RU2006136412A - Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина - Google Patents
Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина Download PDFInfo
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Claims (34)
1. Сополимер, образованный полимеризацией пропилена, 4-метил-1-пентена, стирола или другого C4-20 α-олефина и сополимеризуемого сомономера в присутствии состава, содержащего смесь или продукт реакции, полученный в результате объединения
(А) первого катализатора полимеризации олефинов,
(В) второго катализатора полимеризации олефинов, способствующего получению полимеров, отличающихся по химическим или физическим свойствам от полимера, полученного с катализатором (A) при эквивалентных условиях полимеризации, и
(С) челночного агента цепи.
2. Сополимер, образованный полимеризацией пропилена, 4-метил-1-пентена, стирола или другого C4-20 α-олефина и сополимеризуемого сомономера в присутствии состава, содержащего смесь или продукт реакции, полученный в результате объединения
(А) первого катализатора полимеризации олефинов, имеющего высокий показатель внедрения сомономера,
(В) второго катализатора полимеризации олефинов, имеющего показатель внедрения сомономера менее чем 95% от показателя внедрения сомономера катализатора (A), и
(С) челночного агента цепи.
3. Способ получения содержащего пропилен мульти-блок-сополимера, включающий контактирование пропилена и одного или нескольких аддитивно полимеризуемых сомономеров иных чем пропилен в условиях аддитивной полимеризации с составом, содержащим
смесь или продукт реакции, полученный в результате объединения
(А) первого катализатора полимеризации олефинов,
(В) второго катализатора полимеризации олефинов, способствующего получению полимеров, отличающихся по химическим или физическим свойствам от полимера, полученного с катализатором (A) при эквивалентных условиях полимеризации, и
(С) челночного агента цепи.
4. Способ по п.3, где сомономером является этилен.
5. Способ получения содержащего 4-метил-1-пентен мульти-блок-сополимера, содержащий контактирование 4-метил-1-пентена и одного или нескольких полимеризуемых присоединением сомономеров иных чем 4-метил-1-пентен в условиях полимеризации присоединением с составом, содержащим
смесь или продукт реакции, полученный в результате объединения
(А) первого катализатора полимеризации олефинов,
(В) второго катализатора полимеризации олефинов, способствующего получению полимеров, отличающихся по химическим или физическим свойствам от полимера, полученного с катализатором (A) при эквивалентных условиях полимеризации, и
(C) челночного агента цепи.
6. Способ по п.5, где сомономером является этилен.
7. Мульти-блок-сополимер, содержащий в полимеризованной форме два мономера, выбранные из группы, состоящей из C2-20 α-олефинов, причем указанный сополимер содержит два или более сегментов или блоков, отличающихся по содержанию сомономера, кристалличности, регулярности молекулярной структуры, гомогенности или плотности, и по меньшей мере один из полимерных блоков состоит по существу из полимеризованного пропилена, 4-метил-1-пентена, стирола или другого C4-20 α-олефина.
8. Мульти-блок-сополимер, содержащий в полимеризованной форме пропилен и этилен или 4-метил-1-пентен и этилен, причем указанный сополимер содержит два или более сегментов или блоков, отличающихся по содержанию сомономера, кристалличности, регулярности молекулярной структуры, гомогенности или плотности.
9. Мульти-блок-сополимер, состоящий по существу из пропилена и этилена или 4-метил-1-пентена и этилена в полимеризованной форме, указанный сополимер содержит два или более сегментов или блоков, отличающихся по содержанию сомономера, кристалличности, регулярности молекулярной структуры, гомогенности или плотности.
10. Мульти-блок-сополимер по любому из пп.5-9, содержащий четыре или более сегментов или блоков, отличающихся по содержанию сомономера, кристалличности, регулярности молекулярной структуры, гомогенности или плотности.
11. Функционализованное производное мульти-блок-сополимера по любому из пп.1, 2, 5-9 или полученное способом по п.3 или 4.
12. Функционализованное производное мульти-блок-сополимера по п.10.
13. Гомогенная полимерная смесь, содержащая (1) рганический или неорганический полимер и (2) мульти-блок-сополимер по любому из пп.1, 2, 5-9 или полученный способом по п.3 или 4 по данному изобретению.
