JP2004534890A5 - - Google Patents
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- Publication number
- JP2004534890A5 JP2004534890A5 JP2003511332A JP2003511332A JP2004534890A5 JP 2004534890 A5 JP2004534890 A5 JP 2004534890A5 JP 2003511332 A JP2003511332 A JP 2003511332A JP 2003511332 A JP2003511332 A JP 2003511332A JP 2004534890 A5 JP2004534890 A5 JP 2004534890A5
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- ionomer
- fuel cell
- anode
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 claims description 27
- 229920000554 ionomer Polymers 0.000 claims description 24
- 239000005518 polymer electrolyte Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethyl sulfoxide Natural products CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920000295 expanded polytetrafluoroethylene Polymers 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 239000000446 fuel Substances 0.000 claims 31
- 239000000178 monomer Substances 0.000 claims 30
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 27
- 239000000047 product Substances 0.000 claims 12
- 229920000642 polymer Polymers 0.000 claims 10
- 229910052739 hydrogen Inorganic materials 0.000 claims 9
- 239000001257 hydrogen Substances 0.000 claims 9
- 125000003118 aryl group Chemical group 0.000 claims 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 239000002798 polar solvent Substances 0.000 claims 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 5
- 239000002253 acid Substances 0.000 claims 5
- 239000000701 coagulant Substances 0.000 claims 5
- 229910052736 halogen Inorganic materials 0.000 claims 5
- 150000002367 halogens Chemical class 0.000 claims 5
- PLVUIVUKKJTSDM-UHFFFAOYSA-N 1-fluoro-4-(4-fluorophenyl)sulfonylbenzene Chemical compound C1=CC(F)=CC=C1S(=O)(=O)C1=CC=C(F)C=C1 PLVUIVUKKJTSDM-UHFFFAOYSA-N 0.000 claims 4
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical group CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 claims 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims 4
- 239000012024 dehydrating agents Substances 0.000 claims 4
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- -1 poly (phthalazinone ether ketone Chemical class 0.000 claims 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 4
- LYLHOKOTRWUGIF-UHFFFAOYSA-N 4-(4-hydroxyphenyl)-2H-phthalazin-1-one Chemical compound C1=CC(O)=CC=C1C1=NNC(=O)C2=CC=CC=C12 LYLHOKOTRWUGIF-UHFFFAOYSA-N 0.000 claims 3
- 229910052783 alkali metal Inorganic materials 0.000 claims 3
- 150000001340 alkali metals Chemical class 0.000 claims 3
- 239000002585 base Substances 0.000 claims 3
- 150000002431 hydrogen Chemical class 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 3
- IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 claims 3
- LSQARZALBDFYQZ-UHFFFAOYSA-N 4,4'-difluorobenzophenone Chemical compound C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 LSQARZALBDFYQZ-UHFFFAOYSA-N 0.000 claims 2
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical group [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 claims 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims 2
- 239000012965 benzophenone Substances 0.000 claims 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 230000001112 coagulating effect Effects 0.000 claims 2
- 238000009792 diffusion process Methods 0.000 claims 2
- 238000007865 diluting Methods 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 150000002576 ketones Chemical class 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 239000012429 reaction media Substances 0.000 claims 2
- 230000035484 reaction time Effects 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims 2
- 150000003457 sulfones Chemical group 0.000 claims 2
- 239000008096 xylene Substances 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910021645 metal ion Inorganic materials 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 229910001414 potassium ion Inorganic materials 0.000 claims 1
