RU2011143933A - Удаляемая самоклеющаяся этикетка, включающая слой полимерной пленки с высоким модулем упругости при растяжении - Google Patents
Удаляемая самоклеющаяся этикетка, включающая слой полимерной пленки с высоким модулем упругости при растяжении Download PDFInfo
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- RU2011143933A RU2011143933A RU2011143933/12A RU2011143933A RU2011143933A RU 2011143933 A RU2011143933 A RU 2011143933A RU 2011143933/12 A RU2011143933/12 A RU 2011143933/12A RU 2011143933 A RU2011143933 A RU 2011143933A RU 2011143933 A RU2011143933 A RU 2011143933A
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- Prior art keywords
- film
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- label
- film layer
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- 239000000853 adhesive Substances 0.000 title claims abstract 9
- 229920006254 polymer film Polymers 0.000 title 1
- 239000010410 layer Substances 0.000 claims abstract 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 18
- 239000012790 adhesive layer Substances 0.000 claims abstract 15
- 238000007654 immersion Methods 0.000 claims abstract 11
- 230000001070 adhesive effect Effects 0.000 claims abstract 8
- 229920000642 polymer Polymers 0.000 claims abstract 8
- 238000010521 absorption reaction Methods 0.000 claims abstract 6
- 125000003118 aryl group Chemical group 0.000 claims abstract 6
- 229920001169 thermoplastic Polymers 0.000 claims abstract 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract 4
- 229920000728 polyester Polymers 0.000 claims abstract 4
- 229920000098 polyolefin Polymers 0.000 claims abstract 4
- 239000004962 Polyamide-imide Substances 0.000 claims abstract 2
- 239000004642 Polyimide Substances 0.000 claims abstract 2
- 229910052736 halogen Inorganic materials 0.000 claims abstract 2
- 150000002367 halogens Chemical class 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims abstract 2
- 229920000058 polyacrylate Polymers 0.000 claims abstract 2
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract 2
- 229920002312 polyamide-imide Polymers 0.000 claims abstract 2
- 229920000515 polycarbonate Polymers 0.000 claims abstract 2
- 239000004417 polycarbonate Substances 0.000 claims abstract 2
- 229920001721 polyimide Polymers 0.000 claims abstract 2
- 239000007788 liquid Substances 0.000 claims 3
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000004821 Contact adhesive Substances 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
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- 239000007864 aqueous solution Substances 0.000 claims 1
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- 229920000570 polyether Polymers 0.000 claims 1
- -1 polypropylene Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 239000002356 single layer Substances 0.000 claims 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
1. Этикетка, включающая:(a) пленку, имеющую первую поверхность и вторую поверхность и содержащую первый слой пленки; и(b) адгезивный слой, имеющий первую поверхность и вторую поверхность и содержащий адгезив, где первая поверхность адгезивного слоя адгезивно соединяется со второй поверхностью пленки;(c) где первый слой пленки содержит, по меньшей мере, один термопластичный полимер, где первый слой пленки имеет модуль упругости при растяжении (ASTM D882) в машинном направлении или поперечном направлении, по меньшей мере, 900 МПа после погружения в воду при температуре примерно 80°С в течение, по меньшей мере, примерно 3 мин, и первый слой пленки имеет абсолютное изменение размеров поверхности (ASTM D1204) меньше чем 5,0% после погружения в воду при температуре примерно 80°С в течение, по меньшей мере, примерно 3 мин.2. Этикетка по п.1, где толщина первого слоя пленки больше, чем толщина адгезивного слоя.3. Этикетка по п.1, где толщина первого слоя пленки, по меньшей мере, на 5% больше, чем толщина адгезивного слоя.4. Этикетка по п.1, где первый слой пленки имеет поглощение воды (ASTM D570) меньше, чем 2,1 мас.% после погружения в воду при температуре примерно 80°С в течение, по меньшей мере, примерно 2 ч.5. Этикетка по любому из пп.1-4, где термопластичный полимер первого слоя пленки содержит полимер, выбранный из группы, состоящей из полиолефина, (мет)акрилатного полимера, стирольного полимера, сложного полиэфира, галоген-содержащего полимера, поликарбоната, полиакрилонитрила, ароматического простого полиэфира, ароматического полиимида, ароматического полиамида-имида и смеси двух или более любых из указанных выше полимеров.6. Этикетка по п.1, где первый с�
