AU2003249019A1 - Silica-rubber mixtures having improved hardness - Google Patents
Silica-rubber mixtures having improved hardness Download PDFInfo
- Publication number
- AU2003249019A1 AU2003249019A1 AU2003249019A AU2003249019A AU2003249019A1 AU 2003249019 A1 AU2003249019 A1 AU 2003249019A1 AU 2003249019 A AU2003249019 A AU 2003249019A AU 2003249019 A AU2003249019 A AU 2003249019A AU 2003249019 A1 AU2003249019 A1 AU 2003249019A1
- Authority
- AU
- Australia
- Prior art keywords
- group
- silane
- nxt
- silica
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920001971 elastomer Polymers 0.000 title claims description 195
- 239000005060 rubber Substances 0.000 title claims description 185
- 239000000203 mixture Substances 0.000 title claims description 139
- 230000001976 improved effect Effects 0.000 title description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 305
- 229910000077 silane Inorganic materials 0.000 claims description 168
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 155
- 239000000377 silicon dioxide Substances 0.000 claims description 135
- -1 ureido, carboxyl Chemical group 0.000 claims description 106
- 238000000034 method Methods 0.000 claims description 99
- 238000002156 mixing Methods 0.000 claims description 83
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 76
- 229910052717 sulfur Inorganic materials 0.000 claims description 76
- 239000011593 sulfur Substances 0.000 claims description 73
- 229920005989 resin Polymers 0.000 claims description 70
- 239000011347 resin Substances 0.000 claims description 70
- 150000004756 silanes Chemical class 0.000 claims description 68
- 239000006229 carbon black Substances 0.000 claims description 47
- 125000000217 alkyl group Chemical group 0.000 claims description 38
- 125000004432 carbon atom Chemical group C* 0.000 claims description 30
- 125000003118 aryl group Chemical group 0.000 claims description 28
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 25
- 229920001021 polysulfide Polymers 0.000 claims description 24
- 239000005077 polysulfide Substances 0.000 claims description 24
- 150000008117 polysulfides Polymers 0.000 claims description 24
- 229910021485 fumed silica Inorganic materials 0.000 claims description 20
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 20
- JPPLPDOXWBVPCW-UHFFFAOYSA-N s-(3-triethoxysilylpropyl) octanethioate Chemical group CCCCCCCC(=O)SCCC[Si](OCC)(OCC)OCC JPPLPDOXWBVPCW-UHFFFAOYSA-N 0.000 claims description 20
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 19
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 239000011256 inorganic filler Substances 0.000 claims description 17
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 17
- 229920002554 vinyl polymer Polymers 0.000 claims description 17
- 125000003545 alkoxy group Chemical group 0.000 claims description 15
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 15
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 14
- 229910052710 silicon Inorganic materials 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000004593 Epoxy Substances 0.000 claims description 12
- 125000005842 heteroatom Chemical group 0.000 claims description 12
- 239000003365 glass fiber Substances 0.000 claims description 11
- 229920005992 thermoplastic resin Polymers 0.000 claims description 11
- 239000005995 Aluminium silicate Substances 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims description 10
- 239000004927 clay Substances 0.000 claims description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 10
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 10
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 10
- KBMBVTRWEAAZEY-UHFFFAOYSA-N trisulfane Chemical compound SSS KBMBVTRWEAAZEY-UHFFFAOYSA-N 0.000 claims description 10
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 9
- 239000004917 carbon fiber Substances 0.000 claims description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 150000004820 halides Chemical class 0.000 claims description 9
- 239000010445 mica Substances 0.000 claims description 9
- 229910052618 mica group Inorganic materials 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 239000000454 talc Substances 0.000 claims description 9
- 229910052623 talc Inorganic materials 0.000 claims description 9
- 230000009974 thixotropic effect Effects 0.000 claims description 9
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 8
- 230000009477 glass transition Effects 0.000 claims description 8
- 229920001187 thermosetting polymer Polymers 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 230000001698 pyrogenic effect Effects 0.000 claims description 7
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 6
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 229920001903 high density polyethylene Polymers 0.000 claims description 6
