WO2000062273A1 - Leicht entfernbares etikett für mehrwegbehälter - Google Patents
Leicht entfernbares etikett für mehrwegbehälter Download PDFInfo
- Publication number
- WO2000062273A1 WO2000062273A1 PCT/EP1999/003294 EP9903294W WO0062273A1 WO 2000062273 A1 WO2000062273 A1 WO 2000062273A1 EP 9903294 W EP9903294 W EP 9903294W WO 0062273 A1 WO0062273 A1 WO 0062273A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- label
- adhesive
- label according
- adhesive layer
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/08—Fastening or securing by means not forming part of the material of the label itself
- G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10S156/918—Delaminating processes adapted for specified product, e.g. delaminating medical specimen slide
- Y10S156/919—Delaminating in preparation for post processing recycling step
- Y10S156/921—Delaminating container component in preparation for recycling, e.g. glass bottle, plastic bottle
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/11—Methods of delaminating, per se; i.e., separating at bonding face
- Y10T156/1142—Changing dimension during delaminating [e.g., crushing, expanding, warping, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1462—Polymer derived from material having at least one acrylic or alkacrylic group or the nitrile or amide derivative thereof [e.g., acrylamide, acrylate ester, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1486—Ornamental, decorative, pattern, or indicia
Definitions
- the invention relates to a label for an object, in particular a reusable container, wherein a carrier material layer of the label can be glued to the object by means of an adhesive layer and the label can be detached from the object under the action of heat, in particular in hot washing fluid and / or by heat radiation.
- the objects can be beverage or medicine bottles made of glass or plastic, test tubes, reusable outer packaging for a large number of individual containers, in particular beverage bottle crates, etc.
- the containers used such as bottles
- the containers are subject to a high return rate.
- the containers are cleaned with each return before refilling, the labels also being removed when the containers are washed.
- the containers are then refilled and re-labeled according to the type of drink filled.
- a certain product group e.g. B. a beer bottle
- the bottles returning to the brewery do not need to be sorted according to beer types, as would be the case with permanently pre-decorated bottles.
- the different labeling usually only takes place after filling. If the bottle was not directly printed on, it would be necessary to keep large stocks of appropriately decorated bottles available.
- the containers ie the bottles
- hot washing liquid such as dilute sodium hydroxide solution
- heated to 60 to 90 ° C without additional mechanical support in the form of brushes, high-pressure nozzles, etc.
- Paper labels with wet glue are often used to label reusable containers.
- the wet glue adhesive is applied over the entire surface or in strips, the adhesive being applied to the paper only immediately before labeling.
- the disadvantage is that the bottler has to deal with wet glue, ie machine contamination occurs, and the handling of these labels is more difficult than that of self-adhesive labels.
- Self-adhesive labels that are already supplied with adhesive from the label supplier avoid this disadvantage. Because of the standardized washing-up conditions in the beverage industry, only paper-based labels could previously be used. When washing the labels in the washing station, the water permeability of paper is exploited so that the wet glue adhesive comes into contact with the washing liquid relatively quickly and completely detaches in the specified washing time - in the range of a few minutes, but then the adhesive usually dissolves in the washing liquid.
- the high permeability for washing liquid and water does not have the thermoplastic films used on many labels - such as polyolefins, polycarbonates, polyesters, polyvinyl chlorides, polystyrenes etc.
- sleeve labels made of shrinkable film are also known.
- a film tube is slipped over the container and then shrunk on with heat.
- a glue between label and container is completely missing here.
- To remove the label it has to be slit open.
- Another disadvantage of these labels is that no noble decorations such as metal effects or embossed foil printing are possible, since these sleeves are printed directly from behind in reverse printing and such noble decorations are not shrinkable to the same extent as the foil print carrier. This would result in shifts and loss of brilliance.
- both of the last-mentioned labeling systems are expensive in terms of materials, since a complete all-round decoration of the object is always required.
- the object of the invention is therefore to provide a label of the type mentioned, which can be detached from the object with little effort.
- this label is characterized in that the backing material layer comprises at least one plastic film layer stretched in at least one direction when heat is applied, for example the temperature of the washing fluid or / and by heat radiation, while overcoming the holding force of the adhesive layer.
- the effect of heat causes the plastic film to shrink back, while the adhesive loses its adhesive strength.