Claims (29)
1. Этикетка, включающая:
(a) пленку, имеющую первую поверхность и вторую поверхность и содержащую первый слой пленки; и
(b) адгезивный слой, имеющий первую поверхность и вторую поверхность и содержащий адгезив, где первая поверхность адгезивного слоя адгезивно соединяется со второй поверхностью пленки;
(c) где первый слой пленки содержит, по меньшей мере, один термопластичный полимер, где первый слой пленки имеет модуль упругости при растяжении (ASTM D882) в машинном направлении или поперечном направлении, по меньшей мере, 900 МПа после погружения в воду при температуре примерно 80°С в течение, по меньшей мере, примерно 3 мин, и первый слой пленки имеет абсолютное изменение размеров поверхности (ASTM D1204) меньше чем 5,0% после погружения в воду при температуре примерно 80°С в течение, по меньшей мере, примерно 3 мин.
2. Этикетка по п.1, где толщина первого слоя пленки больше, чем толщина адгезивного слоя.
3. Этикетка по п.1, где толщина первого слоя пленки, по меньшей мере, на 5% больше, чем толщина адгезивного слоя.
4. Этикетка по п.1, где первый слой пленки имеет поглощение воды (ASTM D570) меньше, чем 2,1 мас.% после погружения в воду при температуре примерно 80°С в течение, по меньшей мере, примерно 2 ч.
5. Этикетка по любому из пп.1-4, где термопластичный полимер первого слоя пленки содержит полимер, выбранный из группы, состоящей из полиолефина, (мет)акрилатного полимера, стирольного полимера, сложного полиэфира, галоген-содержащего полимера, поликарбоната, полиакрилонитрила, ароматического простого полиэфира, ароматического полиимида, ароматического полиамида-имида и смеси двух или более любых из указанных выше полимеров.
6. Этикетка по п.1, где первый слой пленки является неориентированным.
7. Этикетка по п.1, где первый слой пленки ориентируется посредством одноосного или двухосного растяжения первого слоя пленки, а затем снимается напряжение одноосного или двухосного растянутого первого слоя пленки.
8. Этикетка по п.1, где пленка представляет собой однослойную пленку.
9. Этикетка по п.1, где пленка представляет собой многослойную пленку.
10. Этикетка по п.1, где первый слой пленки содержит два или более слоев.
11. Этикетка по п.1 или 10, где пленка включает второй слой пленки содержащий, по меньшей мере, один термопластичный полимер, где второй слой пленки имеет свойство, выбранное из
(i) модуля упругости при растяжении (ASTM D882) в машинном направлении или поперечном направлении, по меньшей мере, 900 МПа после погружения в воду, имеющую температуру примерно 80°С, в течение периода примерно 3 мин; и
(ii) абсолютного изменения размеров поверхности (ASTM D1204) меньшего примерно, чем 5,0% после погружения в воду, имеющую температуру примерно 80°С, в течение периода примерно 3 мин;
и сочетания двух указанных выше свойств.
12. Этикетка по п.11, где второй слой пленки содержит два или более слоев, где каждый из указанных двух или более слоев второго слоя пленки имеет свойство, выбранное из
(i) модуля упругости при растяжении (ASTM D882) в машинном направлении или поперечном направлении, по меньшей мере, 900 МПа после погружения в воду, имеющую температуру примерно 80°С, в течение периода примерно 3 мин; и
(ii) абсолютного изменения размеров поверхности (ASTM D1204) меньшего примерно, чем 5,0% после погружения в воду, имеющую температуру примерно 80°С, в течение периода примерно 3 мин;
и сочетания двух указанных выше свойств.
