DE69901451T2 - Ansa bis(.mu.-aluminium)-substituierte gruppe-4-metallkomplexe - Google Patents

Ansa bis(.mu.-aluminium)-substituierte gruppe-4-metallkomplexe

Info

Publication number
DE69901451T2
DE69901451T2 DE69901451T DE69901451T DE69901451T2 DE 69901451 T2 DE69901451 T2 DE 69901451T2 DE 69901451 T DE69901451 T DE 69901451T DE 69901451 T DE69901451 T DE 69901451T DE 69901451 T2 DE69901451 T2 DE 69901451T2
Authority
DE
Germany
Prior art keywords
group
aluminum
metal
groups
lewis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69901451T
Other languages
English (en)
Other versions
DE69901451D1 (de
Inventor
Y Chen
J Kruper
N Nickias
R Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of DE69901451D1 publication Critical patent/DE69901451D1/de
Application granted granted Critical
Publication of DE69901451T2 publication Critical patent/DE69901451T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69901451T 1998-08-11 1999-06-11 Ansa bis(.mu.-aluminium)-substituierte gruppe-4-metallkomplexe Expired - Fee Related DE69901451T2 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US9608898P 1998-08-11 1998-08-11
US9680098P 1998-08-17 1998-08-17
US10049098P 1998-09-16 1998-09-16
US10422998P 1998-10-14 1998-10-14
US12261599P 1999-03-03 1999-03-03
PCT/US1999/013344 WO2000009523A1 (en) 1998-08-11 1999-06-11 Ansa-group-4-metal bis (.mu.-substituted) aluminum complexes

Publications (2)

Publication Number Publication Date
DE69901451D1 DE69901451D1 (de) 2002-06-13
DE69901451T2 true DE69901451T2 (de) 2002-12-12

Family

ID=27536779

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69901451T Expired - Fee Related DE69901451T2 (de) 1998-08-11 1999-06-11 Ansa bis(.mu.-aluminium)-substituierte gruppe-4-metallkomplexe

Country Status (9)

Country Link
US (1) US6140521A (de)
EP (1) EP1104429B1 (de)
JP (1) JP2002522551A (de)
AT (1) ATE217318T1 (de)
AU (1) AU4440499A (de)
CA (1) CA2337024A1 (de)
DE (1) DE69901451T2 (de)
MY (1) MY133950A (de)
WO (1) WO2000009523A1 (de)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI104826B (fi) * 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
ATE222257T1 (de) * 1998-08-11 2002-08-15 Dow Chemical Co Katalysatoraktivatorverbindung
US7951882B2 (en) 2004-03-17 2011-05-31 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
EP2327727B1 (de) 2004-03-17 2015-07-22 Dow Global Technologies LLC Katalysatorzusammensetzung mit Transportwirkstoff zur Formierung von Ethylen-Copolymeren
SG151301A1 (en) 2004-03-17 2009-04-30 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for ethylene multi- block copolymer formation
ATE504349T1 (de) 2004-06-16 2011-04-15 Dow Global Technologies Inc Verfahren zur auswahl von polymerisationsmodifikatoren
US20080051537A1 (en) * 2004-08-09 2008-02-28 Carnahan Edmund M Supported Bis(Hydroxylarylaryloxy) Catalysts For Manufacture Of Polymers
KR20070117675A (ko) 2005-03-17 2007-12-12 다우 글로벌 테크놀로지스 인크. 택틱/아택틱 멀티-블록 공중합체의 형성을 위한 이동제를포함하는 촉매 조성물
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
KR101263966B1 (ko) * 2005-03-17 2013-05-13 다우 글로벌 테크놀로지스 엘엘씨 레지오-불규칙 멀티-블록 공중합체 형성을 위한 이동제를포함하는 촉매 조성물
KR20080055837A (ko) * 2005-09-15 2008-06-19 다우 글로벌 테크놀로지스 인크. 중합가능한 셔틀링제를 통한 촉매성 올레핀 블럭 공중합체
CA2622599A1 (en) 2005-09-15 2007-03-29 Dow Global Technolgies Inc. Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
WO2007136494A2 (en) 2006-05-17 2007-11-29 Dow Global Technologies Inc. Ethylene/ alpha-olefin/ diene solution polymerization process
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
WO2009067337A1 (en) * 2007-11-19 2009-05-28 Dow Global Technologies Inc. Long chain branched propylene-alpha-olefin copolymers
WO2010102163A2 (en) 2009-03-06 2010-09-10 Dow Global Technologies Inc. Catalysts, processes for making catalysts, processes for making polyolefin compositions and polyolefin compositions
WO2011016992A2 (en) 2009-07-29 2011-02-10 Dow Global Technologies Inc. Polymeric chain transfer/shuttling agents
SG178111A1 (en) 2009-07-29 2012-03-29 Dow Global Technologies Llc Dual- or multi-headed chain shuttling agents and their use for the preparation of block copolymers
BR112018005199B1 (pt) 2015-09-30 2020-12-15 Dow Global Technologies Llc Processo para a preparação de uma composição, composição e processo para polimerização de pelo menos um monômero polimerizável por adição para formar uma composição de polímero
BR112019006150B1 (pt) 2016-09-30 2023-02-28 Dow Global Technologies Llc Composição e processo para preparar a composição
US11174329B2 (en) 2016-09-30 2021-11-16 Dow Global Technologies Llc Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
EP3519474A1 (de) 2016-09-30 2019-08-07 Dow Global Technologies LLC Verfahren zur herstellung von mehrfach- oder doppelkopfzusammensetzungen zur kettenübertragung
WO2020140058A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Telechelic polyolefins and processes for preparing the same
US20220073716A1 (en) 2018-12-28 2022-03-10 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
EP3902808A1 (de) 2018-12-28 2021-11-03 Dow Global Technologies LLC Härtbare zusammensetzungen mit ungesättigten polyolefinen
US20220073539A1 (en) 2018-12-28 2022-03-10 Dow Global Technologies Llc Organometallic chain transfer agents
KR20210121029A (ko) 2018-12-28 2021-10-07 다우 글로벌 테크놀로지스 엘엘씨 텔레켈릭 폴리올레핀을 포함하는 경화성 조성물

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
JPH05230134A (ja) * 1992-02-24 1993-09-07 Mitsui Toatsu Chem Inc 分子量分布の広いポリオレフィンの製造方法
KR100292158B1 (ko) * 1992-08-04 2001-06-01 가지와라 야스시 올레핀중합용 촉매 및 올레핀의 중합방법

Also Published As

Publication number Publication date
MY133950A (en) 2007-11-30
US6140521A (en) 2000-10-31
JP2002522551A (ja) 2002-07-23
EP1104429B1 (de) 2002-05-08
DE69901451D1 (de) 2002-06-13
WO2000009523A1 (en) 2000-02-24
CA2337024A1 (en) 2000-02-24
EP1104429A1 (de) 2001-06-06
ATE217318T1 (de) 2002-05-15
AU4440499A (en) 2000-03-06

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Legal Events

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8339 Ceased/non-payment of the annual fee