PT93967B - Processo para a preparacao de novos 1-aril-imidazois e de composicoes pesticidas e farmaceuticas que os contem e metodo para a sua utilizacao para controlar artropodes, nematoides, helmintas ou protozoarios - Google Patents

Info

Publication number

PT93967B

PT93967B PT93967A PT9396790A PT93967B PT 93967 B PT93967 B PT 93967B PT 93967 A PT93967 A PT 93967A PT 9396790 A PT9396790 A PT 9396790A PT 93967 B PT93967 B PT 93967B

Authority

PT

Portugal

Prior art keywords

methyl

group

general formula

alkyl

compound

Prior art date

1989-05-05

Links

• Espacenet
• Global Dossier
• Discuss

• 238000000034 method Methods 0.000 title claims abstract description 446
• 230000008569 process Effects 0.000 title claims abstract description 131
• 241000238421 Arthropoda Species 0.000 title claims abstract description 46
• 244000000013 helminth Species 0.000 title claims abstract description 22
• 238000002360 preparation method Methods 0.000 title claims description 93
• 239000008194 pharmaceutical composition Substances 0.000 title claims description 3
• 239000000575 pesticide Substances 0.000 title description 6
• 150000001875 compounds Chemical class 0.000 claims abstract description 737
• -1 methylsulfenyl Chemical group 0.000 claims abstract description 215
• 239000000203 mixture Substances 0.000 claims abstract description 161
• 239000000543 intermediate Substances 0.000 claims abstract description 139
• 125000005843 halogen group Chemical group 0.000 claims abstract description 116
• 125000000217 alkyl group Chemical group 0.000 claims abstract description 94
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 93
• 125000001188 haloalkyl group Chemical group 0.000 claims abstract description 75
• 125000003545 alkoxy group Chemical group 0.000 claims abstract description 56
• 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 44
• 239000001257 hydrogen Substances 0.000 claims abstract description 44
• 125000004647 alkyl sulfenyl group Chemical group 0.000 claims abstract description 39
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 37
• 125000004644 alkyl sulfinyl group Chemical group 0.000 claims abstract description 35
• 125000004390 alkyl sulfonyl group Chemical group 0.000 claims abstract description 33
• 241000244206 Nematoda Species 0.000 claims abstract description 32
• 241000238876 Acari Species 0.000 claims abstract description 31
• 125000001424 substituent group Chemical group 0.000 claims abstract description 27
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 20
• 241001124076 Aphididae Species 0.000 claims abstract description 11
• 125000006216 methylsulfinyl group Chemical group [H]C([H])([H])S(*)=O 0.000 claims abstract description 7
• 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 claims abstract description 5
• 238000006243 chemical reaction Methods 0.000 claims description 127
• 125000003277 amino group Chemical group 0.000 claims description 108
• RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Substances C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 100
• 239000000460 chlorine Substances 0.000 claims description 87
• 150000003839 salts Chemical class 0.000 claims description 55
• 241000607479 Yersinia pestis Species 0.000 claims description 51
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 50
• 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 42
• 125000004438 haloalkoxy group Chemical group 0.000 claims description 42
• 229910052801 chlorine Inorganic materials 0.000 claims description 37
• 239000004480 active ingredient Substances 0.000 claims description 36
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 34
• 239000002253 acid Substances 0.000 claims description 33
• 241001465754 Metazoa Species 0.000 claims description 31
• JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 30
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 29
• 239000003795 chemical substances by application Substances 0.000 claims description 27
• 125000004432 carbon atom Chemical group C* 0.000 claims description 25
• 125000000304 alkynyl group Chemical group 0.000 claims description 24
• 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 24
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 23
• 239000003153 chemical reaction reagent Substances 0.000 claims description 23
• 125000004093 cyano group Chemical group *C#N 0.000 claims description 22
• 125000003282 alkyl amino group Chemical group 0.000 claims description 21
• 239000007788 liquid Substances 0.000 claims description 21
• 229910052736 halogen Inorganic materials 0.000 claims description 20
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 20
• 239000007787 solid Substances 0.000 claims description 20
• 125000003342 alkenyl group Chemical group 0.000 claims description 18
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 18
• 229910052794 bromium Inorganic materials 0.000 claims description 18
• 229910052751 metal Inorganic materials 0.000 claims description 18
• 239000002184 metal Substances 0.000 claims description 18
• 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 17
• 238000005658 halogenation reaction Methods 0.000 claims description 17
• 125000004663 dialkyl amino group Chemical group 0.000 claims description 16
• 125000004440 haloalkylsulfinyl group Chemical group 0.000 claims description 16
• 125000004441 haloalkylsulfonyl group Chemical group 0.000 claims description 16
• KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 15
• 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 15
• 238000005804 alkylation reaction Methods 0.000 claims description 15
• 125000000468 ketone group Chemical group 0.000 claims description 15
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 15
• 238000006467 substitution reaction Methods 0.000 claims description 15
• 125000003396 thiol group Chemical group [H]S* 0.000 claims description 15
• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
• 239000003638 chemical reducing agent Substances 0.000 claims description 14
• 125000005265 dialkylamine group Chemical group 0.000 claims description 14
• 150000002367 halogens Chemical class 0.000 claims description 14
• 150000003973 alkyl amines Chemical class 0.000 claims description 13
• 125000003806 alkyl carbonyl amino group Chemical group 0.000 claims description 13
• 125000004414 alkyl thio group Chemical group 0.000 claims description 13
• 230000029936 alkylation Effects 0.000 claims description 13
• 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 13
• 230000026030 halogenation Effects 0.000 claims description 13
• 239000012948 isocyanate Substances 0.000 claims description 13
• 230000009467 reduction Effects 0.000 claims description 13
• 239000002168 alkylating agent Substances 0.000 claims description 12
• 229940100198 alkylating agent Drugs 0.000 claims description 12
• 125000004658 aryl carbonyl amino group Chemical group 0.000 claims description 12
• 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 12
• 125000001309 chloro group Chemical group Cl* 0.000 claims description 12
• 125000004472 dialkylaminosulfonyl group Chemical group 0.000 claims description 12
• 125000004692 haloalkylcarbonyl group Chemical group 0.000 claims description 12
• 230000000361 pesticidal effect Effects 0.000 claims description 12
• 125000005208 trialkylammonium group Chemical group 0.000 claims description 12
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 11
• 125000004949 alkyl amino carbonyl amino group Chemical group 0.000 claims description 11
• 229910021529 ammonia Inorganic materials 0.000 claims description 11
• 125000004966 cyanoalkyl group Chemical group 0.000 claims description 11
• 125000004473 dialkylaminocarbonyl group Chemical group 0.000 claims description 11
• 150000004820 halides Chemical class 0.000 claims description 11
• 239000007800 oxidant agent Substances 0.000 claims description 11
• 239000007858 starting material Substances 0.000 claims description 11
• BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 10
• 125000004471 alkyl aminosulfonyl group Chemical group 0.000 claims description 10
• 125000005110 aryl thio group Chemical group 0.000 claims description 10
• 150000002513 isocyanates Chemical class 0.000 claims description 10
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
• 108010034145 Helminth Proteins Proteins 0.000 claims description 9
• 125000004466 alkoxycarbonylamino group Chemical group 0.000 claims description 9
• 125000005233 alkylalcohol group Chemical group 0.000 claims description 9
• 238000006396 nitration reaction Methods 0.000 claims description 9
• 150000003254 radicals Chemical class 0.000 claims description 9
• 150000003457 sulfones Chemical class 0.000 claims description 9
• 150000003462 sulfoxides Chemical class 0.000 claims description 9
• YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims description 8
• 239000007983 Tris buffer Substances 0.000 claims description 8
• 125000004457 alkyl amino carbonyl group Chemical group 0.000 claims description 8
• 229910052799 carbon Inorganic materials 0.000 claims description 8
• CSJLBAMHHLJAAS-UHFFFAOYSA-N diethylaminosulfur trifluoride Chemical compound CCN(CC)S(F)(F)F CSJLBAMHHLJAAS-UHFFFAOYSA-N 0.000 claims description 8
• 239000012279 sodium borohydride Substances 0.000 claims description 8
• 229910000033 sodium borohydride Inorganic materials 0.000 claims description 8
• 239000004094 surface-active agent Substances 0.000 claims description 8
• RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 claims description 8
• 241000251539 Vertebrata <Metazoa> Species 0.000 claims description 7
• 238000005874 Vilsmeier-Haack formylation reaction Methods 0.000 claims description 7
• 238000006481 deamination reaction Methods 0.000 claims description 7
• 229910052731 fluorine Chemical group 0.000 claims description 7
• 230000002140 halogenating effect Effects 0.000 claims description 7
• 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 claims description 7
• 229910052744 lithium Inorganic materials 0.000 claims description 7
• 238000007069 methylation reaction Methods 0.000 claims description 7
• 239000007818 Grignard reagent Substances 0.000 claims description 6
• 239000002841 Lewis acid Substances 0.000 claims description 6
• 125000004429 atom Chemical group 0.000 claims description 6
• 150000001540 azides Chemical class 0.000 claims description 6
• 150000001989 diazonium salts Chemical class 0.000 claims description 6
• 238000006170 formylation reaction Methods 0.000 claims description 6
• 150000004795 grignard reagents Chemical class 0.000 claims description 6
• ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 6
• 230000007062 hydrolysis Effects 0.000 claims description 6
• 238000006460 hydrolysis reaction Methods 0.000 claims description 6
• BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
• 239000012430 organic reaction media Substances 0.000 claims description 6
• 230000001590 oxidative effect Effects 0.000 claims description 6
• YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 claims description 6
• 238000006969 Curtius rearrangement reaction Methods 0.000 claims description 5
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
• 230000037396 body weight Effects 0.000 claims description 5
• 230000009615 deamination Effects 0.000 claims description 5
• 150000008050 dialkyl sulfates Chemical class 0.000 claims description 5
• 239000012954 diazonium Substances 0.000 claims description 5
• 125000005221 halo alkyl carbonyl amino group Chemical group 0.000 claims description 5
• 125000004970 halomethyl group Chemical group 0.000 claims description 5
• 229910052740 iodine Inorganic materials 0.000 claims description 5
• 150000007517 lewis acids Chemical class 0.000 claims description 5
• 125000001979 organolithium group Chemical group 0.000 claims description 5
• 125000002524 organometallic group Chemical group 0.000 claims description 5
• 229910052717 sulfur Inorganic materials 0.000 claims description 5
• 239000011593 sulfur Substances 0.000 claims description 5
• 229910052727 yttrium Inorganic materials 0.000 claims description 5
• NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 claims description 4
• XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 4
• ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 4
• URCLXLVQHAJFSJ-UHFFFAOYSA-N chlorosulfonyl hypochlorite Chemical compound ClOS(Cl)(=O)=O URCLXLVQHAJFSJ-UHFFFAOYSA-N 0.000 claims description 4
• GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims description 4
• 238000010791 quenching Methods 0.000 claims description 4
• 230000000171 quenching effect Effects 0.000 claims description 4
• 238000010561 standard procedure Methods 0.000 claims description 4
• 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 claims description 4
• NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims description 3
• SDDIHPXDXRINNN-UHFFFAOYSA-N 2-bromo-4-chloro-1-[2-chloro-6-methylsulfanyl-4-(trifluoromethyl)phenyl]-5-(difluoromethylsulfonyl)imidazole Chemical compound CSC1=CC(C(F)(F)F)=CC(Cl)=C1N1C(S(=O)(=O)C(F)F)=C(Cl)N=C1Br SDDIHPXDXRINNN-UHFFFAOYSA-N 0.000 claims description 3
