BR112012023673A2 - catalisador de reforma - Google Patents
catalisador de reformaInfo
- Publication number
- BR112012023673A2 BR112012023673A2 BR112012023673A BR112012023673A BR112012023673A2 BR 112012023673 A2 BR112012023673 A2 BR 112012023673A2 BR 112012023673 A BR112012023673 A BR 112012023673A BR 112012023673 A BR112012023673 A BR 112012023673A BR 112012023673 A2 BR112012023673 A2 BR 112012023673A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- reforming
- reform catalyst
- reform
- magnesia
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 238000002407 reforming Methods 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229910000990 Ni alloy Inorganic materials 0.000 abstract 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/397—Egg shell like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/005—Spinels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/068—Ammonia synthesis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
- C01B2203/1017—Packed bed of catalytic structures, e.g. particles, packing elements characterised by the form of the structure
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
catalisador de reforma a presente invenção refere-se a um processo para a reforma a vapor de hidrocarbonetos compreendendo contatar um gás de alimentação com um catalisador que consiste em um composto ativo na forma de uma liga de níquel e uma de irídio, ródio e rutênio, sobre um suporte que compreende alumina, zircônia, magnésia, titânia ou suas combinações.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA201000225 | 2010-03-19 | ||
DKPA201000225 | 2010-03-19 | ||
DKPA201000384 | 2010-04-29 | ||
DKPA201000384 | 2010-04-29 | ||
PCT/EP2011/001364 WO2011113611A2 (en) | 2010-03-19 | 2011-03-18 | Reforming catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112012023673A2 true BR112012023673A2 (pt) | 2016-08-16 |
BR112012023673B1 BR112012023673B1 (pt) | 2021-08-10 |
Family
ID=44475202
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112012023673-3A BR112012023673B1 (pt) | 2010-03-19 | 2011-03-18 | Processo para a reforma a vapor de hidrocarbonetos, catalisador de reforma e seu método de produção |
Country Status (9)
Country | Link |
---|---|
US (2) | US8916492B2 (pt) |
KR (1) | KR101517502B1 (pt) |
CN (1) | CN103068723B (pt) |
AU (1) | AU2011229428B2 (pt) |
BR (1) | BR112012023673B1 (pt) |
CA (1) | CA2792325C (pt) |
MX (1) | MX2012010596A (pt) |
RU (1) | RU2558150C2 (pt) |
WO (1) | WO2011113611A2 (pt) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201105131D0 (en) * | 2011-03-28 | 2011-05-11 | Johnson Matthey Plc | Steam reforming |
CN104736472A (zh) * | 2012-09-26 | 2015-06-24 | 埃讷肯公司 | 合成气分离与重整方法 |
US9850503B2 (en) * | 2013-06-10 | 2017-12-26 | Ineos Bio Sa | Control of conductivity in anaerobic fermentation |
JP6197052B2 (ja) | 2014-02-05 | 2017-09-13 | 三井金属鉱業株式会社 | 燃料改質触媒 |
EA036700B1 (ru) * | 2014-04-07 | 2020-12-09 | Хальдор Топсёэ А/С | Катализатор с пропитанной оболочкой и способ получения катализатора с пропитанной оболочкой |
WO2018004993A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Reduction of greenhouse gas emission |
US9981896B2 (en) | 2016-07-01 | 2018-05-29 | Res Usa, Llc | Conversion of methane to dimethyl ether |
WO2018004994A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Fluidized bed membrane reactor |
BR102016022467B1 (pt) | 2016-09-28 | 2022-02-01 | Petróleo Brasileiro S.A. - Petrobras | Processo para preparação de um catalisador à base de níquel, catalisador à base de níquel, e, seu uso em um processo de reforma a vapor |
RU2638534C1 (ru) | 2016-12-15 | 2017-12-14 | Публичное акционерное общество "Нефтяная компания "Роснефть" | Катализатор конверсии природного или попутного газа в синтез-газ в процессе автотермического риформинга и способ его получения |
US10618042B1 (en) | 2017-05-31 | 2020-04-14 | University Of South Florida | Mixed metal oxide extrudate catalyst |
MX2020003301A (es) * | 2017-10-11 | 2020-07-20 | Haldor Topsoe As | Un metodo para generar gas de sintesis para la produccion de amoniaco. |
