0.000 claims 1
- 239000005017 polysaccharide Substances 0.000 claims 1
- 239000005720 sucrose Substances 0.000 claims 1
- 235000000346 sugar Nutrition 0.000 claims 1
- 150000008163 sugars Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H5/00—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium
- C07H5/04—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/06—Amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J105/00—Adhesives based on polysaccharides or on their derivatives, not provided for in groups C09J101/00 or C09J103/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J179/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
- C09J179/02—Polyamines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/56—Non-aqueous solutions or dispersions
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Forests & Forestry (AREA)
- Genetics & Genomics (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Health & Medical Sciences (AREA)
- Biotechnology (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Claims (47)
1. Растворимая в воде предварительно прореагировавшая связующая композиция, содержащая продукт (продукты) реакции
(i) по меньшей мере одного углеводного компонента, и
(ii) по меньшей мере одного компонента полиаминокислоты, и необязательно
(iii) по меньшей мере одного полиамина и/или по меньшей мере одного полиола.
2. Предварительно прореагировавшая связующая композиция по п. 1, причем указанная связующая композиция содержит по меньшей мере один форполимер, имеющий молекулярную массу в интервале от 1 от 100 кДа.
3. Предварительно прореагировавшая связующая композиция по п. 2, в которой по меньшей мере один указанный форполимер содержится в количестве, равном 2 мас. % или более, на основе общей массы связующей композиции.
4. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, причем указанная связующая композиция содержит по меньшей мере один форполимер, имеющий молекулярную массу в интервале от более 80 до 100 кДа (высокомолекулярный форполимер).
5. Предварительно прореагировавшая связующая композиция по п. 4, в которой по меньшей мере один указанный высокомолекулярный форполимер содержится в количестве, равном 0.2 мас. % или более, на основе общей массы связующей композиции.
6. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, причем указанная связующая композиция содержит по меньшей мере один форполимер, имеющий молекулярную массу в интервале от более 10 до 80 кДа (форполимер со средней молекулярной массой).
7. Предварительно прореагировавшая связующая композиция по п. 6, в которой по меньшей мере один указанный форполимер со средней молекулярной массой содержится в количестве, равном 0.3 мас. % или более, на основе общей массы связующей композиции.
8. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, причем указанная связующая композиция содержит одно или более соединений, имеющих молекулярную массу, равную 10 кДа или менее (низкомолекулярные соединения), и которые отличны от (i) по меньшей мере одного углеводного компонента и (ii) по меньшей мере одного компонента полиаминокислоты.
9. Предварительно прореагировавшая связующая композиция по п. 8, в которой низкомолекулярные соединения содержат одно или более из гликольальдегида, глицеральдегида, 2-оксопропаналя, ацетоля, дигидроксиацетона, ацетоина, бутандиона, этаналя, глюкозона, 1-дезоксигексозулозы, 3-дезоксигексозулозы, 3-дезоксипентозулозы, 1,4-дидезоксигексозулозы, глиоксала, метилглиоксала, диацетила и 5-(гидроксиметил)фурфурала.
10. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, причем водный раствор, содержащий 70 мас. % указанной предварительно прореагировавшей связующей композиции, имеет вязкость при 20°C, равную самое большее 2000 сП.
11. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, причем вязкость водного раствора, содержащего 70 мас. % указанной предварительно прореагировавшей связующей композиции, не увеличивается на более 500 сП, при отстаивании при 20°C в течение 12 часов.
12. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, причем указанная предварительно прореагировавшая связующая композиция способна реагировать со сшивающим агентом с получением одного или более меланоидинов в виде нерастворимой в воде композиции.
13. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, в которой отношение всех карбонильных групп в углеводном компоненте (компонентах) ко всем аминогруппам в компоненте (компонентах) полиаминокислоты составляет от 5:1 до 1:5.
14. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, в которой по меньшей мере один углеводный компонент выбирается из группы, состоящей из моносахаридов, дисахаридов, полисахаридов или их продукта реакции.
15. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, в которой по меньшей мере один углеводный компонент выбирается из группы, состоящей из восстанавливающих сахаров, рибозы, арабинозы, ксилозы, ликзосы, глюкозы (т.е., декстрозы), маннозы, галактозы, аллозы, альтрозы, талозы, гулозы, идозы, фруктозы, псикозы, сорбозы, дигидроксиацетона, сахарозы и тагатозы, а также их смесей.
16. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, в которой по меньшей мере один компонент полиаминокислоты представляет собой лизин, неорганическую соль лизина или органическую соль лизина.
17. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, в которой массовое отношение углеводного компонента и компонента полиаминокислоты составляет от 0.5:1 до 30:1.
18. Предварительно прореагировавшая связующая композиция по любому предшествующему пункту, содержащая по меньшей мере 10% начальных карбонильных групп, обеспеченных углеводным компонентом.
19. Способ получения предварительно прореагировавшей связующей композиции по любому предшествующему пункту, включающий стадии:
(i) обеспечение по меньшей мере одного углеводного компонента,
(ii) обеспечение по меньшей мере одного компонента полиаминокислоты,
(iii) смешивание в растворителе углеводного компонента (компонентов) и компонента (компонентов) полиаминокислоты, и
(iv) реакция углеводного компонента (компонентов) и компонента (компонентов) полиаминокислоты в растворе или дисперсии, полученных на стадии (iii).
20. Способ по п. 19, в котором стадии (i)-(iv) осуществляются, в то время как углеводный компонент (компоненты) и компонент (компоненты) полиаминокислоты не контактируют с набором субстанций, которые должны быть связаны полимерным связующем.
21. Способ по п. 19 или 20, в котором стадия реакции (iv) осуществляется путем реакции углеводного компонента (компонентов) и компонента (компонентов) полиаминокислоты при температуре, равной самое большее 120°C.
22. Способ по любому из пп. 19-21, в котором стадия реакции (iv) осуществляется путем реакции углеводного компонента (компонентов) и компонента (компонентов) полиаминокислоты в течение периода времени, равного самое большее 96 часов.
23. Способ по любому из пп. 19-22, в котором стадия реакции (iv) осуществляется путем реакции углеводного компонента (компонентов) и компонента (компонентов) полиаминокислоты при диапазоне температуры от 40 до 120°C, в течение периода времени от 5 до 180 минут.
24. Способ по любому из пп. 19-22, в котором стадия реакции (iv) осуществляется путем реакции углеводного компонента (компонентов) и компонента (компонентов) полиаминокислоты при диапазоне температуры от 20 до 30°C, в течение периода времени от 1 до 96 часов.
25. Способ по пп. 19-24, в котором вязкость раствора или дисперсии в ходе стадии (iv) реакции углеводного компонента (компонентов) и компонента (компонентов) полиаминокислоты не увеличивается на более 300 сП, при определении при 20°C и исходной концентрации, равной 70 мас. % всех углеводных компонентов и компонентов полиаминокислоты, присутствующих до указанной стадии (iv).
26. Растворимая в воде предварительно прореагировавшая связующая композиция, получаемая способом по любому из пп. 19-25.
27. Применение растворимой в воде предварительно прореагировавшей связующей композиции по любому из пп. 1-18 для получения продукта, содержащего набор субстанций, связанный полимерным связующем.
28. Способ получения набора субстанций, связанных полимерным связующем, включающий стадии:
(i) обеспечение набора субстанций,
(ii) обеспечение предварительно прореагировавшей связующей композиции по любому из пп. 1-18, или предварительно прореагировавшей связующей композиции, полученной способом по любому из пп. 19-25, в растворителе с получением раствора или дисперсии,
(iii) нанесение раствора или дисперсии, полученных на стадии (ii), на набор субстанций, и
(iv) подача энергии на набор субстанций, содержащий указанный раствор или дисперсию, для отверждения связующей композиции.