• QJNPMBJPNNMBAT-UHFFFAOYSA-N 2-chloro-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-(trifluoromethylsulfanyl)imidazole Chemical compound ClC1=NC(SC(F)(F)F)=CN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl QJNPMBJPNNMBAT-UHFFFAOYSA-N 0.000 claims description 3
• LRBYJYUIZZFMGK-UHFFFAOYSA-N 2-chloro-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-methylsulfanyl-4-(trifluoromethylsulfanyl)imidazole Chemical compound CSC1=C(SC(F)(F)F)N=C(Cl)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl LRBYJYUIZZFMGK-UHFFFAOYSA-N 0.000 claims description 3
• OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
• QLYFQPVGLWPCLP-UHFFFAOYSA-N 5-bromo-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-(trifluoromethylsulfanyl)imidazole Chemical compound BrC1=C(SC(F)(F)F)N=CN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl QLYFQPVGLWPCLP-UHFFFAOYSA-N 0.000 claims description 3
• BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
• AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 3
• 229930194542 Keto Natural products 0.000 claims description 3
• NPKGQBIUYHHPOT-UHFFFAOYSA-N [Cu+2].[C-]#[C-] Chemical compound [Cu+2].[C-]#[C-] NPKGQBIUYHHPOT-UHFFFAOYSA-N 0.000 claims description 3
• 150000001351 alkyl iodides Chemical class 0.000 claims description 3
• 230000008033 biological extinction Effects 0.000 claims description 3
• 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 claims description 3
• 239000012039 electrophile Substances 0.000 claims description 3
• 235000019253 formic acid Nutrition 0.000 claims description 3
• 230000022244 formylation Effects 0.000 claims description 3
• 125000001841 imino group Chemical group [H]N=* 0.000 claims description 3
• LAQPNDIUHRHNCV-UHFFFAOYSA-N isophthalonitrile Chemical compound N#CC1=CC=CC(C#N)=C1 LAQPNDIUHRHNCV-UHFFFAOYSA-N 0.000 claims description 3
• 229910052750 molybdenum Inorganic materials 0.000 claims description 3
• 239000011733 molybdenum Substances 0.000 claims description 3
• 150000002978 peroxides Chemical class 0.000 claims description 3
• BEOOHQFXGBMRKU-UHFFFAOYSA-N sodium cyanoborohydride Chemical compound [Na+].[B-]C#N BEOOHQFXGBMRKU-UHFFFAOYSA-N 0.000 claims description 3
• 150000003512 tertiary amines Chemical class 0.000 claims description 3
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
• 125000004775 chlorodifluoromethyl group Chemical group FC(F)(Cl)* 0.000 claims description 2
• 125000004774 dichlorofluoromethyl group Chemical group FC(Cl)(Cl)* 0.000 claims description 2
• OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 2
• ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical group O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 claims description 2
• IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 2
• 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
• 125000002734 organomagnesium group Chemical group 0.000 claims description 2
• 239000012429 reaction media Substances 0.000 claims description 2
• QHMQWEPBXSHHLH-UHFFFAOYSA-N sulfur tetrafluoride Chemical compound FS(F)(F)F QHMQWEPBXSHHLH-UHFFFAOYSA-N 0.000 claims description 2
• 125000005031 thiocyano group Chemical group S(C#N)* 0.000 claims 6
• XSESJGXGZNHROO-UHFFFAOYSA-N 4-chloro-2-(difluoromethylsulfanyl)-1-(2,4,6-trichlorophenyl)imidazole Chemical compound FC(F)SC1=NC(Cl)=CN1C1=C(Cl)C=C(Cl)C=C1Cl XSESJGXGZNHROO-UHFFFAOYSA-N 0.000 claims 2
• ZGLZGTWAXJVSNT-UHFFFAOYSA-N 4-chloro-2-(difluoromethylsulfinyl)-1-(2,4,6-trichlorophenyl)imidazole Chemical compound FC(F)S(=O)C1=NC(Cl)=CN1C1=C(Cl)C=C(Cl)C=C1Cl ZGLZGTWAXJVSNT-UHFFFAOYSA-N 0.000 claims 2
• 125000001153 fluoro group Chemical group F* 0.000 claims 2
• SGRLMRVRKCKTKK-UHFFFAOYSA-N 1-(4-bromo-2,6-dichlorophenyl)-4-chloro-2-(difluoromethylsulfanyl)imidazole Chemical compound FC(F)SC1=NC(Cl)=CN1C1=C(Cl)C=C(Br)C=C1Cl SGRLMRVRKCKTKK-UHFFFAOYSA-N 0.000 claims 1
• XXPDTVUEVHTVPW-UHFFFAOYSA-N 2-bromo-4-chloro-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-(difluoromethylsulfonyl)imidazole Chemical compound FC(F)S(=O)(=O)C1=C(Cl)N=C(Br)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl XXPDTVUEVHTVPW-UHFFFAOYSA-N 0.000 claims 1
• OLDLYTNPLJQYCZ-UHFFFAOYSA-N 5-chloro-2-(difluoromethylsulfanyl)-1H-imidazole Chemical compound ClC=1N=C(NC=1)SC(F)F OLDLYTNPLJQYCZ-UHFFFAOYSA-N 0.000 claims 1
• 230000002152 alkylating effect Effects 0.000 claims 1
• 125000001246 bromo group Chemical group Br* 0.000 claims 1
• 125000004984 dialkylaminoalkoxy group Chemical group 0.000 claims 1
• 125000004356 hydroxy functional group Chemical group O* 0.000 claims 1
• 239000000276 potassium ferrocyanide Substances 0.000 claims 1
• 230000008707 rearrangement Effects 0.000 claims 1
• XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 claims 1
• 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 claims 1
• 241000238631 Hexapoda Species 0.000 abstract description 16
• 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 abstract 1
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 126
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 78
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 70
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 61
• 239000002904 solvent Substances 0.000 description 60
• 241000196324 Embryophyta Species 0.000 description 55
• WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 54
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 51
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 43
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 42
• 239000000243 solution Substances 0.000 description 41
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 39
• YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 36
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 35
• 235000013339 cereals Nutrition 0.000 description 30
• 239000003921 oil Substances 0.000 description 30
• 235000019198 oils Nutrition 0.000 description 29
• 239000000843 powder Substances 0.000 description 29
• 238000009472 formulation Methods 0.000 description 27
• HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 26
• 239000002689 soil Substances 0.000 description 26
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 25
• 239000000047 product Substances 0.000 description 25
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 24
• ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 24
• 239000012442 inert solvent Substances 0.000 description 21
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
• 239000002585 base Substances 0.000 description 19
• 230000015572 biosynthetic process Effects 0.000 description 19
• 239000008187 granular material Substances 0.000 description 17
• 239000003981 vehicle Substances 0.000 description 16
• 241000255925 Diptera Species 0.000 description 15
• 238000003786 synthesis reaction Methods 0.000 description 15
• 238000012360 testing method Methods 0.000 description 15
• 239000007921 spray Substances 0.000 description 14
• 239000000725 suspension Substances 0.000 description 14
• FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 14
• WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic acid anhydride Natural products CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 13
• 150000001412 amines Chemical class 0.000 description 13
• 239000003960 organic solvent Substances 0.000 description 13
• UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 13
• 230000009466 transformation Effects 0.000 description 13
• 241000254173 Coleoptera Species 0.000 description 12
• 235000019439 ethyl acetate Nutrition 0.000 description 12
• 239000000126 substance Substances 0.000 description 12
• 239000003054 catalyst Substances 0.000 description 11
• 230000000694 effects Effects 0.000 description 11
• 239000004615 ingredient Substances 0.000 description 11
• 239000012044 organic layer Substances 0.000 description 11
• 238000006722 reduction reaction Methods 0.000 description 11
• 241000894007 species Species 0.000 description 11
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
• 235000013601 eggs Nutrition 0.000 description 10
• 239000003995 emulsifying agent Substances 0.000 description 10
• 238000007254 oxidation reaction Methods 0.000 description 10
• 238000005507 spraying Methods 0.000 description 10
• 230000009885 systemic effect Effects 0.000 description 10
• VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 10
• 150000001335 aliphatic alkanes Chemical class 0.000 description 9
• 239000000975 dye Substances 0.000 description 9
• 239000000839 emulsion Substances 0.000 description 9
• 230000004048 modification Effects 0.000 description 9
• 238000012986 modification Methods 0.000 description 9
• 239000012299 nitrogen atmosphere Substances 0.000 description 9
• 230000003647 oxidation Effects 0.000 description 9
• PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 8
• IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 8
• 235000007688 Lycopersicon esculentum Nutrition 0.000 description 8
• PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 8
• 238000005481 NMR spectroscopy Methods 0.000 description 8
• PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
• 240000003768 Solanum lycopersicum Species 0.000 description 8
• 229910052782 aluminium Inorganic materials 0.000 description 8
• 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 8
• 239000003814 drug Substances 0.000 description 8
• 235000013305 food Nutrition 0.000 description 8
• 239000002917 insecticide Substances 0.000 description 8
• CTSLXHKWHWQRSH-UHFFFAOYSA-N oxalyl chloride Chemical compound ClC(=O)C(Cl)=O CTSLXHKWHWQRSH-UHFFFAOYSA-N 0.000 description 8
• 238000010992 reflux Methods 0.000 description 8
• QFMDFTQOJHFVNR-UHFFFAOYSA-N 1-[2,2-dichloro-1-(4-ethylphenyl)ethyl]-4-ethylbenzene Chemical compound C1=CC(CC)=CC=C1C(C(Cl)Cl)C1=CC=C(CC)C=C1 QFMDFTQOJHFVNR-UHFFFAOYSA-N 0.000 description 7
• XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 7
• WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 7
• 239000007864 aqueous solution Substances 0.000 description 7
• 201000010099 disease Diseases 0.000 description 7
• 150000002460 imidazoles Chemical class 0.000 description 7
• 230000001069 nematicidal effect Effects 0.000 description 7
• UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 7
• 238000005991 sulfenylation reaction Methods 0.000 description 7
• QRZMXADUXZADTF-UHFFFAOYSA-N 4-aminoimidazole Chemical compound NC1=CNC=N1 QRZMXADUXZADTF-UHFFFAOYSA-N 0.000 description 6
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
• 241000462639 Epilachna varivestis Species 0.000 description 6
• PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 6
• WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
• SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 6
• UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
• DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 6
• 238000005299 abrasion Methods 0.000 description 6
• 125000003118 aryl group Chemical group 0.000 description 6
• UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 6
• 238000005893 bromination reaction Methods 0.000 description 6
• 238000003682 fluorination reaction Methods 0.000 description 6
• 239000011737 fluorine Substances 0.000 description 6
• 150000004678 hydrides Chemical class 0.000 description 6
• 229910052757 nitrogen Inorganic materials 0.000 description 6
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
• 125000006239 protecting group Chemical group 0.000 description 6
• 239000003381 stabilizer Substances 0.000 description 6
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
• 241000257303 Hymenoptera Species 0.000 description 5
• 241000256602 Isoptera Species 0.000 description 5
• 241000257226 Muscidae Species 0.000 description 5
• MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 5
• 235000010627 Phaseolus vulgaris Nutrition 0.000 description 5
• 244000046052 Phaseolus vulgaris Species 0.000 description 5
• 239000000654 additive Substances 0.000 description 5
• 239000000853 adhesive Substances 0.000 description 5
• 230000001070 adhesive effect Effects 0.000 description 5
• 150000001298 alcohols Chemical class 0.000 description 5
• 229910052783 alkali metal Inorganic materials 0.000 description 5
• 150000001350 alkyl halides Chemical class 0.000 description 5
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
• DFNYGALUNNFWKJ-UHFFFAOYSA-N aminoacetonitrile Chemical compound NCC#N DFNYGALUNNFWKJ-UHFFFAOYSA-N 0.000 description 5
• 230000031709 bromination Effects 0.000 description 5
• 238000005660 chlorination reaction Methods 0.000 description 5
• 239000002361 compost Substances 0.000 description 5
• 239000012141 concentrate Substances 0.000 description 5
• 238000011161 development Methods 0.000 description 5
• 239000006185 dispersion Substances 0.000 description 5
• GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 5
• 239000004495 emulsifiable concentrate Substances 0.000 description 5
• 235000013312 flour Nutrition 0.000 description 5
• 125000002883 imidazolyl group Chemical group 0.000 description 5
