KR100817691B1 - 연료 전지에 사용하기 위한 이오노머 및 그의 제조 방법 - Google Patents

연료 전지에 사용하기 위한 이오노머 및 그의 제조 방법 Download PDF

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Publication number
KR100817691B1
KR100817691B1 KR1020047000040A KR20047000040A KR100817691B1 KR 100817691 B1 KR100817691 B1 KR 100817691B1 KR 1020047000040 A KR1020047000040 A KR 1020047000040A KR 20047000040 A KR20047000040 A KR 20047000040A KR 100817691 B1 KR100817691 B1 KR 100817691B1
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South Korea
Prior art keywords
ionomer
anode
cathode
sulfone
phthalazinone
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Expired - Fee Related
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KR1020047000040A
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English (en)
Korean (ko)
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KR20040013094A (ko
Inventor
구유 시아오
구오민 선
데이유 얀
찰스 더블유. 마틴
헤이 유
카린 굴라티
카를로스 알베르토 카발카
신위안 주
Original Assignee
더블유.엘. 고어 앤드 어소시에이트스, 인코포레이티드
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Priority claimed from CNB011132574A external-priority patent/CN1161397C/zh
Priority claimed from CN 02111491 external-priority patent/CN1200029C/zh
Application filed by 더블유.엘. 고어 앤드 어소시에이트스, 인코포레이티드 filed Critical 더블유.엘. 고어 앤드 어소시에이트스, 인코포레이티드
Publication of KR20040013094A publication Critical patent/KR20040013094A/ko
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • C08J5/2256Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275Heterogeneous membranes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1004Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Polyethers (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020047000040A 2001-07-05 2002-07-05 연료 전지에 사용하기 위한 이오노머 및 그의 제조 방법 Expired - Fee Related KR100817691B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CNB011132574A CN1161397C (zh) 2001-07-05 2001-07-05 带磺酸盐侧基的聚二氮杂萘酮醚酮及制备方法
CN01113257.4 2001-07-05
CN02111491.9 2002-04-25
CN 02111491 CN1200029C (zh) 2002-04-25 2002-04-25 带磺酸盐侧基的聚二氮杂萘酮醚砜及制备方法
PCT/US2002/021346 WO2003005474A2 (en) 2001-07-05 2002-07-05 Ionomer for use in fuel cells and method of making same

Publications (2)

Publication Number Publication Date
KR20040013094A KR20040013094A (ko) 2004-02-11
KR100817691B1 true KR100817691B1 (ko) 2008-03-27

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KR1020047000040A Expired - Fee Related KR100817691B1 (ko) 2001-07-05 2002-07-05 연료 전지에 사용하기 위한 이오노머 및 그의 제조 방법

Country Status (10)

Country Link
US (1) US7405015B2 (enExample)
EP (1) EP1402590B1 (enExample)
JP (1) JP4102299B2 (enExample)
KR (1) KR100817691B1 (enExample)
AU (1) AU2002354786B2 (enExample)
BR (1) BR0210803B1 (enExample)
CA (1) CA2451896C (enExample)
DE (1) DE60223539T2 (enExample)
RU (1) RU2004103077A (enExample)
WO (1) WO2003005474A2 (enExample)

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CA2485971A1 (en) 2002-05-13 2004-05-21 Polyfuel, Inc. Ion conductive block copolymers
US7297429B2 (en) * 2002-07-05 2007-11-20 Gore Enterprise Holdings, Inc. Ionomer for use in fuel cells and method of making same
JP2005133092A (ja) * 2003-10-10 2005-05-26 Hitachi Chem Co Ltd 複素環を有する高分子電解質化合物、高分子電解質膜、それを用いた触媒層形成電解質膜及びそれを用いた電気化学素子
JP2006135022A (ja) * 2004-11-04 2006-05-25 Nitto Denko Corp 配線回路基板
KR100614100B1 (ko) * 2005-01-14 2006-08-22 한국과학기술연구원 나피온 이오노머 용액의 완전 건조전 전극상막 방법을이용하는 연료 전지용 막전극접합체의 제조 방법 및 그에의해 제조되는 연료 전지용 막전극접합체
CN101120419B (zh) * 2005-02-15 2011-02-16 东丽株式会社 高分子电解质成型体的制造方法、高分子电解质材料、高分子电解质膜和高分子电解质型燃料电池
US20060199059A1 (en) * 2005-03-01 2006-09-07 Xu Helen X Ion conductive polymer electrolyte and its membrane electrode assembly
EP2355218B1 (en) * 2005-03-04 2012-10-03 Ube Industries, Ltd. Novel polymer electrolyte, polymer electrolyte composition, electrolyte membrane, and production method and use thereof
JP2006338928A (ja) * 2005-05-31 2006-12-14 Hitachi Chem Co Ltd 補強高分子電解質、電極−高分子電解質膜接合体、燃料電池並びにそれらの製造方法
KR100833056B1 (ko) * 2006-03-31 2008-05-27 주식회사 엘지화학 연료전지용 강화-복합 전해질막
KR100897104B1 (ko) 2006-11-02 2009-05-14 현대자동차주식회사 다층구조를 가진 전해질 강화막의 제조 방법
KR100851924B1 (ko) 2007-02-01 2008-08-12 충주대학교 산학협력단 다중 술폰화된 폴리 아릴에테르케톤 공중합체 및 이를포함하는 전해질막
DE102007008268B4 (de) * 2007-02-20 2009-02-19 Staxera Gmbh Prüfstand und Prüfverfahren für einen Brennstoffzellenstapel
US20100159298A1 (en) * 2008-12-22 2010-06-24 3M Innovative Properties Company Fuel cell membrane electrode assembly with multilayer cathode
KR101651093B1 (ko) * 2009-12-11 2016-08-26 건국대학교 글로컬산학협력단 다중황산기를 포함하는 다중페닐 단위체를 지닌 양이온 교환 고분자
US9005841B2 (en) * 2009-12-18 2015-04-14 Lg Chem, Ltd. Polymer electrolyte membrane for fuel cell, membrane electrode assembly and fuel cell including the same
US20110274990A1 (en) * 2010-05-07 2011-11-10 Yang G Xu Methanol and Hydrogen Peroxide Fuel Cell with Hydroxyl Ion Exchange Membrane
JP5725685B2 (ja) * 2011-06-16 2015-05-27 エルジー ケム. エルティーディ. 燃料電池用高分子電解質膜、それを含む膜電極接合体及び燃料電池
US10603639B2 (en) 2016-09-02 2020-03-31 Hossein Beydaghi Nanocomposite blend membrane
EP4466742A1 (en) 2022-01-21 2024-11-27 Basf Se Mixed platinum ruthenium oxide and electrodes for the oxygen evolution reaction

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Also Published As

Publication number Publication date
US20050079399A1 (en) 2005-04-14
WO2003005474A9 (en) 2004-07-01
WO2003005474A2 (en) 2003-01-16
JP4102299B2 (ja) 2008-06-18
DE60223539D1 (de) 2007-12-27
BR0210803A (pt) 2004-06-29
KR20040013094A (ko) 2004-02-11
EP1402590B1 (en) 2007-11-14
WO2003005474A3 (en) 2003-08-28
DE60223539T2 (de) 2008-09-25
CA2451896C (en) 2009-09-08
AU2002354786B2 (en) 2005-08-18
BR0210803B1 (pt) 2011-11-29
US7405015B2 (en) 2008-07-29
JP2004534890A (ja) 2004-11-18
EP1402590A2 (en) 2004-03-31
RU2004103077A (ru) 2005-03-27
CA2451896A1 (en) 2003-01-16

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