BR112014012492A2 - síntese fischer-tropsch de nanopartículas de cobalto com base em material de confinamento poroso - Google Patents

síntese fischer-tropsch de nanopartículas de cobalto com base em material de confinamento poroso

Info

Publication number
BR112014012492A2
BR112014012492A2 BR112014012492A BR112014012492A BR112014012492A2 BR 112014012492 A2 BR112014012492 A2 BR 112014012492A2 BR 112014012492 A BR112014012492 A BR 112014012492A BR 112014012492 A BR112014012492 A BR 112014012492A BR 112014012492 A2 BR112014012492 A2 BR 112014012492A2
Authority
BR
Brazil
Prior art keywords
barcellos
leão
milton
industrial
bahuschewskyj
Prior art date
Application number
BR112014012492A
Other languages
English (en)
Other versions
BR112014012492B1 (pt
Inventor
Tao Leiming
Zhan Xiaodong
Zhang Yanfeng
Chen Yilong
Xue Yongjie
Fang Zhangjian
Original Assignee
Wuhan Kaidi Eng Tech Res Inst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhan Kaidi Eng Tech Res Inst filed Critical Wuhan Kaidi Eng Tech Res Inst
Publication of BR112014012492A2 publication Critical patent/BR112014012492A2/pt
Publication of BR112014012492B1 publication Critical patent/BR112014012492B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/398—Egg yolk like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Nanotechnology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Prostheses (AREA)
  • Materials For Medical Uses (AREA)

Abstract

d e c l a r a ç ã o declaramos que o presente depósito está sendo efetuado sem resumo e que a mesma será juntada dentro do prazo legal para complementação do pedido de patente. porto alegre/rs, 23 de maio de 2014. _______________________________ leão propriedade intelectual api/br 2101 dr. gustavo bahuschewskyj corrêa oab/rs 69.748 –api/br 2039 2 milton leão barcellos norma scherer barcellos milton lucídio leão barcellos cesar alexandre leão barcellos gustavo bahuschewskyj corrêa l e ã o propriedade intelectual desde 1957 advogados e agentes da propriedade industrial brasil e exterior marcas / patentes desenhos industriais direitos autorais software / contratos transferência de tecnologia milton leão barcellos norma scherer barcellos milton lucídio leão barcellos gustavo bahuschewskyj corrêa laura luce maisonnave cristiano prestes braga lucas saretta ferrari l e ã o propriedade intelectual desde 1957 advogados e agentes da propriedade industrial brasil e exterior marcas / patentes desenhos industriais direitos autorais software / contratos transferência de tecnologia avenida carlos gomes, 403, 8º andar, porto alegre/rs fones/fax:+55 51 3224-7896/3226-0624/3286-6707 home page: www.leao.adv.br e-mail: leao@leao.adv.br
BR112014012492A 2011-11-24 2012-10-17 nanocatalisador de cobalto para síntese fischer-tropsch à base de confinamento em material de poroso e método para sua preparação BR112014012492B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2011103787941A CN102489312B (zh) 2011-11-24 2011-11-24 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法
PCT/CN2012/083091 WO2013075559A1 (zh) 2011-11-24 2012-10-17 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法

Publications (2)

Publication Number Publication Date
BR112014012492A2 true BR112014012492A2 (pt) 2017-06-06
BR112014012492B1 BR112014012492B1 (pt) 2020-01-21

Family

ID=46181196

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014012492A BR112014012492B1 (pt) 2011-11-24 2012-10-17 nanocatalisador de cobalto para síntese fischer-tropsch à base de confinamento em material de poroso e método para sua preparação

Country Status (16)