• 208000015181 infectious disease Diseases 0.000 description 5
• 230000000749 insecticidal effect Effects 0.000 description 5
• 244000144972 livestock Species 0.000 description 5
• 239000005645 nematicide Substances 0.000 description 5
• XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 5
• IOGXOCVLYRDXLW-UHFFFAOYSA-N tert-butyl nitrite Chemical compound CC(C)(C)ON=O IOGXOCVLYRDXLW-UHFFFAOYSA-N 0.000 description 5
• BHJCNPNAKGLORZ-UHFFFAOYSA-N 3-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-(trifluoromethylsulfanyl)imidazol-4-amine Chemical compound NC1=C(SC(F)(F)F)N=CN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl BHJCNPNAKGLORZ-UHFFFAOYSA-N 0.000 description 4
• NGNNFDYHJKDHJN-UHFFFAOYSA-N 5-aminoimidazole-2,4-dione Chemical compound N=C1NC(=O)NC1=O NGNNFDYHJKDHJN-UHFFFAOYSA-N 0.000 description 4
• 241000254032 Acrididae Species 0.000 description 4
• 241000271566 Aves Species 0.000 description 4
• 241000254171 Curculionidae Species 0.000 description 4
• PSCXEUSWZWRCMQ-UHFFFAOYSA-N F[S](F)F Chemical compound F[S](F)F PSCXEUSWZWRCMQ-UHFFFAOYSA-N 0.000 description 4
• 206010061217 Infestation Diseases 0.000 description 4
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
• JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 4
• 235000002637 Nicotiana tabacum Nutrition 0.000 description 4
• 244000061176 Nicotiana tabacum Species 0.000 description 4
• 241000238887 Ornithodoros Species 0.000 description 4
• KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 4
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
• HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 4
• 238000007239 Wittig reaction Methods 0.000 description 4
• 240000008042 Zea mays Species 0.000 description 4
• 235000002017 Zea mays subsp mays Nutrition 0.000 description 4
• HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
• 239000000642 acaricide Substances 0.000 description 4
• 150000001266 acyl halides Chemical class 0.000 description 4
• 150000008044 alkali metal hydroxides Chemical class 0.000 description 4
• 150000004703 alkoxides Chemical class 0.000 description 4
• 150000001408 amides Chemical class 0.000 description 4
• 150000001409 amidines Chemical class 0.000 description 4
• 150000008064 anhydrides Chemical class 0.000 description 4
• 239000000010 aprotic solvent Substances 0.000 description 4
• 239000008280 blood Substances 0.000 description 4
• 210000004369 blood Anatomy 0.000 description 4
• 229910000085 borane Inorganic materials 0.000 description 4
• DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 4
• 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 4
• 238000004440 column chromatography Methods 0.000 description 4
• 230000001276 controlling effect Effects 0.000 description 4
• WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 4
• 239000002270 dispersing agent Substances 0.000 description 4
• 238000001035 drying Methods 0.000 description 4
• 150000002148 esters Chemical class 0.000 description 4
• 238000011156 evaluation Methods 0.000 description 4
• 238000003818 flash chromatography Methods 0.000 description 4
• 230000006870 function Effects 0.000 description 4
• ZCSHNCUQKCANBX-UHFFFAOYSA-N lithium diisopropylamide Chemical compound [Li+].CC(C)[N-]C(C)C ZCSHNCUQKCANBX-UHFFFAOYSA-N 0.000 description 4
• 125000004433 nitrogen atom Chemical group N* 0.000 description 4
• 238000005580 one pot reaction Methods 0.000 description 4
• 239000006187 pill Substances 0.000 description 4
• BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
• NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 4
• 230000005180 public health Effects 0.000 description 4
• 239000000741 silica gel Substances 0.000 description 4
• 229910002027 silica gel Inorganic materials 0.000 description 4
• HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 4
• 239000002023 wood Substances 0.000 description 4
• 229910052725 zinc Inorganic materials 0.000 description 4
• 239000011701 zinc Substances 0.000 description 4
• SEULWJSKCVACTH-UHFFFAOYSA-N 1-phenylimidazole Chemical compound C1=NC=CN1C1=CC=CC=C1 SEULWJSKCVACTH-UHFFFAOYSA-N 0.000 description 3
• ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
• 229910002012 Aerosil® Inorganic materials 0.000 description 3
• 244000105624 Arachis hypogaea Species 0.000 description 3
• 241001674044 Blattodea Species 0.000 description 3
• 241000283690 Bos taurus Species 0.000 description 3
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
• 229920000742 Cotton Polymers 0.000 description 3
• 241000489975 Diabrotica Species 0.000 description 3
• 241000223924 Eimeria Species 0.000 description 3
• DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 3
• 241000258937 Hemiptera Species 0.000 description 3
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
• 241000257229 Musca <genus> Species 0.000 description 3
• 240000007594 Oryza sativa Species 0.000 description 3
• 235000007164 Oryza sativa Nutrition 0.000 description 3
• 241001147398 Ostrinia nubilalis Species 0.000 description 3
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
• DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 3
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
• 101100276531 Streptomyces halstedii sch4 gene Proteins 0.000 description 3
• XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
• 238000010521 absorption reaction Methods 0.000 description 3
• 230000002378 acidificating effect Effects 0.000 description 3
• 150000007513 acids Chemical class 0.000 description 3
• 239000000443 aerosol Substances 0.000 description 3
• 239000003513 alkali Substances 0.000 description 3
• 229910000288 alkali metal carbonate Inorganic materials 0.000 description 3
• 150000008041 alkali metal carbonates Chemical class 0.000 description 3
• AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
• 239000011230 binding agent Substances 0.000 description 3
• 150000001721 carbon Chemical group 0.000 description 3
• 238000000576 coating method Methods 0.000 description 3
• 238000005056 compaction Methods 0.000 description 3
• JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 3
• SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 3
• 239000003085 diluting agent Substances 0.000 description 3
• 235000020188 drinking water Nutrition 0.000 description 3
• 239000003651 drinking water Substances 0.000 description 3
• 235000013399 edible fruits Nutrition 0.000 description 3
• 150000002170 ethers Chemical class 0.000 description 3
• 239000003925 fat Substances 0.000 description 3
• 210000003608 fece Anatomy 0.000 description 3
• 239000000945 filler Substances 0.000 description 3
• 239000012530 fluid Substances 0.000 description 3
• 239000006260 foam Substances 0.000 description 3
• 150000008282 halocarbons Chemical class 0.000 description 3
• XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 3
• PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 3
• 238000003973 irrigation Methods 0.000 description 3
• NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
• 229910000103 lithium hydride Inorganic materials 0.000 description 3
• 229910052748 manganese Inorganic materials 0.000 description 3
• 239000011572 manganese Substances 0.000 description 3
• 239000000463 material Substances 0.000 description 3
• 230000008018 melting Effects 0.000 description 3
• 238000002844 melting Methods 0.000 description 3
• 230000011987 methylation Effects 0.000 description 3
• 230000003129 miticidal effect Effects 0.000 description 3
• 230000007935 neutral effect Effects 0.000 description 3
• 239000002420 orchard Substances 0.000 description 3
• 150000007530 organic bases Chemical class 0.000 description 3
• 238000007911 parenteral administration Methods 0.000 description 3
• 239000002245 particle Substances 0.000 description 3
• 235000020232 peanut Nutrition 0.000 description 3
• 230000000149 penetrating effect Effects 0.000 description 3
• FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 3
• 239000004033 plastic Substances 0.000 description 3
• 229920003023 plastic Polymers 0.000 description 3
• 238000000746 purification Methods 0.000 description 3
• 230000002829 reductive effect Effects 0.000 description 3
• 235000009566 rice Nutrition 0.000 description 3
• 239000000377 silicon dioxide Substances 0.000 description 3
• 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
• 235000017557 sodium bicarbonate Nutrition 0.000 description 3
• 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 3
• 239000004550 soluble concentrate Substances 0.000 description 3
• 238000001308 synthesis method Methods 0.000 description 3
• 238000010998 test method Methods 0.000 description 3
• 238000011200 topical administration Methods 0.000 description 3
• 239000011573 trace mineral Substances 0.000 description 3
• 235000013619 trace mineral Nutrition 0.000 description 3
• 238000000844 transformation Methods 0.000 description 3
• 239000003643 water by type Substances 0.000 description 3
• 239000004562 water dispersible granule Substances 0.000 description 3
• 239000001993 wax Substances 0.000 description 3
• 239000004563 wettable powder Substances 0.000 description 3
• 239000000080 wetting agent Substances 0.000 description 3
• OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 2
• FEWLNYSYJNLUOO-UHFFFAOYSA-N 1-Piperidinecarboxaldehyde Chemical compound O=CN1CCCCC1 FEWLNYSYJNLUOO-UHFFFAOYSA-N 0.000 description 2
• ITNMAZSPBLRJLU-UHFFFAOYSA-N 2,6-dichloro-4-(trifluoromethyl)aniline Chemical compound NC1=C(Cl)C=C(C(F)(F)F)C=C1Cl ITNMAZSPBLRJLU-UHFFFAOYSA-N 0.000 description 2
• NJJGZVFSCQSOOY-UHFFFAOYSA-N 2-chloro-3-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-(trifluoromethylsulfanyl)imidazol-4-amine Chemical compound NC1=C(SC(F)(F)F)N=C(Cl)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl NJJGZVFSCQSOOY-UHFFFAOYSA-N 0.000 description 2
• IKERBHQKRSDPFM-UHFFFAOYSA-N 3-[2,6-dichloro-4-(trifluoromethyl)phenyl]imidazol-4-amine Chemical compound NC1=CN=CN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl IKERBHQKRSDPFM-UHFFFAOYSA-N 0.000 description 2
• BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 2
• DXRCJLWBMRIZEQ-UHFFFAOYSA-N 4-amino-1,3-dihydroimidazol-2-one Chemical compound NC1=CN=C(O)N1 DXRCJLWBMRIZEQ-UHFFFAOYSA-N 0.000 description 2
• 241001143309 Acanthoscelides obtectus Species 0.000 description 2
• 241000256111 Aedes <genus> Species 0.000 description 2
• 241000256186 Anopheles <genus> Species 0.000 description 2
• 241001640910 Anthrenus Species 0.000 description 2
• 241000569145 Aphis nasturtii Species 0.000 description 2
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
• 239000004215 Carbon black (E152) Substances 0.000 description 2
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
• 241000426497 Chilo suppressalis Species 0.000 description 2
• 239000005944 Chlorpyrifos Substances 0.000 description 2
• 208000003495 Coccidiosis Diseases 0.000 description 2
• 235000013162 Cocos nucifera Nutrition 0.000 description 2
• 244000060011 Cocos nucifera Species 0.000 description 2
• 241001509964 Coptotermes Species 0.000 description 2
• 241000219112 Cucumis Species 0.000 description 2
• 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
• 240000008067 Cucumis sativus Species 0.000 description 2
• 241001635274 Cydia pomonella Species 0.000 description 2
• 239000005946 Cypermethrin Substances 0.000 description 2
• 241000268912 Damalinia Species 0.000 description 2
• RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
• MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
• 239000005977 Ethylene Substances 0.000 description 2
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
• ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
• 239000004471 Glycine Substances 0.000 description 2
• 241000219146 Gossypium Species 0.000 description 2
• 241000257176 Hypoderma <fly> Species 0.000 description 2
• RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical class C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 2
• UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
• 206010023076 Isosporiasis Diseases 0.000 description 2
• 239000005909 Kieselgur Substances 0.000 description 2
• 241000255777 Lepidoptera Species 0.000 description 2
• 241000258916 Leptinotarsa decemlineata Species 0.000 description 2
• 241000254023 Locusta Species 0.000 description 2
• FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
• 241000766511 Meligethes Species 0.000 description 2
• 241000243785 Meloidogyne javanica Species 0.000 description 2
• ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
• 241000257159 Musca domestica Species 0.000 description 2
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
• GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
• IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
• 238000010934 O-alkylation reaction Methods 0.000 description 2
• ZQTQPYJGMWHXMO-UHFFFAOYSA-N OOOOOOOOOOOOOOOOO Chemical compound OOOOOOOOOOOOOOOOO ZQTQPYJGMWHXMO-UHFFFAOYSA-N 0.000 description 2
• 101150101537 Olah gene Proteins 0.000 description 2
