MXPA05000523A - Mezclas de silice-hule que tienen dureza mejorada. - Google Patents
Mezclas de silice-hule que tienen dureza mejorada.Info
- Publication number
- MXPA05000523A MXPA05000523A MXPA05000523A MXPA05000523A MXPA05000523A MX PA05000523 A MXPA05000523 A MX PA05000523A MX PA05000523 A MXPA05000523 A MX PA05000523A MX PA05000523 A MXPA05000523 A MX PA05000523A MX PA05000523 A MXPA05000523 A MX PA05000523A
- Authority
- MX
- Mexico
- Prior art keywords
- group
- silane
- nxt
- silica
- rubber
- Prior art date
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 196
- 239000005060 rubber Substances 0.000 title claims abstract description 187
- 239000000203 mixture Substances 0.000 title claims abstract description 150
- 230000001976 improved effect Effects 0.000 title description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 353
- 229910000077 silane Inorganic materials 0.000 claims abstract description 162
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 158
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 151
- 238000000034 method Methods 0.000 claims abstract description 100
- 229920005989 resin Polymers 0.000 claims abstract description 74
- 239000011347 resin Substances 0.000 claims abstract description 74
- 239000006229 carbon black Substances 0.000 claims abstract description 45
- 230000001965 increasing effect Effects 0.000 claims abstract description 27
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 22
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 11
- 230000009974 thixotropic effect Effects 0.000 claims abstract description 11
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 8
- 125000000962 organic group Chemical group 0.000 claims abstract description 7
- 229910052909 inorganic silicate Inorganic materials 0.000 claims abstract description 5
- -1 ureido, carboxyl Chemical group 0.000 claims description 124
- 229910052717 sulfur Inorganic materials 0.000 claims description 87
- 239000011593 sulfur Substances 0.000 claims description 87
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 86
- 150000004756 silanes Chemical class 0.000 claims description 60
- 125000000217 alkyl group Chemical group 0.000 claims description 37
- 125000003118 aryl group Chemical group 0.000 claims description 31
- 125000004432 carbon atom Chemical group C* 0.000 claims description 30
- 229920001021 polysulfide Polymers 0.000 claims description 29
- 239000005077 polysulfide Substances 0.000 claims description 29
- 150000008117 polysulfides Polymers 0.000 claims description 29
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 26
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 21
- 229920002554 vinyl polymer Polymers 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 20
- 229910052710 silicon Inorganic materials 0.000 claims description 19
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 19
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000001257 hydrogen Chemical group 0.000 claims description 17
- 229910052739 hydrogen Chemical group 0.000 claims description 17
- 239000011256 inorganic filler Substances 0.000 claims description 17
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 17
- JPPLPDOXWBVPCW-UHFFFAOYSA-N s-(3-triethoxysilylpropyl) octanethioate Chemical group CCCCCCCC(=O)SCCC[Si](OCC)(OCC)OCC JPPLPDOXWBVPCW-UHFFFAOYSA-N 0.000 claims description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 13
- 239000004593 Epoxy Substances 0.000 claims description 12
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 12
- 125000005842 heteroatom Chemical group 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 11
- 125000003545 alkoxy group Chemical group 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 10
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical group NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 10
- KBMBVTRWEAAZEY-UHFFFAOYSA-N trisulfane Chemical compound SSS KBMBVTRWEAAZEY-UHFFFAOYSA-N 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 150000004820 halides Chemical class 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 125000004122 cyclic group Chemical group 0.000 claims description 7
- 239000003365 glass fiber Substances 0.000 claims description 7
- 230000002209 hydrophobic effect Effects 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 7
- 230000007704 transition Effects 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229920001903 high density polyethylene Polymers 0.000 claims description 6