- 239000004700 high-density polyethylene Substances 0.000 claims description 6
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 6
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 125000000962 organic group Chemical group 0.000 claims description 6
- 125000001424 substituent group Chemical group 0.000 claims description 6
- 239000007983 Tris buffer Substances 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 5
- 125000000732 arylene group Chemical group 0.000 claims description 5
- 125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims description 4
- 239000004702 low-density polyethylene Substances 0.000 claims description 3
- 229940099514 low-density polyethylene Drugs 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims 8
- 125000005843 halogen group Chemical group 0.000 claims 4
- 150000002431 hydrogen Chemical group 0.000 claims 4
- 229910020485 SiO4/2 Inorganic materials 0.000 claims 2
- 239000004962 Polyamide-imide Substances 0.000 claims 1
- 239000004642 Polyimide Substances 0.000 claims 1
- 239000004734 Polyphenylene sulfide Substances 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
- 229920002312 polyamide-imide Polymers 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 229920000069 polyphenylene sulfide Polymers 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 144
- 238000006243 chemical reaction Methods 0.000 description 99
- 150000002148 esters Chemical group 0.000 description 67
- 238000007792 addition Methods 0.000 description 59
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical class S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 56
- 239000000945 filler Substances 0.000 description 51
- 238000011068 loading method Methods 0.000 description 47
- 235000019241 carbon black Nutrition 0.000 description 44
- 239000003795 chemical substances by application Substances 0.000 description 38
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 35
- 230000000694 effects Effects 0.000 description 35
- 239000003054 catalyst Substances 0.000 description 28
- 239000000047 product Substances 0.000 description 27
- 230000008569 process Effects 0.000 description 25
- 239000005062 Polybutadiene Substances 0.000 description 24
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 24
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 24
- 239000002904 solvent Substances 0.000 description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 23
- 239000002253 acid Substances 0.000 description 23
- 150000003839 salts Chemical class 0.000 description 23
- 230000000903 blocking effect Effects 0.000 description 22
- 125000000524 functional group Chemical group 0.000 description 21
- 239000000243 solution Substances 0.000 description 20
- 229910052783 alkali metal Inorganic materials 0.000 description 19
- FYYIUODUDSPAJQ-XVBQNVSMSA-N [(1S,6R)-7-oxabicyclo[4.1.0]heptan-3-yl]methyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1CC[C@H]2O[C@H]2C1 FYYIUODUDSPAJQ-XVBQNVSMSA-N 0.000 description 18
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- 238000004073 vulcanization Methods 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
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- 150000001340 alkali metals Chemical class 0.000 description 9
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- DUYAAUVXQSMXQP-UHFFFAOYSA-N ethanethioic S-acid Chemical compound CC(S)=O DUYAAUVXQSMXQP-UHFFFAOYSA-N 0.000 description 8
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- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 239000003586 protic polar solvent Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 239000004943 rubber silane Substances 0.000 description 1
- WHALSQRTWNBBCV-UHFFFAOYSA-N s-aminosulfanylthiohydroxylamine Chemical compound NSSN WHALSQRTWNBBCV-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 229940024463 silicone emollient and protective product Drugs 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- APARIAFVBSRIHF-UHFFFAOYSA-M sodium;methanethioate Chemical class [Na+].[O-]C=S APARIAFVBSRIHF-UHFFFAOYSA-M 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- KHTZKHQMYLOHFT-UHFFFAOYSA-N sulfanylidene-(3-triethoxysilylpropoxy)-bis(3-triethoxysilylpropylsulfanyl)-$l^{5}-phosphane Chemical compound CCO[Si](OCC)(OCC)CCCOP(=S)(SCCC[Si](OCC)(OCC)OCC)SCCC[Si](OCC)(OCC)OCC KHTZKHQMYLOHFT-UHFFFAOYSA-N 0.000 description 1
- VGGJNLGZARHOQV-UHFFFAOYSA-N sulfanylidene-tris(3-triethoxysilylpropylsulfanyl)-$l^{5}-phosphane Chemical compound CCO[Si](OCC)(OCC)CCCSP(=S)(SCCC[Si](OCC)(OCC)OCC)SCCC[Si](OCC)(OCC)OCC VGGJNLGZARHOQV-UHFFFAOYSA-N 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical group [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 125000001010 sulfinic acid amide group Chemical group 0.000 description 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 238000010059 sulfur vulcanization Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- 150000008111 thiosulfinates Chemical class 0.000 description 1
