KR960000484A - 섬유강화수지 플레이트 및 이의 제조방법 - Google Patents

섬유강화수지 플레이트 및 이의 제조방법 Download PDF

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KR960000484A
KR960000484A KR1019950011094A KR19950011094A KR960000484A KR 960000484 A KR960000484 A KR 960000484A KR 1019950011094 A KR1019950011094 A KR 1019950011094A KR 19950011094 A KR19950011094 A KR 19950011094A KR 960000484 A KR960000484 A KR 960000484A
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modified phenolic
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마사히로 쓰무라
히로미 미야시따
가네요시 오야마
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후꾸다 다께지
가시마 세끼유 가부시끼가이샤
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Abstract

본 발명은 섬유성 적층기재 및 상기 섬유성 적층기재에 포함된 섬유질과 결합된 매트릭스를 포함하며, 상기 매트릭스는 고반응성 변성 페놀 수지(A) 및 에폭시 수지(B)를 포함하는 수지 조성물을 경화시켜 제조된 것이고, 상기 고반응성 변성 페놀 수지(A)는 산촉매 존재하에 중유 또는 피치, 포름알데히드 중합체 및 페놀의 중축합에 의해서 제조된 변성 페놀 수지를 산촉매 존재하에 페놀과 반응시켜 분자량을 감소시켜서 제조된 것임을 특징으로 하는 섬유강화수지 플레이트에 관한 것이다. 또한, 본 발명은 수지함침가공재 및 상기 섬유강화수지 플레이트의 제조방법에 관한 것으로, 고반응성 변성 페놀 수지(a) 및 에폭시 수지(b)를 포함하는 상기의 수지 조성물을 경화하여 매트릭스가 형성되기 때문에 상기 섬유강화수지 플레이트는 구리 및 그외 금속에의 부착성, 내열성 및 전기절연성에 있어서 우수할 뿐만 아니라, 특히 가열시에 대법안정도(dimensional stability), 강도 및 다른 기계적 성질에 있어서 우수하다.

Description

섬유강화수지 플레이트 및 이의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 섬유성 적층기재와 매트릭스를 포함하며, 상기 매트릭스는 고반응성 변성 페놀수지(A) 및 에폭시 수지(B)를 포함하는 수지 조성물을 경화시켜 제조된 것이고, 상기 고반응성 변성 페놀 수지(A)는 산촉매 존재하에 중유 또는 피치, 포름알데히드 중합체 및 페놀을 중축합시켜서 제조된 변성 페놀 수지를 페놀과 반응시켜 분자량을 감소시킴으로써 제조된 것임을 특징으로 하는 섬유강화수지 플레이트.
  2. 제1항에 있어서, 다수개의 섬유성 적층기재를 포함하는 라미네이트 형태임을 특징으로 하는 섬유강화수지 플레이트.
  3. 제1항에 있어서, 수지 조성물이 고반응성 변성 페놀 수지(A) 및 에폭시 수지(B)를 혼합 중량비 10/90~90/10으로 포함함을 특징으로 하는 섬유강화수지 플레이트.
  4. 섬유성 적층기재 및 상기 섬유성 적층기재에 함침된 반경화 상태의 수지 조성물을 포함하며, 상기 수지 조성물은 고반응성 변성 페놀 수지(A) 및 에폭시 수지(B)를 포함하고, 상기 고반응성 변성 페놀 수지(A)는 산촉매 존재하에 중유 또는 피치, 포름알데히드 중합체 및 페놀의 중축합에 의해서 제조된 변성 페놀 수지를, 산촉매 존재하에 페놀과 반응시켜 분자량을 감소시켜서 제조한 것임을 특징으로 하는 수지함침가공재.
  5. 하기단계 (a) 내지 (c): (a) 산촉매 존재하 중유 또는 피치, 포름알데히드 중합체 및 페놀의 중축합에 의해서 제조된 변성 페놀 수지를, 산촉매 존재하에 페놀과 반응시켜 분자량을 감소시킴으로써 제조된 고반응성 변성 페놀 수지(A), 에폭시 수지(B) 및 경화제 및/또는 경화촉진제(C)를 포함하는 수지 조성물을 유기용매에 용해시켜서 유약를 제조하는 단계; (b) 산기 유약을 섬유성 적층기재에 함침시킨 후, 상기 수지조성물을 건조시키고 반쯤 경화시켜 수지함침가공재를 제조하는 단계 및; (c) 상기 수지 침투가공재 내에 포함된 수지 조성물을 완전히 경화시키는 단계를 포함함을 특징으로 하는 섬유강화수지 플레이트의 제조방법.
  6. 제5항에 있어서, 상기 수지 조성물의 완전 경화 단계 이전에 다수개의 수지함침가공재를 제조하고 적충시킴을 특징으로 하는 섬유강화수지 플레이트의 제조방법.
  7. 제5항에 있어서, 상기 유약은, 유기용매에 고반응성 변성 페놀 수지(A)를 용해시킴으로써 얻어진 페놀 수지 유약을, 유기용매에 에폭시 수지(B)를 용해시킴으로써 얻어진 에폭시 수지 유약과 혼합함으로써 제조되어짐을 특징으로 하는 섬유강화수지 플레이트의 제조 방법.
  8. 제5항에 있어서, 상기 유약은, 유기용매에 고반응성 변성 페놀 수지(A)를 유기용매에 용해시킴으로써 얻어진 페놀 수지 유약 내에 에폭시 수지(B)를 첨가하여 용해시킴으로써 제조되어짐을 특징으로 하는 상기 섬유강화수지 플레이트의 제조 방법.
  9. 제5항에 있어서, 상기 유기용매는 방향족 탄화수소, 아미드, 케톤, 할로겐화 방향족 탄화수소 및 알코올로 구성된 군에서 선택된 적어도 1종임을 특징으로 하는 섬유강화수지 플레이트의 제조 방법.
  10. 제9항에 있어서, 상기 방향족 탄화수소는 벤젠, 톨루엔 및 크실렌으로 구성된 군에서 선택된 적어도 1종임을 특징으로 하는 섬유강화수지 플레이트의 제조 방법.
  11. 제5항에 있어서, 상기 수지함침가공재 내에 함침된 수지 조성물은 150~300℃에서 열경화처리하여 완전히 경화됨을 특징으로 하는 섬유강화수지 플레이트의 제조 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950011094A 1994-06-03 1995-05-06 섬유강화수지 플레이트 및 이의 제조방법 KR0168714B1 (ko)