- 239000004700 high-density polyethylene Substances 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 5
- 239000007983 Tris buffer Substances 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 5
- 125000000732 arylene group Chemical group 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- 239000004917 carbon fiber Substances 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 5
- 125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 claims description 5
- 239000003446 ligand Substances 0.000 claims description 5
- 239000010445 mica Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 230000001698 pyrogenic effect Effects 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical group [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Chemical group SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 4
- 239000006233 lamp black Substances 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
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- 239000010456 wollastonite Substances 0.000 claims description 4
- 229910052882 wollastonite Inorganic materials 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims description 3
- 239000004702 low-density polyethylene Substances 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 2
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims 4
- YGCCPHYWRAPWIP-UHFFFAOYSA-N (carbamoylamino) thiocyanate Chemical group NC(=O)NSC#N YGCCPHYWRAPWIP-UHFFFAOYSA-N 0.000 claims 2
- 241001300078 Vitrea Species 0.000 claims 2
- 150000002431 hydrogen Chemical group 0.000 claims 2
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004962 Polyamide-imide Substances 0.000 claims 1
- 239000004734 Polyphenylene sulfide Substances 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920002312 polyamide-imide Polymers 0.000 claims 1
- 229920000069 polyphenylene sulfide Polymers 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 97
- 150000001875 compounds Chemical class 0.000 description 160
- 238000006243 chemical reaction Methods 0.000 description 100
- 238000007792 addition Methods 0.000 description 65
- 150000002148 esters Chemical class 0.000 description 64
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical class S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 52
- 239000000945 filler Substances 0.000 description 51
- 235000019241 carbon black Nutrition 0.000 description 43
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 42
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- 125000005023 xylyl group Chemical group 0.000 description 1
- NEYNBSGIXOOZGZ-UHFFFAOYSA-L zinc;butoxymethanedithioate Chemical compound [Zn+2].CCCCOC([S-])=S.CCCCOC([S-])=S NEYNBSGIXOOZGZ-UHFFFAOYSA-L 0.000 description 1
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/549—Silicon-containing compounds containing silicon in a ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39426402P | 2002-07-09 | 2002-07-09 | |
| US45144903P | 2003-03-03 | 2003-03-03 | |
| PCT/US2003/021616 WO2004005395A2 (en) | 2002-07-09 | 2003-07-08 | Silica-rubber mixtures having improved hardness |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA05000523A true MXPA05000523A (es) | 2005-04-19 |
Family
ID=30118407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA05000523A MXPA05000523A (es) | 2002-07-09 | 2003-07-08 | Mezclas de silice-hule que tienen dureza mejorada. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7432321B2 (enExample) |
| EP (1) | EP1551913B1 (enExample) |
| JP (1) | JP4722482B2 (enExample) |
| KR (1) | KR101053009B1 (enExample) |
| CN (2) | CN1681876B (enExample) |
| AU (1) | AU2003249019A1 (enExample) |
| MX (1) | MXPA05000523A (enExample) |
| NZ (1) | NZ537861A (enExample) |
| RU (1) | RU2323230C2 (enExample) |
| TW (1) | TWI324623B (enExample) |
| WO (1) | WO2004005395A2 (enExample) |
| ZA (1) | ZA200500747B (enExample) |
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| US20090143538A1 (en) * | 2004-08-11 | 2009-06-04 | Dow Corning Toray Co., Ltd. | Silane-Coupling-Agent-Treated Silica, Preparation Method Thereof, And Vibration-Damping And Vibration-Isolating Rubber Composition Containing The Same |
| US7928258B2 (en) | 2004-08-20 | 2011-04-19 | Momentive Performance Materials Inc. | Cyclic diol-derived blocked mercaptofunctional silane compositions |
| JP4643207B2 (ja) * | 2004-09-08 | 2011-03-02 | 東洋ゴム工業株式会社 | 空気入りタイヤ用ゴム組成物及び空気入りタイヤ |
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| US7510670B2 (en) | 2006-02-21 | 2009-03-31 | Momentive Performance Materials Inc. | Free flowing filler composition based on organofunctional silane |
