MX366574B - Nanocatalizador de cobalto para sintesis de fischer-tropsch, basado en confinacion de material poroso, y metodo para su preparacion. - Google Patents

Nanocatalizador de cobalto para sintesis de fischer-tropsch, basado en confinacion de material poroso, y metodo para su preparacion.

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Publication number
MX366574B
MX366574B MX2014006257A MX2014006257A MX366574B MX 366574 B MX366574 B MX 366574B MX 2014006257 A MX2014006257 A MX 2014006257A MX 2014006257 A MX2014006257 A MX 2014006257A MX 366574 B MX366574 B MX 366574B
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MX
Mexico
Prior art keywords
porous material
percent
component
metallic
present
Prior art date
Application number
MX2014006257A
Other languages
English (en)
Spanish (es)
Other versions
MX2014006257A (es
Inventor
Chen Yilong
Zhang Yanfeng
Xue Yongjie
Tao Leiming
Fang Zhangjian
Zhan Xiaodong
Original Assignee
Wuhan Kaidi Eng Tech Res Inst
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Filing date
Publication date
Application filed by Wuhan Kaidi Eng Tech Res Inst filed Critical Wuhan Kaidi Eng Tech Res Inst
Publication of MX2014006257A publication Critical patent/MX2014006257A/es
Publication of MX366574B publication Critical patent/MX366574B/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Nanotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Prostheses (AREA)
  • Materials For Medical Uses (AREA)
MX2014006257A 2011-11-24 2012-10-17 Nanocatalizador de cobalto para sintesis de fischer-tropsch, basado en confinacion de material poroso, y metodo para su preparacion. MX366574B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2011103787941A CN102489312B (zh) 2011-11-24 2011-11-24 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法
PCT/CN2012/083091 WO2013075559A1 (zh) 2011-11-24 2012-10-17 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法

Publications (2)

Publication Number Publication Date
MX2014006257A MX2014006257A (es) 2014-09-22
MX366574B true MX366574B (es) 2019-07-12

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MX2014006257A MX366574B (es) 2011-11-24 2012-10-17 Nanocatalizador de cobalto para sintesis de fischer-tropsch, basado en confinacion de material poroso, y metodo para su preparacion.

Country Status (16)

Country Link
US (1) US9266097B2 (cg-RX-API-DMAC10.html)
EP (1) EP2783750A4 (cg-RX-API-DMAC10.html)
JP (1) JP5947912B2 (cg-RX-API-DMAC10.html)
KR (1) KR101625987B1 (cg-RX-API-DMAC10.html)
CN (1) CN102489312B (cg-RX-API-DMAC10.html)
AP (1) AP2014007678A0 (cg-RX-API-DMAC10.html)
AU (1) AU2012343061B2 (cg-RX-API-DMAC10.html)
BR (1) BR112014012492B1 (cg-RX-API-DMAC10.html)
CA (1) CA2856748A1 (cg-RX-API-DMAC10.html)
IN (1) IN2014MN00970A (cg-RX-API-DMAC10.html)
MX (1) MX366574B (cg-RX-API-DMAC10.html)
MY (1) MY166549A (cg-RX-API-DMAC10.html)
RU (1) RU2624441C2 (cg-RX-API-DMAC10.html)
SG (1) SG11201402557PA (cg-RX-API-DMAC10.html)
WO (1) WO2013075559A1 (cg-RX-API-DMAC10.html)
ZA (1) ZA201404572B (cg-RX-API-DMAC10.html)

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Publication number Priority date Publication date Assignee Title
CN102489312B (zh) * 2011-11-24 2013-06-19 武汉凯迪工程技术研究总院有限公司 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法
WO2014088538A1 (en) * 2012-12-03 2014-06-12 United Technologies Corporation Core-shell catalyst and method for palladium-based core particle
CN103055849B (zh) * 2012-12-27 2016-08-17 新奥科技发展有限公司 一种催化燃烧用复合催化剂及其制备方法
CN104226312B (zh) * 2013-06-20 2017-03-29 北京化工大学 一种核壳结构催化剂、制备方法及其应用
CN104289226B (zh) * 2014-09-08 2016-07-06 芜湖市纽泰知识产权信息咨询有限公司 一种多功能固体催化剂
CN104174443B (zh) * 2014-09-09 2016-04-27 安徽工程大学 一种核壳结构的催化剂
CN104607190B (zh) * 2015-01-30 2018-01-16 武汉凯迪工程技术研究总院有限公司 用于费托合成的单分散过渡金属纳米催化剂及其制备方法和应用
GB201506325D0 (en) 2015-04-14 2015-05-27 Johnson Matthey Plc Shaped catalyst particle
CN106311358B (zh) * 2015-07-08 2019-03-22 中国石油化工股份有限公司 一种壳层分布型催化剂及其制备方法和一种费托合成方法
CN105797717B (zh) * 2015-09-07 2018-07-20 中国科学院福建物质结构研究所 一种合成草酸二甲酯用催化剂及其制备方法
FR3044005B1 (fr) * 2015-11-23 2017-12-15 Ifp Energies Now Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt piege dans une matrice oxyde mesoporeuse et obtenu a partir d'au moins un precurseur monomerique
FR3044004B1 (fr) * 2015-11-23 2017-12-15 Ifp Energies Now Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt piege dans une matrice oxyde mesoporeuse et obtenu a partir d'au moins un precurseur colloidal
JPWO2017131231A1 (ja) * 2016-01-29 2018-11-22 Jxtgエネルギー株式会社 フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法
CN108654638B (zh) * 2017-03-30 2020-12-11 神华集团有限责任公司 一种核壳型钴基费托合成催化剂及其制备方法
CN107185572A (zh) * 2017-05-09 2017-09-22 中科合成油技术有限公司 包含氮化物载体的费托合成催化剂及其制备方法和应用
CN109876866B (zh) * 2017-12-06 2022-03-08 中国石油化工股份有限公司 一种用于芳香醛合成芳香胺的催化剂及其制备方法
CN114160130B (zh) * 2021-12-21 2024-03-19 黑龙江省能源环境研究院 一种限域纳米金有序多孔整体催化剂及其制备方法
US12042785B1 (en) 2023-09-13 2024-07-23 Dimensional Energy, Inc. Fischer-Tropsch catalysts

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IN2014MN00970A (cg-RX-API-DMAC10.html) 2015-04-24
CN102489312A (zh) 2012-06-13
AU2012343061B2 (en) 2016-04-28
AP2014007678A0 (en) 2014-06-30
RU2014124012A (ru) 2015-12-27
SG11201402557PA (en) 2014-09-26
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BR112014012492B1 (pt) 2020-01-21
CN102489312B (zh) 2013-06-19
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EP2783750A1 (en) 2014-10-01
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US9266097B2 (en) 2016-02-23
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EP2783750A4 (en) 2015-08-05
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