RU2004103077A - Иономер для использования в топливных элементах и способ его получения - Google Patents
Иономер для использования в топливных элементах и способ его получения Download PDFInfo
- Publication number
- RU2004103077A RU2004103077A RU2004103077/04A RU2004103077A RU2004103077A RU 2004103077 A RU2004103077 A RU 2004103077A RU 2004103077/04 A RU2004103077/04 A RU 2004103077/04A RU 2004103077 A RU2004103077 A RU 2004103077A RU 2004103077 A RU2004103077 A RU 2004103077A
- Authority
- RU
- Russia
- Prior art keywords
- ionomer
- monomer
- anode
- cathode
- electrolyte membrane
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title claims 25
- 229920000554 ionomer Polymers 0.000 title claims 25
- 238000004519 manufacturing process Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 27
- 239000000178 monomer Substances 0.000 claims 27
- 239000012528 membrane Substances 0.000 claims 23
- 238000000034 method Methods 0.000 claims 20
- 239000005518 polymer electrolyte Substances 0.000 claims 16
- 239000000047 product Substances 0.000 claims 12
- 239000003795 chemical substances by application Substances 0.000 claims 10
- -1 poly (phthalazinone ether ketones Chemical class 0.000 claims 8
- 239000002798 polar solvent Substances 0.000 claims 7
- 229920000307 polymer substrate Polymers 0.000 claims 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 125000003118 aryl group Chemical group 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 5
- PLVUIVUKKJTSDM-UHFFFAOYSA-N 1-fluoro-4-(4-fluorophenyl)sulfonylbenzene Chemical compound C1=CC(F)=CC=C1S(=O)(=O)C1=CC=C(F)C=C1 PLVUIVUKKJTSDM-UHFFFAOYSA-N 0.000 claims 4
- LSQARZALBDFYQZ-UHFFFAOYSA-N 4,4'-difluorobenzophenone Chemical compound C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 LSQARZALBDFYQZ-UHFFFAOYSA-N 0.000 claims 4
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical group CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 claims 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims 4
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims 4
- 239000002585 base Substances 0.000 claims 4
- 230000015271 coagulation Effects 0.000 claims 4
- 238000005345 coagulation Methods 0.000 claims 4
- 230000018044 dehydration Effects 0.000 claims 4
- 238000006297 dehydration reaction Methods 0.000 claims 4
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims 4
- IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 claims 4
- 150000003839 salts Chemical class 0.000 claims 4
- 239000002904 solvent Substances 0.000 claims 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 4
- LYLHOKOTRWUGIF-UHFFFAOYSA-N 4-(4-hydroxyphenyl)-2H-phthalazin-1-one Chemical compound C1=CC(O)=CC=C1C1=NNC(=O)C2=CC=CC=C12 LYLHOKOTRWUGIF-UHFFFAOYSA-N 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 3
- 230000015572 biosynthetic process Effects 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 239000007795 chemical reaction product Substances 0.000 claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 3
- 150000002367 halogens Chemical class 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 2
- 230000002378 acidificating effect Effects 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 150000001491 aromatic compounds Chemical class 0.000 claims 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims 2
- 239000012965 benzophenone Substances 0.000 claims 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 230000001112 coagulating effect Effects 0.000 claims 2
- 238000007334 copolymerization reaction Methods 0.000 claims 2
- 238000009792 diffusion process Methods 0.000 claims 2
- 238000007865 diluting Methods 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 230000005611 electricity Effects 0.000 claims 2
- 239000012634 fragment Substances 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 230000001939 inductive effect Effects 0.000 claims 2
- 150000002576 ketones Chemical class 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 239000012429 reaction media Substances 0.000 claims 2
- 230000035484 reaction time Effects 0.000 claims 2
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims 2
- 239000008096 xylene Substances 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims 1