14. Сшитое производное полимера по любому из пп.1, 2, 5-9 или полученное способом по п.3 или 4.
15. Сшитое производное полимера по п.10.
16. Сшитое производное полимера по п.11.
17. Сшитое производное полимера по п.12.
18. Полимер по любому из пп.1, 2, 5-9 или полученный способом по п.3 или 4, или состав, содержащий его в виде пленки, по меньшей мере одного слоя многослойной пленки, по меньшей мере одного слоя ламинированного изделия, вспененного изделия, волокна, нетканого материала, сформованного литьем под давлением изделия, сформованного раздувом изделия, сформованного роторным прессованием изделия или адгезива.
19. Полимер по п.14 или состав, содержащий его в виде пленки, по меньшей мере одного слоя многослойной пленка, по меньшей мере одного слоя ламинированного изделия, вспененного изделия, волокна, нетканого материала, сформованного литьем под давлением изделия, сформованного раздувом изделия, сформованного роторным прессованием изделия или адгезива.
20. Полимер по п.15 или состав, содержащий его в виде пленки, по меньшей мере одного слоя многослойной пленка, по меньшей мере одного слоя ламинированного изделия, вспененного изделия, волокна, нетканого материала, сформованного литьем под давлением изделия, сформованного раздувом изделия, сформованного роторным прессованием изделия или адгезива.
21. Полимер по п.16 или состав, содержащий его в виде пленки, по меньшей мере одного слоя многослойной пленка, по меньшей мере одного слоя ламинированного изделия, вспененного изделия, волокна, нетканого материала, сформованного литьем под давлением изделия, сформованного раздувом изделия, сформованного роторным прессованием изделия или адгезива.
22. Полимер по п.17 или состав, содержащий его в виде пленки, по меньшей мере одного слоя многослойной пленка, по меньшей мере одного слоя ламинированного изделия, вспененного изделия, волокна, нетканого материала, сформованного литьем под давлением изделия, сформованного раздувом изделия, сформованного роторным прессованием изделия или адгезива.
23. Сополимер по п.1 или 2, где челночным агентом является соединение тригидрокарбилалюминия или дигидрокарбилцинка, содержащее от 1 до 12 атомов углерода в каждой гидрокарбил-группе.
24. Сополимер по п.23, где челночным агентом является триэтилалюминий или диэтилцинк.
25. Сополимер по п.1 или 2, где катализатор (A) содержит комплекс, содержащий переходный металл, выбранный из групп 4-8 Периодической таблицы элементов, и один или несколько делокализованных π-связанных лигандов или лигандов поливалентного основания Льюиса.
26. Сополимер по п.25, где катализатор (A) отвечает формуле
где T3 представляет двухвалентную мостиковую группу из от 2 до 20 атомов, не считая водород, и
Ar2, независимо в каждом случае, представляет арилен или алкил- или арил-замещенную арилен-группу из от 6 до 20 атомов, не считая водород,
M3 представляет металл группы 4,
G, независимо в каждом случае, представляет анионную, нейтральную или дианионную лиганд-группу,
g представляет целое число от 1 до 5, указывающее число таких G групп, и
электронодонорные взаимодействия представлены стрелками.
27. Сополимер по п.23, где катализатор (A) отвечает формуле
где M3 представляет Hf или Zr;
Ar4 представляет C6-20 арил или инертно замещенные его производные, особенно 3,5-ди(изопропил)фенил, 3,5-ди(изобутил)фенил, дибензо-1H-пиррол-1-ил или антрацен-5-ил, и
T4, независимо в каждом случае, содержит C3-6 алкилен-группу, C3-6 циклоалкилен-группу или их инертно замещенные производные;
R21, независимо в каждом случае, представляет водород, галоген, гидрокарбил, тригидрокарбилсилил или тригидрокарбилсилилгидрокарбил из вплоть до 50 атомов, не считая водород; и
G, независимо в каждом случае, представляет галоген или гидрокарбил или тригидрокарбилсилил-группу из вплоть до 20 атомов, не считая водород, или 2 группы G вместе представляют двухвалентное производное указанных групп гидрокарбила или тригидрокарбилсилила.