- 238000010248 power generation Methods 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910001415 sodium ion Inorganic materials 0.000 claims 1
- 125000003944 tolyl group Chemical group 0.000 claims 1
- 239000007787 solid Substances 0.000 description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 description 5
- 239000002131 composite material Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011132574A CN1161397C (zh) | 2001-07-05 | 2001-07-05 | 带磺酸盐侧基的聚二氮杂萘酮醚酮及制备方法 |
| CN 02111491 CN1200029C (zh) | 2002-04-25 | 2002-04-25 | 带磺酸盐侧基的聚二氮杂萘酮醚砜及制备方法 |
| PCT/US2002/021346 WO2003005474A2 (en) | 2001-07-05 | 2002-07-05 | Ionomer for use in fuel cells and method of making same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004534890A JP2004534890A (ja) | 2004-11-18 |
| JP2004534890A5 true JP2004534890A5 (enExample) | 2006-01-05 |
| JP4102299B2 JP4102299B2 (ja) | 2008-06-18 |
Family
ID=25740356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003511332A Expired - Fee Related JP4102299B2 (ja) | 2001-07-05 | 2002-07-05 | 燃料電池に用いるイオノマー及びその製造方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7405015B2 (enExample) |
| EP (1) | EP1402590B1 (enExample) |
| JP (1) | JP4102299B2 (enExample) |
| KR (1) | KR100817691B1 (enExample) |
| AU (1) | AU2002354786B2 (enExample) |
| BR (1) | BR0210803B1 (enExample) |
| CA (1) | CA2451896C (enExample) |
| DE (1) | DE60223539T2 (enExample) |
| RU (1) | RU2004103077A (enExample) |
| WO (1) | WO2003005474A2 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2485971A1 (en) | 2002-05-13 | 2004-05-21 | Polyfuel, Inc. | Ion conductive block copolymers |
| US7297429B2 (en) * | 2002-07-05 | 2007-11-20 | Gore Enterprise Holdings, Inc. | Ionomer for use in fuel cells and method of making same |
| JP2005133092A (ja) * | 2003-10-10 | 2005-05-26 | Hitachi Chem Co Ltd | 複素環を有する高分子電解質化合物、高分子電解質膜、それを用いた触媒層形成電解質膜及びそれを用いた電気化学素子 |
| JP2006135022A (ja) * | 2004-11-04 | 2006-05-25 | Nitto Denko Corp | 配線回路基板 |
| KR100614100B1 (ko) * | 2005-01-14 | 2006-08-22 | 한국과학기술연구원 | 나피온 이오노머 용액의 완전 건조전 전극상막 방법을이용하는 연료 전지용 막전극접합체의 제조 방법 및 그에의해 제조되는 연료 전지용 막전극접합체 |
| CN101120419B (zh) * | 2005-02-15 | 2011-02-16 | 东丽株式会社 | 高分子电解质成型体的制造方法、高分子电解质材料、高分子电解质膜和高分子电解质型燃料电池 |
| US20060199059A1 (en) * | 2005-03-01 | 2006-09-07 | Xu Helen X | Ion conductive polymer electrolyte and its membrane electrode assembly |
| EP2355218B1 (en) * | 2005-03-04 | 2012-10-03 | Ube Industries, Ltd. | Novel polymer electrolyte, polymer electrolyte composition, electrolyte membrane, and production method and use thereof |
| JP2006338928A (ja) * | 2005-05-31 | 2006-12-14 | Hitachi Chem Co Ltd | 補強高分子電解質、電極−高分子電解質膜接合体、燃料電池並びにそれらの製造方法 |
| KR100833056B1 (ko) * | 2006-03-31 | 2008-05-27 | 주식회사 엘지화학 | 연료전지용 강화-복합 전해질막 |
| KR100897104B1 (ko) | 2006-11-02 | 2009-05-14 | 현대자동차주식회사 | 다층구조를 가진 전해질 강화막의 제조 방법 |
| KR100851924B1 (ko) | 2007-02-01 | 2008-08-12 | 충주대학교 산학협력단 | 다중 술폰화된 폴리 아릴에테르케톤 공중합체 및 이를포함하는 전해질막 |
| DE102007008268B4 (de) * | 2007-02-20 | 2009-02-19 | Staxera Gmbh | Prüfstand und Prüfverfahren für einen Brennstoffzellenstapel |
| US20100159298A1 (en) * | 2008-12-22 | 2010-06-24 | 3M Innovative Properties Company | Fuel cell membrane electrode assembly with multilayer cathode |
| KR101651093B1 (ko) * | 2009-12-11 | 2016-08-26 | 건국대학교 글로컬산학협력단 | 다중황산기를 포함하는 다중페닐 단위체를 지닌 양이온 교환 고분자 |
| US9005841B2 (en) * | 2009-12-18 | 2015-04-14 | Lg Chem, Ltd. | Polymer electrolyte membrane for fuel cell, membrane electrode assembly and fuel cell including the same |
| US20110274990A1 (en) * | 2010-05-07 | 2011-11-10 | Yang G Xu | Methanol and Hydrogen Peroxide Fuel Cell with Hydroxyl Ion Exchange Membrane |
| JP5725685B2 (ja) * | 2011-06-16 | 2015-05-27 | エルジー ケム． エルティーディ． | 燃料電池用高分子電解質膜、それを含む膜電極接合体及び燃料電池 |
| US10603639B2 (en) | 2016-09-02 | 2020-03-31 | Hossein Beydaghi | Nanocomposite blend membrane |
| EP4466742A1 (en) | 2022-01-21 | 2024-11-27 | Basf Se | Mixed platinum ruthenium oxide and electrodes for the oxygen evolution reaction |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3282875A (en) * | 1964-07-22 | 1966-11-01 | Du Pont | Fluorocarbon vinyl ether polymers |