13. Этикетка по п.11, где второй слой пленки имеет первую поверхность и вторую поверхность, первый слой пленки имеет первую поверхность и вторую поверхность, первая поверхность первого слоя пленки лежит под второй поверхностью второго слоя пленки, и первая поверхность адгезивного слоя лежит под второй поверхностью первого слоя пленки.
14. Этикетка по п.11, где первый слой пленки имеет первую поверхность и вторую поверхность, второй слой пленки имеет первую поверхность и вторую поверхность, первая поверхность второго слоя пленки лежит под второй поверхностью первого слоя пленки, и первая поверхность адгезивного слоя лежит под второй поверхностью второго слоя пленки.
15. Этикетка по п.1, где адгезив для адгезивного слоя представляет собой контактный адгезив.
16. Этикетка по п.1, где пленка является прозрачной.
17. Этикетка по п.1, где этикетка дополнительно включает покрывную пленку, имеющую первую поверхность и вторую поверхность, где первая поверхность покрывной пленки прикрепляется с возможностью последующего удаления ко второй поверхности адгезивного слоя.
18. Контейнер с наклеенной этикеткой, содержащий:
этикетку по любому из пп.1-17; и
контейнер, имеющий горизонтальную ось;
где этикетка прикрепляется к контейнеру, где вторая поверхность адгезивного слоя адгезивно соединяется с внешней поверхностью контейнера и машинное направление или поперечное направление первого слоя пленки следует по окружности горизонтальной оси контейнера.
19. Контейнер с наклеенной этикеткой по п.18, где контейнер представляет собой контейнер цилиндрической формы, и горизонтальная ось контейнера параллельна окружности контейнера цилиндрической формы.
20. Способ удаления этикетки с контейнера, включающий:
(i) получение контейнера с наклеенной этикеткой по п.18 или 19;
(ii) удаление этикетки с контейнера посредством погружения контейнера с прикрепленной этикеткой в жидкость, где температура жидкости составляет, по меньшей мере, примерно 50°С, и этикетка отделяется от контейнера.
21. Способ по п.20, где жидкость представляет собой воду или каустический водный раствор.
22. Этикетка, включающая:
(a) первую пленку, имеющую первую поверхность и вторую поверхность и содержащую первый слой пленки;
(b) вторую пленку, имеющую первую поверхность и вторую поверхность и содержащую второй слой пленки;
(c) адгезивный слой, имеющий первую поверхность и вторую поверхность и содержащий адгезив, где первая поверхность адгезивного слоя адгезивно соединяется со второй поверхностью первой пленки;
(d) где первая пленка содержит полиолефин и вторая пленка содержит сложный полиэфир, и второй слой пленки демонстрирует поглощение воды (ASTM D570) более 1,6 мас.% после погружения в воду при температуре около 80°С в течение по меньшей мере примерно 2 ч.
23. Этикетка по п.22, где второй слой пленки имеет поглощение воды более 1,8%.
24. Этикетка по п.23, где второй слой пленки имеет поглощение воды более 2%.
25. Этикетка по п.24, где второй слой пленки имеет поглощение воды более 2,1%.
26. Этикетка по п.22, где полиолефин представляет собой полипропилен.
27. Этикетка по п.22, где по меньшей мере один первый слой пленки и второй слой пленки существенно не изменяется в размерах при воздействии повышенных температур.
28. Этикетка по п.22, где по меньшей мере один слой имеет линейную усадку (ASTM D1204) при 100°С в машинном направлении и поперечном направлении менее 5%.
29. Этикетка по любому из пп.22-28 дополнительно включает слой с печатью, расположенный между слоями пленки.