28. Сополимер по п.23, где катализатор (A) отвечает формуле
где Ar4 представляет 3,5-ди(изопропил)фенил, 3,5-ди(изобутил)фенил, дибензо-1H-пиррол-1-ил или антрацен-5-ил,
R21 представляет водород, галоген или C1-4 алкил, особенно метил,
T4 представляет пропан-1,3-диил или бутан-1,4-диил и
G представляет хлор, метил или бензил.
29. Сополимер по п.1 или 2, где катализатор (B) отвечает формуле
где M2 представляет металл групп 4-10 Периодической таблицы элементов;
T2 представляет группу, содержащую азот, кислород или фосфор;
X2 представляет галоген, гидрокарбил или гидрокарбилокси;
t означает один или два;
x" означает целое число, выбранное, чтобы обеспечить баланс заряда;
и T2 и N связаны мостиковым лигандом.
30. Способ по п.3 или 4, который является непрерывным способом.
31. Способ по п.30, который является осуществляемым в растворе.
32. Способ по п.30, где пропилен и этилен или 4-метил-1-пентен и этилен полимеризуют.
33. Способ по п.30, где катализатор (A) отвечает формуле
где T3 представляет двухвалентную мостиковую группу из от 2 до 20 атомов, не считая водород, и
Ar2, независимо в каждом случае, представляет арилен или алкил- или арил-замещенную арилен-группу из от 6 до 20 атомов, не считая водород;
M3 представляет металл группы 4,
G, независимо в каждом случае, представляет анионную, нейтральную или дианионную лиганд-группу;
g представляет целое число от 1 до 5, указывающее число таких G групп, и
электронодонорные взаимодействия представлены стрелками.
34. Способ по п.30, где катализатор (B) отвечает формуле
где M2 представляет металл групп 4-10 Периодической таблицы элементов;
T2 представляет группу, содержащую азот, кислород или фосфор;
X2 представляет галоген, гидрокарбил или гидрокарбилокси;
t означает один или два;
x" означает целое число, выбранное, чтобы обеспечить баланс заряда;
и T2 и N связаны мостиковым лигандом.
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Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW200536870A (en) * | 2004-03-17 | 2005-11-16 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
WO2012164914A1 (ja) * | 2011-06-02 | 2012-12-06 | 株式会社ブリヂストン | 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ |
WO2016114916A1 (en) * | 2015-01-14 | 2016-07-21 | Exxonmobil Chemical Patents Inc. | Polymer compositions with improved rheological properties |
US10563015B2 (en) | 2015-01-28 | 2020-02-18 | Dow Silicones Corporation | Elastomeric compositions and their applications |
EP3491033B1 (en) | 2016-07-29 | 2020-05-13 | Dow Global Technologies LLC | Mixed catalyst systems for producing multimodal elastomers |
GB201613412D0 (en) * | 2016-08-03 | 2016-09-14 | Dow Corning | Elastomeric compositions and their applications |
GB201613399D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Cosmetic composition comprising silicone materials |
GB201613397D0 (en) | 2016-08-03 | 2016-09-14 | Dow Corning | Cosmetic composition comprising silicone materials |
WO2018170138A1 (en) * | 2017-03-15 | 2018-09-20 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
GB201707439D0 (en) | 2017-05-09 | 2017-06-21 | Dow Corning | Lamination Process |
GB201707437D0 (en) | 2017-05-09 | 2017-06-21 | Dow Corning | Lamination adhesive compositions and their applications |
US11542350B2 (en) | 2018-03-30 | 2023-01-03 | Dow Global Technologies Llc | Binuclear olefin polymerization activators |
WO2019191068A1 (en) | 2018-03-30 | 2019-10-03 | Dow Global Technologies Llc | Olefin polymerization activators |
JP2021519362A (ja) | 2018-03-30 | 2021-08-10 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合活性化剤 |
SG11202008655RA (en) | 2018-03-30 | 2020-10-29 | Dow Global Technologies Llc | Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations |
DE102019004236A1 (de) | 2018-07-02 | 2020-01-02 | Ngk Insulators, Ltd. | Gassensor und Sensorelement |