Country Link
US (1) US9266097B2 (pt)
EP (1) EP2783750A4 (pt)
JP (1) JP5947912B2 (pt)
KR (1) KR101625987B1 (pt)
CN (1) CN102489312B (pt)
AP (1) AP2014007678A0 (pt)
AU (1) AU2012343061B2 (pt)
BR (1) BR112014012492B1 (pt)
CA (1) CA2856748A1 (pt)
IN (1) IN2014MN00970A (pt)
MX (1) MX366574B (pt)
MY (1) MY166549A (pt)
RU (1) RU2624441C2 (pt)
SG (1) SG11201402557PA (pt)
WO (1) WO2013075559A1 (pt)
ZA (1) ZA201404572B (pt)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102489312B (zh) * 2011-11-24 2013-06-19 武汉凯迪工程技术研究总院有限公司 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法
JP6435269B2 (ja) * 2012-12-03 2018-12-05 アウディ アクチェンゲゼルシャフトＡｕｄｉ Ａｇ コア−シェル触媒およびパラジウム基コア粒子用の方法
CN103055849B (zh) * 2012-12-27 2016-08-17 新奥科技发展有限公司 一种催化燃烧用复合催化剂及其制备方法
CN104226312B (zh) * 2013-06-20 2017-03-29 北京化工大学 一种核壳结构催化剂、制备方法及其应用
CN104289226B (zh) * 2014-09-08 2016-07-06 芜湖市纽泰知识产权信息咨询有限公司 一种多功能固体催化剂
CN104174443B (zh) * 2014-09-09 2016-04-27 安徽工程大学 一种核壳结构的催化剂
CN104607190B (zh) * 2015-01-30 2018-01-16 武汉凯迪工程技术研究总院有限公司 用于费托合成的单分散过渡金属纳米催化剂及其制备方法和应用
GB201506325D0 (en) * 2015-04-14 2015-05-27 Johnson Matthey Plc Shaped catalyst particle
CN106311358B (zh) * 2015-07-08 2019-03-22 中国石油化工股份有限公司 一种壳层分布型催化剂及其制备方法和一种费托合成方法
CN105797717B (zh) * 2015-09-07 2018-07-20 中国科学院福建物质结构研究所 一种合成草酸二甲酯用催化剂及其制备方法
FR3044004B1 (fr) * 2015-11-23 2017-12-15 Ifp Energies Now Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt piege dans une matrice oxyde mesoporeuse et obtenu a partir d'au moins un precurseur colloidal
FR3044005B1 (fr) * 2015-11-23 2017-12-15 Ifp Energies Now Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt piege dans une matrice oxyde mesoporeuse et obtenu a partir d'au moins un precurseur monomerique
WO2017131231A1 (ja) * 2016-01-29 2017-08-03 Ｊｘエネルギー株式会社 フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法
CN108654638B (zh) * 2017-03-30 2020-12-11 神华集团有限责任公司 一种核壳型钴基费托合成催化剂及其制备方法
CN107185572A (zh) * 2017-05-09 2017-09-22 中科合成油技术有限公司 包含氮化物载体的费托合成催化剂及其制备方法和应用
CN109876866B (zh) * 2017-12-06 2022-03-08 中国石油化工股份有限公司 一种用于芳香醛合成芳香胺的催化剂及其制备方法
CN114160130B (zh) * 2021-12-21 2024-03-19 黑龙江省能源环境研究院 一种限域纳米金有序多孔整体催化剂及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6458741B1 (en) * 1999-12-20 2002-10-01 Eltron Research, Inc. Catalysts for low-temperature destruction of volatile organic compounds in air
GB0503818D0 (en) * 2005-02-25 2005-04-06 Johnson Matthey Plc Catalysts
JP5267841B2 (ja) * 2005-07-21 2013-08-21 株式会社豊田中央研究所 複合材料、複合材料基材、複合材料分散液、及びそれらの製造方法
CN100493701C (zh) * 2007-05-08 2009-06-03 中科合成油技术有限公司 一种进行费托合成反应的方法及其专用催化剂
KR100837377B1 (ko) * 2007-05-29 2008-06-12 한국화학연구원 지르코니아와 알루미나의 혼합담체를 이용한 피셔-트롭쉬 반응용 촉매 및 이를 이용한 합성가스로부터 액체탄화수소의 제조방법
KR101397020B1 (ko) * 2007-11-20 2014-05-21 삼성에스디아이 주식회사 연료전지용 전극촉매, 그 제조방법, 상기 전극촉매를포함하는 전극을 구비한 연료전지
KR100918105B1 (ko) * 2008-03-27 2009-09-22 한국화학연구원 피셔-트롭쉬 합성용 코발트／지르코늄-인/실리카 촉매와이의 제조방법
US8168561B2 (en) * 2008-07-31 2012-05-01 University Of Utah Research Foundation Core shell catalyst
CN101444711B (zh) * 2008-12-11 2012-04-04 上海医脉赛科技有限公司 一种核壳结构的磁性二氧化硅复合微球及其制备方法
US20110311635A1 (en) * 2009-02-12 2011-12-22 The Regents Of The University Of California Hollow metal oxide spheres and nanoparticles encapsulated therein
FR2945756B1 (fr) * 2009-05-20 2011-08-05 Commissariat Energie Atomique Materiau solide nanocomposite a base d'hexa-et octacyanometallates, son procede de preparation et procede de fixation de polluants mineraux le mettant en oeuvre.
CN101698152A (zh) * 2009-10-20 2010-04-28 武汉凯迪科技发展研究院有限公司 一种钴基费托合成催化剂及其制备方法和应用
CN101804351B (zh) * 2010-04-01 2012-05-30 中国科学院山西煤炭化学研究所 一种用于合成气制备中间馏分油核壳结构钴基催化剂的制法及应用
CN102000575A (zh) * 2010-09-20 2011-04-06 中国科学院山西煤炭化学研究所 一种用于浆态床反应器的钴基费托合成催化剂及其制备和应用
CN102489312B (zh) * 2011-11-24 2013-06-19 武汉凯迪工程技术研究总院有限公司 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法