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| US7968636B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing silated cyclic core polysulfides |
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| US6080809A (en) | 1997-07-30 | 2000-06-27 | Bridgestone/Firestone, Inc. | Kaolin clay in silica tread compounds technical field |
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| EP1034083A1 (en) | 1997-10-30 | 2000-09-13 | The Goodyear Tire & Rubber Company | Tires having improved high speed properties |
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| US6075096A (en) * | 1998-02-27 | 2000-06-13 | The Goodyear Tire & Rubber Company | Rubber compounds containing aromatic ketone polysulfides |
| DE19814655A1 (de) * | 1998-04-01 | 1999-10-07 | Bayer Ag | Trimethylolpropan-Destillationsrückstände enthaltende Kautschukmischungen |
| DE19814839A1 (de) * | 1998-04-02 | 1999-10-07 | Bayer Ag | Hydrophobierte oxidische oder silikatische Füllstoffe enthaltende Emulsionskautschukmischungen sowie deren Verwendung zur Herstellung von Reifen |
| US6014998A (en) | 1998-06-09 | 2000-01-18 | Pirelli Pneumatici S.P.A. | Silica-reinforced tire compositions containing triazoles |
| JP4363697B2 (ja) * | 1998-06-25 | 2009-11-11 | 株式会社ブリヂストン | タイヤトレッド用ゴム組成物及びそのゴム組成物を使用した空気入りタイヤ |
| KR100505325B1 (ko) | 1998-11-11 | 2005-10-14 | 한국타이어 주식회사 | 타이어 트레드용 고무조성물 |
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| JP2000189710A (ja) | 1998-12-31 | 2000-07-11 | Dow Corning Corp | 超高分子量樹脂を含有する泡止め組成物 |
| US6075087A (en) * | 1998-12-31 | 2000-06-13 | Dow Corning Corporation | Resin-fillers produced in-situ in silicone polymer compositions method for preparation of the compositions |
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| DE19954815C1 (de) * | 1999-11-13 | 2001-06-07 | Degussa | Verfahren zur Herstellung von schwefel- und phosphorhaltigen Organosiliziumverbindungen |
| EP1113036B1 (en) | 1999-12-28 | 2005-12-21 | General Electric Company | Continuous process for producing a silicon resin |
| CA2352927C (en) | 2000-07-14 | 2008-03-18 | Sumitomo Rubber Industries, Ltd. | Rubber composition for tyre tread |
| CA2417681A1 (fr) * | 2000-07-31 | 2002-02-07 | Michelin Recherche Et Technique S.A. | Bande de roulement pour pneumatique |
| US7301042B2 (en) * | 2002-04-23 | 2007-11-27 | Cruse Richard W | Blocked mercaptosilane hydrolyzates as coupling agents for mineral-filled elastomer compositions |
| US7432321B2 (en) | 2002-07-09 | 2008-10-07 | Momentive Performance Materials Inc. | Silica-rubber mixtures having improved hardness |
| US7138537B2 (en) * | 2003-04-02 | 2006-11-21 | General Electric Company | Coupling agents for mineral-filled elastomer compositions |
-
2003
- 2003-07-08 US US10/617,165 patent/US7432321B2/en not_active Expired - Lifetime
- 2003-07-08 NZ NZ537861A patent/NZ537861A/en unknown
- 2003-07-08 KR KR1020057000489A patent/KR101053009B1/ko not_active Expired - Lifetime
- 2003-07-08 CN CN038213427A patent/CN1681876B/zh not_active Expired - Lifetime
- 2003-07-08 AU AU2003249019A patent/AU2003249019A1/en not_active Abandoned
- 2003-07-08 RU RU2005103236/04A patent/RU2323230C2/ru not_active IP Right Cessation
- 2003-07-08 EP EP03763461.5A patent/EP1551913B1/en not_active Expired - Lifetime
- 2003-07-08 WO PCT/US2003/021616 patent/WO2004005395A2/en not_active Ceased
- 2003-07-08 MX MXPA05000523A patent/MXPA05000523A/es unknown
- 2003-07-08 CN CN2010102296295A patent/CN101880415B/zh not_active Expired - Lifetime
- 2003-07-08 JP JP2004520123A patent/JP4722482B2/ja not_active Expired - Lifetime
- 2003-07-09 TW TW092118707A patent/TWI324623B/zh not_active IP Right Cessation
-
2005
- 2005-01-25 ZA ZA200500747A patent/ZA200500747B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004005395A2 (en) | 2004-01-15 |
| NZ537861A (en) | 2008-09-26 |
| CN1681876B (zh) | 2012-05-30 |
| US20050277717A1 (en) | 2005-12-15 |
| TWI324623B (en) | 2010-05-11 |
| JP2005533140A (ja) | 2005-11-04 |
| WO2004005395A3 (en) | 2004-08-05 |
| ZA200500747B (en) | 2006-04-26 |
| EP1551913B1 (en) | 2021-03-31 |
| TW200417569A (en) | 2004-09-16 |
| JP4722482B2 (ja) | 2011-07-13 |
| US7432321B2 (en) | 2008-10-07 |
| CN101880415B (zh) | 2013-05-22 |
| KR20050025962A (ko) | 2005-03-14 |
| RU2005103236A (ru) | 2005-08-27 |
| CN101880415A (zh) | 2010-11-10 |
| RU2323230C2 (ru) | 2008-04-27 |
| KR101053009B1 (ko) | 2011-07-29 |
| EP1551913A2 (en) | 2005-07-13 |
| CN1681876A (zh) | 2005-10-12 |
| AU2003249019A1 (en) | 2004-01-23 |
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