WO2020069952A1 (en) | 2018-10-02 | 2020-04-09 | Borealis Ag | Low speed cross-linking catalyst for silane-grafted plastomers |
CN110628010B (zh) * | 2019-10-18 | 2022-09-27 | 辽宁奥克医药辅料股份有限公司 | 一种催化剂组合物及其应用于制备中等分子量聚乙二醇的方法 |
CN114846035A (zh) * | 2019-12-27 | 2022-08-02 | 陶氏环球技术有限责任公司 | 乙烯/丁烯多嵌段共聚物及其制备方法 |
KR20230009908A (ko) * | 2020-05-07 | 2023-01-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 바이메탈 활성화제 |
Family Cites Families (166)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3970719A (en) | 1958-01-16 | 1976-07-20 | Phillips Petroleum Company | Preparation of block copolymers |
US4039632A (en) | 1958-01-16 | 1977-08-02 | Phillips Petroleum Company | Preparation of block copolymers |
US3485706A (en) | 1968-01-18 | 1969-12-23 | Du Pont | Textile-like patterned nonwoven fabrics and their production |
US3758643A (en) | 1971-01-20 | 1973-09-11 | Uniroyal Inc | D polyolefin plastic thermoplastic blend of partially cured monoolefin copolymer rubber an |
US3806558A (en) | 1971-08-12 | 1974-04-23 | Uniroyal Inc | Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic |
US4130535A (en) | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
US4104210A (en) | 1975-12-17 | 1978-08-01 | Monsanto Company | Thermoplastic compositions of high unsaturation diene rubber and polyolefin resin |
US4340684A (en) | 1977-06-13 | 1982-07-20 | The Firestone Tire & Rubber Company | Thermoplastic elastomer blends |
US4250273A (en) | 1977-06-13 | 1981-02-10 | The Firestone Tire & Rubber Company | Thermoplastic elastomer blends |
US4311628A (en) | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
US4202801A (en) | 1977-12-30 | 1980-05-13 | Uniroyal, Inc. | Thermoplastic elastomer composition |
US4271049A (en) | 1979-09-10 | 1981-06-02 | Monsanto Company | Elastoplastic compositions of cured diene rubber and polypropylene |
US4322027A (en) | 1980-10-02 | 1982-03-30 | Crown Zellerbach Corporation | Filament draw nozzle |
US4413110A (en) | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
DZ520A1 (fr) | 1982-03-24 | 2004-09-13 | Union Carbide Corp | Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé. |
US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
US4430563A (en) | 1982-04-30 | 1984-02-07 | Minnesota Mining And Manufacturing Company | Data processing form |
JPS6088016A (ja) * | 1983-10-21 | 1985-05-17 | Mitsui Petrochem Ind Ltd | エチレン共重合体 |
US4663220A (en) | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
US4668566A (en) | 1985-10-07 | 1987-05-26 | Kimberly-Clark Corporation | Multilayer nonwoven fabric made with poly-propylene and polyethylene |
US4798081A (en) | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5391629A (en) * | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
US5248729A (en) | 1987-12-28 | 1993-09-28 | Nippon Petrochemicals Company Limited | Process for preparing thermoplastic resin composition |
FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
US4927882A (en) | 1988-10-11 | 1990-05-22 | The West Company, Incorporated | SBR thermoplastic elastomer |
US5270276A (en) | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
US5270410A (en) | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
US4971936A (en) | 1989-07-10 | 1990-11-20 | Shell Oil Company | Catalyst component for making primarily isotactic elastomeric polypropylene or polybutene |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
FR2656314B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
US5032562A (en) | 1989-12-27 | 1991-07-16 | Mobil Oil Corporation | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
AU7324491A (en) * | 1990-02-09 | 1991-09-03 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
US5118767A (en) | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for producing mildly elastomeric primarily isotatic polypropylene and poly-1-butene |
