MX368239B - Catalizador para la oxidación de diésel, con estructura estratificada que contiene una composición de cerio como material de soporte de paladio para mejorar la conversión de gas hc y co. - Google Patents

Catalizador para la oxidación de diésel, con estructura estratificada que contiene una composición de cerio como material de soporte de paladio para mejorar la conversión de gas hc y co.

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Publication number
MX368239B
MX368239B MX2014003469A MX2014003469A MX368239B MX 368239 B MX368239 B MX 368239B MX 2014003469 A MX2014003469 A MX 2014003469A MX 2014003469 A MX2014003469 A MX 2014003469A MX 368239 B MX368239 B MX 368239B
Authority
MX
Mexico
Prior art keywords
layer
diesel
support material
palladium
oxidation
Prior art date
Application number
MX2014003469A
Other languages
English (en)
Other versions
MX2014003469A (es
Inventor
Grubert Gerd
Neubauer Torsten
Punke Alfred
Hilgendorff Marcus
Müller-Stach Torsten
Gerlach Olga
Wei Xinyi
Hoke Jeffrey
Sung Shiang
Roth Stanley
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=47913964&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX368239(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basf Se filed Critical Basf Se
Publication of MX2014003469A publication Critical patent/MX2014003469A/es
Publication of MX368239B publication Critical patent/MX368239B/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7057—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7415—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2255/2065—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2255/902—Multilayered catalyst
    • B01D2255/9025—Three layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/912—HC-storage component incorporated in the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

La presente invención se refiere a un catalizador para la oxidación de diesel (DOC) estratificado, que consiste en: a) un sustrato portador; b) un material catalítico para la oxidación de diesel que consiste en: b1) una primera capa colocada sobre el sustrato portador, la primera capa consistente en paladio impregnado sobre un material de soporte que contiene cerio en una cantidad de al menos 45% en peso, con base en el peso total del material de soporte, y como una opción contiene paladio; b2) una segunda capa colocada sobre la primer capa, la segunda capa consiste en paladio y platino cada uno impregnado sobre un material de soporte que consiste en un óxido metálico; en donde la relación en peso de platino a paladio de la primera capa es menor que la relación en peso de platino a paladio de la segunda capa.
MX2014003469A 2011-09-23 2012-09-21 Catalizador para la oxidación de diésel, con estructura estratificada que contiene una composición de cerio como material de soporte de paladio para mejorar la conversión de gas hc y co. MX368239B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11182585 2011-09-23
PCT/IB2012/055030 WO2013042080A1 (en) 2011-09-23 2012-09-21 Diesel oxidation catalyst with layered structure containing ceria composition as palladium support material for enhanced hc and co gas conversion

Publications (2)

Publication Number Publication Date
MX2014003469A MX2014003469A (es) 2014-08-26
MX368239B true MX368239B (es) 2019-09-25

Family

ID=47913964

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014003469A MX368239B (es) 2011-09-23 2012-09-21 Catalizador para la oxidación de diésel, con estructura estratificada que contiene una composición de cerio como material de soporte de paladio para mejorar la conversión de gas hc y co.

Country Status (10)

Country Link
EP (1) EP2758168B2 (es)
JP (1) JP6236389B2 (es)
KR (1) KR102064620B1 (es)
CN (1) CN103945936B (es)
BR (1) BR112014006900B8 (es)
CA (1) CA2849700C (es)
IN (1) IN2014CN02204A (es)
MX (1) MX368239B (es)
PL (1) PL2758168T3 (es)
WO (1) WO2013042080A1 (es)

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WO2015121248A1 (en) * 2014-02-11 2015-08-20 Basf Se Process of treating diesel exhaust gas using ceria-zirconia-mixed oxide particles produced by pyrolysis
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PL3277406T3 (pl) * 2015-03-03 2024-02-05 Basf Corporation Pochłaniacz NOx z mieszanki ubogiej o zwiększonej wydajności w wysokich i niskich temperaturach
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US11794174B2 (en) * 2016-12-05 2023-10-24 Basf Corporation Tetra-functional catalyst for the oxidation of NO, the oxidation of a hydrocarbon, the oxidation of NH3 and the selective catalytic reduction of NOx
GB2557673A (en) * 2016-12-15 2018-06-27 Johnson Matthey Plc NOx adsorber catalyst
WO2018167055A1 (en) 2017-03-14 2018-09-20 Basf Corporation Pt/pd doc with enhanced co oxidation, hydrocarbon oxidation and no oxidation and improved sulfation/desulfation behavior
KR102705124B1 (ko) * 2017-06-09 2024-09-12 바스프 코포레이션 촉매 물품 및 배기가스 처리 시스템
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JP7391042B2 (ja) * 2018-04-30 2023-12-04 ビーエーエスエフ コーポレーション ＮＯの酸化、炭化水素の酸化、ＮＨ３の酸化およびＮＯｘの選択的接触還元のための触媒
CN108940270B (zh) * 2018-06-19 2021-03-16 天津大学 一种钯-氧化铝-堇青石复合材料及其制备方法和用途
CN108569861A (zh) * 2018-07-05 2018-09-25 安徽思凯瑞环保科技有限公司 抗潮解的粗钛粉及其制备方法
CN113164947B (zh) * 2018-12-06 2023-12-01 巴斯夫欧洲公司 包含沸石材料和锆螯合配合物的水性悬浮液
JP2022531492A (ja) * 2019-05-09 2022-07-06 ビーエーエスエフ コーポレーション 向上した水熱安定性を有する低温ＮＯｘ吸着剤
CN110252313A (zh) * 2019-06-20 2019-09-20 武汉科林精细化工有限公司 一种宽温干法烟气脱硝剂及其制备方法
EP3815780B1 (en) 2019-10-30 2024-06-19 Umicore AG & Co. KG Diesel oxidation catalyst
EP4072709A1 (en) * 2019-12-13 2022-10-19 BASF Corporation Zeolite with cu and pd co-exchanged in a composite
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CN111715204B (zh) * 2020-06-11 2021-03-19 华北电力大学 高温烟气用平板式scr脱硝催化剂及其制备方法

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CA2849700A1 (en) 2013-03-28
CN103945936A (zh) 2014-07-23
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WO2013042080A1 (en) 2013-03-28
IN2014CN02204A (es) 2015-06-12
EP2758168B2 (en) 2022-11-16
JP6236389B2 (ja) 2017-11-22
BR112014006900B1 (pt) 2019-08-20
BR112014006900A2 (pt) 2017-04-11
EP2758168A4 (en) 2015-12-02
CA2849700C (en) 2020-02-18
KR102064620B1 (ko) 2020-01-09
CN103945936B (zh) 2016-11-16
KR20140073533A (ko) 2014-06-16
EP2758168B1 (en) 2019-07-31
PL2758168T3 (pl) 2020-02-28
EP2758168A1 (en) 2014-07-30
MX2014003469A (es) 2014-08-26

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