WO2013075559A1 - 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法 - Google Patents
基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法 Download PDFInfo
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- WO2013075559A1 WO2013075559A1 PCT/CN2012/083091 CN2012083091W WO2013075559A1 WO 2013075559 A1 WO2013075559 A1 WO 2013075559A1 CN 2012083091 W CN2012083091 W CN 2012083091W WO 2013075559 A1 WO2013075559 A1 WO 2013075559A1
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- Prior art keywords
- metal component
- porous material
- cobalt
- fischer
- component
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- 239000011148 porous material Substances 0.000 title claims abstract description 64
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 45
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 45
- 229910017052 cobalt Inorganic materials 0.000 title claims abstract description 37
- 239000010941 cobalt Substances 0.000 title claims abstract description 37
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000011943 nanocatalyst Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 74
- 239000002184 metal Substances 0.000 claims abstract description 74
- 239000003054 catalyst Substances 0.000 claims abstract description 63
- 239000002245 particle Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 5
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 5
- 229910052702 rhenium Inorganic materials 0.000 claims abstract description 5
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 5
- 238000003980 solgel method Methods 0.000 claims abstract description 5
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 5
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 23
- 239000000243 solution Substances 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229910001960 metal nitrate Inorganic materials 0.000 claims description 6
- 238000001694 spray drying Methods 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 5
- 239000000376 reactant Substances 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- 229940011182 cobalt acetate Drugs 0.000 claims description 3
- 229910021446 cobalt carbonate Inorganic materials 0.000 claims description 3
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 claims description 3
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 3
- 239000002798 polar solvent Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- PNPIRSNMYIHTPS-UHFFFAOYSA-N nitroso nitrate Chemical compound [O-][N+](=O)ON=O PNPIRSNMYIHTPS-UHFFFAOYSA-N 0.000 claims description 2
- KTPIHRZQGZDLSN-UHFFFAOYSA-N cobalt;nitric acid Chemical compound [Co].O[N+]([O-])=O KTPIHRZQGZDLSN-UHFFFAOYSA-N 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 16
- 238000006555 catalytic reaction Methods 0.000 abstract description 8
- 239000012188 paraffin wax Substances 0.000 abstract description 6
- 239000011258 core-shell material Substances 0.000 abstract description 5
- 230000009257 reactivity Effects 0.000 abstract description 4
- 239000002283 diesel fuel Substances 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 description 28
- 239000000047 product Substances 0.000 description 23
- 230000004913 activation Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 12
- 239000002002 slurry Substances 0.000 description 12
- 230000003197 catalytic effect Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- QQZMWMKOWKGPQY-UHFFFAOYSA-N cerium(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O QQZMWMKOWKGPQY-UHFFFAOYSA-N 0.000 description 4
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 239000012429 reaction media Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229920002873 Polyethylenimine Polymers 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000003094 microcapsule Substances 0.000 description 3
- -1 nitrosyl group Chemical group 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 238000007036 catalytic synthesis reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- NWAHZABTSDUXMJ-UHFFFAOYSA-N platinum(2+);dinitrate Chemical compound [Pt+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O NWAHZABTSDUXMJ-UHFFFAOYSA-N 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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- B82—NANOTECHNOLOGY
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
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- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
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Abstract
Description
Claims
Priority Applications (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2014006257A MX366574B (es) | 2011-11-24 | 2012-10-17 | Nanocatalizador de cobalto para sintesis de fischer-tropsch, basado en confinacion de material poroso, y metodo para su preparacion. |
BR112014012492A BR112014012492B1 (pt) | 2011-11-24 | 2012-10-17 | nanocatalisador de cobalto para síntese fischer-tropsch à base de confinamento em material de poroso e método para sua preparação |
IN970MUN2014 IN2014MN00970A (zh) | 2011-11-24 | 2012-10-17 | |