US5089573A (en) | 1990-02-26 | 1992-02-18 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
US5118768A (en) | 1990-05-11 | 1992-06-02 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5051478A (en) | 1990-07-26 | 1991-09-24 | Advanced Elastomer Systems, L. P. | Ethylene copolymer - modified dynamically vulcanized alloys |
US5134209A (en) | 1990-12-26 | 1992-07-28 | Shell Oil Company | Process of producing ethylene-propylene rubbery copolymer |
US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5229477A (en) | 1991-08-26 | 1993-07-20 | Shell Oil Company | Process for producing ethylene-propylene-diene monomer terpolymer |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
US5525695A (en) | 1991-10-15 | 1996-06-11 | The Dow Chemical Company | Elastic linear interpolymers |
US5210338A (en) | 1991-10-25 | 1993-05-11 | Ethyl Corporation | Catalyzed chain growth process |
EP0619827B1 (en) | 1991-12-30 | 1996-06-12 | The Dow Chemical Company | Ethylene interpolymer polymerizations |
US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
KR100262023B1 (ko) | 1992-01-06 | 2000-07-15 | 그레이스 스티븐 에스. | 개선된 촉매 조성물 |
US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
BE1005957A5 (fr) | 1992-06-05 | 1994-04-05 | Solvay | Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine. |
US5276220A (en) | 1992-06-18 | 1994-01-04 | Ethyl Corporation | Actinide catalyzed chain growth process |
JPH08502093A (ja) | 1992-10-02 | 1996-03-05 | ザ・ダウ・ケミカル・カンパニー | オレフィン重合用の担持均一触媒錯体 |
US5608019A (en) | 1992-12-28 | 1997-03-04 | Mobil Oil Corporation | Temperature control of MW in olefin polymerization using supported metallocene catalyst |
US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
HU225374B1 (en) | 1993-01-29 | 2006-10-28 | Dow Global Technologies Inc | Process for producing ethylene/alfa-olefin interpolymer composition |
US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
TW298593B (ru) | 1993-02-12 | 1997-02-21 | Hoechst Ag | |
EP0699212A1 (en) | 1993-04-26 | 1996-03-06 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
BE1007148A3 (fr) | 1993-05-17 | 1995-04-11 | Solvay | Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur. |
FR2705252B1 (fr) | 1993-05-19 | 1995-07-21 | Bp Chemicals Snc | Procédé d'introduction d'un solide dans un réacteur et appareillage. |
ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
US5372682A (en) | 1993-06-24 | 1994-12-13 | The Dow Chemical Company | Electrochemical preparation of addition polymerization catalysts |
US5470993A (en) | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
WO1995014044A1 (en) | 1993-11-19 | 1995-05-26 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
JPH07144455A (ja) | 1993-11-25 | 1995-06-06 | Canon Inc | インクジェット記録装置 |
US5648310A (en) | 1993-12-23 | 1997-07-15 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
US5672669A (en) | 1993-12-23 | 1997-09-30 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
US5461123A (en) | 1994-07-14 | 1995-10-24 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase fluidized bed polyolefin polymerization process using sound waves |
US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
US5625087A (en) | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
JP3275223B2 (ja) * | 1994-09-22 | 2002-04-15 | 科学技術振興事業団 | ポリプロピレン−b−ポリ(エチレン−co−プロピレン)とその製造方法 |
US6030917A (en) | 1996-07-23 | 2000-02-29 | Symyx Technologies, Inc. | Combinatorial synthesis and analysis of organometallic compounds and catalysts |
US5543458A (en) | 1995-01-31 | 1996-08-06 | Shell Oil Company | Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones |
US5550194A (en) | 1995-01-31 | 1996-08-27 | Shell Oil Company | Process for making graft block copolymers by grafting anionic polymer chains onto functionalized polyolefins |