• 241000238814 Orthoptera Species 0.000 description 2
• 208000002193 Pain Diseases 0.000 description 2
• 241001494479 Pecora Species 0.000 description 2
• 241000238661 Periplaneta Species 0.000 description 2
• 241001608567 Phaedon cochleariae Species 0.000 description 2
• 241001401861 Phorodon humuli Species 0.000 description 2
• 241000500437 Plutella xylostella Species 0.000 description 2
• 241001481703 Rhipicephalus <genus> Species 0.000 description 2
• 241000282849 Ruminantia Species 0.000 description 2
• 238000000297 Sandmeyer reaction Methods 0.000 description 2
• 241000256108 Simulium <genus> Species 0.000 description 2
• 241000258242 Siphonaptera Species 0.000 description 2
• 241000254181 Sitophilus Species 0.000 description 2
• PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 2
• 240000003829 Sorghum propinquum Species 0.000 description 2
• 235000011684 Sorghum saccharatum Nutrition 0.000 description 2
• 241000256248 Spodoptera Species 0.000 description 2
• 241001521235 Spodoptera eridania Species 0.000 description 2
• 229930006000 Sucrose Natural products 0.000 description 2
• CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
• 241000282887 Suidae Species 0.000 description 2
• 241000255628 Tabanidae Species 0.000 description 2
• 241001454293 Tetranychus urticae Species 0.000 description 2
• 241001414833 Triatoma Species 0.000 description 2
• 241000254086 Tribolium <beetle> Species 0.000 description 2
• 235000021307 Triticum Nutrition 0.000 description 2
• 244000098338 Triticum aestivum Species 0.000 description 2
• 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
• 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 2
• 230000000895 acaricidal effect Effects 0.000 description 2
• WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 2
• 239000012346 acetyl chloride Substances 0.000 description 2
• 230000009471 action Effects 0.000 description 2
• 150000001340 alkali metals Chemical class 0.000 description 2
• 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
• 150000001347 alkyl bromides Chemical class 0.000 description 2
• 230000000507 anthelmentic effect Effects 0.000 description 2
• 239000000921 anthelmintic agent Substances 0.000 description 2
• 229940124339 anthelmintic agent Drugs 0.000 description 2
• 229950005228 bromoform Drugs 0.000 description 2
• 229910052793 cadmium Inorganic materials 0.000 description 2
• BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
• 239000002775 capsule Substances 0.000 description 2
• 230000003197 catalytic effect Effects 0.000 description 2
• 239000012320 chlorinating reagent Substances 0.000 description 2
• NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
• 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
• XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
• SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 2
• 239000010949 copper Substances 0.000 description 2
• ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
• 235000005822 corn Nutrition 0.000 description 2
• 230000007797 corrosion Effects 0.000 description 2
• 238000005260 corrosion Methods 0.000 description 2
• 239000006071 cream Substances 0.000 description 2
• 239000012043 crude product Substances 0.000 description 2
• JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
• 229960005424 cypermethrin Drugs 0.000 description 2
• KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 2
• 238000006297 dehydration reaction Methods 0.000 description 2
• GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
• JSYGRUBHOCKMGQ-UHFFFAOYSA-N dichloramine Chemical compound ClNCl JSYGRUBHOCKMGQ-UHFFFAOYSA-N 0.000 description 2
• 229940117389 dichlorobenzene Drugs 0.000 description 2
• UOAMTSKGCBMZTC-UHFFFAOYSA-N dicofol Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)(Cl)Cl)(O)C1=CC=C(Cl)C=C1 UOAMTSKGCBMZTC-UHFFFAOYSA-N 0.000 description 2
• 235000014113 dietary fatty acids Nutrition 0.000 description 2
• 235000015872 dietary supplement Nutrition 0.000 description 2
• 238000010790 dilution Methods 0.000 description 2
• 239000012895 dilution Substances 0.000 description 2
• 229910001882 dioxygen Inorganic materials 0.000 description 2
• 238000006073 displacement reaction Methods 0.000 description 2
• 150000002019 disulfides Chemical class 0.000 description 2
• 230000009189 diving Effects 0.000 description 2
• 229940079593 drug Drugs 0.000 description 2
• 230000001804 emulsifying effect Effects 0.000 description 2
• 239000002702 enteric coating Substances 0.000 description 2
• 238000009505 enteric coating Methods 0.000 description 2
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
• ARIUNKRPYAAUQE-UHFFFAOYSA-N ethyl n-[2,6-dichloro-4-(trifluoromethyl)phenyl]methanimidate Chemical compound CCOC=NC1=C(Cl)C=C(C(F)(F)F)C=C1Cl ARIUNKRPYAAUQE-UHFFFAOYSA-N 0.000 description 2
• 238000001125 extrusion Methods 0.000 description 2
• 239000000194 fatty acid Substances 0.000 description 2
• 229930195729 fatty acid Natural products 0.000 description 2
• YYJNOYZRYGDPNH-MFKUBSTISA-N fenpyroximate Chemical compound C=1C=C(C(=O)OC(C)(C)C)C=CC=1CO/N=C/C=1C(C)=NN(C)C=1OC1=CC=CC=C1 YYJNOYZRYGDPNH-MFKUBSTISA-N 0.000 description 2
• 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 description 2
• 238000003958 fumigation Methods 0.000 description 2
• 239000000417 fungicide Substances 0.000 description 2
• 210000001035 gastrointestinal tract Anatomy 0.000 description 2
• 238000010438 heat treatment Methods 0.000 description 2
• 239000004009 herbicide Substances 0.000 description 2
• 238000003898 horticulture Methods 0.000 description 2
• 229930195733 hydrocarbon Natural products 0.000 description 2
• 150000002430 hydrocarbons Chemical class 0.000 description 2
• 229940071870 hydroiodic acid Drugs 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
• SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 2
• 238000007654 immersion Methods 0.000 description 2
• 239000003112 inhibitor Substances 0.000 description 2
• 229910052500 inorganic mineral Inorganic materials 0.000 description 2
• 229910052742 iron Inorganic materials 0.000 description 2
• 230000002262 irrigation Effects 0.000 description 2
• OWFXIOWLTKNBAP-UHFFFAOYSA-N isoamyl nitrite Chemical compound CC(C)CCON=O OWFXIOWLTKNBAP-UHFFFAOYSA-N 0.000 description 2
• 229910052745 lead Inorganic materials 0.000 description 2
• 230000003902 lesion Effects 0.000 description 2
• 150000002641 lithium Chemical class 0.000 description 2
• WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 2
• 239000010871 livestock manure Substances 0.000 description 2
• 239000011777 magnesium Substances 0.000 description 2
• 229910052749 magnesium Inorganic materials 0.000 description 2
• 235000009973 maize Nutrition 0.000 description 2
• 229910052987 metal hydride Inorganic materials 0.000 description 2
• 150000004681 metal hydrides Chemical class 0.000 description 2
• 235000010755 mineral Nutrition 0.000 description 2
• 239000011707 mineral Substances 0.000 description 2
• 150000007522 mineralic acids Chemical class 0.000 description 2
• 230000004899 motility Effects 0.000 description 2
• JIKUXBYRTXDNIY-UHFFFAOYSA-N n-methyl-n-phenylformamide Chemical compound O=CN(C)C1=CC=CC=C1 JIKUXBYRTXDNIY-UHFFFAOYSA-N 0.000 description 2
• 230000000269 nucleophilic effect Effects 0.000 description 2
• 231100000194 ovacidal Toxicity 0.000 description 2
• 230000003151 ovacidal effect Effects 0.000 description 2
• 239000006072 paste Substances 0.000 description 2
• 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
• 150000002989 phenols Chemical class 0.000 description 2
• IPNPIHIZVLFAFP-UHFFFAOYSA-N phosphorus tribromide Chemical compound BrP(Br)Br IPNPIHIZVLFAFP-UHFFFAOYSA-N 0.000 description 2
• 230000008635 plant growth Effects 0.000 description 2
• 229910000027 potassium carbonate Inorganic materials 0.000 description 2
• 239000011698 potassium fluoride Substances 0.000 description 2
• 235000003270 potassium fluoride Nutrition 0.000 description 2
• 239000012286 potassium permanganate Substances 0.000 description 2
• 239000003755 preservative agent Substances 0.000 description 2
• 239000011541 reaction mixture Substances 0.000 description 2
• 230000009257 reactivity Effects 0.000 description 2
• 239000005871 repellent Substances 0.000 description 2
• 230000002940 repellent Effects 0.000 description 2
• 229920005989 resin Polymers 0.000 description 2
• 239000011347 resin Substances 0.000 description 2
• 238000006798 ring closing metathesis reaction Methods 0.000 description 2
• 229920006395 saturated elastomer Polymers 0.000 description 2
• 238000007873 sieving Methods 0.000 description 2
• 235000012239 silicon dioxide Nutrition 0.000 description 2
• NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
• 239000000344 soap Substances 0.000 description 2
• 239000011775 sodium fluoride Substances 0.000 description 2
• 235000013024 sodium fluoride Nutrition 0.000 description 2
• PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Inorganic materials [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
• 239000008247 solid mixture Substances 0.000 description 2
• 238000003797 solvolysis reaction Methods 0.000 description 2
• 238000009331 sowing Methods 0.000 description 2
• 235000013599 spices Nutrition 0.000 description 2
• 238000003892 spreading Methods 0.000 description 2
• 230000007480 spreading Effects 0.000 description 2
• 238000003756 stirring Methods 0.000 description 2
• 239000000758 substrate Substances 0.000 description 2
• 239000005720 sucrose Substances 0.000 description 2
• 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 2
• 239000012747 synergistic agent Substances 0.000 description 2
• XLNZEKHULJKQBA-UHFFFAOYSA-N terbufos Chemical compound CCOP(=S)(OCC)SCSC(C)(C)C XLNZEKHULJKQBA-UHFFFAOYSA-N 0.000 description 2
• 239000004753 textile Substances 0.000 description 2
• 238000009210 therapy by ultrasound Methods 0.000 description 2
• 239000013008 thixotropic agent Substances 0.000 description 2
• 229910052718 tin Inorganic materials 0.000 description 2
• 230000000699 topical effect Effects 0.000 description 2
• GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 2
• 235000013311 vegetables Nutrition 0.000 description 2
• 239000010455 vermiculite Substances 0.000 description 2
• 229910052902 vermiculite Inorganic materials 0.000 description 2
• 235000019354 vermiculite Nutrition 0.000 description 2
• 238000005406 washing Methods 0.000 description 2
• 238000009736 wetting Methods 0.000 description 2
• FZENGILVLUJGJX-NSCUHMNNSA-N (E)-acetaldehyde oxime Chemical compound C\C=N\O FZENGILVLUJGJX-NSCUHMNNSA-N 0.000 description 1
• ZMMRLWFGWQVVJD-UHFFFAOYSA-O (n,n-dimethylcarbamimidoyl)-dimethylazanium;azide Chemical compound [N-]=[N+]=[N-].CN(C)C(N)=[N+](C)C ZMMRLWFGWQVVJD-UHFFFAOYSA-O 0.000 description 1
• UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
• AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
• SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
• KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
• RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
• 238000005160 1H NMR spectroscopy Methods 0.000 description 1
• XYPISWUKQGWYGX-UHFFFAOYSA-N 2,2,2-trifluoroethaneperoxoic acid Chemical compound OOC(=O)C(F)(F)F XYPISWUKQGWYGX-UHFFFAOYSA-N 0.000 description 1
• TVFWYUWNQVRQRG-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol Chemical compound C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 TVFWYUWNQVRQRG-UHFFFAOYSA-N 0.000 description 1
• XFKYKTBPRBZDFG-UHFFFAOYSA-N 2-aminoacetonitrile;hydrochloride Chemical compound Cl.NCC#N XFKYKTBPRBZDFG-UHFFFAOYSA-N 0.000 description 1
• DZYRCTRDLRLXGG-UHFFFAOYSA-N 2-bromo-3-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-(trifluoromethylsulfanyl)imidazol-4-amine Chemical compound NC1=C(SC(F)(F)F)N=C(Br)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl DZYRCTRDLRLXGG-UHFFFAOYSA-N 0.000 description 1
• LFPYUAPDBGDNMS-UHFFFAOYSA-N 2-chloro-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-(trifluoromethylsulfonyl)imidazole Chemical compound ClC1=CC(C(F)(F)F)=CC(Cl)=C1N1C(Cl)=NC(S(=O)(=O)C(F)(F)F)=C1 LFPYUAPDBGDNMS-UHFFFAOYSA-N 0.000 description 1
• GPZXFICWCMCQPF-UHFFFAOYSA-N 2-methylbenzoyl chloride Chemical compound CC1=CC=CC=C1C(Cl)=O GPZXFICWCMCQPF-UHFFFAOYSA-N 0.000 description 1
• RLKDZKGRMRWQNG-UHFFFAOYSA-N 3-[2,6-dichloro-4-(trifluoromethyl)phenyl]-2-methylimidazol-4-amine Chemical compound CC1=NC=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl RLKDZKGRMRWQNG-UHFFFAOYSA-N 0.000 description 1
• SRVXSISGYBMIHR-UHFFFAOYSA-N 3-[3-[3-(2-amino-2-oxoethyl)phenyl]-5-chlorophenyl]-3-(5-methyl-1,3-thiazol-2-yl)propanoic acid Chemical compound S1C(C)=CN=C1C(CC(O)=O)C1=CC(Cl)=CC(C=2C=C(CC(N)=O)C=CC=2)=C1 SRVXSISGYBMIHR-UHFFFAOYSA-N 0.000 description 1
• NHQDETIJWKXCTC-UHFFFAOYSA-N 3-chloroperbenzoic acid Chemical compound OOC(=O)C1=CC=CC(Cl)=C1 NHQDETIJWKXCTC-UHFFFAOYSA-N 0.000 description 1
• WIBROJGYJNSXCM-UHFFFAOYSA-N 4-chloro-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-(difluoromethylsulfanyl)-2-methylimidazole Chemical compound CC1=NC(Cl)=C(SC(F)F)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl WIBROJGYJNSXCM-UHFFFAOYSA-N 0.000 description 1
