KR970070124A - 열경화성수지조성물, 경화물, 프리프레그, 금속장적층판 및 배선판 - Google Patents

열경화성수지조성물, 경화물, 프리프레그, 금속장적층판 및 배선판 Download PDF

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KR970070124A
KR970070124A KR1019970003795A KR19970003795A KR970070124A KR 970070124 A KR970070124 A KR 970070124A KR 1019970003795 A KR1019970003795 A KR 1019970003795A KR 19970003795 A KR19970003795 A KR 19970003795A KR 970070124 A KR970070124 A KR 970070124A
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thermosetting resin
resin composition
prepreg
compound
substrate
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KR100205271B1 (ko
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히데오 나가세
데루끼 아이자와
야스유끼 히라이
요시히꼬 사또
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단노 다께시
히다찌 가세이 고오교 가부시끼가이샤
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/14Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/08Impregnating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/34Condensation polymers of aldehydes or ketones with monomers covered by at least two of the groups C08L61/04, C08L61/18 and C08L61/20
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0313Organic insulating material
    • H05K1/032Organic insulating material consisting of one material
    • H05K1/0326Organic insulating material consisting of one material containing O
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2315/00Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
    • B32B2315/08Glass
    • B32B2315/085Glass fiber cloth or fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • B32B2457/08PCBs, i.e. printed circuit boards
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/901Printed circuit
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24917Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including metal layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • Y10T428/31515As intermediate layer
    • Y10T428/31522Next to metal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • Y10T428/31529Next to metal

Abstract

디히드로벤족사진 고리를 함유하는 열경화성수지를 60 내지 97중량% 및 노볼락 페놀 수지 3 내지 40중량%를 함유하는 열 경화성 수지 조성물 (a) 및 디히드로벤족사진 고리를 함유하는 열경화성수지를 5 내지 30중량% 및 노볼락 페놀 수지 70 내지 95중량%를 함유하는 열 경화성 수지 조성물 (b)는 빠르게 경화되고, 이의 경화물은 기게적 특정 및 비인화성에서 우수하다.

Description

열경화성수지조성물, 경화물, 프리프레그, 금속장적층판 및 배선판
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 디히드로벤족사진 고리를 함유하는 열경화성수지를 60 내지 97중량% 및 노볼락 페놀 수지를 3 내지 40중량% 함유하는 열경화성 수지 조성물.
  2. 제1항에 있어서, 노볼락 페놀 수지는 50% 이상의 오르토비를 갖는 열경화성 수지 조성물.
  3. 제1항에 있어서, 열경화성 수지 조성물내의 페놀성 히드록실기 및 디히드로벤족사진 고리내에 함유된 질소원자는 1.5 이하의 페놀성 히드록실기/질소원자의 수비를 갖는 열경화성 수지 조성물.
  4. 제1항에 있어서, 디히드로벤족사진 고리를 함유하는 열경화성수지는 히드록실기에 대한 한쪽 또는 양쪽 오르토-위치에서 각각 수소를 함유하는 2개이상의 히드록시페닐렌기를 갖는 화합물, 화합물의 페놀성 히드록 실기의 1몰당 0.5 내지 1.0몰의 일차아민, 및 일차 아민 1몰당 2몰이상의 포름알데히드의 반응 생성물인 열경화성 수지 조성물.
  5. 제4항에 있어서, 화합물은 페놀 노볼락 수지 또는 비스페놀 A인 열경화성 수지 조성물.
  6. 제1항의 열경화성 수지 조성물의 경화물.
  7. 기재에 제1항의 열경화성 수지 조성물을 함유하는 니스를 함침시킨 후, 이어서 열로 건조시켜 제조한 프리프레그.
  8. 제7항에 있어서, 기재는 유리포, 부직유리포, 유기섬유포, 부직유기섬유포 또는 종이인 프리프레그.
  9. 제7항의 프리프레그를 두 쉬트이상 열 및 압력을 이용하여 함께 결합시켜 제조한 적층물, 및 적층물의 한면 또는 양면에 결합된 금속박으로 구성된 금속장적층판.
  10. 제1항의 열경화성 수지 조성물의 매트릭스 및 매트릭스 강화 기재로 구성된 절연기판 및 절연기판의 내부 또는 한면 또는 양면에 형성된 도선패턴으로 구성된 배선판.
  11. 디히드로벤족사진 고리를 함유하는 열경화성수지를 5 내지 30중량% 및 노볼락 페놀수지를 70 내지 95중량% 함유하는 열경화성 수지 조성물.
  12. 제11항에 있어서, 노볼락 페놀 수지는 50%이상의 오르토비를 갖는 열경화성 수지 조성물.
  13. 제11항에 있어서, 디히드로벤족사진 고리를 함유하는 열경화성수지는 히드록실기에 대한 한쪽 또는 양쪽 오르토-위치에서 각각 수소를 함유하는 2개이상의 히드록시페닐렌기를 갖는 화합물, 화합물의 페놀성 히드록 실기의 1몰당 0.5 내지 1.0몰의 일차아민, 및 일차 아민 1몰당 2몰이상의 포름알데히드의 반응 생성물인 열경화성 수지 조성물.
  14. 제13항에 있어서, 화합물은 페놀 노볼락 수지 또는 비스페놀 A인 열경화성 수지 조성물.
  15. 제11항의 열경화성 수지 조성물의 경화물.
  16. 제11항의 열경화성 수지 조성물을 함유하는 니스를 기재에 함침시킨 후, 이어서 열로 건조시켜 제조한 프리프레그.
  17. 제16항에 있어서, 기재는 유리포, 부직유리포, 유기섬유포, 부직유기섬유포 또는 종이인 프리프레그.
  18. 제16항의 프리프레그를 두 쉬트이상 열 및 압력을 이용하여 함께 결합시켜 제조한 적층물, 및 적층물의 한면 또는 양면에 결합된 금속박으로 구성된 금속장적층판.
  19. 제11항의 열경화성 수지 조성물의 매트릭스 및 매트릭스 강화 기재로 구성된 절연기판 및 절연기판의 내부 또는 한면 또는 양면에 형성된 도선패턴으로 구성된 배선판.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970003795A 1996-02-09 1997-02-06 열경화성수지조성물, 경화물, 프리프레그, 금속장적층판 및 배선판 KR100205271B1 (ko)

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JP2429296 1996-02-09
JP96-024292 1996-02-09
JP16778596A JP3487083B2 (ja) 1996-02-09 1996-06-27 熱硬化性樹脂組成物及びその硬化物
JP96-167785 1996-06-27

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US (1) US5945222A (ko)
EP (1) EP0789056B1 (ko)
JP (1) JP3487083B2 (ko)
KR (1) KR100205271B1 (ko)
CN (1) CN1088727C (ko)
DE (1) DE69724169T2 (ko)
MY (1) MY121250A (ko)
TW (1) TW460537B (ko)

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CN1161986A (zh) 1997-10-15
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DE69724169T2 (de) 2004-05-27
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MY121250A (en) 2006-01-28
TW460537B (en) 2001-10-21
DE69724169D1 (de) 2003-09-25
KR100205271B1 (ko) 1999-07-01
US5945222A (en) 1999-08-31
JPH09272786A (ja) 1997-10-21
CN1088727C (zh) 2002-08-07
JP3487083B2 (ja) 2004-01-13

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