WO1996024627A1 (fr) * | 1995-02-07 | 1996-08-15 | Mitsui Petrochemical Industries, Ltd. | Procede de preparation d'un polymere olefinique |
US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
US5693713A (en) | 1995-05-30 | 1997-12-02 | Shell Oil Company | Process for making block graft copolymers by grafting halosilanes onto polyolefin/diene polymers |
EP0775707B1 (en) | 1995-06-08 | 2001-11-28 | Showa Denko Kabushiki Kaisha | Ionic compounds and catalyst for olefin polymerisation using the compounds |
US5869575A (en) | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
US6051681A (en) | 1995-11-17 | 2000-04-18 | Dsm N.V. | Process for the preparation of a thermoplastic elastomer |
WO1997035893A1 (en) | 1996-03-27 | 1997-10-02 | The Dow Chemical Company | Highly soluble olefin polymerization catalyst activator |
DE69719961T2 (de) | 1996-03-27 | 2004-01-08 | Dow Global Technologies, Inc., Midland | Lösungspolymerisationsverfahren mit dispergierten katalysator-aktivierer |
US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
JP3749756B2 (ja) * | 1996-04-09 | 2006-03-01 | 三井化学株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
JP2000513399A (ja) * | 1996-06-17 | 2000-10-10 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の混合遷移金属触媒系 |
CN1114609C (zh) | 1996-08-08 | 2003-07-16 | 陶氏环球技术公司 | 含3-杂原子取代的环戊二烯基金属配合物和烯烃聚合方法 |
US5854166A (en) | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
WO1998009996A1 (en) | 1996-09-06 | 1998-03-12 | Hyundai Petrochemical Co., Ltd. | Catalyst system for (co)polymerization of olefins and process for the preparation of olefin (co)polymers using the catalyst system |
US6015868A (en) | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
US5783512A (en) | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
US6177377B1 (en) * | 1996-12-18 | 2001-01-23 | Amherst Polymer Technology, Inc. | Polymer blends and process for preparation |
AU726123B2 (en) | 1996-12-19 | 2000-11-02 | Dow Chemical Company, The | 3-aryl substituted indenyl containing metal complexes and polymerization process |
US5965756A (en) | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
FI970349A (fi) | 1997-01-28 | 1998-07-29 | Borealis As | Uudet metalloseeniyhdisteiden aktivaattorisysteemit |
DE69808243T2 (de) * | 1997-02-07 | 2003-05-08 | Exxonmobil Chem Patents Inc | Thermoplastische,elastomere zusammensetzungen aus verzweigten olefincopolymeren |
CA2204803C (en) | 1997-05-08 | 2005-11-15 | Nova Chemicals Ltd. | Process to prepare bridged phosphole-cyclopentadienyl compounds |
WO1998057996A1 (en) * | 1997-06-14 | 1998-12-23 | The Board Of Trustees Of The Leland Stanford, Jr. University | ETHYLENE ENHANCEMENT OF PROCESSES FOR SYNTHESIS OF HIGH MELTING THERMOPLASTIC ELASTOMERIC α-OLEFIN POLYMERS (PRE/EPE EFFECTS) |
US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
CA2210131C (en) | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
US6319989B1 (en) | 1997-07-21 | 2001-11-20 | The Dow Chemical Company | Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom |
US6150297A (en) | 1997-09-15 | 2000-11-21 | The Dow Chemical Company | Cyclopentaphenanthrenyl metal complexes and polymerization process |
KR20010024063A (ko) | 1997-09-19 | 2001-03-26 | 그래햄 이. 테일러 | 좁은 분자량 분포도 및 최적화된 조성을 갖는 에틸렌상호중합체 조성물, 이의 제조 방법 및 이로부터 제조된제품 |
US6696379B1 (en) | 1997-09-19 | 2004-02-24 | The Dow Chemical Company | Supported modified alumoxane catalyst activator |
CA2302173A1 (en) | 1997-09-19 | 1999-04-01 | The Dow Chemical Company | Modified alumoxane catalyst activator |
DE19744102A1 (de) | 1997-10-06 | 1999-04-15 | Targor Gmbh | Katalysatorsystem |
US5986024A (en) * | 1997-10-17 | 1999-11-16 | Sri International | Preparation of multimodal polymer compositions using multinuclear metallocene catalysts |