- the label gradually detaches from the object, for example from the edge or with channel formation, and can be removed without further notice within a very short time.
- the hot washing fluid can be liquid, gaseous or vaporous or a mixture thereof and contain surfactants and bases, in particular sodium hydroxide solution.
- surfactants and bases in particular sodium hydroxide solution.
- infrared emitters or others Infrared emitters can be used.
- the labels peel off particularly quickly under the combined action of hot washing fluid and heat radiation.
- a washing liquid is used as the washing fluid, it can advance even faster from the edge or through the channels to the adhesive and detach it in the shortest possible time.
- the adhesive can be such that it essentially does not dissolve under the action of pure water, but detaches relatively quickly from the container under the action of the washing liquid usually used in the beverage industry, for example 1-2% hot sodium hydroxide solution.
- the shrinkage force of the film layer and the adhesive effect of the adhesive are preferably matched to one another in such a way that the label is at a temperature of more than 50 ° C., in particular more than 60 ° C., for a period of 10 seconds to 15 minutes, in particular 3 - 6 minutes, completely detached from the container under the influence of washing liquid.
- These are typical washing conditions in conventional bottle washing systems in the beverage industry.
- the decrease in the adhesive effect of the adhesive is preferably based on a decrease in its viscosity when the label is heated during the washing process.
- the holding force of the adhesive to the label material is preferably chosen to be higher than the loosening force caused by the shrinkage of the plastic film layer, so that when the label is detached from the object, the adhesive layer remains on the label and is removed and disposed of from the washing liquid, for example with the aid of a simple sieve can. This also ensures that the washing liquid cannot accumulate adhesive.
- the adhesive is preferably an adhesive which does not dissolve in water at least until the label is detached, in particular a redispersible adhesive, such as a dispersion adhesive based on acrylate or copolymeric acrylate / polyurethane compounds, and copolymers with an acrylate component (e.g. B. rubber / acrylate).
- the adhesive is preferably applied to the label material over the entire surface or in some areas with gaps, possibly with a pattern.
- the full-surface application allows for a so-called no-label look label, which allows a view of the product where it is unprinted. In some areas, d. H. Adhesive applied in the form of facets is usually disturbed.
- the adhesive layer can also be a hot glue or glue or radiation-curing or hot-melt adhesive applied to the object or the label immediately before labeling.
- the label is preferably used to stick to a cylindrically curved surface of the container, for example a beverage bottle, with its stretching direction or — in the case of biaxially stretched film material — the main stretching direction being circumferential or transverse, in particular perpendicular, to the circumferential direction of the container.
- the plastic films can be a single monoaxially or biaxially stretched plastic film layer or a plurality of plastic film layers, the respective stretching direction or main stretching direction of which is often essentially identical.
- the plurality of plastic film layers can be co-extruded or produced individually and connected by means of laminating adhesive.
- Both film layers can be stretched shrinkable in the same direction or in crossing directions with the same or different dimensions, the weakly shrinking film layer preferably being located in the label assembly at the bottom, ie on the side facing the adhesive layer is coming.
- the two film layers can be connected to one another by laminating adhesive.
- the two layers of film can be connected with each other using lamination adhesive, e.g. One- or two-component laminating adhesive, for example based on polyurethane, as well as pressure sensitive adhesives or thermally activated adhesives.
- lamination adhesive e.g. One- or two-component laminating adhesive, for example based on polyurethane, as well as pressure sensitive adhesives or thermally activated adhesives.
- the (main) stretching direction and thus the (main) shrinkage direction of the plastic film (s) run in the circumferential direction of the cylindrical container, so that the label adheres to the container only in the area of a line shortly before it is completely detached .
- Another possibility is to arrange the (main) stretching direction of the plastic film (s) transversely to the circumferential direction of the container, so that the label adheres to the container only at one point shortly before it is completely detached.
- the degree of shrinkage of the at least one plastic film layer - at least in the main shrinking direction - when heated to one of the above-mentioned temperatures is preferably in the range from> 5%, in particular> 10%, further in particular> 15-20% or above.
- the plastic film layer is preferably made of mono- or biaxially stretched polyethylene terephthalate (PET) or polyvinyl chloride (PVC) film, which shows a high degree of shrinkage.