- GWIKYPMLNBTJHR-UHFFFAOYSA-M thiosulfonate group Chemical group S(=S)(=O)[O-] GWIKYPMLNBTJHR-UHFFFAOYSA-M 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- RVXDOOILWAALRJ-UHFFFAOYSA-N tributoxy-[(tributoxysilylmethyldisulfanyl)methyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CSSC[Si](OCCCC)(OCCCC)OCCCC RVXDOOILWAALRJ-UHFFFAOYSA-N 0.000 description 1
- KFZYOLRKZIKUSD-UHFFFAOYSA-N triethoxy(2-hydroxysulfonothioylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CCS(O)(=O)=S KFZYOLRKZIKUSD-UHFFFAOYSA-N 0.000 description 1
- BRTXVSVHFSOGED-UHFFFAOYSA-N triethoxy(4-hydroxysulfonothioylbutyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCCS(O)(=O)=S BRTXVSVHFSOGED-UHFFFAOYSA-N 0.000 description 1
- SHQJOFANKPSLCU-UHFFFAOYSA-N triethoxy-(4-hydroxysulfonothioyl-4-propyl-3H-naphthalen-2-yl)silane Chemical compound C1=CC=C2C(CCC)(S(O)(=O)=S)CC([Si](OCC)(OCC)OCC)=CC2=C1 SHQJOFANKPSLCU-UHFFFAOYSA-N 0.000 description 1
- XGCGZQRQPNUUPB-UHFFFAOYSA-N triethoxy-(5-hydroxysulfonothioyl-5-propylcyclohexa-1,3-dien-1-yl)silane Chemical compound CCCC1(S(O)(=O)=S)CC([Si](OCC)(OCC)OCC)=CC=C1 XGCGZQRQPNUUPB-UHFFFAOYSA-N 0.000 description 1
- ZQFHHQHREABVNX-UHFFFAOYSA-N triethoxy-(propyldisulfanyl)silane Chemical compound CCCSS[Si](OCC)(OCC)OCC ZQFHHQHREABVNX-UHFFFAOYSA-N 0.000 description 1
- NESLVXDUKMNMOG-UHFFFAOYSA-N triethoxy-(propyltetrasulfanyl)silane Chemical compound CCCSSSS[Si](OCC)(OCC)OCC NESLVXDUKMNMOG-UHFFFAOYSA-N 0.000 description 1
- FVCAMBAGVUGJHH-UHFFFAOYSA-N triethoxy-[5-(hydroxysulfonothioylmethyl)-5-propylcyclohexa-1,3-dien-1-yl]silane Chemical compound CCCC1(CC(=CC=C1)[Si](OCC)(OCC)OCC)CS(=O)(=S)O FVCAMBAGVUGJHH-UHFFFAOYSA-N 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- HIZCIEIDIFGZSS-UHFFFAOYSA-L trithiocarbonate Chemical compound [S-]C([S-])=S HIZCIEIDIFGZSS-UHFFFAOYSA-L 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- NEYNBSGIXOOZGZ-UHFFFAOYSA-L zinc;butoxymethanedithioate Chemical compound [Zn+2].CCCCOC([S-])=S.CCCCOC([S-])=S NEYNBSGIXOOZGZ-UHFFFAOYSA-L 0.000 description 1
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/549—Silicon-containing compounds containing silicon in a ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39426402P | 2002-07-09 | 2002-07-09 | |
| US60/394,264 | 2002-07-09 | ||
| US45144903P | 2003-03-03 | 2003-03-03 | |
| US60/451,449 | 2003-03-03 | ||
| PCT/US2003/021616 WO2004005395A2 (en) | 2002-07-09 | 2003-07-08 | Silica-rubber mixtures having improved hardness |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2003249019A1 true AU2003249019A1 (en) | 2004-01-23 |
Family
ID=30118407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2003249019A Abandoned AU2003249019A1 (en) | 2002-07-09 | 2003-07-08 | Silica-rubber mixtures having improved hardness |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7432321B2 (enExample) |
| EP (1) | EP1551913B1 (enExample) |
| JP (1) | JP4722482B2 (enExample) |
| KR (1) | KR101053009B1 (enExample) |
| CN (2) | CN1681876B (enExample) |
| AU (1) | AU2003249019A1 (enExample) |
| MX (1) | MXPA05000523A (enExample) |
| NZ (1) | NZ537861A (enExample) |
| RU (1) | RU2323230C2 (enExample) |
| TW (1) | TWI324623B (enExample) |
| WO (1) | WO2004005395A2 (enExample) |
| ZA (1) | ZA200500747B (enExample) |
Families Citing this family (108)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7432321B2 (en) | 2002-07-09 | 2008-10-07 | Momentive Performance Materials Inc. | Silica-rubber mixtures having improved hardness |
| EP1559744A1 (en) * | 2004-01-30 | 2005-08-03 | Rhodia Chimie | Use of a pretreated precipitated silica as a reinforcing filler for silicone elastomer and curable compositions thus obtained |
| GB0402972D0 (en) * | 2004-02-11 | 2004-03-17 | Dow Corning Ltd | Process for making filled silicone rubber compositions |
| JP4555011B2 (ja) * | 2004-07-20 | 2010-09-29 | 東洋ゴム工業株式会社 | スタッドレスタイヤ用ゴム組成物及びスタッドレスタイヤ |
| US20090143538A1 (en) * | 2004-08-11 | 2009-06-04 | Dow Corning Toray Co., Ltd. | Silane-Coupling-Agent-Treated Silica, Preparation Method Thereof, And Vibration-Damping And Vibration-Isolating Rubber Composition Containing The Same |
| US7928258B2 (en) | 2004-08-20 | 2011-04-19 | Momentive Performance Materials Inc. | Cyclic diol-derived blocked mercaptofunctional silane compositions |
| JP4643207B2 (ja) * | 2004-09-08 | 2011-03-02 | 東洋ゴム工業株式会社 | 空気入りタイヤ用ゴム組成物及び空気入りタイヤ |
| JP5006532B2 (ja) * | 2004-09-08 | 2012-08-22 | 東洋ゴム工業株式会社 | 冬用空気入りタイヤ用ゴム組成物及び冬用空気入りタイヤ |
| JP4762562B2 (ja) * | 2005-02-01 | 2011-08-31 | 東洋ゴム工業株式会社 | 空気入りタイヤ用ゴム組成物 |