AU2111599A (en) | 1998-01-09 | 1999-07-26 | Board Of Trustees Of The Leland Stanford Junior University | High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis |
US6380341B1 (en) | 1998-01-09 | 2002-04-30 | The Board Of Trustees Of Leland Stanford Jr. University | Ethylene copolymers with narrow composition distribution and high melting temperatures, and methods of production thereof |
EP1056752B1 (en) | 1998-02-20 | 2003-06-25 | Dow Global Technologies Inc. | Catalyst activators comprising expanded anions |
JPH11279216A (ja) * | 1998-03-25 | 1999-10-12 | Sumitomo Chem Co Ltd | オレフィン重合体の製造方法 |
JP2000072824A (ja) * | 1998-06-19 | 2000-03-07 | Nippon Polyolefin Kk | エチレン・α−オレフィン共重合体、その組成物およびそれらのフィルム |
CA2337024A1 (en) | 1998-08-11 | 2000-02-24 | Peter N. Nickias | Ansa-group-4-metal bis (.mu.-substituted) aluminum complexes |
DE69902548T2 (de) | 1998-08-11 | 2003-04-10 | Dow Chemical Co | Katalysatoraktivatorverbindung |
US6306658B1 (en) | 1998-08-13 | 2001-10-23 | Symyx Technologies | Parallel reactor with internal sensing |
US6316663B1 (en) | 1998-09-02 | 2001-11-13 | Symyx Technologies, Inc. | Catalyst ligands, catalytic metal complexes and processes using and methods of making the same |
TW576843B (en) * | 1998-12-25 | 2004-02-21 | Mitsui Chemicals Inc | Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst |
WO2000049023A1 (en) | 1999-02-19 | 2000-08-24 | The Dow Chemical Company | Process for preparing trifluoroarylaluminum etherates |
US6362309B1 (en) | 1999-04-01 | 2002-03-26 | Symyx Technologies, Inc. | Polymerization catalyst ligands, catalytic metal complexes and compositions and processes using and method of making same |
JP2001081120A (ja) * | 1999-09-16 | 2001-03-27 | Agency Of Ind Science & Technol | オレフィン系リビング重合体の製法 |
WO2000069871A1 (en) | 1999-05-13 | 2000-11-23 | The Dow Chemical Company | Di- and tri-heteroatom substituted indenyl metal complexes |
JP2001098162A (ja) * | 1999-09-30 | 2001-04-10 | Daicel Chem Ind Ltd | 熱可塑性樹脂組成物、感熱性粘着シート及び感熱性粘着シートの製造方法 |
US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
US6399722B1 (en) * | 1999-12-01 | 2002-06-04 | Univation Technologies, Llc | Solution feed of multiple catalysts |
US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
ATE547437T1 (de) | 1999-12-10 | 2012-03-15 | Dow Global Technologies Llc | Substituierte gruppe-4-metallkomplexe, katalysatoren und olefinpolymerisationsverfahren |
US6323284B1 (en) * | 1999-12-10 | 2001-11-27 | Exxonmobil Chemical Patents, Inc. | Method of preparation of crosslinked blends of amorphous and crystalline polymers |
JP2001233923A (ja) * | 1999-12-17 | 2001-08-28 | Idemitsu Petrochem Co Ltd | プロピレン−エチレンブロック共重合体、樹脂組成物及びブロー成形体 |
US6838540B2 (en) * | 2000-01-26 | 2005-01-04 | Mitsui Chemicals, Inc. | Olefin polymer and production processes thereof |
EP1299405B1 (en) | 2000-06-30 | 2009-05-13 | Dow Global Technologies Inc. | Polycyclic, fused ring compounds, metal complexes and polymerization process |
JP2002105132A (ja) * | 2000-07-26 | 2002-04-10 | Mitsui Chemicals Inc | ポリマーおよびその製造方法 |
NO20013880L (no) * | 2000-08-22 | 2002-02-25 | Rohm & Haas | Matriks og fremgangsmåte for fremstilling av polyolefiner |
US6706829B2 (en) | 2000-11-07 | 2004-03-16 | Symyx Technologies, Inc. | Methods of polymerizing ethylene and styrene copolymers with substituted pyridyl amine catalysts and catalysts therefor |
PL363217A1 (en) * | 2000-12-04 | 2004-11-15 | Univaton Technologies, Llc | Polimerization process |
US20030105250A1 (en) * | 2001-02-23 | 2003-06-05 | Whiteker Gregory T. | Olefin oligomerization catalysts, their production and use |
JP2002275325A (ja) * | 2001-03-15 | 2002-09-25 | Mitsui Chemicals Inc | プロピレン系重合体組成物 |
MY131000A (en) * | 2001-03-16 | 2007-07-31 | Dow Global Technologies Inc | High melt strength polymers and method of making same |