• FLDSMVTWEZKONL-AWEZNQCLSA-N 5,5-dimethyl-N-[(3S)-5-methyl-4-oxo-2,3-dihydro-1,5-benzoxazepin-3-yl]-1,4,7,8-tetrahydrooxepino[4,5-c]pyrazole-3-carboxamide Chemical compound CC1(CC2=C(NN=C2C(=O)N[C@@H]2C(N(C3=C(OC2)C=CC=C3)C)=O)CCO1)C FLDSMVTWEZKONL-AWEZNQCLSA-N 0.000 description 1
• BJNHAJBSDHGQTJ-UHFFFAOYSA-N 5-chloro-3-[2,6-dichloro-4-(trifluoromethyl)phenyl]-2-(difluoromethylsulfanyl)-2-methyl-1h-imidazol-4-amine Chemical compound FC(F)SC1(C)NC(Cl)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl BJNHAJBSDHGQTJ-UHFFFAOYSA-N 0.000 description 1
• ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
• 239000005660 Abamectin Substances 0.000 description 1
• 244000215068 Acacia senegal Species 0.000 description 1
• 241000916768 Acalymma Species 0.000 description 1
• 241000934067 Acarus Species 0.000 description 1
• 241000238819 Acheta Species 0.000 description 1
• 241000238818 Acheta domesticus Species 0.000 description 1
• 241001133760 Acoelorraphe Species 0.000 description 1
• 244000298697 Actinidia deliciosa Species 0.000 description 1
• 241000251468 Actinopterygii Species 0.000 description 1
• 241001516607 Adelges Species 0.000 description 1
• 241000902874 Agelastica alni Species 0.000 description 1
• 241001136265 Agriotes Species 0.000 description 1
• 241001368048 Agrochola Species 0.000 description 1
• 241000218473 Agrotis Species 0.000 description 1
• 241000449794 Alabama argillacea Species 0.000 description 1
• 235000006667 Aleurites moluccana Nutrition 0.000 description 1
• RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
• 244000291564 Allium cepa Species 0.000 description 1
• 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
• 239000005995 Aluminium silicate Substances 0.000 description 1
• 244000055702 Amaranthus viridis Species 0.000 description 1
• 241000238679 Amblyomma Species 0.000 description 1
• 241001398046 Amphimallon solstitiale Species 0.000 description 1
• 206010002091 Anaesthesia Diseases 0.000 description 1
• 241000411449 Anobium punctatum Species 0.000 description 1
• 241001010981 Anomis erosa Species 0.000 description 1
• 240000002339 Anredera cordifolia Species 0.000 description 1
• 241000254177 Anthonomus Species 0.000 description 1
• 241000396431 Anthrenus scrophulariae Species 0.000 description 1
• 241001414827 Aonidiella Species 0.000 description 1
• 241000294569 Aphelenchoides Species 0.000 description 1
• 241000134843 Aphelenchoides besseyi Species 0.000 description 1
• 241000680417 Aphelenchoides ritzemabosi Species 0.000 description 1
• 241001465983 Aphidoidea Species 0.000 description 1
• 241001600407 Aphis <genus> Species 0.000 description 1
• 241001425390 Aphis fabae Species 0.000 description 1
• 241001095118 Aphis pomi Species 0.000 description 1
• 241001002469 Archips Species 0.000 description 1
• 241001162025 Archips podana Species 0.000 description 1
• 206010060969 Arthropod infestation Diseases 0.000 description 1
• 241000319476 Asellus Species 0.000 description 1
• 241000387321 Aspidiotus nerii Species 0.000 description 1
• 241001503479 Athalia Species 0.000 description 1
• 241000940781 Atherigona Species 0.000 description 1
• 241001174347 Atomaria Species 0.000 description 1
• 241000726103 Atta Species 0.000 description 1
• 241000131286 Attagenus Species 0.000 description 1
• 241001490249 Bactrocera oleae Species 0.000 description 1
• 241000580217 Belonolaimus Species 0.000 description 1
• 241000254123 Bemisia Species 0.000 description 1
• 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
• 241001142392 Bibio Species 0.000 description 1
• 241001573714 Blaniulus Species 0.000 description 1
• 241000238662 Blatta orientalis Species 0.000 description 1
• 241000238658 Blattella Species 0.000 description 1
• 241000238657 Blattella germanica Species 0.000 description 1
• ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
• 229910014265 BrCl Inorganic materials 0.000 description 1
• 240000002791 Brassica napus Species 0.000 description 1
• 240000007124 Brassica oleracea Species 0.000 description 1
• 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
• 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
• 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
• 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
• 241000982105 Brevicoryne brassicae Species 0.000 description 1
• CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
• 241000488564 Bryobia Species 0.000 description 1
• 241001517925 Bucculatrix Species 0.000 description 1
• 241001491790 Bupalus piniaria Species 0.000 description 1
• FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
• DASQIKOOFDJYKA-UHFFFAOYSA-N CCIF Chemical compound CCIF DASQIKOOFDJYKA-UHFFFAOYSA-N 0.000 description 1
• 229910021532 Calcite Inorganic materials 0.000 description 1
• OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
• 241000257163 Calliphora vicina Species 0.000 description 1
• 241000282472 Canis lupus familiaris Species 0.000 description 1
• 241000283707 Capra Species 0.000 description 1
• 235000002566 Capsicum Nutrition 0.000 description 1
• BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
• 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
• 241000700198 Cavia Species 0.000 description 1
• 241000717851 Cephus Species 0.000 description 1
• 241000255580 Ceratitis <genus> Species 0.000 description 1
• 241000255579 Ceratitis capitata Species 0.000 description 1
• 241001098608 Ceratophyllus Species 0.000 description 1
• 241001156313 Ceutorhynchus Species 0.000 description 1
• 241000426499 Chilo Species 0.000 description 1
• 241000258920 Chilopoda Species 0.000 description 1
• VGCXGMAHQTYDJK-UHFFFAOYSA-N Chloroacetyl chloride Chemical compound ClCC(Cl)=O VGCXGMAHQTYDJK-UHFFFAOYSA-N 0.000 description 1
• 241000088885 Chlorops Species 0.000 description 1
• 241000359266 Chorioptes Species 0.000 description 1
• 241001327638 Cimex lectularius Species 0.000 description 1
• 241001465977 Coccoidea Species 0.000 description 1
• 241001478240 Coccus Species 0.000 description 1
• 240000007154 Coffea arabica Species 0.000 description 1
• 235000016795 Cola Nutrition 0.000 description 1
• 244000228088 Cola acuminata Species 0.000 description 1
• 235000011824 Cola pachycarpa Nutrition 0.000 description 1
• 241000683561 Conoderus Species 0.000 description 1
• 241001126268 Cooperia Species 0.000 description 1
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
• 241000500845 Costelytra zealandica Species 0.000 description 1
• 241001267662 Criconemoides Species 0.000 description 1
• 241000238424 Crustacea Species 0.000 description 1
• 241001094916 Cryptomyzus ribis Species 0.000 description 1
• 241000258922 Ctenocephalides Species 0.000 description 1
• 235000009849 Cucumis sativus Nutrition 0.000 description 1
• 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
• 241000256054 Culex <genus> Species 0.000 description 1
• 241000256113 Culicidae Species 0.000 description 1
• 241001414890 Delia Species 0.000 description 1
• 241001128004 Demodex Species 0.000 description 1
• 241001480824 Dermacentor Species 0.000 description 1
• 241001124144 Dermaptera Species 0.000 description 1
• 241001641895 Dermestes Species 0.000 description 1
• 241000214908 Dermolepida Species 0.000 description 1
• MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
• 241000122105 Diatraea Species 0.000 description 1
• 241000709823 Dictyoptera <beetle genus> Species 0.000 description 1
• QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
• 241000511318 Diprion Species 0.000 description 1
• 241000399934 Ditylenchus Species 0.000 description 1
• 241000399949 Ditylenchus dipsaci Species 0.000 description 1
• 241001517923 Douglasiidae Species 0.000 description 1
• 241000255601 Drosophila melanogaster Species 0.000 description 1
• 241001425477 Dysdercus Species 0.000 description 1
• 241000241133 Earias Species 0.000 description 1
• 241000353522 Earias insulana Species 0.000 description 1
• 241000499566 Eimeria brunetti Species 0.000 description 1
• 241000223934 Eimeria maxima Species 0.000 description 1
• 241000499563 Eimeria necatrix Species 0.000 description 1
• 241000223932 Eimeria tenella Species 0.000 description 1
• 241000995023 Empoasca Species 0.000 description 1
• 241000224431 Entamoeba Species 0.000 description 1
• 241000630736 Ephestia Species 0.000 description 1
• 241000122098 Ephestia kuehniella Species 0.000 description 1
• 241000303278 Epitrix Species 0.000 description 1
• 241000283086 Equidae Species 0.000 description 1
• 241001558857 Eriophyes Species 0.000 description 1
• 241001221110 Eriophyidae Species 0.000 description 1
• 241000917107 Eriosoma lanigerum Species 0.000 description 1
• 241000060469 Eupoecilia ambiguella Species 0.000 description 1
• 241000483001 Euproctis chrysorrhoea Species 0.000 description 1
• 241001488207 Eutrombicula Species 0.000 description 1
• 241001585293 Euxoa Species 0.000 description 1
• 241000371383 Fannia Species 0.000 description 1
• 241000282326 Felis catus Species 0.000 description 1
• 241000233488 Feltia Species 0.000 description 1
• 239000005958 Fenamiphos (aka phenamiphos) Substances 0.000 description 1
• 241001284615 Frangula californica Species 0.000 description 1
• 241000189565 Frankliniella Species 0.000 description 1
• 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
• 241000233866 Fungi Species 0.000 description 1
• 241000255896 Galleria mellonella Species 0.000 description 1
• 241000287828 Gallus gallus Species 0.000 description 1
• 241001660203 Gasterophilus Species 0.000 description 1
• 241000248126 Geophilus Species 0.000 description 1
• 241000224466 Giardia Species 0.000 description 1
• 241001043186 Gibbium Species 0.000 description 1
• 241001442498 Globodera Species 0.000 description 1
• 241000482313 Globodera ellingtonae Species 0.000 description 1
• 241001442497 Globodera rostochiensis Species 0.000 description 1
• 235000010469 Glycine max Nutrition 0.000 description 1
• 241000890029 Gonocephalum Species 0.000 description 1
• 240000000047 Gossypium barbadense Species 0.000 description 1
• 235000009429 Gossypium barbadense Nutrition 0.000 description 1
• 241001243091 Gryllotalpa Species 0.000 description 1
• 241000238821 Gryllus Species 0.000 description 1
• 229920000084 Gum arabic Polymers 0.000 description 1
• 241001480796 Haemaphysalis Species 0.000 description 1
• 241000790933 Haematopinus Species 0.000 description 1
• 241000243974 Haemonchus contortus Species 0.000 description 1
• 241001148481 Helicotylenchus Species 0.000 description 1
• 241001445511 Helicotylenchus multicinctus Species 0.000 description 1
• 241001147381 Helicoverpa armigera Species 0.000 description 1
• 241000255967 Helicoverpa zea Species 0.000 description 1
• 241000256257 Heliothis Species 0.000 description 1
• 241000256244 Heliothis virescens Species 0.000 description 1
• 241000678550 Helopeltis Species 0.000 description 1
• 241001267658 Hemicycliophora Species 0.000 description 1
• 241000458093 Hemicycliophora gracilis Species 0.000 description 1
• 208000032843 Hemorrhage Diseases 0.000 description 1
• 241001659688 Hercinothrips femoralis Species 0.000 description 1
• 241001480224 Heterodera Species 0.000 description 1
• 241001227244 Heteronychus Species 0.000 description 1
• 241000590466 Heterotermes Species 0.000 description 1
• 241001201623 Hofmannophila pseudospretella Species 0.000 description 1
• 101000834981 Homo sapiens Testis, prostate and placenta-expressed protein Proteins 0.000 description 1
• 241000679711 Homona Species 0.000 description 1
• 241001540513 Hoplolaimus Species 0.000 description 1
• 241001540500 Hoplolaimus galeatus Species 0.000 description 1
• 241001480803 Hyalomma Species 0.000 description 1
• 241001251909 Hyalopterus pruni Species 0.000 description 1
• 241000832180 Hylotrupes bajulus Species 0.000 description 1
• 241001464384 Hymenolepis nana Species 0.000 description 1
• 241001508558 Hypera Species 0.000 description 1
• 241000577496 Hypothenemus hampei Species 0.000 description 1
• 239000005867 Iprodione Substances 0.000 description 1
• 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
• 241001149911 Isopoda Species 0.000 description 1
• 241000238681 Ixodes Species 0.000 description 1
• 239000003810 Jones reagent Substances 0.000 description 1
• 235000009496 Juglans regia Nutrition 0.000 description 1
• 240000007049 Juglans regia Species 0.000 description 1
• 235000003228 Lactuca sativa Nutrition 0.000 description 1
• 240000008415 Lactuca sativa Species 0.000 description 1
• 241000218652 Larix Species 0.000 description 1
• 235000005590 Larix decidua Nutrition 0.000 description 1
• 241000256686 Lasius <genus> Species 0.000 description 1
• 241001142635 Lema Species 0.000 description 1
• 241000500881 Lepisma Species 0.000 description 1
• 241000683448 Limonius Species 0.000 description 1
• 241000966204 Lissorhoptrus oryzophilus Species 0.000 description 1
• 241001220360 Longidorus Species 0.000 description 1
• 241001220357 Longidorus elongatus Species 0.000 description 1
