EA201590105A1 - Катализатор и способ селективного получения низших углеводородов c-cиз синтез-газа с низким выходом метана и co - Google Patents

Катализатор и способ селективного получения низших углеводородов c-cиз синтез-газа с низким выходом метана и co

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EA201590105A1
EA201590105A1 EA201590105A EA201590105A EA201590105A1 EA 201590105 A1 EA201590105 A1 EA 201590105A1 EA 201590105 A EA201590105 A EA 201590105A EA 201590105 A EA201590105 A EA 201590105A EA 201590105 A1 EA201590105 A1 EA 201590105A1
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Eurasian Patent Office
Prior art keywords
low
catalyst
ciz
synthesis
gas
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EA201590105A
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English (en)
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EA029026B1 (ru
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Кхалид Карим
Мохаммед Аль-Семахи
Асад Хан
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Сауди Бейсик Индастриз Корпорейшн
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Publication of EA201590105A1 publication Critical patent/EA201590105A1/ru
Publication of EA029026B1 publication Critical patent/EA029026B1/ru

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Abstract

Изобретение относится к каталитической композиции, содержащей оксид кобальта-марганца, который модифицирован диоксидом кремния в форме гидрофильного диоксида кремния, указанный катализатор дополнительно содержит по меньшей мере один из лантана, фосфора, Fe, Zr и Zn и необязательно один или несколько основных элементов, выбранных из группы, состоящей из щелочного металла, щелочно-земельного металла и переходного металла. Кроме того, представлен способ получения указанной каталитической композиции и способ получения алифатических и ароматических углеводородов с применением указанной каталитической композиции.
EA201590105A 2012-06-27 2013-06-25 Катализатор и способ селективного получения низших углеводородов с1-с5 из синтез-газа с низким выходом метана и co EA029026B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261665005P 2012-06-27 2012-06-27
PCT/EP2013/063311 WO2014001354A1 (en) 2012-06-27 2013-06-25 Catalyst and process for the selective production of lower hydrocarbons c1-c5 from syngass with low methane and co2 production

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EA201590105A1 true EA201590105A1 (ru) 2015-05-29
EA029026B1 EA029026B1 (ru) 2018-01-31

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US (2) US9545620B2 (ru)
EP (1) EP2866937A1 (ru)
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9416067B2 (en) 2010-12-22 2016-08-16 Saudi Basic Industries Corporation Catalyst useful in fisher-tropsch synthesis
US9422204B2 (en) 2012-06-25 2016-08-23 Saudi Basic Industries Corporation Process for producing ethylene and propylene from syngas

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA029026B1 (ru) 2012-06-27 2018-01-31 Сауди Бейсик Индастриз Корпорейшн Катализатор и способ селективного получения низших углеводородов с1-с5 из синтез-газа с низким выходом метана и co
EP3027314A2 (en) * 2013-07-31 2016-06-08 Saudi Basic Industries Corporation Catalyst for conversion of synthesis gas
CN107428710A (zh) * 2015-03-05 2017-12-01 赛贝克环球科技公司 与生产环氧乙烷、乙二醇和/或乙醇胺有关的系统和方法
CN105107523A (zh) * 2015-09-02 2015-12-02 中国科学院上海高等研究院 一种用于合成气直接转化为低碳烯烃的钴基催化剂及其制备方法和用途
US20180298292A1 (en) * 2015-09-29 2018-10-18 Sabic Global Technologies B.V. Cyrogenic separation of light olefins and methane from syngas
CN106582708B (zh) * 2015-10-20 2019-06-14 中国石油化工股份有限公司 一种负载型催化剂和应用及费托合成反应的方法
CN110891925A (zh) * 2017-06-30 2020-03-17 华电煤业集团有限公司 一种合成气制芳烃的系统及方法
WO2019150306A1 (en) * 2018-02-05 2019-08-08 Sabic Global Technologies B.V. Catalyst and method related for producing thereof
CN110295054A (zh) * 2018-03-22 2019-10-01 中国石油化工股份有限公司 一种生产混合异构烷烃的方法
US20210238484A1 (en) * 2018-06-05 2021-08-05 Sabic Global Technologies B.V. Bulk-metal crystalline transition metal based heterogeneous catalysts, methods of making and uses thereof
US20210213429A1 (en) * 2018-06-05 2021-07-15 Sabic Global Technologies B.V. Iron-magnesium silica supported catalysts, methods of making and uses thereof
EP3946730A1 (en) 2019-03-29 2022-02-09 ExxonMobil Chemical Patents Inc. Supported nanoparticle compositions and precursors, processes for making the same and syngas conversion processes
CN112517066B (zh) * 2020-12-18 2022-02-01 武汉大学 一种负载型纳米铁基催化剂及其制备方法和应用
CN114588911B (zh) * 2022-03-23 2023-04-14 昆明理工大学 一种钴基催化剂催化丙烷二氧化碳制备合成气的方法