- PET polyethylene terephthalate
- PVC polyvinyl chloride
- the can Adhesive-bearing label layer must be treated before the adhesive adhesive is applied, for example by corona treatment, flame pretreatment, plasma pretreatment or chemical grafting or with the aid of an adhesion-promoting intermediate layer, such as chlorinated polyolefins, chlorinated rubber, ethylene-vinyl acetate (EVA) copolymer, chlorinated polypropylene or contains polymerized ethylene / acrylamide comonomers.
- an adhesion-promoting intermediate layer such as chlorinated polyolefins, chlorinated rubber, ethylene-vinyl acetate (EVA) copolymer, chlorinated polypropylene or contains polymerized ethylene / acrylamide comonomers.
- the label can be washed off in standard industrial washing systems.
- the washing liquid is neither enriched with adhesive nor with film components, since these can be filtered out in the simplest way, for example with a sieve.
- the film label as a whole can be removed from the object together with the adhesive adhering to it.
- Fig. 1 shows schematically the detachment of a label according to the invention on a cylindrically curved object under the action of heat; 1 a, 1 b, 1 c show variants of FIG. 1;
- Fig. 1 shows schematically a partial section normal to the axis through a cylindrical container 1, such as a beverage bottle, on the peripheral surface of which an adhesive label 3 sticks.
- the label 3 has on the top at least one shrinkable plastic film layer 5 stretched at least in the circumferential direction, which is directly printed on the underside by means of an imprint layer 7, which may only be present in partial areas of the surface of the film layer 3.
- the film layer 5 can carry an imprint 7 'on the top, which in turn can carry a protective layer 8, for example in the form of lacquer or laminating film.
- the label 3 has a pressure-sensitive adhesive layer 9.
- the top cover layer 5 preferably shrinks in the main direction of stretching of the label, ie. H. in the circumferential direction U of the container 1, as shown in FIG. 1 with the arrows R.
- the viscosity of the adhesive layer 9 decreases in such a way that the label 3 begins to detach from the edge in the circumferential direction of the container 1. This facilitates the access of the surrounding washing liquid to the adhesive 9, which further accelerates the dissolving process.
- the label sticks only in the area of a line L, which corresponds to a generatrix of the peripheral surface of the container 1. If the surface of the container is slightly or not curved, channels can also form between the adhesive label and the surface of the container in order to facilitate the access of the washing liquid to the adhesive layer.
- the stretching direction of the film layer 5 does not necessarily coincide with the circumferential direction U of the container.
- the reason for this shrink-back process of the film layer 5 is that mono- or biaxially oriented, non-heat-set films stretched in this way have a “frozen” internal state of tension in their molecules, which is applied with heat leads to a reorientation of the molecules, ie to a shrinkage of the film layer in the direction R in which it was previously stretched. This is also known as the memory effect.
- thermoplastic films preferably used here are insoluble in the washing liquid or water, but may have a certain tendency to swell.
- Single-layer films as well as multilayer film composites 5a, 5b can be used, either in the form of coextrudates and film laminates, i.e. H. laminated foils. 1 shows such a laminate with an outer, upper film 5a which is connected to a lower film 5b by means of a laminating adhesive layer 5c.
- the individual film layers of coextrudates or laminates can have the same or different degrees of shrinkage. In the case of coextruded films 5a, 5b, the lamination adhesive layer 5c is missing.
- the layer 5b facing the container preferably shrinks less than the layer 5a facing away from the container.
- Layer 5a or layer 5b can also be dimensionally stable, i. H. essentially do not shrink at the elevated wash temperature.
- the different shrinkage behavior of the individual layers 5a, b leads to a kind of bimetal effect, which leads to the label edges first detaching from the container, and / or, depending on the degree of shrinkage of the one or more films and the direction of shrinkage in relation to the container top - Area, in addition to the above-mentioned channel formation, which also enables accelerated access of the washing liquid to the adhesive.
- Fig. 1 a shows a variant of Fig. 1, in which the print 7 is not printed directly on the underside of the film layer 5, but with the interposition of an adhesive layer 8, z. B. an acrylate layer (top coating). If, in contrast to FIG. 1 a, the print 7 is printed on the film layer 5 from above, as denoted by 7 'in FIG. 1, there can also be an adhesion promoter layer between the imprint 7 'and the film layer 5.