| JP4762563B2 (ja) * | 2005-02-02 | 2011-08-31 | 東洋ゴム工業株式会社 | 空気入りタイヤ用ゴム組成物 |
| JP4421547B2 (ja) * | 2005-02-10 | 2010-02-24 | 住友ゴム工業株式会社 | ゴム組成物およびそれを用いたトレッドを有するタイヤ |
| EP1871824B1 (en) | 2005-03-24 | 2017-03-01 | Bridgestone Corporation | Compounding silica-reinforced rubber with low volatile organic compound (voc) emission |
| KR100608139B1 (ko) * | 2005-06-09 | 2006-08-02 | 금호타이어 주식회사 | 실리카 친화형 타이어 트레드 고무 조성물 |
| JP5044903B2 (ja) * | 2005-08-01 | 2012-10-10 | 横浜ゴム株式会社 | タイヤ用ゴム組成物 |
| US20070037908A1 (en) * | 2005-08-09 | 2007-02-15 | Wolfgang Pille-Wolf | Rubber compositions containing improved tackifiers |
| JP4813845B2 (ja) * | 2005-08-09 | 2011-11-09 | 東洋ゴム工業株式会社 | 空気入りタイヤ用ゴム組成物及び空気入りタイヤ |
| JP2007051170A (ja) * | 2005-08-12 | 2007-03-01 | Toyo Tire & Rubber Co Ltd | タイヤトレッド用ゴム組成物及び空気入りタイヤ |
| JP5006531B2 (ja) * | 2005-09-06 | 2012-08-22 | 東洋ゴム工業株式会社 | 冬用空気入りタイヤ用ゴム組成物及び冬用空気入りタイヤ |
| US7504456B2 (en) | 2006-02-21 | 2009-03-17 | Momentive Performance Materials Inc. | Rubber composition containing organofunctional silane |
| US7510670B2 (en) | 2006-02-21 | 2009-03-31 | Momentive Performance Materials Inc. | Free flowing filler composition based on organofunctional silane |
| US7919650B2 (en) | 2006-02-21 | 2011-04-05 | Momentive Performance Materials Inc. | Organofunctional silanes and their mixtures |
| US7514494B2 (en) * | 2006-04-26 | 2009-04-07 | The Goodyear Tire & Rubber Company | Pneumatic tire containing a silica pretreated with a fluorinated silane |
| EP1884376B1 (en) * | 2006-08-03 | 2010-02-10 | The Yokohama Rubber Co., Ltd. | Pneumatic tire |
| US7368584B2 (en) | 2006-08-14 | 2008-05-06 | Momentive Performance Materials Inc. | Mercapto-functional silane |
| US7550540B2 (en) | 2006-08-14 | 2009-06-23 | Momentive Performance Materials Inc. | Rubber composition and articles therefrom both comprising mercapto-functional silane |
| US7550524B2 (en) | 2006-10-06 | 2009-06-23 | Momentive Performance Materials Inc. | Elastomer composition containing mercaptofunctional silane and process for making same |
| US20080114134A1 (en) | 2006-11-14 | 2008-05-15 | General Electric Company | Process for crosslinking thermoplastic polymers with silanes employing peroxide blends, the resulting crosslinked thermoplastic polymer composition and articles made therefrom |
| US7687558B2 (en) | 2006-12-28 | 2010-03-30 | Momentive Performance Materials Inc. | Silated cyclic core polysulfides, their preparation and use in filled elastomer compositions |
| US7960460B2 (en) | 2006-12-28 | 2011-06-14 | Momentive Performance Materials, Inc. | Free-flowing filler composition and rubber composition containing same |
| US8592506B2 (en) * | 2006-12-28 | 2013-11-26 | Continental Ag | Tire compositions and components containing blocked mercaptosilane coupling agent |
| US7696269B2 (en) | 2006-12-28 | 2010-04-13 | Momentive Performance Materials Inc. | Silated core polysulfides, their preparation and use in filled elastomer compositions |
| US7968635B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing free-flowing filler compositions |
| US7968633B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing free-flowing filler compositions |
| US7968634B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing silated core polysulfides |
| US7968636B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing silated cyclic core polysulfides |
| US7592384B2 (en) * | 2006-12-29 | 2009-09-22 | Shaun Fox | Elatomeric composition containing multiple silane coupling agents |
| JP4843549B2 (ja) * | 2007-04-04 | 2011-12-21 | 住友ゴム工業株式会社 | ゴム組成物 |
| US8501895B2 (en) | 2007-05-23 | 2013-08-06 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes |
| US7915368B2 (en) | 2007-05-23 | 2011-03-29 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes |
| US10023723B2 (en) * | 2007-06-05 | 2018-07-17 | Momentive Performance Materials Inc. | Process for preparing rubber compositions and articles made therefrom |
| WO2009004918A1 (ja) * | 2007-07-03 | 2009-01-08 | The Yokohama Rubber Co., Ltd. | 硫黄含有共役ジオレフィン系共重合体ゴム及びそれを含むゴム組成物 |
| FR2918384A1 (fr) * | 2007-07-06 | 2009-01-09 | Rhodia Operations Sas | Materiau composite de faible densite |
| CN101157844B (zh) * | 2007-09-20 | 2010-07-07 | 卢儒 | 耐火云母带专用有机硅粘合剂及生产方法 |
| KR100869904B1 (ko) * | 2007-09-21 | 2008-11-24 | 금호타이어 주식회사 | 내마모 성능이 향상된 타이어 트레드용 고무 조성물 |
| US7816435B2 (en) | 2007-10-31 | 2010-10-19 | Momentive Performance Materials Inc. | Halo-functional silane, process for its preparation, rubber composition containing same and articles manufactured therefrom |
| GB0723384D0 (en) | 2007-11-29 | 2008-01-09 | Dow Corning | Filled rubber compositions |
| US8962746B2 (en) | 2007-12-27 | 2015-02-24 | Bridgestone Corporation | Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds |
| US8513371B2 (en) | 2007-12-31 | 2013-08-20 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxanes and method of preparation |
| US8794282B2 (en) | 2007-12-31 | 2014-08-05 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
| WO2009088483A1 (en) * | 2008-01-02 | 2009-07-16 | East Carolina University | Emergency snake bite treatment devices, medical kits and related methods |
| JP5414182B2 (ja) * | 2008-01-11 | 2014-02-12 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
| JP5463042B2 (ja) * | 2008-01-17 | 2014-04-09 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
| DE102008016338A1 (de) * | 2008-03-28 | 2009-10-01 | Continental Aktiengesellschaft | Kautschukmischung und daraus hergestellte Reifen |
| JP5656366B2 (ja) * | 2008-04-30 | 2015-01-21 | 株式会社ブリヂストン | 変性重合体を含有するゴム組成物を使用したタイヤ |
| US8227538B2 (en) * | 2008-06-05 | 2012-07-24 | Continental Ag | Rubber mixture with improved abrasion |
| JP5487566B2 (ja) * | 2008-06-23 | 2014-05-07 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物 |
| JP5711870B2 (ja) * | 2008-11-05 | 2015-05-07 | 株式会社森清化工 | 封止材 |
| FR2940301B1 (fr) * | 2008-12-22 | 2012-07-27 | Michelin Soc Tech | Composition de caoutchouc comportant un agent de couplage mercaptosilane bloque |
| FR2940302B1 (fr) * | 2008-12-22 | 2012-07-27 | Michelin Soc Tech | Composition de caoutchouc comportant un agent de couplage mercaptosilane bloque |
| US7935283B2 (en) * | 2009-01-09 | 2011-05-03 | Honeywell International Inc. | Melt spinning blends of UHMWPE and HDPE and fibers made therefrom |
| TWI491619B (zh) * | 2009-10-21 | 2015-07-11 | Jsr Corp | A method for producing a conjugated diene rubber, a modified conjugated diene rubber, and a rubber composition |
| US20110105669A1 (en) * | 2009-10-30 | 2011-05-05 | Flexsys America L.P. | Process of forming vulcanizable elastomeric compositions using ultra accelerators and products formed therefrom |
| US8642691B2 (en) | 2009-12-28 | 2014-02-04 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
| TWI404874B (zh) * | 2010-06-18 | 2013-08-11 | Sanwu Rubber Mfg Co Ltd | 多槽傳動皮帶及其製造方法 |
| JP2012057001A (ja) * | 2010-09-07 | 2012-03-22 | Yokohama Rubber Co Ltd:The | コンベヤベルト用ゴム組成物およびコンベヤベルト |
| IT1403424B1 (it) * | 2010-12-23 | 2013-10-17 | Bridgestone Corp | Metodo per la preparazione di una mescola per battistrada |
| JP5698050B2 (ja) * | 2011-03-29 | 2015-04-08 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| CN103492471B (zh) * | 2011-04-22 | 2015-04-29 | 横滨橡胶株式会社 | 轮胎用橡胶组合物以及无钉轮胎 |
| EP2703441B1 (en) * | 2011-04-28 | 2016-03-30 | Bridgestone Corporation | Rubber composition |
| BR112013027610A2 (pt) * | 2011-04-28 | 2017-02-14 | Bridgestone Corp | composição de borracha |
| US9267019B2 (en) | 2011-06-15 | 2016-02-23 | Lion Copolymer Holdings, Llc | Functionalized silica for silica wet masterbatches and styrene butadiene rubber compositions |
| RU2491306C2 (ru) * | 2011-07-20 | 2013-08-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Московский государственный университет тонких химических технологий имени М.В. Ломоносова" (МИТХТ им. М.В.Ломоносова) | Резиновые смеси на основе диеновых и этиленпропиленовых каучуков, наполненные белой сажей |
| US8927652B2 (en) * | 2012-12-07 | 2015-01-06 | Ppg Industries Ohio, Inc. | Coating compositions for food and beverage containers |
| CN102492190B (zh) * | 2011-11-21 | 2014-08-13 | 夏华松 | 用于制造防火耐高温特种安全轮胎的材料 |
| US8835536B2 (en) * | 2012-02-02 | 2014-09-16 | Lion Copolymer Holdings, Llc | Highly silica loaded styrene butadiene rubber masterbatch |
| WO2014018980A1 (en) * | 2012-07-27 | 2014-01-30 | Lion Copolymer, Llc | Functionalized silica for silica wet masterbatches and styrene butadiene rubber compositions |
| US9434870B2 (en) | 2012-09-19 | 2016-09-06 | Momentive Performance Materials Inc. | Thermally conductive plastic compositions, extrusion apparatus and methods for making thermally conductive plastics |
| US8946333B2 (en) | 2012-09-19 | 2015-02-03 | Momentive Performance Materials Inc. | Thermally conductive plastic compositions, extrusion apparatus and methods for making thermally conductive plastics |
| US20150274930A1 (en) * | 2012-09-19 | 2015-10-01 | Momentive Performance Materials Inc. | Masterbatch comprising boron nitride, composite powders thereof, and compositions and articles comprising such materials |
| CN103865379A (zh) * | 2012-12-11 | 2014-06-18 | 深圳富泰宏精密工业有限公司 | 聚二甲基硅氧烷溶胶，应用该聚二甲基硅氧烷溶胶对金属基体进行表面处理的方法及制品 |
| ITRM20130398A1 (it) * | 2013-07-08 | 2015-01-09 | Bridgestone Corp | Metodo per la preparazione di una mescola in gomma per pneumatici |
| ITRM20130424A1 (it) * | 2013-07-18 | 2015-01-19 | Bridgestone Corp | Metodo per la preparazione di una mescola in gomma per pneumatici |
| KR101572106B1 (ko) * | 2013-08-20 | 2015-11-26 | 한국타이어 주식회사 | 타이어 트레드용 고무 조성물 및 이를 이용하여 제조한 타이어 |