• 241000257162 Lucilia <blowfly> Species 0.000 description 1
• 241001177134 Lyctus Species 0.000 description 1
• 241000721696 Lymantria Species 0.000 description 1
• 241000273338 Macronyssidae Species 0.000 description 1
• 241000255685 Malacosoma neustria Species 0.000 description 1
• 241000555300 Mamestra Species 0.000 description 1
• 235000014826 Mangifera indica Nutrition 0.000 description 1
• 240000007228 Mangifera indica Species 0.000 description 1
• 235000010624 Medicago sativa Nutrition 0.000 description 1
• 240000004658 Medicago sativa Species 0.000 description 1
• 241000171293 Megoura viciae Species 0.000 description 1
• 241001415015 Melanoplus differentialis Species 0.000 description 1
• 241000243786 Meloidogyne incognita Species 0.000 description 1
• 241000254099 Melolontha melolontha Species 0.000 description 1
• 239000005916 Methomyl Substances 0.000 description 1
• NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
• UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
• 241000555285 Monomorium Species 0.000 description 1
• 241000952627 Monomorium pharaonis Species 0.000 description 1
• 240000005561 Musa balbisiana Species 0.000 description 1
• 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
• 208000031888 Mycoses Diseases 0.000 description 1
• 208000006123 Myiasis Diseases 0.000 description 1
• 241000883290 Myriapoda Species 0.000 description 1
• 241000721623 Myzus Species 0.000 description 1
• FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
• 229910017917 NH4 Cl Inorganic materials 0.000 description 1
• 241001137882 Nematodirus Species 0.000 description 1
• 241000359016 Nephotettix Species 0.000 description 1
• 241001671714 Nezara Species 0.000 description 1
• 241001556090 Nilaparvata Species 0.000 description 1
• IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
• 241000819999 Nymphes Species 0.000 description 1
• 239000012425 OXONE® Substances 0.000 description 1
• 241000866537 Odontotermes Species 0.000 description 1
• 240000007817 Olea europaea Species 0.000 description 1
• 235000002725 Olea europaea Nutrition 0.000 description 1
• 241000384105 Oniscus Species 0.000 description 1
• 241000963706 Onychiurus Species 0.000 description 1
• 241000273340 Ornithonyssus Species 0.000 description 1
• 241000283973 Oryctolagus cuniculus Species 0.000 description 1
• 241000131101 Oryzaephilus surinamensis Species 0.000 description 1
• 241000975417 Oscinella frit Species 0.000 description 1
• 241001147397 Ostrinia Species 0.000 description 1
• 239000005950 Oxamyl Substances 0.000 description 1
• 241000660935 Oxycarenus Species 0.000 description 1
• 241000486438 Panolis flammea Species 0.000 description 1
• 241000721452 Pectinophora Species 0.000 description 1
• 241000721451 Pectinophora gossypiella Species 0.000 description 1
• 241000517306 Pediculus humanus corporis Species 0.000 description 1
• 241000562493 Pegomya Species 0.000 description 1
• 241000238675 Periplaneta americana Species 0.000 description 1
• 241001253325 Perkinsiella Species 0.000 description 1
• 244000025272 Persea americana Species 0.000 description 1
• 235000008673 Persea americana Nutrition 0.000 description 1
• 241000257149 Phormia Species 0.000 description 1
• 241001517955 Phyllonorycter blancardella Species 0.000 description 1
• 241001516577 Phylloxera Species 0.000 description 1
• 241000913072 Phytomyza Species 0.000 description 1
• 241000255972 Pieris <butterfly> Species 0.000 description 1
• 241000255969 Pieris brassicae Species 0.000 description 1
• 241000690748 Piesma Species 0.000 description 1
• 241000758706 Piperaceae Species 0.000 description 1
• 241000224016 Plasmodium Species 0.000 description 1
• 241000256835 Polistes Species 0.000 description 1
• 239000004721 Polyphenylene oxide Substances 0.000 description 1
• 239000004372 Polyvinyl alcohol Substances 0.000 description 1
• 241000254103 Popillia Species 0.000 description 1
• 241000908127 Porcellio scaber Species 0.000 description 1
• 241001311138 Porina Species 0.000 description 1
• 241000193943 Pratylenchus Species 0.000 description 1
• 241001148486 Pratylenchus pratensis Species 0.000 description 1
• 235000005805 Prunus cerasus Nutrition 0.000 description 1
• 241001649229 Psoroptes Species 0.000 description 1
• 241000526145 Psylla Species 0.000 description 1
• 241001160824 Psylliodes Species 0.000 description 1
• 241001180370 Psylliodes chrysocephalus Species 0.000 description 1
• 241000932787 Pyrilla Species 0.000 description 1
• 241000201377 Radopholus Species 0.000 description 1
• 241000201375 Radopholus similis Species 0.000 description 1
• 241000700159 Rattus Species 0.000 description 1
• 238000007013 Reimer-Tiemann formylation reaction Methods 0.000 description 1
• 241001509970 Reticulitermes <genus> Species 0.000 description 1
• 241001481704 Rhipicephalus appendiculatus Species 0.000 description 1
• 241000238680 Rhipicephalus microplus Species 0.000 description 1
• 241000722249 Rhodnius prolixus Species 0.000 description 1
• 241000125167 Rhopalosiphum padi Species 0.000 description 1
• 241000344244 Rhynchophorus Species 0.000 description 1
• 241000314691 Rhysamphichloris similis Species 0.000 description 1
• 241000318997 Rhyzopertha dominica Species 0.000 description 1
• 241001540480 Rotylenchulus Species 0.000 description 1
• 241000702971 Rotylenchulus reniformis Species 0.000 description 1
• 241000855013 Rotylenchus Species 0.000 description 1
• 241000710331 Rotylenchus robustus Species 0.000 description 1
• 241000257190 Sarcophaga <genus> Species 0.000 description 1
• 241000509416 Sarcoptes Species 0.000 description 1
• 241000509427 Sarcoptes scabiei Species 0.000 description 1
• 241000254026 Schistocerca Species 0.000 description 1
• 241000253973 Schistocerca gregaria Species 0.000 description 1
• 241000545593 Scolytinae Species 0.000 description 1
• 241001157779 Scutigera Species 0.000 description 1
• 241000883293 Scutigerella Species 0.000 description 1
• 239000004113 Sepiolite Substances 0.000 description 1
• WABPPBHOPMUJHV-UHFFFAOYSA-N Sesamex Chemical compound CCOCCOCCOC(C)OC1=CC=C2OCOC2=C1 WABPPBHOPMUJHV-UHFFFAOYSA-N 0.000 description 1
• 235000004433 Simmondsia californica Nutrition 0.000 description 1
• 241000180219 Sitobion avenae Species 0.000 description 1
• 241000254179 Sitophilus granarius Species 0.000 description 1
• 241000254152 Sitophilus oryzae Species 0.000 description 1
• 241001562126 Sminthurus Species 0.000 description 1
• 229920002125 Sokalan® Polymers 0.000 description 1
• 235000002595 Solanum tuberosum Nutrition 0.000 description 1
• 244000061456 Solanum tuberosum Species 0.000 description 1
• 241001492664 Solenopsis <angiosperm> Species 0.000 description 1
• 241000277984 Sparganothis pilleriana Species 0.000 description 1
• 241000931755 Spodoptera exempta Species 0.000 description 1
• 241000985245 Spodoptera litura Species 0.000 description 1
• 240000003949 Sporobolus virginicus Species 0.000 description 1
• 241001494139 Stomoxys Species 0.000 description 1
• 235000021536 Sugar beet Nutrition 0.000 description 1
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
• ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
• UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
• IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 description 1
• 241000255626 Tabanus <genus> Species 0.000 description 1
• 239000005938 Teflubenzuron Substances 0.000 description 1
• 241000254109 Tenebrio molitor Species 0.000 description 1
• 241000255588 Tephritidae Species 0.000 description 1
• 241000032211 Terebra Species 0.000 description 1
• 102100026164 Testis, prostate and placenta-expressed protein Human genes 0.000 description 1
• 241001454294 Tetranychus Species 0.000 description 1
• 241001122767 Theaceae Species 0.000 description 1
• 241000223777 Theileria Species 0.000 description 1
• 244000299461 Theobroma cacao Species 0.000 description 1
• 235000009470 Theobroma cacao Nutrition 0.000 description 1
• 241000339374 Thrips tabaci Species 0.000 description 1
• ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
• 241000130771 Tinea pellionella Species 0.000 description 1
• 241000333690 Tineola bisselliella Species 0.000 description 1
• 241000511627 Tipula paludosa Species 0.000 description 1
• 241000223996 Toxoplasma Species 0.000 description 1
• 241000018135 Trialeurodes Species 0.000 description 1
• 241000243777 Trichinella spiralis Species 0.000 description 1
• 241001259047 Trichodectes Species 0.000 description 1
• 241001220308 Trichodorus Species 0.000 description 1
• 241001220305 Trichodorus primitivus Species 0.000 description 1
• 241001502500 Trichomonadida Species 0.000 description 1
• 241000255993 Trichoplusia ni Species 0.000 description 1
• 241000243796 Trichostrongylus colubriformis Species 0.000 description 1
• 241000595935 Triops Species 0.000 description 1
• 241000267823 Trogoderma Species 0.000 description 1
• 240000008573 Tropaeolum minus Species 0.000 description 1
• 241001267618 Tylenchulus Species 0.000 description 1
• 241001267621 Tylenchulus semipenetrans Species 0.000 description 1
• 241000256838 Vespula Species 0.000 description 1
• 241001274788 Viteus vitifoliae Species 0.000 description 1
• 238000006959 Williamson synthesis reaction Methods 0.000 description 1
• 241001530234 Wiseana Species 0.000 description 1
• 241000353223 Xenopsylla cheopis Species 0.000 description 1
• 241000201423 Xiphinema Species 0.000 description 1
• 241001423921 Xiphinema diversicaudatum Species 0.000 description 1
• 241001466337 Yponomeuta Species 0.000 description 1
• CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical class [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
• MCIGNPLOOOVZAG-UHFFFAOYSA-N [Cl].ClS(Cl)=O Chemical compound [Cl].ClS(Cl)=O MCIGNPLOOOVZAG-UHFFFAOYSA-N 0.000 description 1
• 239000002250 absorbent Substances 0.000 description 1
• 230000002745 absorbent Effects 0.000 description 1
• 239000000205 acacia gum Substances 0.000 description 1
• 235000010489 acacia gum Nutrition 0.000 description 1
• 238000009825 accumulation Methods 0.000 description 1
• YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 1
• 125000002252 acyl group Chemical group 0.000 description 1
• 230000006978 adaptation Effects 0.000 description 1
• 239000002671 adjuvant Substances 0.000 description 1
• 230000002411 adverse Effects 0.000 description 1
• QGLZXHRNAYXIBU-WEVVVXLNSA-N aldicarb Chemical compound CNC(=O)O\N=C\C(C)(C)SC QGLZXHRNAYXIBU-WEVVVXLNSA-N 0.000 description 1
• HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
• 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
• 150000001342 alkaline earth metals Chemical class 0.000 description 1
• 125000002877 alkyl aryl group Chemical group 0.000 description 1
• 150000008051 alkyl sulfates Chemical class 0.000 description 1
• 150000001356 alkyl thiols Chemical class 0.000 description 1
• 230000004075 alteration Effects 0.000 description 1
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
• 235000012211 aluminium silicate Nutrition 0.000 description 1
• MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 description 1
• 239000000908 ammonium hydroxide Substances 0.000 description 1
• 150000003863 ammonium salts Chemical class 0.000 description 1
• 230000037005 anaesthesia Effects 0.000 description 1
• 238000004458 analytical method Methods 0.000 description 1
• 150000001448 anilines Chemical class 0.000 description 1
• 239000010775 animal oil Substances 0.000 description 1
• 125000000129 anionic group Chemical group 0.000 description 1
• 150000001450 anions Chemical class 0.000 description 1
• 230000000844 anti-bacterial effect Effects 0.000 description 1
• 230000001165 anti-coccidial effect Effects 0.000 description 1
• 230000002528 anti-freeze Effects 0.000 description 1
• 239000002518 antifoaming agent Substances 0.000 description 1
• 239000013011 aqueous formulation Substances 0.000 description 1
• 150000001491 aromatic compounds Chemical class 0.000 description 1
• 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
• 239000003849 aromatic solvent Substances 0.000 description 1
• 125000003710 aryl alkyl group Chemical group 0.000 description 1
• 125000005129 aryl carbonyl group Chemical group 0.000 description 1
• HYGWNUKOUCZBND-UHFFFAOYSA-N azanide Chemical compound [NH2-] HYGWNUKOUCZBND-UHFFFAOYSA-N 0.000 description 1
• 230000001580 bacterial effect Effects 0.000 description 1
• 239000003899 bactericide agent Substances 0.000 description 1
• RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 description 1
• 239000000440 bentonite Substances 0.000 description 1
• 229910000278 bentonite Inorganic materials 0.000 description 1
• SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
• MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 description 1
• PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
• VBQDSLGFSUGBBE-UHFFFAOYSA-N benzyl(triethyl)azanium Chemical compound CC[N+](CC)(CC)CC1=CC=CC=C1 VBQDSLGFSUGBBE-UHFFFAOYSA-N 0.000 description 1
• 239000003139 biocide Substances 0.000 description 1
• 235000010290 biphenyl Nutrition 0.000 description 1
