RU2012143414A - Гибкий листовой материал для ограничения пространства подачи матричного материала и способ его получения - Google Patents

Гибкий листовой материал для ограничения пространства подачи матричного материала и способ его получения Download PDF

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Publication number
RU2012143414A
RU2012143414A RU2012143414/05A RU2012143414A RU2012143414A RU 2012143414 A RU2012143414 A RU 2012143414A RU 2012143414/05 A RU2012143414/05 A RU 2012143414/05A RU 2012143414 A RU2012143414 A RU 2012143414A RU 2012143414 A RU2012143414 A RU 2012143414A
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Russia
Prior art keywords
paste
textile layer
foam
matrix material
sheet material
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RU2012143414/05A
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English (en)
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RU2532573C2 (ru
Inventor
Вильхельм КРИНГС
Манфред ХЕНШ
Леопольд ПРИБИЛЬ
Вильхельм ХИЕРХАММЕР
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Транс-Текстиль Гмбх
Эадс Дойчланд Гмбх
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/12—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/546—Measures for feeding or distributing the matrix material in the reinforcing structure
    • B29C70/548—Measures for feeding or distributing the matrix material in the reinforcing structure using distribution constructions, e.g. channels incorporated in or associated with the mould
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/20—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
    • B29C44/32—Incorporating or moulding on preformed parts, e.g. linings, inserts or reinforcements
    • B29C44/321—Incorporating or moulding on preformed parts, e.g. linings, inserts or reinforcements the preformed part being a lining, e.g. a film or a support lining
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
    • B29C70/443—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding and impregnating by vacuum or injection
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    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
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    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
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    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D—TEXTILES; PAPER
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    • Y10T442/2139—Coating or impregnation specified as porous or permeable to a specific substance [e.g., water vapor, air, etc.]

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

1. Гибкий листовой материал, предназначенный для ограничения пространства подачи матричного материала при вакуумном получении деталей из армированной волокнами пластмассы из заготовок из волокнистого композита, причем гибкий листовой материал содержит текстильный слой, а также газопроницаемый, но непроницаемый для матричного материала барьерный слой для матричного материала, которым покрыт текстильный слой и который состоит из пены или сухой пасты, которая, по меньшей мере, в основном, получена с одним или несколькими из следующих веществ: полиуретан, фторполимеры, акрилат, стиролакрилат, бутадиен-нитрильный латекс, бутадиен-стирольный латекс, этиленвинилацетат, поливинилацетат, силикон, сополимеры вышеуказанных веществ, плюс добавки, причем барьерный слой для матричного материала имеет плотность сухого покрытия 10-120 г/м.2. Гибкий листовой материал по п.1, отличающийся тем, что текстильный слой является тканью, вязанным, трикотажным, нетканым материалом или войлоком и, по меньшей мере, в основном, состоит из одного или нескольких из следующих материалов: сложный полиэфир, полиамид, арамидное волокно, стекловолокно, полиакрил, полипропилен, полиэтилен, вискоза, целлюлоза, хлопок.3. Способ получения гибкого листового материала, предназначенного для ограничения пространства подачи матричного материала при вакуумном процессе получения армированных волокнами пластмассовых деталей из заготовок из волокнистого композита, отличающийся тем, что он содержит следующие этапы:- получение пены или пасты, по меньшей мере, в основном, из одного или нескольких из следующих веществ: полиуретан, фторполимеры, акрилат, ст�

Claims (14)