GB201907062D0 (en) | 2019-05-20 | 2019-07-03 | Johnson Matthey Plc | Catalyst preparation method |
BR102020000434A2 (pt) * | 2020-01-08 | 2021-07-13 | Petróleo Brasileiro S.A. - Petrobras | Método de preparo de catalisador de reforma a vapor, catalisador e seu uso |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4104201A (en) * | 1974-09-06 | 1978-08-01 | British Gas Corporation | Catalytic steam reforming and catalysts therefor |
BE886363A (fr) * | 1980-11-26 | 1981-03-16 | Catalysts & Chem Europ | Catalyseurs de reformage et leur utilisation |
US5814112A (en) * | 1992-06-05 | 1998-09-29 | Battelle Memorial Institute | Nickel/ruthenium catalyst and method for aqueous phase reactions |
NZ253874A (en) | 1992-06-05 | 1996-04-26 | Battelle Memorial Institute | Catalytic conversion of liquid organic materials into a product gas of methane, carbon dioxide and hydrogen |
ES2120538T3 (es) | 1993-05-17 | 1998-11-01 | Haldor Topsoe As | Reformacion por vapor a alta temperatura. |
IT1283585B1 (it) | 1996-04-11 | 1998-04-22 | Snam Progetti | Apparecchiatura per effettuare reazioni di ossidazione parziale |
US6409940B1 (en) * | 1999-10-18 | 2002-06-25 | Conoco Inc. | Nickel-rhodium based catalysts and process for preparing synthesis gas |
WO2002038268A1 (fr) | 2000-11-08 | 2002-05-16 | Idemitsu Kosan Co., Ltd. | Catalyseur de reformage pour hydrocarbures et procede de reformage correspondant |
US7230035B2 (en) | 2002-12-30 | 2007-06-12 | Conocophillips Company | Catalysts for the conversion of methane to synthesis gas |
US20050089464A1 (en) | 2003-10-22 | 2005-04-28 | General Electric Company | Production Of Syngas For Fuel Cells Using Multiple Catalyst Configuration |
GB0510514D0 (en) * | 2005-05-24 | 2005-06-29 | Johnson Matthey Plc | Steam reforming |
CN101257971A (zh) | 2005-08-04 | 2008-09-03 | Sk能源株式会社 | 不经过预还原处理的蒸汽转化镍基催化剂 |
WO2007015620A1 (en) | 2005-08-04 | 2007-02-08 | Sk Energy Co., Ltd. | Steam reforming ni-based catalyst without pre-reduction treatment |
US20070238610A1 (en) | 2006-04-05 | 2007-10-11 | Laiyuan Chen | Fuel reformer catalyst |
US9387470B2 (en) | 2007-01-19 | 2016-07-12 | The Penn State Research Foundation | Sulfur-tolerant and carbon-resistant catalysts |
US20090108238A1 (en) | 2007-10-31 | 2009-04-30 | Sud-Chemie Inc. | Catalyst for reforming hydrocarbons |
GB0816703D0 (en) * | 2008-09-12 | 2008-10-22 | Johnson Matthey Plc | Shaped heterogeneous catalysts |
WO2010078035A2 (en) | 2008-12-17 | 2010-07-08 | Synch Energy Corporation | Process and system for converting biogas to liquid fuels |
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2011
- 2011-03-18 MX MX2012010596A patent/MX2012010596A/es active IP Right Grant
- 2011-03-18 US US13/583,597 patent/US8916492B2/en active Active
- 2011-03-18 CN CN201180024791.6A patent/CN103068723B/zh active Active
- 2011-03-18 AU AU2011229428A patent/AU2011229428B2/en active Active
- 2011-03-18 KR KR1020127026603A patent/KR101517502B1/ko active IP Right Grant
- 2011-03-18 WO PCT/EP2011/001364 patent/WO2011113611A2/en active Application Filing
- 2011-03-18 RU RU2012144371/04A patent/RU2558150C2/ru active
- 2011-03-18 CA CA2792325A patent/CA2792325C/en active Active
- 2011-03-18 BR BR112012023673-3A patent/BR112012023673B1/pt active IP Right Grant
-
2014
- 2014-11-25 US US14/552,594 patent/US9393552B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
AU2011229428B2 (en) | 2014-07-03 |
MX2012010596A (es) | 2012-10-03 |
CN103068723B (zh) | 2016-02-10 |
CN103068723A (zh) | 2013-04-24 |
RU2558150C2 (ru) | 2015-07-27 |
US20120329645A1 (en) | 2012-12-27 |
KR101517502B1 (ko) | 2015-05-04 |
RU2012144371A (ru) | 2014-04-27 |
CA2792325C (en) | 2015-11-03 |
CA2792325A1 (en) | 2011-09-22 |
WO2011113611A3 (en) | 2011-11-10 |
WO2011113611A2 (en) | 2011-09-22 |
US9393552B2 (en) | 2016-07-19 |
US20150080212A1 (en) | 2015-03-19 |
BR112012023673B1 (pt) | 2021-08-10 |
KR20130016271A (ko) | 2013-02-14 |
AU2011229428A1 (en) | 2012-10-11 |
US8916492B2 (en) | 2014-12-23 |
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