• 239000004305 biphenyl Substances 0.000 description 1
• 208000011090 bird disease Diseases 0.000 description 1
• BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
• 238000009835 boiling Methods 0.000 description 1
• UORVGPXVDQYIDP-BJUDXGSMSA-N borane Chemical class [10BH3] UORVGPXVDQYIDP-BJUDXGSMSA-N 0.000 description 1
• 229910021538 borax Inorganic materials 0.000 description 1
• 229910052796 boron Inorganic materials 0.000 description 1
• 210000000481 breast Anatomy 0.000 description 1
• CODNYICXDISAEA-UHFFFAOYSA-N bromine monochloride Chemical compound BrCl CODNYICXDISAEA-UHFFFAOYSA-N 0.000 description 1
• 125000005997 bromomethyl group Chemical group 0.000 description 1
• 244000309464 bull Species 0.000 description 1
• 229910052792 caesium Inorganic materials 0.000 description 1
• 239000011575 calcium Substances 0.000 description 1
• 229910052791 calcium Inorganic materials 0.000 description 1
• 239000001506 calcium phosphate Substances 0.000 description 1
• RLDQYSHDFVSAPL-UHFFFAOYSA-L calcium;dithiocyanate Chemical class [Ca+2].[S-]C#N.[S-]C#N RLDQYSHDFVSAPL-UHFFFAOYSA-L 0.000 description 1
• 239000004202 carbamide Substances 0.000 description 1
• DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 1
• 239000006229 carbon black Substances 0.000 description 1
• 239000001569 carbon dioxide Substances 0.000 description 1
• 229910002092 carbon dioxide Inorganic materials 0.000 description 1
• 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 1
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
• JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 1
• 150000003857 carboxamides Chemical class 0.000 description 1
• 239000001768 carboxy methyl cellulose Substances 0.000 description 1
• 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
• 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
• IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 1
• 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
• 239000004464 cereal grain Substances 0.000 description 1
• 238000012512 characterization method Methods 0.000 description 1
• KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 1
• 235000013330 chicken meat Nutrition 0.000 description 1
• YDLXTSGSCLQMAL-UHFFFAOYSA-N chloro(difluoro)methanesulfonyl chloride Chemical compound FC(F)(Cl)S(Cl)(=O)=O YDLXTSGSCLQMAL-UHFFFAOYSA-N 0.000 description 1
• 150000008422 chlorobenzenes Chemical class 0.000 description 1
• KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
• 229940117975 chromium trioxide Drugs 0.000 description 1
• WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
• GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 1
• 235000020971 citrus fruits Nutrition 0.000 description 1
• 238000003776 cleavage reaction Methods 0.000 description 1
• 239000011248 coating agent Substances 0.000 description 1
• 239000010941 cobalt Substances 0.000 description 1
• 229910017052 cobalt Inorganic materials 0.000 description 1
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
• 235000016213 coffee Nutrition 0.000 description 1
• 235000013353 coffee beverage Nutrition 0.000 description 1
• 239000000084 colloidal system Substances 0.000 description 1
• 239000003086 colorant Substances 0.000 description 1
• 239000013065 commercial product Substances 0.000 description 1
• 239000002131 composite material Substances 0.000 description 1
• 238000012790 confirmation Methods 0.000 description 1
• 239000013068 control sample Substances 0.000 description 1
• 238000013270 controlled release Methods 0.000 description 1
• 229910052802 copper Inorganic materials 0.000 description 1
• DOBRDRYODQBAMW-UHFFFAOYSA-N copper(i) cyanide Chemical compound [Cu+].N#[C-] DOBRDRYODQBAMW-UHFFFAOYSA-N 0.000 description 1
• 239000007799 cork Substances 0.000 description 1
• 229960003280 cupric chloride Drugs 0.000 description 1
• 238000007333 cyanation reaction Methods 0.000 description 1
• 208000031513 cyst Diseases 0.000 description 1
• 230000009089 cytolysis Effects 0.000 description 1
• 230000006378 damage Effects 0.000 description 1
• 230000034994 death Effects 0.000 description 1
• 238000000354 decomposition reaction Methods 0.000 description 1
• 239000012024 dehydrating agents‎ Substances 0.000 description 1
• WEBQKRLKWNIYKK-UHFFFAOYSA-N demeton-S-methyl Chemical compound CCSCCSP(=O)(OC)OC WEBQKRLKWNIYKK-UHFFFAOYSA-N 0.000 description 1
• 239000002781 deodorant agent Substances 0.000 description 1
• 230000008021 deposition Effects 0.000 description 1
• 238000010511 deprotection reaction Methods 0.000 description 1
• 229910003460 diamond Inorganic materials 0.000 description 1
• 239000010432 diamond Substances 0.000 description 1
• LDBTVAXGKYIFHO-UHFFFAOYSA-N diaveridine Chemical compound C1=C(OC)C(OC)=CC=C1CC1=CN=C(N)N=C1N LDBTVAXGKYIFHO-UHFFFAOYSA-N 0.000 description 1
• 229950000246 diaveridine Drugs 0.000 description 1
• IJGRMHOSHXDMSA-UHFFFAOYSA-O diazynium Chemical compound [NH+]#N IJGRMHOSHXDMSA-UHFFFAOYSA-O 0.000 description 1
• OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
• 229950001327 dichlorvos Drugs 0.000 description 1
• SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
• 235000005911 diet Nutrition 0.000 description 1
• 230000037213 diet Effects 0.000 description 1
• FAXIJTUDSBIMHY-UHFFFAOYSA-N diethoxy-(2-ethylsulfanylethoxy)-sulfanylidene-$l^{5}-phosphane;1-diethoxyphosphorylsulfanyl-2-ethylsulfanylethane Chemical compound CCOP(=O)(OCC)SCCSCC.CCOP(=S)(OCC)OCCSCC FAXIJTUDSBIMHY-UHFFFAOYSA-N 0.000 description 1
• 238000009792 diffusion process Methods 0.000 description 1
• 230000001079 digestive effect Effects 0.000 description 1
• 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
• AJQDMTKWSVMVQA-UHFFFAOYSA-N dimethylamino thiohypofluorite Chemical compound CN(SF)C AJQDMTKWSVMVQA-UHFFFAOYSA-N 0.000 description 1
• OMBRFUXPXNIUCZ-UHFFFAOYSA-N dioxidonitrogen(1+) Chemical class O=[N+]=O OMBRFUXPXNIUCZ-UHFFFAOYSA-N 0.000 description 1
• FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
• 239000001177 diphosphate Substances 0.000 description 1
• XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
• 235000011180 diphosphates Nutrition 0.000 description 1
• BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
• 235000019800 disodium phosphate Nutrition 0.000 description 1
• 229910000397 disodium phosphate Inorganic materials 0.000 description 1
• 208000035475 disorder Diseases 0.000 description 1
• 239000004491 dispersible concentrate Substances 0.000 description 1
• 238000009826 distribution Methods 0.000 description 1
• DOFZAZXDOSGAJZ-UHFFFAOYSA-N disulfoton Chemical compound CCOP(=S)(OCC)SCCSCC DOFZAZXDOSGAJZ-UHFFFAOYSA-N 0.000 description 1
• TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
• YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
• GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
• 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
• 239000010459 dolomite Substances 0.000 description 1
• 229910000514 dolomite Inorganic materials 0.000 description 1
• 229920001971 elastomer Polymers 0.000 description 1
• 238000010828 elution Methods 0.000 description 1
• RDYMFSUJUZBWLH-SVWSLYAFSA-N endosulfan Chemical compound C([C@@H]12)OS(=O)OC[C@@H]1[C@]1(Cl)C(Cl)=C(Cl)[C@@]2(Cl)C1(Cl)Cl RDYMFSUJUZBWLH-SVWSLYAFSA-N 0.000 description 1
• 230000012173 estrus Effects 0.000 description 1
• VJYFKVYYMZPMAB-UHFFFAOYSA-N ethoprophos Chemical compound CCCSP(=O)(OCC)SCCC VJYFKVYYMZPMAB-UHFFFAOYSA-N 0.000 description 1
• DQYBDCGIPTYXML-UHFFFAOYSA-N ethoxyethane;hydrate Chemical compound O.CCOCC DQYBDCGIPTYXML-UHFFFAOYSA-N 0.000 description 1
• IDNUEBSJWINEMI-UHFFFAOYSA-N ethyl nitrate Chemical compound CCO[N+]([O-])=O IDNUEBSJWINEMI-UHFFFAOYSA-N 0.000 description 1
• XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 1
• 238000000605 extraction Methods 0.000 description 1
• XPYGGHVSFMUHLH-UUSULHAXSA-N falecalcitriol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@@H](CCCC(O)(C(F)(F)F)C(F)(F)F)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C XPYGGHVSFMUHLH-UUSULHAXSA-N 0.000 description 1
• 150000004665 fatty acids Chemical class 0.000 description 1
• 150000002191 fatty alcohols Chemical class 0.000 description 1
• 150000002194 fatty esters Chemical class 0.000 description 1
• 210000003746 feather Anatomy 0.000 description 1
• ZCJPOPBZHLUFHF-UHFFFAOYSA-N fenamiphos Chemical compound CCOP(=O)(NC(C)C)OC1=CC=C(SC)C(C)=C1 ZCJPOPBZHLUFHF-UHFFFAOYSA-N 0.000 description 1
• ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
• 239000003337 fertilizer Substances 0.000 description 1
• 238000001914 filtration Methods 0.000 description 1
• 235000019688 fish Nutrition 0.000 description 1
• 239000000796 flavoring agent Substances 0.000 description 1
• 125000003709 fluoroalkyl group Chemical group 0.000 description 1
• 238000005187 foaming Methods 0.000 description 1
• 235000013355 food flavoring agent Nutrition 0.000 description 1
• 230000037406 food intake Effects 0.000 description 1
• 150000003948 formamides Chemical class 0.000 description 1
• 230000000855 fungicidal effect Effects 0.000 description 1
• AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
• JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 1
• JLYXXMFPNIAWKQ-UHFFFAOYSA-N gamma-hexachlorocyclohexane Natural products ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 1
• 239000007789 gas Substances 0.000 description 1
• 239000000499 gel Substances 0.000 description 1
• 150000004676 glycans Chemical class 0.000 description 1
• 238000005469 granulation Methods 0.000 description 1
• 230000003179 granulation Effects 0.000 description 1
• 238000000227 grinding Methods 0.000 description 1
• 210000004209 hair Anatomy 0.000 description 1
• 150000002366 halogen compounds Chemical class 0.000 description 1
• 125000001475 halogen functional group Chemical group 0.000 description 1
• 230000036541 health Effects 0.000 description 1
• 231100000086 high toxicity Toxicity 0.000 description 1
• 239000012456 homogeneous solution Substances 0.000 description 1
• 239000010903 husk Substances 0.000 description 1
• BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
• 230000003301 hydrolyzing effect Effects 0.000 description 1
• 150000004679 hydroxides Chemical class 0.000 description 1
• DOUHZFSGSXMPIE-UHFFFAOYSA-N hydroxidooxidosulfur(.) Chemical compound [O]SO DOUHZFSGSXMPIE-UHFFFAOYSA-N 0.000 description 1
• WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
• 125000000879 imine group Chemical group 0.000 description 1
• 238000002513 implantation Methods 0.000 description 1
• 238000005470 impregnation Methods 0.000 description 1
• 238000011065 in-situ storage Methods 0.000 description 1
• 238000010348 incorporation Methods 0.000 description 1
• 230000002458 infectious effect Effects 0.000 description 1
• 230000002401 inhibitory effect Effects 0.000 description 1
• 238000002347 injection Methods 0.000 description 1
• 239000007924 injection Substances 0.000 description 1
• 150000007529 inorganic bases Chemical class 0.000 description 1
• 239000001023 inorganic pigment Substances 0.000 description 1
• 230000000968 intestinal effect Effects 0.000 description 1
• 238000006192 iodination reaction Methods 0.000 description 1
• 150000002496 iodine Chemical class 0.000 description 1
• ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 description 1
• RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
• DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
• 239000003621 irrigation water Substances 0.000 description 1
• APNSGVMLAYLYCT-UHFFFAOYSA-N isobutyl nitrite Chemical compound CC(C)CON=O APNSGVMLAYLYCT-UHFFFAOYSA-N 0.000 description 1
• 238000002955 isolation Methods 0.000 description 1
• 150000002576 ketones Chemical class 0.000 description 1
• 239000004816 latex Substances 0.000 description 1
• 229920000126 latex Polymers 0.000 description 1
• 239000000787 lecithin Substances 0.000 description 1
• 235000010445 lecithin Nutrition 0.000 description 1
• 229960002809 lindane Drugs 0.000 description 1
• 239000012280 lithium aluminium hydride Substances 0.000 description 1
• XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
• 239000000391 magnesium silicate Substances 0.000 description 1
• 235000012243 magnesium silicates Nutrition 0.000 description 1
• 238000012423 maintenance Methods 0.000 description 1
• 230000014759 maintenance of location Effects 0.000 description 1
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 239000004579 marble Substances 0.000 description 1
• 235000013372 meat Nutrition 0.000 description 1
• 239000012528 membrane Substances 0.000 description 1
• 238000006263 metalation reaction Methods 0.000 description 1
• 150000002739 metals Chemical class 0.000 description 1
• UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 description 1
• LRMHVVPPGGOAJQ-UHFFFAOYSA-N methyl nitrate Chemical compound CO[N+]([O-])=O LRMHVVPPGGOAJQ-UHFFFAOYSA-N 0.000 description 1
• JNMIXMFEVJHFNY-UHFFFAOYSA-M methyl(triphenyl)phosphanium;iodide Chemical compound [I-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(C)C1=CC=CC=C1 JNMIXMFEVJHFNY-UHFFFAOYSA-M 0.000 description 1