| CA962021A (en) * | 1970-05-21 | 1975-02-04 | Robert W. Gore | Porous products and process therefor |
| US4083768A (en) * | 1976-05-24 | 1978-04-11 | Allied Chemical Corporation | Preparation of high performance polyelectrolyte membrane |
| DE2861696D1 (en) * | 1977-09-07 | 1982-04-29 | Ici Plc | Thermoplastic aromatic polyetherketones, a method for their preparation and their application as electrical insulants |
| US4358545A (en) * | 1980-06-11 | 1982-11-09 | The Dow Chemical Company | Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000 |
| US4940525A (en) * | 1987-05-08 | 1990-07-10 | The Dow Chemical Company | Low equivalent weight sulfonic fluoropolymers |
| USRE37707E1 (en) * | 1990-02-22 | 2002-05-21 | Stmicroelectronics S.R.L. | Leadframe with heat dissipator connected to S-shaped fingers |
| US5306789A (en) * | 1990-10-31 | 1994-04-26 | Hay Allan S | Amorphous, soluble, aromatic polymers with high glass transition temperatures |
| US5254663A (en) * | 1992-04-28 | 1993-10-19 | Hay Allan S | Polymers derived from phenolphthaleins |
| US5237062A (en) * | 1992-04-28 | 1993-08-17 | Hay Allan S | Polymers derived from phenolphthaleins |
| US5834523A (en) * | 1993-09-21 | 1998-11-10 | Ballard Power Systems, Inc. | Substituted α,β,β-trifluorostyrene-based composite membranes |
| USRE37756E1 (en) * | 1994-06-29 | 2002-06-18 | Jiann H. Chen | Fuser members overcoated with fluorocarbon elastomer containing aluminum oxide |
| US5525436A (en) * | 1994-11-01 | 1996-06-11 | Case Western Reserve University | Proton conducting polymers used as membranes |
| US5547551A (en) * | 1995-03-15 | 1996-08-20 | W. L. Gore & Associates, Inc. | Ultra-thin integral composite membrane |
| USRE37701E1 (en) * | 1994-11-14 | 2002-05-14 | W. L. Gore & Associates, Inc. | Integral composite membrane |
| US5882810A (en) * | 1996-03-08 | 1999-03-16 | The Dow Chemicalcompany | Active layer for membrane electrode assembly |
| US5716727A (en) * | 1996-04-01 | 1998-02-10 | Case Western Reserve University | Proton conducting polymers prepared by direct acid casting |
| JP3861367B2 (ja) * | 1996-04-18 | 2006-12-20 | 住友化学株式会社 | 高分子電解質、その製造方法およびそれを使用してなる燃料電池 |
| US6444343B1 (en) | 1996-11-18 | 2002-09-03 | University Of Southern California | Polymer electrolyte membranes for use in fuel cells |
| US6399254B1 (en) * | 1997-05-23 | 2002-06-04 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Solid electrolyte |
| US6365294B1 (en) * | 1999-04-30 | 2002-04-02 | The Administrators Of The Tulane Educational Fund | Sulfonated polyphosphazenes for proton-exchange membrane fuel cells |
| WO2000077874A1 (en) | 1999-06-11 | 2000-12-21 | The Penn State Research Foundation | Proton conducting polymer membranes |
| JP4234422B2 (ja) | 2000-09-20 | 2009-03-04 | バージニア テック インテレクチュアル プロパティーズ インコーポレーテッド | イオン導電性スルホン化重合体材料 |
| US7297429B2 (en) * | 2002-07-05 | 2007-11-20 | Gore Enterprise Holdings, Inc. | Ionomer for use in fuel cells and method of making same |
-
2002
- 2002-07-05 US US10/481,226 patent/US7405015B2/en not_active Expired - Fee Related
- 2002-07-05 DE DE60223539T patent/DE60223539T2/de not_active Expired - Lifetime
- 2002-07-05 AU AU2002354786A patent/AU2002354786B2/en not_active Ceased
- 2002-07-05 KR KR1020047000040A patent/KR100817691B1/ko not_active Expired - Fee Related
- 2002-07-05 EP EP02752181A patent/EP1402590B1/en not_active Expired - Lifetime
- 2002-07-05 BR BRPI0210803-8A patent/BR0210803B1/pt not_active IP Right Cessation
- 2002-07-05 JP JP2003511332A patent/JP4102299B2/ja not_active Expired - Fee Related
- 2002-07-05 CA CA002451896A patent/CA2451896C/en not_active Expired - Fee Related
- 2002-07-05 WO PCT/US2002/021346 patent/WO2003005474A2/en not_active Ceased
- 2002-07-05 RU RU2004103077/04A patent/RU2004103077A/ru not_active Application Discontinuation
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