- 238000010533 azeotropic distillation Methods 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 229910001414 potassium ion Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910001415 sodium ion Inorganic materials 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2275—Heterogeneous membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Polyethers (AREA)
- Fuel Cell (AREA)
- Conductive Materials (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011132574A CN1161397C (zh) | 2001-07-05 | 2001-07-05 | 带磺酸盐侧基的聚二氮杂萘酮醚酮及制备方法 |
| CN01113257.4 | 2001-07-05 | ||
| CN02111491.9 | 2002-04-25 | ||
| CN 02111491 CN1200029C (zh) | 2002-04-25 | 2002-04-25 | 带磺酸盐侧基的聚二氮杂萘酮醚砜及制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2004103077A true RU2004103077A (ru) | 2005-03-27 |
Family
ID=25740356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004103077/04A RU2004103077A (ru) | 2001-07-05 | 2002-07-05 | Иономер для использования в топливных элементах и способ его получения |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7405015B2 (enExample) |
| EP (1) | EP1402590B1 (enExample) |
| JP (1) | JP4102299B2 (enExample) |
| KR (1) | KR100817691B1 (enExample) |
| AU (1) | AU2002354786B2 (enExample) |
| BR (1) | BR0210803B1 (enExample) |
| CA (1) | CA2451896C (enExample) |
| DE (1) | DE60223539T2 (enExample) |
| RU (1) | RU2004103077A (enExample) |
| WO (1) | WO2003005474A2 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2485971A1 (en) | 2002-05-13 | 2004-05-21 | Polyfuel, Inc. | Ion conductive block copolymers |
| US7297429B2 (en) * | 2002-07-05 | 2007-11-20 | Gore Enterprise Holdings, Inc. | Ionomer for use in fuel cells and method of making same |
| JP2005133092A (ja) * | 2003-10-10 | 2005-05-26 | Hitachi Chem Co Ltd | 複素環を有する高分子電解質化合物、高分子電解質膜、それを用いた触媒層形成電解質膜及びそれを用いた電気化学素子 |
| JP2006135022A (ja) * | 2004-11-04 | 2006-05-25 | Nitto Denko Corp | 配線回路基板 |
| KR100614100B1 (ko) * | 2005-01-14 | 2006-08-22 | 한국과학기술연구원 | 나피온 이오노머 용액의 완전 건조전 전극상막 방법을이용하는 연료 전지용 막전극접합체의 제조 방법 및 그에의해 제조되는 연료 전지용 막전극접합체 |
| CN101120419B (zh) * | 2005-02-15 | 2011-02-16 | 东丽株式会社 | 高分子电解质成型体的制造方法、高分子电解质材料、高分子电解质膜和高分子电解质型燃料电池 |
| US20060199059A1 (en) * | 2005-03-01 | 2006-09-07 | Xu Helen X | Ion conductive polymer electrolyte and its membrane electrode assembly |
| EP2355218B1 (en) * | 2005-03-04 | 2012-10-03 | Ube Industries, Ltd. | Novel polymer electrolyte, polymer electrolyte composition, electrolyte membrane, and production method and use thereof |
| JP2006338928A (ja) * | 2005-05-31 | 2006-12-14 | Hitachi Chem Co Ltd | 補強高分子電解質、電極−高分子電解質膜接合体、燃料電池並びにそれらの製造方法 |
| KR100833056B1 (ko) * | 2006-03-31 | 2008-05-27 | 주식회사 엘지화학 | 연료전지용 강화-복합 전해질막 |
| KR100897104B1 (ko) | 2006-11-02 | 2009-05-14 | 현대자동차주식회사 | 다층구조를 가진 전해질 강화막의 제조 방법 |
| KR100851924B1 (ko) | 2007-02-01 | 2008-08-12 | 충주대학교 산학협력단 | 다중 술폰화된 폴리 아릴에테르케톤 공중합체 및 이를포함하는 전해질막 |
| DE102007008268B4 (de) * | 2007-02-20 | 2009-02-19 | Staxera Gmbh | Prüfstand und Prüfverfahren für einen Brennstoffzellenstapel |
| US20100159298A1 (en) * | 2008-12-22 | 2010-06-24 | 3M Innovative Properties Company | Fuel cell membrane electrode assembly with multilayer cathode |
| KR101651093B1 (ko) * | 2009-12-11 | 2016-08-26 | 건국대학교 글로컬산학협력단 | 다중황산기를 포함하는 다중페닐 단위체를 지닌 양이온 교환 고분자 |
| US9005841B2 (en) * | 2009-12-18 | 2015-04-14 | Lg Chem, Ltd. | Polymer electrolyte membrane for fuel cell, membrane electrode assembly and fuel cell including the same |
| US20110274990A1 (en) * | 2010-05-07 | 2011-11-10 | Yang G Xu | Methanol and Hydrogen Peroxide Fuel Cell with Hydroxyl Ion Exchange Membrane |
| JP5725685B2 (ja) * | 2011-06-16 | 2015-05-27 | エルジー ケム． エルティーディ． | 燃料電池用高分子電解質膜、それを含む膜電極接合体及び燃料電池 |
| US10603639B2 (en) | 2016-09-02 | 2020-03-31 | Hossein Beydaghi | Nanocomposite blend membrane |
| EP4466742A1 (en) | 2022-01-21 | 2024-11-27 | Basf Se | Mixed platinum ruthenium oxide and electrodes for the oxygen evolution reaction |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3282875A (en) * | 1964-07-22 | 1966-11-01 | Du Pont | Fluorocarbon vinyl ether polymers |
| CA962021A (en) * | 1970-05-21 | 1975-02-04 | Robert W. Gore | Porous products and process therefor |
| US4083768A (en) * | 1976-05-24 | 1978-04-11 | Allied Chemical Corporation | Preparation of high performance polyelectrolyte membrane |
| DE2861696D1 (en) * | 1977-09-07 | 1982-04-29 | Ici Plc | Thermoplastic aromatic polyetherketones, a method for their preparation and their application as electrical insulants |
