RU2007141710A - Способ получения полуфабриката с пониженным содержанием микроуглеродного остатка и катализатор для его осуществления - Google Patents

Способ получения полуфабриката с пониженным содержанием микроуглеродного остатка и катализатор для его осуществления Download PDF

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RU2007141710A
RU2007141710A RU2007141710/04A RU2007141710A RU2007141710A RU 2007141710 A RU2007141710 A RU 2007141710A RU 2007141710/04 A RU2007141710/04 A RU 2007141710/04A RU 2007141710 A RU2007141710 A RU 2007141710A RU 2007141710 A RU2007141710 A RU 2007141710A
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periodic table
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Опиндер Кишан БХАН (US)
Опиндер Кишан БХАН
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL)
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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Abstract

1. Способ получения полупродукта, включающий контактирование нефтяного сырья с одним или более катализатором для получения общего продукта, содержащего полупродукт, где полупродукт является жидкой смесью при 25°С и 0,101 МПа; нефтяное сырье имеет содержание микроуглеродного остатка (MCR), по меньшей мере, 0,0001 г на грамм нефтяного сырья; и, по меньшей мере, один из катализаторов является катализатором на основе металла группы 6, который содержит: один или более металлов группы 6 Периодической таблицы и/или одно или более соединений металлов группы 6 Периодической таблицы; имеет медианное распределение пор по размерам с диаметром пор более чем 110 Å; и объем пор, в котором поры, имеющие диаметр пор, по меньшей мере, 350 Å обеспечивают не более 5% объема пор, где диаметр пор и объем пор определяют методом ASTM D4282. ! 2. Способ по п.1, в котором условия контактирования: температуру, давление, скорость потока источника водорода или их комбинации регулируют таким образом, что полупродукт имеет содержание MCR не более 80%, не более 50%, не более 30% или не более 10% от содержания MCR нефтяного сырья. ! 3. Способ по п.1, в котором нефтяное сырье содержит от 0,0001 г до 0,5 г, от 0,005 г до 0,1 г или от 0,01 г до 0,05 г MCR на грамм нефтяного сырья. ! 4. Способ по п.1, в котором катализатор на основе металла группы 6 дополнительно содержит один или более металлов групп 7-10 Периодической таблицы и/или одно или более соединений одного или более металлов групп 7-10 Периодической таблицы. ! 5. Способ по п.1, в котором катализатор на основе металла группы 6 дополнительно содержит один или более металл группы 10 Периодической таблицы и/или одно или более соединений одного или более металлов

Claims (24)