AU2012343061A AU2012343061B2 (en) | 2011-11-24 | 2012-10-17 | Fischer-Tropsch synthesis cobalt nano-catalyst based on porous material confinement, and preparation method therefor |
KR1020147014655A KR101625987B1 (ko) | 2011-11-24 | 2012-10-17 | 다공성 재료 갇힘 기반의 피셔-트롭쉬 합성 코발트 나노 결정 및 이의 제조 방법 |
AP2014007678A AP2014007678A0 (en) | 2011-11-24 | 2012-10-17 | Fischer-tropsch synthesis cobalt nano-catalyst based on porous material confinement, and preparationmethod therefor |
JP2014542687A JP5947912B2 (ja) | 2011-11-24 | 2012-10-17 | 多孔質材料閉じ込め系のコバルト系フィッシャー・トロプシュ合成ナノ触媒とその調整方法 |
SG11201402557PA SG11201402557PA (en) | 2011-11-24 | 2012-10-17 | Fischer-tropsch synthesis cobalt nano-catalyst based on porous material confinement, and preparation method therefor |
CA2856748A CA2856748A1 (en) | 2011-11-24 | 2012-10-17 | Fischer-tropsch synthesis cobalt nano-catalyst based on porous material confinement, and preparation method therefor |
EP12851601.0A EP2783750A4 (en) | 2011-11-24 | 2012-10-17 | COBALT NANOCATALYZER FOR FISCHER-TROPSCH SYNTHESIS BASED ON THE INCLUSION OF POROUS MATERIAL AND METHOD OF MANUFACTURING THEREOF |
RU2014124012A RU2624441C2 (ru) | 2011-11-24 | 2012-10-17 | Кобальтовый нанокатализатор синтеза фишера-тропша, локализованный в пористом материале, и способ его получения |
US14/285,665 US9266097B2 (en) | 2011-11-24 | 2014-05-23 | Cobalt-based nano catalyst and preparation method thereof |
ZA2014/04572A ZA201404572B (en) | 2011-11-24 | 2014-06-20 | Fischer-tropsch synthesis cobalt nano-catalyst based on porous material confinement, and preparation method therefor |
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US (1) | US9266097B2 (zh) |
EP (1) | EP2783750A4 (zh) |
JP (1) | JP5947912B2 (zh) |
KR (1) | KR101625987B1 (zh) |
CN (1) | CN102489312B (zh) |
AP (1) | AP2014007678A0 (zh) |
AU (1) | AU2012343061B2 (zh) |
BR (1) | BR112014012492B1 (zh) |
CA (1) | CA2856748A1 (zh) |
IN (1) | IN2014MN00970A (zh) |
MX (1) | MX366574B (zh) |
MY (1) | MY166549A (zh) |
RU (1) | RU2624441C2 (zh) |
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CN102489312B (zh) * | 2011-11-24 | 2013-06-19 | 武汉凯迪工程技术研究总院有限公司 | 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法 |
CN104994952A (zh) * | 2012-12-03 | 2015-10-21 | 奥迪股份公司 | 核壳催化剂及钯基核颗粒的制备方法 |
CN103055849B (zh) * | 2012-12-27 | 2016-08-17 | 新奥科技发展有限公司 | 一种催化燃烧用复合催化剂及其制备方法 |
CN104226312B (zh) * | 2013-06-20 | 2017-03-29 | 北京化工大学 | 一种核壳结构催化剂、制备方法及其应用 |
CN104289226B (zh) * | 2014-09-08 | 2016-07-06 | 芜湖市纽泰知识产权信息咨询有限公司 | 一种多功能固体催化剂 |
CN104174443B (zh) * | 2014-09-09 | 2016-04-27 | 安徽工程大学 | 一种核壳结构的催化剂 |
CN104607190B (zh) * | 2015-01-30 | 2018-01-16 | 武汉凯迪工程技术研究总院有限公司 | 用于费托合成的单分散过渡金属纳米催化剂及其制备方法和应用 |
GB201506325D0 (en) * | 2015-04-14 | 2015-05-27 | Johnson Matthey Plc | Shaped catalyst particle |
CN106311358B (zh) * | 2015-07-08 | 2019-03-22 | 中国石油化工股份有限公司 | 一种壳层分布型催化剂及其制备方法和一种费托合成方法 |
CN105797717B (zh) * | 2015-09-07 | 2018-07-20 | 中国科学院福建物质结构研究所 | 一种合成草酸二甲酯用催化剂及其制备方法 |
FR3044005B1 (fr) * | 2015-11-23 | 2017-12-15 | Ifp Energies Now | Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt piege dans une matrice oxyde mesoporeuse et obtenu a partir d'au moins un precurseur monomerique |
FR3044004B1 (fr) * | 2015-11-23 | 2017-12-15 | Ifp Energies Now | Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt piege dans une matrice oxyde mesoporeuse et obtenu a partir d'au moins un precurseur colloidal |
JPWO2017131231A1 (ja) * | 2016-01-29 | 2018-11-22 | Jxtgエネルギー株式会社 | フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法 |
CN108654638B (zh) * | 2017-03-30 | 2020-12-11 | 神华集团有限责任公司 | 一种核壳型钴基费托合成催化剂及其制备方法 |
CN107185572A (zh) * | 2017-05-09 | 2017-09-22 | 中科合成油技术有限公司 | 包含氮化物载体的费托合成催化剂及其制备方法和应用 |
CN109876866B (zh) * | 2017-12-06 | 2022-03-08 | 中国石油化工股份有限公司 | 一种用于芳香醛合成芳香胺的催化剂及其制备方法 |
CN114160130B (zh) * | 2021-12-21 | 2024-03-19 | 黑龙江省能源环境研究院 | 一种限域纳米金有序多孔整体催化剂及其制备方法 |
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- 2012-10-17 BR BR112014012492A patent/BR112014012492B1/pt not_active IP Right Cessation
- 2012-10-17 WO PCT/CN2012/083091 patent/WO2013075559A1/zh active Application Filing
- 2012-10-17 KR KR1020147014655A patent/KR101625987B1/ko active IP Right Grant
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BR112014012492A2 (pt) | 2017-06-06 |
JP2014534068A (ja) | 2014-12-18 |
KR20140097266A (ko) | 2014-08-06 |
CN102489312B (zh) | 2013-06-19 |
IN2014MN00970A (zh) | 2015-04-24 |
SG11201402557PA (en) | 2014-09-26 |
RU2624441C2 (ru) | 2017-07-04 |
AU2012343061A1 (en) | 2014-06-12 |
MY166549A (en) | 2018-07-16 |
KR101625987B1 (ko) | 2016-05-31 |
CA2856748A1 (en) | 2013-05-30 |
US9266097B2 (en) | 2016-02-23 |
JP5947912B2 (ja) | 2016-07-06 |
EP2783750A4 (en) | 2015-08-05 |
MX2014006257A (es) | 2014-09-22 |
BR112014012492B1 (pt) | 2020-01-21 |
MX366574B (es) | 2019-07-12 |
AU2012343061B2 (en) | 2016-04-28 |
RU2014124012A (ru) | 2015-12-27 |
ZA201404572B (en) | 2015-09-30 |
CN102489312A (zh) | 2012-06-13 |
US20140256535A1 (en) | 2014-09-11 |
AP2014007678A0 (en) | 2014-06-30 |
EP2783750A1 (en) | 2014-10-01 |
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