DE60204686T2 (de) | 2001-05-14 | 2006-05-18 | Dow Global Technologies, Inc., Midland | 3-arylsubstituierte zyklopentadienyl-metal-komplexe und polymerisationsverfahren |
US6444867B1 (en) | 2001-05-17 | 2002-09-03 | Bp Corporation North America Inc. | Process for linear alpha olefins |
AU2002310315A1 (en) | 2001-07-23 | 2003-02-17 | Dow Global Technologies, Inc. | Salt of lewis acid/acid adducts and catalyst activators therefrom |
US7087686B2 (en) * | 2001-08-06 | 2006-08-08 | Bp Chemicals Limited | Chain growth reaction process |
US20040242808A1 (en) * | 2001-09-11 | 2004-12-02 | Mink Robert I | Method for preparaing polyolefins |
US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
JP2005508415A (ja) * | 2001-11-06 | 2005-03-31 | ダウ グローバル テクノロジーズ インコーポレイティド | アイソタクチックプロピレンコポリマー類、その製法および用途 |
JP2003160684A (ja) * | 2001-11-26 | 2003-06-03 | Chisso Corp | ポリプロピレン樹脂成形体 |
KR20050035183A (ko) * | 2001-11-30 | 2005-04-15 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 비-단일 부위/단일 부위 촉매 복합물을 이용하여 제조된에틸렌/알파-올레핀 공중합체, 이의 제조 방법 및 용도 |
JP4013555B2 (ja) * | 2002-01-11 | 2007-11-28 | 住友化学株式会社 | 収縮包装用フィルムおよびラベル |
JP2003211481A (ja) * | 2002-01-25 | 2003-07-29 | Chisso Corp | 熱可塑性樹脂と発泡剤を用いた成形方法およびその成形方法により得られた成形体 |
JP2003238611A (ja) * | 2002-02-18 | 2003-08-27 | Japan Polyolefins Co Ltd | オレフィン類重合用触媒成分、オレフィン類重合用触媒及びポリオレフィン類の製造方法 |
DE60322684D1 (de) | 2002-03-14 | 2008-09-18 | Dow Global Technologies Inc | Metallkomplexe mit substituierten indenylliganden und polymerisationsverfahren |
WO2003078480A2 (en) | 2002-03-14 | 2003-09-25 | Dow Global Technologies Inc. | Polycyclic, fused heteroring compounds, metal complexes and polymerization process |
DE60335459D1 (de) | 2002-04-24 | 2011-02-03 | Symyx Solutions Inc | Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere |
US6875828B2 (en) * | 2002-09-04 | 2005-04-05 | Univation Technologies, Llc | Bimodal polyolefin production process and films therefrom |
WO2004024740A1 (en) | 2002-09-12 | 2004-03-25 | Dow Global Technologies Inc. | Preparation of metal complexes |
AU2003304716A1 (en) * | 2002-10-15 | 2005-11-25 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US6797779B1 (en) | 2003-03-28 | 2004-09-28 | The Goodyear Tire & Rubber Company | Thermoplastic composition |
US6953764B2 (en) | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
US7858706B2 (en) * | 2004-03-17 | 2010-12-28 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
TW200536870A (en) * | 2004-03-17 | 2005-11-16 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
AU2005224258B2 (en) * | 2004-03-17 | 2010-09-02 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene copolymer formation |
CN101001885B (zh) * | 2004-08-09 | 2011-05-25 | 陶氏环球技术公司 | 用于制备聚合物的负载型双(羟基芳基芳氧基)催化剂 |
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SG183749A1 (en) | 2012-09-27 |
JP2014065920A (ja) | 2014-04-17 |
TW200604224A (en) | 2006-02-01 |
SG151301A1 (en) | 2009-04-30 |
JP6887983B2 (ja) | 2021-06-16 |
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EP2221329B1 (en) | 2014-11-26 |
EP2221329A1 (en) | 2010-08-25 |
RU2006136414A (ru) | 2008-04-27 |
TW200604225A (en) | 2006-02-01 |
JP2018188666A (ja) | 2018-11-29 |
JP6651348B2 (ja) | 2020-02-19 |
JP2019059955A (ja) | 2019-04-18 |
KR20070004731A (ko) | 2007-01-09 |
JP6907163B2 (ja) | 2021-07-21 |
TWI391412B (zh) | 2013-04-01 |
EP2792690B1 (en) | 2019-05-15 |
KR101266331B1 (ko) | 2013-05-23 |
EP2221328B1 (en) | 2017-04-19 |
RU2375381C2 (ru) | 2009-12-10 |
JP2016094624A (ja) | 2016-05-26 |
EP2792690A1 (en) | 2014-10-22 |
RU2381240C2 (ru) | 2010-02-10 |
EP2221328A2 (en) | 2010-08-25 |
EP2221328A3 (en) | 2010-12-22 |
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ES2342895T3 (es) | 2010-07-16 |
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