1. Способ получения полупродукта, включающий контактирование нефтяного сырья с одним или более катализатором для получения общего продукта, содержащего полупродукт, где полупродукт является жидкой смесью при 25°С и 0,101 МПа; нефтяное сырье имеет содержание микроуглеродного остатка (MCR), по меньшей мере, 0,0001 г на грамм нефтяного сырья; и, по меньшей мере, один из катализаторов является катализатором на основе металла группы 6, который содержит: один или более металлов группы 6 Периодической таблицы и/или одно или более соединений металлов группы 6 Периодической таблицы; имеет медианное распределение пор по размерам с диаметром пор более чем 110 Å; и объем пор, в котором поры, имеющие диаметр пор, по меньшей мере, 350 Å обеспечивают не более 5% объема пор, где диаметр пор и объем пор определяют методом ASTM D4282.
2. Способ по п.1, в котором условия контактирования: температуру, давление, скорость потока источника водорода или их комбинации регулируют таким образом, что полупродукт имеет содержание MCR не более 80%, не более 50%, не более 30% или не более 10% от содержания MCR нефтяного сырья.
3. Способ по п.1, в котором нефтяное сырье содержит от 0,0001 г до 0,5 г, от 0,005 г до 0,1 г или от 0,01 г до 0,05 г MCR на грамм нефтяного сырья.
4. Способ по п.1, в котором катализатор на основе металла группы 6 дополнительно содержит один или более металлов групп 7-10 Периодической таблицы и/или одно или более соединений одного или более металлов групп 7-10 Периодической таблицы.
5. Способ по п.1, в котором катализатор на основе металла группы 6 дополнительно содержит один или более металл группы 10 Периодической таблицы и/или одно или более соединений одного или более металлов группы 10 Периодической таблицы.
6. Способ по п.1, в котором катализатор на основе металла группы 6 дополнительно содержит один или более элементов из группы 15 Периодической таблицы и/или одно или более соединений одного или более элементов группы 15 Периодической таблицы.
7. Способ по п.1, в котором катализатор на основе металла группы 6 дополнительно содержит носитель, и носитель содержит на грамм носителя, по меньшей мере, 0,8 г, по меньшей мере, 0,9 г или по меньшей мере, 0,95 г гамма-оксида алюминия.
8. Способ по п.1, в котором контактирование осуществляют в присутствии источника водорода, и скорость потока источника водорода в условиях контактирования регулируют для переработки нефтяного сырья.
9. Способ по п.1, в котором нефтяное сырье/общий продукт в процессе контактирования имеет Р-величину равную, по меньшей мере, 1,5.
10. Способ по п.1, который дополнительно включает комбинирование полупродукта с сырьем, которое является нефтяным сырьем или отличается от нефтяного сырья для образования смеси.
11. Способ по любому из пп.1-10, который дополнительно включает стадию переработки полупродукта или смеси для производства транспортного топлива, нагревательного топлива, горючего для отопления, смазочных материалов или химикатов.
12. Катализатор, содержащий: носитель и один или более металл группы 6 Периодической таблицы и/или одно или более соединений одного или более металлов группы 6 Периодической таблицы, где катализатор имеет медианное распределение пор по размеру с диаметром пор более чем 110 Å; и объем пор, в котором поры, имеющие диаметр, по меньшей мере, 350 Å обеспечивают не менее 10% объема пор, где диаметр пор и объем пор определяют методом ASTM D4282.
13. Катализатор по п.12, где носитель имеет содержание гамма-оксида аллюминия, по меньшей мере, 0,8 г, по меньшей мере 0,9 г или, по меньшей мере, 0,95 г на грамм носителя.
14. Катализатор по п.12, где носитель имеет распределение пор по размерам со средним диаметром пор, по меньшей мере, 90 Å и объем пор, в котором поры, имеющие диаметр пор, по меньшей мере, 350 Å, обеспечивают не более 15% объема пор.
15. Катализатор по п.12, где катализатор дополнительно содержит один или более элементов группы 15 Периодической таблицы и/или одно или более соединений одного или более элементов группы 15 Периодической таблицы.
16. Катализатор по любому из пп.12-15, где катализатор содержит на грамм катализатора не более 0,001 г одного или более металлов группы 5 Периодической таблицы и/или одно или более соединений металла группы 5, рассчитанного на общий вес металла группы 5.
17. Способ получения катализатора, включающий комбинирование носителя с раствором металла, содержащего один или более металлов группы 6 Периодической таблицы и/или одно или более соединений одного или более металлов группы 6 Периодической таблицы, где носитель имеет распределение пор по размеру со средним диаметром пор, равным по меньшей мере, 90 Å и объем пор, в котором поры, имеющие диаметр, по меньшей мере, 350 Å обеспечивают не более 15% объема пор, где диаметр пор и объем пор определяют методом ASTM D4282.
18. Способ по п.17, где раствор металла имеет рН до 3.
19. Способ по п.17, где раствор металла дополнительно содержит один или более металлов групп 7-10 Периодической таблицы и/или одно или более соединений одного или более металлов групп 7-10 Периодической таблицы.
20. Способ по п.17, где раствор металла дополнительно содержит один или более элементов группы 15 Периодической таблицы и/или одно или более соединений одного или более элементов группы 15 Периодической таблицы.
21. Способ по п.17, где раствор металла дополнительно содержит одну или более минеральных кислот.
22. Способ по п.17, где раствор металла дополнительно содержит один или более компонентов органических кислот.
23. Способ по п.17, где раствор металла дополнительно содержит пероксид водорода.
24. Способ по п.17, где раствор металла дополнительно содержит амин.
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CA2604009A1 (en) * 2005-04-11 2006-10-19 Opinder Kishan Bhan Method and catalyst for producing a crude product having a reduced nitrogen content
US20080135449A1 (en) * 2006-10-06 2008-06-12 Opinder Kishan Bhan Methods for producing a crude product

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BRPI0610670B1 (pt) 2016-01-19
US20060231465A1 (en) 2006-10-19
JP2013067808A (ja) 2013-04-18
CN101166808A (zh) 2008-04-23
CA2604012A1 (en) 2006-10-19
RU2424275C2 (ru) 2011-07-20
BRPI0610670A2 (pt) 2012-10-30
NL2000050A1 (nl) 2006-10-12
US20110160044A1 (en) 2011-06-30
EP1874897A1 (en) 2008-01-09
US7918992B2 (en) 2011-04-05
NL2000050C2 (nl) 2007-07-27
US8481450B2 (en) 2013-07-09
CN101166808B (zh) 2013-03-27
CA2604012C (en) 2013-11-19
NO20075770L (no) 2007-11-09
WO2006110660A1 (en) 2006-10-19
JP2008536003A (ja) 2008-09-04

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