1. Гибкий листовой материал, предназначенный для ограничения пространства подачи матричного материала при вакуумном получении деталей из армированной волокнами пластмассы из заготовок из волокнистого композита, причем гибкий листовой материал содержит текстильный слой, а также газопроницаемый, но непроницаемый для матричного материала барьерный слой для матричного материала, которым покрыт текстильный слой и который состоит из пены или сухой пасты, которая, по меньшей мере, в основном, получена с одним или несколькими из следующих веществ: полиуретан, фторполимеры, акрилат, стиролакрилат, бутадиен-нитрильный латекс, бутадиен-стирольный латекс, этиленвинилацетат, поливинилацетат, силикон, сополимеры вышеуказанных веществ, плюс добавки, причем барьерный слой для матричного материала имеет плотность сухого покрытия 10-120 г/м2.
2. Гибкий листовой материал по п.1, отличающийся тем, что текстильный слой является тканью, вязанным, трикотажным, нетканым материалом или войлоком и, по меньшей мере, в основном, состоит из одного или нескольких из следующих материалов: сложный полиэфир, полиамид, арамидное волокно, стекловолокно, полиакрил, полипропилен, полиэтилен, вискоза, целлюлоза, хлопок.
3. Способ получения гибкого листового материала, предназначенного для ограничения пространства подачи матричного материала при вакуумном процессе получения армированных волокнами пластмассовых деталей из заготовок из волокнистого композита, отличающийся тем, что он содержит следующие этапы:
- получение пены или пасты, по меньшей мере, в основном, из одного или нескольких из следующих веществ: полиуретан, фторполимеры, акрилат, стиролакрилат, бутадиен-нитрильный латекс, бутадиен-стирольный латекс, этиленвинилацетат, поливинилацетат, силикон, сополимеры вышеуказанных веществ, плюс добавки,
- покрытие текстильного слоя пеной или пастой таким образом, что пена или паста образуют газопроницаемый, но не проницаемый для матричного материала барьерный слой для матричного материала, плотность сухого покрытия которого составляет 10-120 г/м2.
4. Способ по п.3, отличающийся тем, что слой пены или пасты при повышенной температуре и повышенном давлении уплотняют посредством устройства каландрования для целенаправленного воздействия на характеристики газопроницаемости и/или непроницаемости для матричного материала.
5. Способ по п.3 или 4, отличающийся тем, что пена при нанесении текстильного слоя имеет вес 100-900 г/л.
6. Способ по п.3 или 4, отличающийся тем, что пена при нанесении на текстильный слой имеет вес 200-350 г/л, причем плотность сухого покрытия составляет 30-40 г/м2.
7. Способ по п.3 или 4, отличающийся тем, что текстильный слой покрывают водной пастой, причем плотность сухого покрытия составляет 35-45 г/м2.
8. Способ по п.3 или 4, что текстильный слой покрывают содержащей растворитель пастой, причем плотность сухого покрытия составляет 40-50 г/м2.
9. Способ по п.3 или 4, отличающийся тем, что текстильный слой перед его покрытием предварительно обрабатывается присадками, которые получены из водных или органических растворов и содержат одно или несколько из следующих веществ: фторуглеродные смолы, пропиточные смолы, ПАВы, производные кремниевого золя, промоторы адгезии.
10. Способ по п.3 или 4, отличающийся тем, что осуществляют коагуляционное покрытие текстильного слоя водно-дисперсионной пастой, пеной или пастой на основе растворителя, причем на текстильный слой перед его покрытием наносят электролитические соли, химические присадки или добавки с другими ионами, чтобы вызвать реакции осаждения в материале покрытия.
11. Способ по п.3 или 4, отличающийся тем, что осуществляют коагуляционное покрытие текстильного слоя водно-дисперсионной пастой, пеной или пастой на основе растворителя, причем снабженный покрытием листовой материал подвергают последующей дополнительной обработке подщелачиванием или отщеплением кислоты из водных ванн, чтобы создать пористость в полимерной пленке.
12. Способ по п.3 или 4, отличающийся тем, что осуществляют экстракционное покрытие текстильного слоя водно-дисперсионной пастой, пеной или пастой на основе растворителя, причем материал покрытия содержит присадки, которые можно снова частично или полностью экстрагировать из материала покрытия посредством дополнительной обработки покрытого листового материала.
13. Способ по п.3 или 4, отличающийся тем, что пену или пасту наносят на текстильный слой для осаждения/коагуляции за счет термочувствительности.
14. Способ по п.3 или 4, отличающийся тем, что пену или пасту наносят на текстильный слой для осаждения/коагуляции в результате возникающей при сушке нестабильности.
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