| US9463997B2 (en) * | 2013-08-28 | 2016-10-11 | Shin-Etsu Chemical Co., Ltd. | Composite particle, method of producing same, resin composition containing the particle, reflector formed from the composition, and light-emitting semiconductor device using the reflector |
| US8813802B1 (en) | 2013-11-13 | 2014-08-26 | The Goodyear Tire & Rubber Company | Pneumatic tire with rubber component containing thermoplastic/filler composite |
| JP6181529B2 (ja) | 2013-11-25 | 2017-08-16 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| WO2015100449A2 (en) | 2013-12-27 | 2015-07-02 | Bridgestone Corporation | Vulcanizates and tire components prepared from compositions including mercapto-functional siloxanes |
| JP6481255B2 (ja) * | 2014-03-24 | 2019-03-13 | 横浜ゴム株式会社 | タイヤ用ゴム組成物 |
| CA2964346C (en) * | 2014-10-24 | 2020-07-21 | Exxonmobil Chemical Patents Inc. | Chain end functionalized polyolefins for improving wet traction and rolling resistance of tire treads |
| JP2015096614A (ja) * | 2014-12-08 | 2015-05-21 | 株式会社森清化工 | 封止材 |
| EP3241221A4 (en) | 2014-12-31 | 2018-08-08 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for adhering steel alloy to rubber |
| CN105037895A (zh) * | 2015-08-21 | 2015-11-11 | 安徽吉安特种线缆制造有限公司 | 一种新型耐高温低烟阻燃的复合电缆料及其制备方法 |
| JP6633972B2 (ja) * | 2016-05-27 | 2020-01-22 | 株式会社ブリヂストン | 空気入りタイヤ |
| KR101878260B1 (ko) * | 2016-09-22 | 2018-07-13 | 금호타이어 주식회사 | 타이어 트레드용 고무 조성물 |
| WO2018128141A1 (ja) * | 2017-01-06 | 2018-07-12 | 住友ゴム工業株式会社 | 加硫後ゴム組成物及び空気入りタイヤ |
| JP6890475B2 (ja) * | 2017-06-07 | 2021-06-18 | 株式会社ブリヂストン | タイヤ用ゴム組成物及びタイヤ |
| US10328311B2 (en) | 2017-06-09 | 2019-06-25 | Acushnet Company | Golf ball incorporating at least one cast layer of thermoset polymer mixture having a centering time that is independent of cure time and is lower than the centering time of the thermoset polymer composition portion of the mixture |
| US10427003B2 (en) | 2017-06-28 | 2019-10-01 | Acushnet Company | Golf ball having at least one layer consisting of a mixture of a thermoset or thermoplastic composition and a plurality of alkoxylated siloxane-surface treated particles and/or polyether-modified siloxane-surface treated particles |
| JP6917455B2 (ja) | 2017-07-12 | 2021-08-11 | 大塚化学株式会社 | ゴム組成物及びタイヤ |
| EP3661764A1 (en) | 2017-08-04 | 2020-06-10 | Rhodia Operations | Elastomer composition comprising precipitated silica and a sulfur-containing aromatic polymer |
| MX2021005211A (es) | 2018-11-05 | 2021-07-21 | Momentive Performance Mat Inc | Composiciones de silano que forman red polimerica. |
| CN113710739A (zh) * | 2019-05-28 | 2021-11-26 | 花王株式会社 | 橡胶用添加剂 |
| CA3142527A1 (en) | 2019-06-05 | 2020-12-10 | Beyond Lotus Llc | Methods of preparing a composite having elastomer and filler |
| CN110467366B (zh) * | 2019-08-23 | 2022-01-04 | 广东中南建设有限公司 | 节能环保的建筑施工用机制砂 |
| KR20220063373A (ko) | 2020-11-10 | 2022-05-17 | 현대자동차주식회사 | 타이어 트레드용 조성물 및 이를 이용하여 제조된 타이어 트레드 |
| JP2022107374A (ja) * | 2021-01-08 | 2022-07-21 | 昭和電工マテリアルズ株式会社 | 熱硬化性樹脂組成物の製造方法、熱硬化性樹脂組成物、及び電子部品装置 |
| CN114106033B (zh) * | 2021-12-02 | 2024-02-27 | 山东阳谷华泰化工股份有限公司 | 一种3-烃基丙基硫醚基三乙氧基硅烷及其制备方法和应用 |
| CN114479294A (zh) * | 2022-03-25 | 2022-05-13 | 厦门万新橡胶有限公司 | 一种改性SiO2三元乙丙橡胶材料及其制备方法 |
Family Cites Families (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL128384C (enExample) * | 1965-07-15 | 1900-01-01 | ||
| DE2035778C3 (de) * | 1970-07-18 | 1980-06-19 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Thiocyanatopropyl-organooxYsilane und sie enthaltende Formmmassen |
| US3692812A (en) * | 1971-04-21 | 1972-09-19 | Gen Electric | Method of producing alkoxy-substituted mercaptoalkyl silanes |
| BE790735A (fr) * | 1971-11-03 | 1973-02-15 | Dynamit Nobel Ag | Application de phosphoro-organosilanes comme promoteurs d'adhesion |
| SU443881A1 (ru) * | 1973-03-09 | 1974-09-25 | Предприятие П/Я Г-4236 | Вулканизуема резинова смесь |
| AT332642B (de) * | 1973-10-11 | 1976-10-11 | Degussa | Vulkanisierbare kautschukmischungen fur reifen-laufflachen und vormischung hiefur |
| AR207457A1 (es) * | 1974-01-10 | 1976-10-08 | Degussa | Mezcla adhesiva de caucho para mejorar la adhesividad de mezclas vulcanizables de textiles o tejidos metalicos despues del vulcanizado |
| US3922436A (en) * | 1974-09-13 | 1975-11-25 | Owens Corning Fiberglass Corp | Silanes useful as coupling agents and flame retardants |
| DE2508931A1 (de) | 1975-03-01 | 1976-09-09 | Dynamit Nobel Ag | Schwefelorganische silicium-verbindungen - verfahren zu deren herstellung und verwendung als haftvermittler |
| DE2658368C2 (de) * | 1976-12-23 | 1982-09-23 | Degussa Ag, 6000 Frankfurt | Schwefel und Phosphor enthaltende Organosiliciumverbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US4184998A (en) * | 1977-11-30 | 1980-01-22 | The B. F. Goodrich Company | Non odorous silane coupling agent |