- the print 7 ' can be covered by means of a protective layer 8, for example a protective lacquer or a laminating film.
- the print 7 can also be enclosed between two film layers 5a, 5b.
- the lamination adhesive 5c can be located between the imprint 7 and the film layer 5a lying on top.
- the laminating adhesive layer can also be located between the imprint 7 and the lower film layer 5b.
- FIG. 1 c shows a variant with the same layer structure as FIG. 1, but the main stretching direction R 'of the label extends transversely to the circumferential direction, here parallel to the generating E-E of the cylindrical peripheral surface of the label. Shortly before complete detachment, the label sticks only in the area of a point P on the peripheral surface of the container 1. Labels with the structure of FIGS. 1 a and b can also be used for this.
- the direction of orientation of the individual layers can be the same or different, ie. H. both in and across the machine direction in the production of the film strip.
- an identical orientation of the individual layers is preferred. It is essential that the shrinking force of the foils overall is higher than the adhesive force between the adhesive and the container surface under the given washing conditions.
- Preferred temperature ranges in which the films suitable in this context shrink begin above 40 ° C., in particular in the range from 60-90 ° C., in which the usual bottle washing systems in the beverage industry operate.
- the shrinkage of such films should be at least 5% in the main direction of shrinkage under these washing conditions, preferably 15-20% or more.
- Examples of such films are in particular monoaxially or biaxially stretched shrinkable PET or PVC or polyester films or also other shrinkable films, such as polyethylene, polypropylene, polyolefin, acetate or COC (cycloolefin copolymer) or others, as well as mixtures of one or more of these film materials in thickness ranges from 10 to 200 ⁇ m, but preferably in the thickness range from 30 to 100 ⁇ m.
- FIGS. 2 and 3 Examples of possible foils and their shrinkage behavior can be found in FIGS. 2 and 3.
- a comparison of FIGS. 2 and 3 shows that in the case of monoaxially shrunk films, the transverse shrinkage (FIG. 2) at 90 ° C. is below 5% for all tested PET and PVC films, while the longitudinal shrinkage (FIG. 3) is 90 ° C of the tested PET films is significantly weaker than that of the PVC film, which reaches almost 30% here at 90 ° C.
- PVC film is therefore preferred for the present application, since it shows a particularly high shrinking force at the temperatures customary in washing plants.
- the adhesive does not dissolve in the washing liquid during the washing process, but detaches from the container together with the label film, the washing liquid not being enriched with dissolved adhesive.
- an easily dispersible adhesive such as. B. with aqueous acrylate dispersions or with other adhesives with a high proportion of dispersing aids or emulsifiers.
- all dispersion adhesives are suitable, all adhesives made redispersible by additives, all adhesives where Binding agents or formulating agents can be made easily redispersible by structural changes (other copolymers or copolymers changed in their composition or in their sequence changed), all adhesives based on water-soluble or water-swellable backbone binders (such as acrylates, polyvinyl alcohols or their esters, glues, polyglycolic acid, polylactides, polyethylene glycols as well as various polyamides, polyesters etc.).
- water-soluble or water-swellable backbone binders such as acrylates, polyvinyl alcohols or their esters, glues, polyglycolic acid, polylactides, polyethylene glycols as well as various polyamides, polyesters etc.
- the water-solubility of these adhesives must be adjusted such that they only take place after the washing substance has taken effect for more than 10 minutes, ie only after the label has been removed.
- This can be a pressure-sensitive as well as a heat-sensitive adhesive.
- the adhesive can be applied over the entire surface or partially, such as. B. in strip or dot order or in another pattern.
- solvent-based adhesives e.g. B. based on natural or synthetic rubber z. B. based on styrene-butadiene-styrene (SBS) block copolymers or styrene-isoprene-styrene (SIS) block copolymers, or acrylates and acrylic hot melt adhesives, and radiation-curing adhesives, for. B. UV or electro-curing adhesives, e.g. B. based on acrylate or rubber.
- SBS styrene-butadiene-styrene
- SIS styrene-isoprene-styrene
- UV or electro-curing adhesives e.g. B. based on acrylate or rubber.
- the relative adhesive force - the adhesive force between the film and the adhesive and its adhesive force to the print layer, if any, in between - must be present for each Phase of the washing-up process must be greater than the absolute adhesive strength, namely the adhesive force between the adhesive and the container top area.