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3932552A (en) 1974-03-25 1976-01-13 Continental Oil Company Integrated process for producing C2 hydrocarbons from carbon monoxide and hydrogen
US4131568A (en) 1975-08-14 1978-12-26 Air Products And Chemicals, Inc. Catalytic synthesis of low molecular weight hydrocarbons
US4177203A (en) 1976-02-12 1979-12-04 Schering Aktiengesellschaft Process for the production of hydrocarbons and oxygen-containing compounds and catalysts therefor
US4451579A (en) 1982-11-08 1984-05-29 The Standard Oil Company Mixed metal oxide catalyst for producing low molecular weight hydrocarbons from carbon monoxide and hydrogen
JPS59179154A (ja) 1983-03-30 1984-10-11 Yoshinobu Takegami 還元触媒およびその製造方法
US5248701A (en) 1991-08-05 1993-09-28 Exxon Research And Engineering Company Substituted cobalt catalysts for Fischer-Tropsch synthesis
EP0833807B1 (en) * 1995-06-16 2004-04-14 Shell Internationale Researchmaatschappij B.V. Catalyst and process for the preparation of hydrocarbons
US5990369A (en) 1995-08-10 1999-11-23 Uop Llc Process for producing light olefins
AT402961B (de) 1996-03-25 1997-10-27 Hoerbiger & Co Reibsystem
ZA9711090B (en) 1996-12-13 1998-06-15 Shell Int Research Process for the preparation of hydrocarbons.
US20020010221A1 (en) 1999-05-19 2002-01-24 Olga Ionkina Fischer-tropsch processes and catalysts with promoters
AU4925799A (en) 1998-09-04 2000-03-27 Sasol Technology (Proprietary) Limited Production of propylene
US6300268B1 (en) 1999-09-10 2001-10-09 Exxon Research And Engineering Company Process for the reactivation of sulfur deactivated cobalt titania catalysts
MY136454A (en) 2000-04-07 2008-10-31 Shell Int Research A process for producing hydrocarbons, and a catalyst suitable for use in the process
JP2004503358A (ja) 2000-06-12 2004-02-05 サソール　テクノロジー（プロプライエタリー）リミテッド コバルト触媒
US20030027874A1 (en) 2001-06-28 2003-02-06 Conoco Inc. Metal oxide-containing catalysts and use thereof in fischer-tropsch processes
US6900151B2 (en) 2001-11-13 2005-05-31 Exxonmobil Research And Engineering Company In situ catalyst regeneration/activation process
US7199068B2 (en) 2002-03-05 2007-04-03 Sasol North America Inc. Reactive distillation alkylation process including in situ catalyst regeneration
US7253136B2 (en) 2003-04-11 2007-08-07 Exxonmobile Research And Engineering Company Preparation of titania and cobalt aluminate catalyst supports and their use in Fischer-Tropsch synthesis
US6992113B2 (en) 2003-11-25 2006-01-31 Chevron U.S.A. Inc. Control of CO2 emissions from a fischer-tropsch facility by use of dual functional syngas conversion
DE102005019103B4 (de) 2004-04-26 2023-09-21 Sasol Technology (Proprietary) Ltd. Verfahren zur Herstellung eines auf Cobalt basierenden Katalysators für die Fischer-Tropsch-Synthese und Verfahren zur Herstellung eines Fischer-Tropsch-Kohlenwasserstoffproduktes
US20080033218A1 (en) 2006-08-03 2008-02-07 Lattner James R Alcohol and olefin production from syngas
WO2008087147A1 (en) 2007-01-18 2008-07-24 Shell Internationale Research Maatschappij B.V. Fischer-tropsch catalyst support and catalyst
EP1970361A1 (en) 2007-03-13 2008-09-17 Total Petrochemicals Research Feluy MTO process based on MeAPO molecular sieves combined with an OCP process to make olefins
WO2008147836A1 (en) 2007-05-23 2008-12-04 David Bradin Production of polypropylene from renewable resources
JP5298195B2 (ja) 2008-08-12 2013-09-25 ルマス テクノロジー インコーポレイテッド 統合されたプロピレン生成
CN101745403B (zh) 2008-12-18 2012-09-12 中国石油化工股份有限公司 一种由合成气制备甲醇、二甲醚和低碳烯烃的方法
EP2439185A1 (en) 2010-08-20 2012-04-11 Shell Internationale Research Maatschappij B.V. Process for preparing olefins from synthesis gas using a cobalt and manganese containing catalyst
EP2422876A1 (en) * 2010-08-20 2012-02-29 Shell Internationale Research Maatschappij B.V. Process for preparing olefins from synthesis gas using a cobalt and manganese containing catalyst
WO2012062721A1 (en) * 2010-11-08 2012-05-18 Shell Internationale Research Maatschappij B.V. Improvements relating to fischer-tropsch catalysts
US9416067B2 (en) 2010-12-22 2016-08-16 Saudi Basic Industries Corporation Catalyst useful in fisher-tropsch synthesis
CN102500425B (zh) * 2011-12-02 2013-09-25 中国科学院山西煤炭化学研究所 硅基多级孔钴基催化剂的制备方法和应用
EP2679568A1 (en) 2012-06-25 2014-01-01 Saudi Basic Industries Corporation Process for production ethylene and propylene from syngas
EA029026B1 (ru) 2012-06-27 2018-01-31 Сауди Бейсик Индастриз Корпорейшн Катализатор и способ селективного получения низших углеводородов с1-с5 из синтез-газа с низким выходом метана и co

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9416067B2 (en) 2010-12-22 2016-08-16 Saudi Basic Industries Corporation Catalyst useful in fisher-tropsch synthesis
US9422204B2 (en) 2012-06-25 2016-08-23 Saudi Basic Industries Corporation Process for producing ethylene and propylene from syngas

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