29. Способ по п. 28, в котором на стадии (ii) сшивающий агент добавляется к предварительно прореагировавшей связующей композиции по любому из пп. 1-18, или предварительно прореагировавшей связующей композиции, полученной способом по любому из пп. 19-25, или их раствору или дисперсии.
30. Способ получения набора субстанций по п. 28 или 29, в котором предварительно прореагировавшая связующая композиция по любому из пп. 1-18, или предварительно прореагировавшее связующее, получаемое способом по любому из пп. 19-25, выдерживали по меньшей мере 24 часов до подачи энергии на стадии (iv) на набор субстанций.
31. Способ получения набор субстанций по любому из пп. 28-30, в котором перед стадией нанесения раствора или дисперсии, полученных на стадии (ii), на набор субстанций, набор субстанций по существу не содержит связующее.
32. Раствор или дисперсия связующего, содержащие в растворителе предварительно прореагировавшую связующую композицию по любому из пп. 1-18 и сшивающий агент.
33. Продукт, содержащий волокна или частицы, содержащий один или более видов волокон и/или частиц и предварительно прореагировавшую связующую композицию, как определено в любом из пп. 1-18, в отвержденном состоянии.
34. Продукт, содержащий волокна или частицы, по п. 33, получаемый способом по любому из пп. 28-31.
35. Продукт, содержащий волокна или частицы, по п. 33 или 34, причем указанный продукт содержит один или более фруктозазинов.
36. Продукт, содержащий волокна или частицы, по п. 35, в котором указанные один или более фруктозазины присутствуют в количестве от 0.001 до 5 мас. % на основе общей массы отвержденного связующего.
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-
2014
- 2014-05-20 GB GBGB1408909.8A patent/GB201408909D0/en not_active Ceased
-
2015
- 2015-05-19 RU RU2016149802A patent/RU2732948C2/ru active
- 2015-05-19 CN CN201580034517.5A patent/CN106661418B/zh active Active
- 2015-05-19 KR KR1020247002321A patent/KR20240015153A/ko active Application Filing
- 2015-05-19 JP JP2016568849A patent/JP2017525780A/ja active Pending
- 2015-05-19 CA CA2949401A patent/CA2949401A1/en active Pending
- 2015-05-19 KR KR1020227034645A patent/KR20220141349A/ko not_active Application Discontinuation
- 2015-05-19 WO PCT/EP2015/060951 patent/WO2015177114A1/en active Application Filing
- 2015-05-19 ES ES15723506T patent/ES2969322T3/es active Active
- 2015-05-19 KR KR1020167035482A patent/KR102453144B1/ko active IP Right Grant
- 2015-05-19 PL PL15723506.0T patent/PL3146010T3/pl unknown
- 2015-05-19 US US15/310,837 patent/US20170174836A1/en not_active Abandoned
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US20190119446A1 (en) | 2019-04-25 |
JP2020100803A (ja) | 2020-07-02 |
PL3146010T3 (pl) | 2024-03-25 |
EP3146010B1 (en) | 2023-12-13 |
WO2015177114A1 (en) | 2015-11-26 |
KR20170008825A (ko) | 2017-01-24 |
CN106661418A (zh) | 2017-05-10 |
EP4324882A2 (en) | 2024-02-21 |
CA2949401A1 (en) | 2015-11-26 |
CN106661418B (zh) | 2021-07-09 |
ES2969322T3 (es) | 2024-05-17 |
GB201408909D0 (en) | 2014-07-02 |
US20170174836A1 (en) | 2017-06-22 |
JP2017525780A (ja) | 2017-09-07 |
KR20240015153A (ko) | 2024-02-02 |
EP3146010A1 (en) | 2017-03-29 |
US11332577B2 (en) | 2022-05-17 |
KR20220141349A (ko) | 2022-10-19 |
RU2732948C2 (ru) | 2020-09-24 |
EP4324882A3 (en) | 2024-02-28 |
KR102453144B1 (ko) | 2022-10-12 |
RU2016149802A3 (ru) | 2018-12-13 |
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