- the pretreatment of the film surface before the adhesive coating is preferably carried out by corona treatment. However, it can also be flame pretreatment, plasma pretreatment or chemical grafting.
- an adhesion promoter can also be used between the film and the adhesive layer, such as an adhesion promoter based on chlorinated polyolefins with a low molecular weight or a composition of chlorinated rubber (20 - 60%; 60% chlorine), EVA copolymer (40 - 80%; 25% VA) and chlorinated polypropylene (1 - 15%; 25 - 50% chlorine) or an adhesion promoter made of ethylene / Acrylamide comonomers that harden through polymerization.
- an adhesion promoter based on chlorinated polyolefins with a low molecular weight or a composition of chlorinated rubber (20 - 60%; 60% chlorine), EVA copolymer (40 - 80%; 25% VA) and chlorinated polypropylene (1 - 15%; 25 - 50% chlorine) or an adhesion promoter made of ethylene / Acrylamide comonomers that harden through polymerization.
- the holding force between the carrier material layer 5 and the print layer 7 and the print layer 7 and the adhesive layer 9, as well as the internal cohesion of the print layer 7 and the internal cohesion of the adhesive layer 9 are greater than the holding force from the adhesive layer 9 to the container surface 1, so that there is neither delamination between the carrier material layer 5 and the print layer 7 or the print layer 7 and the adhesive layer 9 nor a cohesive breakage of the print layer 7 or the Adhesive layer 9 comes and with it Carrier material layer 5, the print layer 7 and the adhesive layer as a unit are detached from the container.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Theoretical Computer Science (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU42611/99A AU4261199A (en) | 1999-04-14 | 1999-05-12 | Easily removable label for reusable containers |
US09/926,325 US6680097B1 (en) | 1999-04-14 | 1999-05-12 | Easily removable label for reusable containers |
CA002370038A CA2370038C (en) | 1999-04-14 | 1999-05-12 | Easily removable label for reusable containers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99107508A EP0951004B1 (de) | 1998-04-15 | 1999-04-14 | Leicht entfernbares Etikett für Mehrwegbehälter |
EP99107508.6 | 1999-04-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000062273A1 true WO2000062273A1 (de) | 2000-10-19 |
Family
ID=8237964
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1999/003294 WO2000062273A1 (de) | 1999-04-14 | 1999-05-12 | Leicht entfernbares etikett für mehrwegbehälter |
Country Status (4)
Country | Link |
---|---|
US (1) | US6680097B1 (de) |
AU (1) | AU4261199A (de) |
CA (1) | CA2370038C (de) |
WO (1) | WO2000062273A1 (de) |
Cited By (10)
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WO2007061774A1 (en) * | 2005-11-21 | 2007-05-31 | General Electric Company | Optical article having a multi-component structure as an anti-theft feature and a system and method for inhibiting theft of same |
WO2009034466A2 (de) * | 2007-09-14 | 2009-03-19 | Ooo 'likoflex' | Selbstklebeetikette |
WO2009043975A3 (en) * | 2007-10-05 | 2009-08-13 | Upm Raflatac Oy | Wash-off pressure-sensitive label |
WO2010026163A1 (en) * | 2008-09-03 | 2010-03-11 | Ccl Label Meerane Gmbh | Label, especially for a reusable container |
WO2011161325A1 (en) * | 2010-06-24 | 2011-12-29 | Upm Raflatac Oy | Removable label for containers |
DE102011114137A1 (de) * | 2011-09-23 | 2013-03-28 | X-Label Gmbh | Selbstklebeetikett |
WO2015157203A1 (en) * | 2014-04-07 | 2015-10-15 | Avery Dennison Corporation | Compositions for removable labels |
EP2830796A4 (de) * | 2012-03-27 | 2015-10-28 | Upm Raflatac Oy | Markierung von gegenständen mit abwaschbaren etiketten |