| FR2471947A1 (fr) * | 1979-12-20 | 1981-06-26 | Rhone Poulenc Ind | Silice de precipitation, notamment utilisable comme charge renforcante |
| US4519430A (en) * | 1982-07-29 | 1985-05-28 | The B. F. Goodrich Company | Energy saving tire with silica-rich tread |
| BR8307103A (pt) | 1983-12-19 | 1985-07-30 | Rhodia Sa | Processo de obtencao de uma silica de precipitacao e processo de reforco de elastomeros utilizando essa silica |
| GB8400149D0 (en) * | 1984-01-05 | 1984-02-08 | Bp Chem Int Ltd | Polymer composition |
| JPS62235368A (ja) | 1986-04-04 | 1987-10-15 | Nitsuko Corp | 樹脂外装フイルムコンデンサの下塗り剤 |
| US4675349A (en) * | 1986-09-02 | 1987-06-23 | Gencorp Inc. | Method of preparing composition for tire tread cap |
| US5006603A (en) | 1986-09-26 | 1991-04-09 | Ube Industries, Ltd. | Fiber-reinforced rubber composition and production process and use thereof |
| JPH068366B2 (ja) * | 1987-04-23 | 1994-02-02 | 株式会社ブリヂストン | タイヤ用ゴム組成物 |
| JPH0819266B2 (ja) | 1987-04-30 | 1996-02-28 | 株式会社ブリヂストン | タイヤトレツド用ゴム組成物 |
| JPH0689067B2 (ja) | 1987-05-07 | 1994-11-09 | 東亞合成化学工業株式会社 | シアノアクリレ−ト系組成物 |
| JPS6454043A (en) * | 1987-08-26 | 1989-03-01 | Bridgestone Corp | Rubber composition for tire |
| DE4004781A1 (de) * | 1990-02-16 | 1991-08-22 | Degussa | Verfahren zur herstellung von mit organosiliciumverbindungen modifizierten fuellstoffen, die so hergestellten fuellstoffe und deren verwendung |
| ES2085959T5 (es) * | 1990-03-02 | 2001-02-01 | Bridgestone Corp | Neumaticos. |
| JP3175016B2 (ja) * | 1991-10-08 | 2001-06-11 | 横浜ゴム株式会社 | 高硬度ゴム組成物 |
| JPH06507938A (ja) * | 1992-03-17 | 1994-09-08 | ゼネラル エレクトリック カンパニイ | 屈折率を整合させるために透明な熱硬化性のシリコンラバーと樹脂との組成物 |
| US5387637A (en) * | 1992-08-20 | 1995-02-07 | Lisco, Inc. | Golf ball core compositions |
| US5324806A (en) * | 1993-03-12 | 1994-06-28 | General Electric Company | Free flowing silicone resin powder and method for making |
| US5341863A (en) * | 1993-05-17 | 1994-08-30 | The Goodyear Tire & Rubber Company | Tire with tread composition |
| JPH0778155A (ja) | 1993-06-18 | 1995-03-20 | N T T Data Tsushin Kk | 文書認識装置 |
| CA2105719A1 (en) | 1993-06-28 | 1994-12-29 | Rene Jean Zimmer | Silica based aggregates, elastomers reinforced therewith and tire with tread thereof |
| US5378754A (en) | 1993-09-28 | 1995-01-03 | The Goodyear Tire & Rubber Company | Tires having improved rolling resistance |
| JP2865577B2 (ja) * | 1993-11-26 | 1999-03-08 | 住友ゴム工業株式会社 | トレッドゴム組成物 |
| JP3553632B2 (ja) * | 1994-03-16 | 2004-08-11 | ダウ コーニング アジア株式会社 | 硬化性オルガノポリシロキサン組成物 |
| US5580919A (en) * | 1995-03-14 | 1996-12-03 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and use in tires |
| US5510430A (en) * | 1995-03-31 | 1996-04-23 | General Electric Company | Method of functionalizing organosiloxane condensation products |
| US5869550A (en) * | 1995-05-22 | 1999-02-09 | Cabot Corporation | Method to improve traction using silicon-treated carbon blacks |
| JP3366995B2 (ja) * | 1995-08-16 | 2003-01-14 | オーエスアイ スペシャルティーズ インコーポレーテッド | シリカ担体上の安定なシラン組成物 |
| US5623028A (en) * | 1995-12-01 | 1997-04-22 | General Electric Company | Heat cured rubbers |
| FR2743565B1 (fr) * | 1996-01-11 | 1998-02-20 | Rhone Poulenc Chimie | Utilisation d'une association de composes silicones comme agent de couplage dans les compositions d'elastomeres chargees de silice |
| FR2743564A1 (fr) | 1996-01-11 | 1997-07-18 | Michelin & Cie | Compositions de caoutchouc pour enveloppes de pneumatiques a base de silices contenant un additif de renforcement a base d'un polyorganosiloxane fonctionnalise et d'un compose organosilane . |
| US5780538A (en) * | 1996-03-11 | 1998-07-14 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and tire with tread |
| DE19610281A1 (de) * | 1996-03-15 | 1997-09-18 | Bayer Ag | Verfahren zur Herstellung von polysulfidischen Silylethern |
| US6028143A (en) * | 1996-05-16 | 2000-02-22 | Bridgestone Corporation | Rubber composition containing cross linkable polyethylene |
| US6036800A (en) * | 1996-08-28 | 2000-03-14 | The Goodyear Tire & Rubber Company | Method of preparing tire with tread of cap/base construction |
| US5785927A (en) | 1996-10-24 | 1998-07-28 | Eli Lilly And Company | Vessel handling system useful for combinatorial chemistry |
| JPH10204221A (ja) | 1997-01-21 | 1998-08-04 | Bridgestone Corp | スタッドレスタイヤおよびその製造方法 |
| US5886074A (en) * | 1997-03-04 | 1999-03-23 | The Goodyear Tire & Rubber Company | Rubber compositions containing o-salicylsalicyclic acid |
| JP3601569B2 (ja) * | 1997-03-26 | 2004-12-15 | 株式会社ブリヂストン | 樹脂強化エラストマー、その製造方法、及びそれを用いた空気入りタイヤ |
| US6080809A (en) | 1997-07-30 | 2000-06-27 | Bridgestone/Firestone, Inc. | Kaolin clay in silica tread compounds technical field |
| JP3592899B2 (ja) * | 1997-08-20 | 2004-11-24 | 株式会社ブリヂストン | 重荷重用空気入りタイヤ |