• 125000004674 methylcarbonyl group Chemical group CC(=O)* 0.000 description 1
• 239000003094 microcapsule Substances 0.000 description 1
• 235000013379 molasses Nutrition 0.000 description 1
• 229910052901 montmorillonite Inorganic materials 0.000 description 1
• 238000000465 moulding Methods 0.000 description 1
• DBBGVUMDZIJRHX-UHFFFAOYSA-N n-[2,6-dichloro-4-(trifluoromethyl)phenyl]acetamide Chemical compound CC(=O)NC1=C(Cl)C=C(C(F)(F)F)C=C1Cl DBBGVUMDZIJRHX-UHFFFAOYSA-N 0.000 description 1
• PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
• 229940042880 natural phospholipid Drugs 0.000 description 1
• 229920005615 natural polymer Polymers 0.000 description 1
• 230000000802 nitrating effect Effects 0.000 description 1
• 150000002825 nitriles Chemical group 0.000 description 1
• JCZMXVGQBBATMY-UHFFFAOYSA-N nitro acetate Chemical compound CC(=O)O[N+]([O-])=O JCZMXVGQBBATMY-UHFFFAOYSA-N 0.000 description 1
• QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
• 239000012457 nonaqueous media Substances 0.000 description 1
• SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
• 210000003250 oocyst Anatomy 0.000 description 1
• 230000003287 optical effect Effects 0.000 description 1
• 150000007524 organic acids Chemical class 0.000 description 1
• 239000011368 organic material Substances 0.000 description 1
• 229910017059 organic montmorillonite Inorganic materials 0.000 description 1
• KZAUOCCYDRDERY-UHFFFAOYSA-N oxamyl Chemical compound CNC(=O)ON=C(SC)C(=O)N(C)C KZAUOCCYDRDERY-UHFFFAOYSA-N 0.000 description 1
• SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
• 244000045947 parasite Species 0.000 description 1
• 230000003071 parasitic effect Effects 0.000 description 1
• 238000005192 partition Methods 0.000 description 1
• 230000001717 pathogenic effect Effects 0.000 description 1
• 239000003415 peat Substances 0.000 description 1
• 239000008188 pellet Substances 0.000 description 1
• 230000035515 penetration Effects 0.000 description 1
• 230000002688 persistence Effects 0.000 description 1
• 239000003208 petroleum Substances 0.000 description 1
• 239000003444 phase transfer catalyst Substances 0.000 description 1
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
• 239000003016 pheromone Substances 0.000 description 1
• BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 1
• IOUNQDKNJZEDEP-UHFFFAOYSA-N phosalone Chemical compound C1=C(Cl)C=C2OC(=O)N(CSP(=S)(OCC)OCC)C2=C1 IOUNQDKNJZEDEP-UHFFFAOYSA-N 0.000 description 1
• 150000003904 phospholipids Chemical class 0.000 description 1
• XUYJLQHKOGNDPB-UHFFFAOYSA-N phosphonoacetic acid Chemical class OC(=O)CP(O)(O)=O XUYJLQHKOGNDPB-UHFFFAOYSA-N 0.000 description 1
• 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
• 229960005235 piperonyl butoxide Drugs 0.000 description 1
• QHOQHJPRIBSPCY-UHFFFAOYSA-N pirimiphos-methyl Chemical group CCN(CC)C1=NC(C)=CC(OP(=S)(OC)OC)=N1 QHOQHJPRIBSPCY-UHFFFAOYSA-N 0.000 description 1
• 238000009372 pisciculture Methods 0.000 description 1
• 239000005648 plant growth regulator Substances 0.000 description 1
• 239000004014 plasticizer Substances 0.000 description 1
• 239000002798 polar solvent Substances 0.000 description 1
• 229920000570 polyether Polymers 0.000 description 1
• 229920005862 polyol Polymers 0.000 description 1
• 150000003077 polyols Chemical class 0.000 description 1
• 229920001282 polysaccharide Polymers 0.000 description 1
• 239000005017 polysaccharide Substances 0.000 description 1
• 239000005077 polysulfide Substances 0.000 description 1
• 229920001021 polysulfide Polymers 0.000 description 1
• 150000008117 polysulfides Polymers 0.000 description 1
• 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
• 239000004810 polytetrafluoroethylene Substances 0.000 description 1
• 239000011118 polyvinyl acetate Substances 0.000 description 1
• 229920002689 polyvinyl acetate Polymers 0.000 description 1
• 229920002451 polyvinyl alcohol Polymers 0.000 description 1
• 229920000915 polyvinyl chloride Polymers 0.000 description 1
• 239000004800 polyvinyl chloride Substances 0.000 description 1
• 239000011148 porous material Substances 0.000 description 1
• 229910052700 potassium Inorganic materials 0.000 description 1
• XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
• NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
• NTTOTNSKUYCDAV-UHFFFAOYSA-N potassium hydride Chemical compound [KH] NTTOTNSKUYCDAV-UHFFFAOYSA-N 0.000 description 1
• 229910000105 potassium hydride Inorganic materials 0.000 description 1
• OKBMCNHOEMXPTM-UHFFFAOYSA-M potassium peroxymonosulfate Chemical compound [K+].OOS([O-])(=O)=O OKBMCNHOEMXPTM-UHFFFAOYSA-M 0.000 description 1
• ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 1
• 229940116357 potassium thiocyanate Drugs 0.000 description 1
• 244000144977 poultry Species 0.000 description 1
• 238000009374 poultry farming Methods 0.000 description 1
• 235000013594 poultry meat Nutrition 0.000 description 1
• 238000012746 preparative thin layer chromatography Methods 0.000 description 1
• 238000012545 processing Methods 0.000 description 1
• 230000002035 prolonged effect Effects 0.000 description 1
• 230000001681 protective effect Effects 0.000 description 1
• 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
• 244000000040 protozoan parasite Species 0.000 description 1
• 229960003351 prussian blue Drugs 0.000 description 1
• 239000013225 prussian blue Substances 0.000 description 1
• 239000008262 pumice Substances 0.000 description 1
• 238000000197 pyrolysis Methods 0.000 description 1
• 239000010453 quartz Substances 0.000 description 1
• 125000001453 quaternary ammonium group Chemical group 0.000 description 1
• 239000000376 reactant Substances 0.000 description 1
• 230000035484 reaction time Effects 0.000 description 1
• 238000006485 reductive methylation reaction Methods 0.000 description 1
• 230000001105 regulatory effect Effects 0.000 description 1
• 230000000717 retained effect Effects 0.000 description 1
• 238000007363 ring formation reaction Methods 0.000 description 1
• XOVSRHHCHKUFKM-UHFFFAOYSA-N s-methylthiohydroxylamine Chemical compound CSN XOVSRHHCHKUFKM-UHFFFAOYSA-N 0.000 description 1
• 230000007017 scission Effects 0.000 description 1
• 238000012216 screening Methods 0.000 description 1
• 239000013049 sediment Substances 0.000 description 1
• 238000004062 sedimentation Methods 0.000 description 1
• 229910052624 sepiolite Inorganic materials 0.000 description 1
• 235000019355 sepiolite Nutrition 0.000 description 1
• 239000003352 sequestering agent Substances 0.000 description 1
• 230000035939 shock Effects 0.000 description 1
• 150000004760 silicates Chemical class 0.000 description 1
• 229910001923 silver oxide Inorganic materials 0.000 description 1
• 229910052708 sodium Inorganic materials 0.000 description 1
• 239000011734 sodium Substances 0.000 description 1
• 229960004599 sodium borate Drugs 0.000 description 1
• HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
• 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
• 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
• HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
• 229920005552 sodium lignosulfonate Polymers 0.000 description 1
• 229940001584 sodium metabisulfite Drugs 0.000 description 1
• 235000010262 sodium metabisulphite Nutrition 0.000 description 1
• RMBAVIFYHOYIFM-UHFFFAOYSA-M sodium methanethiolate Chemical compound [Na+].[S-]C RMBAVIFYHOYIFM-UHFFFAOYSA-M 0.000 description 1
• 239000001488 sodium phosphate Substances 0.000 description 1
• 159000000000 sodium salts Chemical class 0.000 description 1
• 229910052938 sodium sulfate Inorganic materials 0.000 description 1
• 235000011152 sodium sulphate Nutrition 0.000 description 1
• 235000010339 sodium tetraborate Nutrition 0.000 description 1
• HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical group O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
• 239000008279 sol Substances 0.000 description 1
• 230000003381 solubilizing effect Effects 0.000 description 1
• 239000011877 solvent mixture Substances 0.000 description 1
• 235000015040 sparkling wine Nutrition 0.000 description 1
• 238000004611 spectroscopical analysis Methods 0.000 description 1
• 238000001228 spectrum Methods 0.000 description 1
• 230000001954 sterilising effect Effects 0.000 description 1
• 238000004659 sterilization and disinfection Methods 0.000 description 1
• 239000004575 stone Substances 0.000 description 1
• 238000003860 storage Methods 0.000 description 1
• 238000007920 subcutaneous administration Methods 0.000 description 1
• 125000000547 substituted alkyl group Chemical group 0.000 description 1
• 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
• 125000004646 sulfenyl group Chemical group S(*)* 0.000 description 1
• BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
• 150000003871 sulfonates Chemical class 0.000 description 1
• RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
• XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
• 239000013589 supplement Substances 0.000 description 1
• 210000004243 sweat Anatomy 0.000 description 1
• 229920002994 synthetic fiber Polymers 0.000 description 1
• 229920001059 synthetic polymer Polymers 0.000 description 1
• 239000003826 tablet Substances 0.000 description 1
• 239000000454 talc Substances 0.000 description 1
• 235000012222 talc Nutrition 0.000 description 1
• 229910052623 talc Inorganic materials 0.000 description 1
• 239000008399 tap water Substances 0.000 description 1
• 235000020679 tap water Nutrition 0.000 description 1
• 230000008685 targeting Effects 0.000 description 1
• XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
• 235000013616 tea Nutrition 0.000 description 1
• CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
• 239000012085 test solution Substances 0.000 description 1
• 238000012956 testing procedure Methods 0.000 description 1
• 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
• MLGCXEBRWGEOQX-UHFFFAOYSA-N tetradifon Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC(Cl)=C(Cl)C=C1Cl MLGCXEBRWGEOQX-UHFFFAOYSA-N 0.000 description 1
• RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
• 229940124597 therapeutic agent Drugs 0.000 description 1
• 239000002562 thickening agent Substances 0.000 description 1
• 238000004809 thin layer chromatography Methods 0.000 description 1
• 150000003568 thioethers Chemical class 0.000 description 1
• 239000011135 tin Substances 0.000 description 1
• OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
• XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
• 231100000331 toxic Toxicity 0.000 description 1
• 230000002588 toxic effect Effects 0.000 description 1
• 231100000419 toxicity Toxicity 0.000 description 1
• 230000001988 toxicity Effects 0.000 description 1
• 238000012546 transfer Methods 0.000 description 1
• 125000005270 trialkylamine group Chemical group 0.000 description 1
• AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
• QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
• 229940078499 tricalcium phosphate Drugs 0.000 description 1
• 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
• 235000019731 tricalcium phosphate Nutrition 0.000 description 1
• 229940096911 trichinella spiralis Drugs 0.000 description 1
• GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 description 1
• AEXDMFVPDVVSQJ-UHFFFAOYSA-N trifluoro(trifluoromethylsulfonyl)methane Chemical group FC(F)(F)S(=O)(=O)C(F)(F)F AEXDMFVPDVVSQJ-UHFFFAOYSA-N 0.000 description 1
• RQYLOOVORNJDQX-UHFFFAOYSA-N trifluoromethyl thiohypochlorite Chemical compound FC(F)(F)SCl RQYLOOVORNJDQX-UHFFFAOYSA-N 0.000 description 1
• AFZDAWIXETXKRE-UHFFFAOYSA-M triphenyl(prop-2-ynyl)phosphanium;bromide Chemical compound [Br-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CC#C)C1=CC=CC=C1 AFZDAWIXETXKRE-UHFFFAOYSA-M 0.000 description 1
• HHBXWXJLQYJJBW-UHFFFAOYSA-M triphenyl(propan-2-yl)phosphanium;iodide Chemical compound [I-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(C(C)C)C1=CC=CC=C1 HHBXWXJLQYJJBW-UHFFFAOYSA-M 0.000 description 1
• YFMZQCCTZUJXEB-UHFFFAOYSA-N tris(methylsulfanyl)methane Chemical compound CSC(SC)SC YFMZQCCTZUJXEB-UHFFFAOYSA-N 0.000 description 1
• BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
• 239000002966 varnish Substances 0.000 description 1
• 239000013598 vector Substances 0.000 description 1
• 235000015112 vegetable and seed oil Nutrition 0.000 description 1
• 239000008158 vegetable oil Substances 0.000 description 1
• 230000035899 viability Effects 0.000 description 1
• 229920003169 water-soluble polymer Polymers 0.000 description 1
• 210000002268 wool Anatomy 0.000 description 1
• 239000000230 xanthan gum Substances 0.000 description 1
• 229920001285 xanthan gum Polymers 0.000 description 1
• 235000010493 xanthan gum Nutrition 0.000 description 1
• 229940082509 xanthan gum Drugs 0.000 description 1
• 239000008096 xylene Substances 0.000 description 1
• 150000003738 xylenes Chemical class 0.000 description 1
• 150000003751 zinc Chemical class 0.000 description 1