| US4358545A (en) * | 1980-06-11 | 1982-11-09 | The Dow Chemical Company | Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000 |
| US4940525A (en) * | 1987-05-08 | 1990-07-10 | The Dow Chemical Company | Low equivalent weight sulfonic fluoropolymers |
| USRE37707E1 (en) * | 1990-02-22 | 2002-05-21 | Stmicroelectronics S.R.L. | Leadframe with heat dissipator connected to S-shaped fingers |
| US5306789A (en) * | 1990-10-31 | 1994-04-26 | Hay Allan S | Amorphous, soluble, aromatic polymers with high glass transition temperatures |
| US5254663A (en) * | 1992-04-28 | 1993-10-19 | Hay Allan S | Polymers derived from phenolphthaleins |
| US5237062A (en) * | 1992-04-28 | 1993-08-17 | Hay Allan S | Polymers derived from phenolphthaleins |
| US5834523A (en) * | 1993-09-21 | 1998-11-10 | Ballard Power Systems, Inc. | Substituted α,β,β-trifluorostyrene-based composite membranes |
| USRE37756E1 (en) * | 1994-06-29 | 2002-06-18 | Jiann H. Chen | Fuser members overcoated with fluorocarbon elastomer containing aluminum oxide |
| US5525436A (en) * | 1994-11-01 | 1996-06-11 | Case Western Reserve University | Proton conducting polymers used as membranes |
| US5547551A (en) * | 1995-03-15 | 1996-08-20 | W. L. Gore & Associates, Inc. | Ultra-thin integral composite membrane |
| USRE37701E1 (en) * | 1994-11-14 | 2002-05-14 | W. L. Gore & Associates, Inc. | Integral composite membrane |
| US5882810A (en) * | 1996-03-08 | 1999-03-16 | The Dow Chemicalcompany | Active layer for membrane electrode assembly |
| US5716727A (en) * | 1996-04-01 | 1998-02-10 | Case Western Reserve University | Proton conducting polymers prepared by direct acid casting |
| JP3861367B2 (ja) * | 1996-04-18 | 2006-12-20 | 住友化学株式会社 | 高分子電解質、その製造方法およびそれを使用してなる燃料電池 |
| US6444343B1 (en) | 1996-11-18 | 2002-09-03 | University Of Southern California | Polymer electrolyte membranes for use in fuel cells |
| US6399254B1 (en) * | 1997-05-23 | 2002-06-04 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Solid electrolyte |
| US6365294B1 (en) * | 1999-04-30 | 2002-04-02 | The Administrators Of The Tulane Educational Fund | Sulfonated polyphosphazenes for proton-exchange membrane fuel cells |
| WO2000077874A1 (en) | 1999-06-11 | 2000-12-21 | The Penn State Research Foundation | Proton conducting polymer membranes |
| JP4234422B2 (ja) | 2000-09-20 | 2009-03-04 | バージニア テック インテレクチュアル プロパティーズ インコーポレーテッド | イオン導電性スルホン化重合体材料 |
| US7297429B2 (en) * | 2002-07-05 | 2007-11-20 | Gore Enterprise Holdings, Inc. | Ionomer for use in fuel cells and method of making same |
-
2002
- 2002-07-05 US US10/481,226 patent/US7405015B2/en not_active Expired - Fee Related
- 2002-07-05 DE DE60223539T patent/DE60223539T2/de not_active Expired - Lifetime
- 2002-07-05 AU AU2002354786A patent/AU2002354786B2/en not_active Ceased
- 2002-07-05 KR KR1020047000040A patent/KR100817691B1/ko not_active Expired - Fee Related
- 2002-07-05 EP EP02752181A patent/EP1402590B1/en not_active Expired - Lifetime
- 2002-07-05 BR BRPI0210803-8A patent/BR0210803B1/pt not_active IP Right Cessation
- 2002-07-05 JP JP2003511332A patent/JP4102299B2/ja not_active Expired - Fee Related
- 2002-07-05 CA CA002451896A patent/CA2451896C/en not_active Expired - Fee Related
- 2002-07-05 WO PCT/US2002/021346 patent/WO2003005474A2/en not_active Ceased
- 2002-07-05 RU RU2004103077/04A patent/RU2004103077A/ru not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US20050079399A1 (en) | 2005-04-14 |
| WO2003005474A9 (en) | 2004-07-01 |
| WO2003005474A2 (en) | 2003-01-16 |
| JP4102299B2 (ja) | 2008-06-18 |
| DE60223539D1 (de) | 2007-12-27 |
| BR0210803A (pt) | 2004-06-29 |
| KR20040013094A (ko) | 2004-02-11 |
| KR100817691B1 (ko) | 2008-03-27 |
| EP1402590B1 (en) | 2007-11-14 |
| WO2003005474A3 (en) | 2003-08-28 |
| DE60223539T2 (de) | 2008-09-25 |
| CA2451896C (en) | 2009-09-08 |
| AU2002354786B2 (en) | 2005-08-18 |
| BR0210803B1 (pt) | 2011-11-29 |
| US7405015B2 (en) | 2008-07-29 |
| JP2004534890A (ja) | 2004-11-18 |
| EP1402590A2 (en) | 2004-03-31 |
| CA2451896A1 (en) | 2003-01-16 |
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| FA93 | Acknowledgement of application withdrawn (no request for examination) |
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