Also Published As

Publication number Publication date
MX2014006257A (es) 2014-09-22
ZA201404572B (en) 2015-09-30
EP2783750A1 (en) 2014-10-01
US9266097B2 (en) 2016-02-23
CA2856748A1 (en) 2013-05-30
WO2013075559A1 (zh) 2013-05-30
AU2012343061B2 (en) 2016-04-28
RU2014124012A (ru) 2015-12-27
RU2624441C2 (ru) 2017-07-04
KR101625987B1 (ko) 2016-05-31
MX366574B (es) 2019-07-12
IN2014MN00970A (pt) 2015-04-24
MY166549A (en) 2018-07-16
AU2012343061A1 (en) 2014-06-12
US20140256535A1 (en) 2014-09-11
JP2014534068A (ja) 2014-12-18
JP5947912B2 (ja) 2016-07-06
BR112014012492B1 (pt) 2020-01-21
KR20140097266A (ko) 2014-08-06
AP2014007678A0 (en) 2014-06-30
EP2783750A4 (en) 2015-08-05
SG11201402557PA (en) 2014-09-26
CN102489312A (zh) 2012-06-13
CN102489312B (zh) 2013-06-19

Similar Documents

Publication Publication Date Title
BR112014012492A2 (pt) síntese fischer-tropsch de nanopartículas de cobalto com base em material de confinamento poroso
BR112014015929A2 (pt) gaseificador de leito arrastado de biomassa de plasma de microondas e seu processo correspondente
BR112014011374A2 (pt) processo melhorado de fabricação de bebidas alcóolicas e produtos produzidos por esse processo
BR112014015304A2 (pt) método para capturar dióxido de carbono em uma central elétrica de gás de combustão e um dispositivo para o mesmo
BR112014015927A2 (pt) processo de purificação de biomassa de gás de síntese sob pressão negativa para produzir petróleo e configuração do sistema do mesmo
BR112014015925A2 (pt) processo de purificação de biomassa de gás de síntese sob pressão positiva para produzir petróleo e configuração do sistema do mesmo
BR112012027303A2 (pt) comprimido de desintegração oral contendo acarbose
Brandt et al. Numerical Simulations of the Internal Waves Produced by a Submerged Body in a Stratified Fluid
Waltmann et al. Many Body Effects in Nanoparticle Superlattices
Sun et al. Quantum Boundary Effect on Electronic Structures of Nanomaterials
Williams With Great Measurements Come Great Results
Bristow et al. Whole-field velocity measurements of flow around interacting barchan dunes in a novel flume environment
Xiao et al. Bio-inspired structural colors from deposition of synthetic melanin nanoparticles by evaporative self-assembly
Remus et al. The elasto-viscous equilibrium tide in exoplanetary systems
Pursimo et al. Optical flare observed in the flaring gamma-ray blazar CGRaBS J0809+ 5341 (87GB 080551.6+ 535010)
King et al. Emergent quantum size effects at topological insulator surfaces
Dobrosavljevic et al. Equation of State of Iron-Rich (Mg, Fe) O
Bozzo et al. INTEGRAL observation of MAXI J0911-655
Flierl et al. Multi-Eady models of surface and deep instabilities
Tat Lam et al. Conformal Basis, Optical Theorem, and the Bulk Point Singularity
Carrasco et al. Recent NIR photometry of the Flaring Quasar 3C454. 3
Choi et al. Origin of ferromagnetic ordering in LaCoO 3 epitaxial thin films
Angelica Cueto Implicitization of surfaces via geometric tropicalization
Murase Cascaded Gamma Rays as a Probe of Cosmic Rays
Haojiang Zhou et al. Glare suppression by coherence gated negation

Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/10/2012, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 9A ANUIDADE.

B24D Patent annual fee: restoration after fee payment
B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 11A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2744 DE 08-08-2023 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.