BR112012023673A2 - catalisador de reforma - Google Patents

catalisador de reforma

Info

Publication number
BR112012023673A2
BR112012023673A2 BR112012023673A BR112012023673A BR112012023673A2 BR 112012023673 A2 BR112012023673 A2 BR 112012023673A2 BR 112012023673 A BR112012023673 A BR 112012023673A BR 112012023673 A BR112012023673 A BR 112012023673A BR 112012023673 A2 BR112012023673 A2 BR 112012023673A2
Authority
BR
Brazil
Prior art keywords
catalyst
reforming
reform catalyst
reform
magnesia
Prior art date
Application number
BR112012023673A
Other languages
English (en)
Other versions
BR112012023673B1 (pt
Inventor
Fernando Cano Morales
Jens-Henrik Bak Hansen
Martin Ostberg
Martin Skov Skjoth-Rasmussen
Thomas Sandahl Christensen
Original Assignee
Haldor Topsoe As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe As filed Critical Haldor Topsoe As
Publication of BR112012023673A2 publication Critical patent/BR112012023673A2/pt
Publication of BR112012023673B1 publication Critical patent/BR112012023673B1/pt

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892Nickel and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/397Egg shell like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/005Spinels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/062Hydrocarbon production, e.g. Fischer-Tropsch process
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/068Ammonia synthesis
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1011Packed bed of catalytic structures, e.g. particles, packing elements
    • C01B2203/1017Packed bed of catalytic structures, e.g. particles, packing elements characterised by the form of the structure
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • C01B2203/1058Nickel catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

catalisador de reforma a presente invenção refere-se a um processo para a reforma a vapor de hidrocarbonetos compreendendo contatar um gás de alimentação com um catalisador que consiste em um composto ativo na forma de uma liga de níquel e uma de irídio, ródio e rutênio, sobre um suporte que compreende alumina, zircônia, magnésia, titânia ou suas combinações.
BR112012023673-3A 2010-03-19 2011-03-18 Processo para a reforma a vapor de hidrocarbonetos, catalisador de reforma e seu método de produção BR112012023673B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DKPA201000225 2010-03-19
DKPA201000225 2010-03-19
DKPA201000384 2010-04-29
DKPA201000384 2010-04-29
PCT/EP2011/001364 WO2011113611A2 (en) 2010-03-19 2011-03-18 Reforming catalyst

Publications (2)

Publication Number Publication Date
BR112012023673A2 true BR112012023673A2 (pt) 2016-08-16
BR112012023673B1 BR112012023673B1 (pt) 2021-08-10

Family

ID=44475202

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012023673-3A BR112012023673B1 (pt) 2010-03-19 2011-03-18 Processo para a reforma a vapor de hidrocarbonetos, catalisador de reforma e seu método de produção

Country Status (9)

Country Link
US (2) US8916492B2 (pt)
KR (1) KR101517502B1 (pt)
CN (1) CN103068723B (pt)
AU (1) AU2011229428B2 (pt)
BR (1) BR112012023673B1 (pt)
CA (1) CA2792325C (pt)
MX (1) MX2012010596A (pt)
RU (1) RU2558150C2 (pt)
WO (1) WO2011113611A2 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201105131D0 (en) * 2011-03-28 2011-05-11 Johnson Matthey Plc Steam reforming
CN104736472A (zh) * 2012-09-26 2015-06-24 埃讷肯公司 合成气分离与重整方法
US9850503B2 (en) * 2013-06-10 2017-12-26 Ineos Bio Sa Control of conductivity in anaerobic fermentation
JP6197052B2 (ja) 2014-02-05 2017-09-13 三井金属鉱業株式会社 燃料改質触媒
EA036700B1 (ru) * 2014-04-07 2020-12-09 Хальдор Топсёэ А/С Катализатор с пропитанной оболочкой и способ получения катализатора с пропитанной оболочкой
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
WO2018004994A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Fluidized bed membrane reactor
BR102016022467B1 (pt) 2016-09-28 2022-02-01 Petróleo Brasileiro S.A. - Petrobras Processo para preparação de um catalisador à base de níquel, catalisador à base de níquel, e, seu uso em um processo de reforma a vapor
RU2638534C1 (ru) 2016-12-15 2017-12-14 Публичное акционерное общество "Нефтяная компания "Роснефть" Катализатор конверсии природного или попутного газа в синтез-газ в процессе автотермического риформинга и способ его получения
US10618042B1 (en) 2017-05-31 2020-04-14 University Of South Florida Mixed metal oxide extrudate catalyst
MX2020003301A (es) * 2017-10-11 2020-07-20 Haldor Topsoe As Un metodo para generar gas de sintesis para la produccion de amoniaco.
GB201907062D0 (en) 2019-05-20 2019-07-03 Johnson Matthey Plc Catalyst preparation method
BR102020000434A2 (pt) * 2020-01-08 2021-07-13 Petróleo Brasileiro S.A. - Petrobras Método de preparo de catalisador de reforma a vapor, catalisador e seu uso

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US4104201A (en) * 1974-09-06 1978-08-01 British Gas Corporation Catalytic steam reforming and catalysts therefor
BE886363A (fr) * 1980-11-26 1981-03-16 Catalysts & Chem Europ Catalyseurs de reformage et leur utilisation
US5814112A (en) * 1992-06-05 1998-09-29 Battelle Memorial Institute Nickel/ruthenium catalyst and method for aqueous phase reactions
NZ253874A (en) 1992-06-05 1996-04-26 Battelle Memorial Institute Catalytic conversion of liquid organic materials into a product gas of methane, carbon dioxide and hydrogen
ES2120538T3 (es) 1993-05-17 1998-11-01 Haldor Topsoe As Reformacion por vapor a alta temperatura.
IT1283585B1 (it) 1996-04-11 1998-04-22 Snam Progetti Apparecchiatura per effettuare reazioni di ossidazione parziale
US6409940B1 (en) * 1999-10-18 2002-06-25 Conoco Inc. Nickel-rhodium based catalysts and process for preparing synthesis gas
WO2002038268A1 (fr) 2000-11-08 2002-05-16 Idemitsu Kosan Co., Ltd. Catalyseur de reformage pour hydrocarbures et procede de reformage correspondant
US7230035B2 (en) 2002-12-30 2007-06-12 Conocophillips Company Catalysts for the conversion of methane to synthesis gas
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GB0510514D0 (en) * 2005-05-24 2005-06-29 Johnson Matthey Plc Steam reforming
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Also Published As

Publication number Publication date
AU2011229428B2 (en) 2014-07-03
MX2012010596A (es) 2012-10-03
CN103068723B (zh) 2016-02-10
CN103068723A (zh) 2013-04-24
RU2558150C2 (ru) 2015-07-27
US20120329645A1 (en) 2012-12-27
KR101517502B1 (ko) 2015-05-04
RU2012144371A (ru) 2014-04-27
CA2792325C (en) 2015-11-03
CA2792325A1 (en) 2011-09-22
WO2011113611A3 (en) 2011-11-10
WO2011113611A2 (en) 2011-09-22
US9393552B2 (en) 2016-07-19
US20150080212A1 (en) 2015-03-19
BR112012023673B1 (pt) 2021-08-10
KR20130016271A (ko) 2013-02-14
AU2011229428A1 (en) 2012-10-11
US8916492B2 (en) 2014-12-23

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06T Formal requirements before examination [chapter 6.20 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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