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PCT/US2010/029169 WO2010117767A1 (en) | 2009-03-30 | 2010-03-30 | Removable adhesive label containing high tensile modulus polymeric film layer |
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RU2016101329A Division RU2635037C1 (ru) | 2009-03-30 | 2010-03-30 | Удаляемая самоклеящаяся этикетка, включающая слой полимерной пленки с высоким модулем упругости при растяжении |
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RU2011143933/12A RU2011143933A (ru) | 2009-03-30 | 2010-03-30 | Удаляемая самоклеющаяся этикетка, включающая слой полимерной пленки с высоким модулем упругости при растяжении |
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AU2007317421B2 (en) | 2006-11-02 | 2012-11-15 | Avery Dennison Corporation | Emulsion adhesive for washable film |
US20120018098A1 (en) | 2009-03-30 | 2012-01-26 | Avery Dennison Corporation | Removable Adhesive Label Containing Inherently Shrinkable Polymeric Film |
CN102449677B (zh) | 2009-03-30 | 2016-02-03 | 艾利丹尼森公司 | 含具有亲水性的高分子膜层的可移除粘合标签 |
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EP3450163B1 (en) * | 2017-08-30 | 2019-07-17 | Evonik Röhm GmbH | Brittle acrylic films and forgery prevention labels comprising the same |
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2010
- 2010-03-30 BR BRPI1013652-5A patent/BRPI1013652B1/pt active IP Right Grant
- 2010-03-30 AU AU2010234830A patent/AU2010234830A1/en not_active Abandoned
- 2010-03-30 CN CN201710130456.3A patent/CN106652770A/zh active Pending
- 2010-03-30 RU RU2016101329A patent/RU2635037C1/ru not_active IP Right Cessation
- 2010-03-30 WO PCT/US2010/029169 patent/WO2010117767A1/en active Application Filing
- 2010-03-30 CN CN2010800238842A patent/CN102449088A/zh active Pending
- 2010-03-30 EP EP10712840.7A patent/EP2414472B1/en active Active
- 2010-03-30 EP EP17001047.4A patent/EP3255111B1/en active Active
- 2010-03-30 CA CA2757447A patent/CA2757447C/en not_active Expired - Fee Related
- 2010-03-30 ES ES10712840.7T patent/ES2633096T3/es active Active
- 2010-03-30 ES ES17001047T patent/ES2929654T3/es active Active
- 2010-03-30 RU RU2011143933/12A patent/RU2011143933A/ru unknown
- 2010-03-30 US US13/262,416 patent/US9334425B2/en active Active
- 2010-03-30 PL PL10712840T patent/PL2414472T3/pl unknown
- 2010-03-30 MX MX2011010350A patent/MX339260B/es active IP Right Grant
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2011
- 2011-10-04 ZA ZA2011/07249A patent/ZA201107249B/en unknown
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WO2010117767A1 (en) | 2010-10-14 |
EP2414472A1 (en) | 2012-02-08 |
CN102449088A (zh) | 2012-05-09 |
PL2414472T3 (pl) | 2017-11-30 |
EP3255111A1 (en) | 2017-12-13 |
US9334425B2 (en) | 2016-05-10 |
MX2011010350A (es) | 2011-12-06 |
AU2010234830A1 (en) | 2011-11-17 |
ES2633096T3 (es) | 2017-09-19 |
ES2929654T3 (es) | 2022-11-30 |
CA2757447C (en) | 2017-10-24 |
BRPI1013652B1 (pt) | 2019-05-07 |
CA2757447A1 (en) | 2010-10-14 |
MX339260B (es) | 2016-05-18 |
ZA201107249B (en) | 2012-12-27 |
US20130008613A1 (en) | 2013-01-10 |
BRPI1013652A2 (pt) | 2017-05-16 |
EP3255111B1 (en) | 2022-10-12 |
EP2414472B1 (en) | 2017-06-28 |
RU2635037C1 (ru) | 2017-11-08 |
CN106652770A (zh) | 2017-05-10 |
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