| AU8917998A (en) * | 1997-08-21 | 1999-03-08 | Crompton Corporation | Blocked mercaptosilane coupling agents for filled rubbers |
| EP1034083A1 (en) | 1997-10-30 | 2000-09-13 | The Goodyear Tire & Rubber Company | Tires having improved high speed properties |
| FR2770849B1 (fr) * | 1997-11-10 | 1999-12-03 | Michelin & Cie | Composition de caoutchouc destinee a la fabrication d'enveloppes de pneumatiques a base d'elastomere comportant des fonctions oxygenees et de charge de type silice |
| BR9814192A (pt) | 1997-12-15 | 2000-09-26 | Exxon Chemical Patents Inc | Composições elastoméricas transparentes e tingìveis |
| US6075096A (en) * | 1998-02-27 | 2000-06-13 | The Goodyear Tire & Rubber Company | Rubber compounds containing aromatic ketone polysulfides |
| DE19814655A1 (de) * | 1998-04-01 | 1999-10-07 | Bayer Ag | Trimethylolpropan-Destillationsrückstände enthaltende Kautschukmischungen |
| DE19814839A1 (de) * | 1998-04-02 | 1999-10-07 | Bayer Ag | Hydrophobierte oxidische oder silikatische Füllstoffe enthaltende Emulsionskautschukmischungen sowie deren Verwendung zur Herstellung von Reifen |
| US6014998A (en) | 1998-06-09 | 2000-01-18 | Pirelli Pneumatici S.P.A. | Silica-reinforced tire compositions containing triazoles |
| JP4363697B2 (ja) * | 1998-06-25 | 2009-11-11 | 株式会社ブリヂストン | タイヤトレッド用ゴム組成物及びそのゴム組成物を使用した空気入りタイヤ |
| KR100505325B1 (ko) | 1998-11-11 | 2005-10-14 | 한국타이어 주식회사 | 타이어 트레드용 고무조성물 |
| US6072012A (en) * | 1998-12-31 | 2000-06-06 | Dow Corning Corporation | Ultra-high molecular weight, soluble siloxane resins |
| JP2000189710A (ja) | 1998-12-31 | 2000-07-11 | Dow Corning Corp | 超高分子量樹脂を含有する泡止め組成物 |
| US6075087A (en) * | 1998-12-31 | 2000-06-13 | Dow Corning Corporation | Resin-fillers produced in-situ in silicone polymer compositions method for preparation of the compositions |
| JP4344041B2 (ja) * | 1999-05-12 | 2009-10-14 | 住友ゴム工業株式会社 | トレッドゴム組成物およびスタッドレスタイヤ |
| US6969739B1 (en) * | 1999-09-27 | 2005-11-29 | Asahi Kasei Kabushiki Kaisha | Rubber composition |
| DE19954815C1 (de) * | 1999-11-13 | 2001-06-07 | Degussa | Verfahren zur Herstellung von schwefel- und phosphorhaltigen Organosiliziumverbindungen |
| EP1113036B1 (en) | 1999-12-28 | 2005-12-21 | General Electric Company | Continuous process for producing a silicon resin |
| CA2352927C (en) | 2000-07-14 | 2008-03-18 | Sumitomo Rubber Industries, Ltd. | Rubber composition for tyre tread |
| CA2417681A1 (fr) * | 2000-07-31 | 2002-02-07 | Michelin Recherche Et Technique S.A. | Bande de roulement pour pneumatique |
| US7301042B2 (en) * | 2002-04-23 | 2007-11-27 | Cruse Richard W | Blocked mercaptosilane hydrolyzates as coupling agents for mineral-filled elastomer compositions |
| US7432321B2 (en) | 2002-07-09 | 2008-10-07 | Momentive Performance Materials Inc. | Silica-rubber mixtures having improved hardness |
| US7138537B2 (en) * | 2003-04-02 | 2006-11-21 | General Electric Company | Coupling agents for mineral-filled elastomer compositions |
-
2003
- 2003-07-08 US US10/617,165 patent/US7432321B2/en not_active Expired - Lifetime
- 2003-07-08 NZ NZ537861A patent/NZ537861A/en unknown
- 2003-07-08 KR KR1020057000489A patent/KR101053009B1/ko not_active Expired - Lifetime
- 2003-07-08 CN CN038213427A patent/CN1681876B/zh not_active Expired - Lifetime
- 2003-07-08 AU AU2003249019A patent/AU2003249019A1/en not_active Abandoned
- 2003-07-08 RU RU2005103236/04A patent/RU2323230C2/ru not_active IP Right Cessation
- 2003-07-08 EP EP03763461.5A patent/EP1551913B1/en not_active Expired - Lifetime
- 2003-07-08 WO PCT/US2003/021616 patent/WO2004005395A2/en not_active Ceased
- 2003-07-08 MX MXPA05000523A patent/MXPA05000523A/es unknown
- 2003-07-08 CN CN2010102296295A patent/CN101880415B/zh not_active Expired - Lifetime
- 2003-07-08 JP JP2004520123A patent/JP4722482B2/ja not_active Expired - Lifetime
- 2003-07-09 TW TW092118707A patent/TWI324623B/zh not_active IP Right Cessation
-
2005
- 2005-01-25 ZA ZA200500747A patent/ZA200500747B/en unknown
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| Publication number | Publication date |
|---|---|
| WO2004005395A2 (en) | 2004-01-15 |
| NZ537861A (en) | 2008-09-26 |
| CN1681876B (zh) | 2012-05-30 |
| US20050277717A1 (en) | 2005-12-15 |
| MXPA05000523A (es) | 2005-04-19 |
| TWI324623B (en) | 2010-05-11 |
| JP2005533140A (ja) | 2005-11-04 |
| WO2004005395A3 (en) | 2004-08-05 |
| ZA200500747B (en) | 2006-04-26 |
| EP1551913B1 (en) | 2021-03-31 |
| TW200417569A (en) | 2004-09-16 |
| JP4722482B2 (ja) | 2011-07-13 |
| US7432321B2 (en) | 2008-10-07 |
| CN101880415B (zh) | 2013-05-22 |
| KR20050025962A (ko) | 2005-03-14 |
| RU2005103236A (ru) | 2005-08-27 |
| CN101880415A (zh) | 2010-11-10 |
| RU2323230C2 (ru) | 2008-04-27 |
| KR101053009B1 (ko) | 2011-07-29 |
| EP1551913A2 (en) | 2005-07-13 |
| CN1681876A (zh) | 2005-10-12 |
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