DE102015205935A1 (de) | 2015-04-01 | 2016-10-06 | Ccl Label Meerane Gmbh | Leicht entfernbares Etikett ohne Trennfolie insbesondere für Mehrwegbehälter |
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US6670015B1 (en) * | 2000-05-11 | 2003-12-30 | Hewlett-Packard Development Company, L.P. | Restickable and removable label technology labels |
US7070841B2 (en) * | 2001-04-11 | 2006-07-04 | E. I. Du Pont De Nemours And Company | Insulating label stock |
US6775937B2 (en) * | 2001-06-07 | 2004-08-17 | Bruce M. Ruana | Railing advertising - surface, system and method |
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WO2004078467A1 (ja) * | 2003-03-03 | 2004-09-16 | Iwata Label Co., Ltd. | タックラベル、タックラベルの製造方法及び製造装置 |
US20050170123A1 (en) * | 2003-03-13 | 2005-08-04 | Colleen Zielske | Pressure sensitive label |
FI20040044A0 (fi) | 2003-08-20 | 2004-01-15 | Raimo Erik Sepponen | Menetelmä ja laiteisto valvontaan |
EA011898B1 (ru) * | 2004-03-09 | 2009-06-30 | Спир Груп Холдингз Лимитед | Этикетка для стеклянной бутылки и способ ее удаления |
GB2411877A (en) * | 2004-03-09 | 2005-09-14 | Spear Europ Ltd | Removable label with channels in surface of adhesive |
EP1743006A1 (de) | 2004-03-09 | 2007-01-17 | Spear Group Holdings Limited | Haftfolienetikette für wiederverwendbare behälter |
AU2006205076B2 (en) * | 2005-01-10 | 2010-12-23 | Avery Dennison Corporation | Removable curl labels |
GB2424865C (en) * | 2005-04-06 | 2007-12-11 | Spear Group Holdings Ltd | A label for removable attachment to an article. |
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KR20080033241A (ko) * | 2005-08-01 | 2008-04-16 | 스토라 엔조 아베 | 패키지와 패키지로의 요소를 함께 고정하기 위한 방법 |
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WO2009034466A2 (de) * | 2007-09-14 | 2009-03-19 | Ooo 'likoflex' | Selbstklebeetikette |
WO2009034466A3 (de) * | 2007-09-14 | 2009-07-09 | Ooo Likoflex | Selbstklebeetikette |
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US10029404B2 (en) | 2007-11-21 | 2018-07-24 | Mitsubishi Polyester Film, Inc. | Polyester film having latent shrink properties and process for producing same |
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KR20110084165A (ko) * | 2008-09-03 | 2011-07-21 | 체체엘 라벨 메라네 게엠베하 | 라벨,특히 재사용 용기를 위한 라벨 |
EA018853B1 (ru) * | 2008-09-03 | 2013-11-29 | Ссл Лейбл Мееране Гмбх | Этикетка, в частности, для контейнера многоразового использования |
KR101660459B1 (ko) | 2008-09-03 | 2016-09-27 | 체체엘 라벨 메라네 게엠베하 | 라벨 |
EP3257911A1 (de) * | 2008-09-03 | 2017-12-20 | CCL Label Meerane GmbH | Etikett, insbesondere für wiederverwendbaren behälter |
US9978291B2 (en) | 2008-09-03 | 2018-05-22 | Ccl Label Meerane Gmbh | Label, especially for a reusable container |
WO2010026163A1 (en) * | 2008-09-03 | 2010-03-11 | Ccl Label Meerane Gmbh | Label, especially for a reusable container |
WO2011161325A1 (en) * | 2010-06-24 | 2011-12-29 | Upm Raflatac Oy | Removable label for containers |
DE102011114137A1 (de) * | 2011-09-23 | 2013-03-28 | X-Label Gmbh | Selbstklebeetikett |
EP2830796A4 (de) * | 2012-03-27 | 2015-10-28 | Upm Raflatac Oy | Markierung von gegenständen mit abwaschbaren etiketten |
WO2015157203A1 (en) * | 2014-04-07 | 2015-10-15 | Avery Dennison Corporation | Compositions for removable labels |
DE102015205935A1 (de) | 2015-04-01 | 2016-10-06 | Ccl Label Meerane Gmbh | Leicht entfernbares Etikett ohne Trennfolie insbesondere für Mehrwegbehälter |
Also Published As
Publication number | Publication date |
---|---|
CA2370038C (en) | 2008-06-17 |
US6680097B1 (en) | 2004-01-20 |
CA2370038A1 (en) | 2000-10-19 |
AU4261199A (en) | 2000-11-14 |
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