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JPH0239928A (ja) * 1988-07-29 1990-02-08 Shin Kobe Electric Mach Co Ltd フェノール樹脂積層板
JPH0662734B2 (ja) * 1988-09-09 1994-08-17 住友ベークライト株式会社 積層板用エポキシ樹脂組成物
JPH02229823A (ja) * 1989-03-03 1990-09-12 Kashima Sekiyu Kk 熱硬化性縮合多環芳香族炭化水素樹脂の製造方法及びそれからの熱硬化体の製造方法
JPH0689092B2 (ja) * 1989-04-17 1994-11-09 鹿島石油株式会社 石油系重質油類またはピッチ類により変性したフェノール樹脂の製造法
JPH03247616A (ja) * 1990-02-27 1991-11-05 Kashima Sekiyu Kk 芳香族系石油樹脂の製造方法
JPH0442804A (ja) * 1990-06-08 1992-02-13 Kashima Sekiyu Kk 炭素材料の製造方法
JPH04142359A (ja) * 1990-10-03 1992-05-15 Kashima Sekiyu Kk ガラス繊維強化熱硬化性樹脂および該樹脂成形品の製造方法
JPH04145116A (ja) * 1990-10-05 1992-05-19 Kashima Sekiyu Kk 新規変性フェノール樹脂の製造方法
JPH04250034A (ja) * 1990-10-16 1992-09-04 Kashima Sekiyu Kk 変性フェノール樹脂積層板の製造方法
JPH04348933A (ja) * 1991-03-18 1992-12-03 Kashima Sekiyu Kk エポキシ樹脂混合変性フェノール樹脂積層板の製造方法
JP2966974B2 (ja) * 1991-07-15 1999-10-25 鹿島石油株式会社 変性フェノール樹脂混合エポキシ樹脂積層板の製造方法
JPH05217900A (ja) * 1992-02-03 1993-08-27 Nec Kyushu Ltd 半導体製造装置
JP3158695B2 (ja) * 1992-08-17 2001-04-23 日立化成工業株式会社 積層板用フェノール樹脂の可撓剤、積層板用植物油変性フェノール樹脂、プリプレグ及び銅張り積層板の製造法
JPH06228257A (ja) * 1993-02-05 1994-08-16 Kashima Sekiyu Kk 酸不含の変性フェノール樹脂、エポキシ樹脂含有変性フェノール樹脂成形材料と半導体封止材
TW354796B (en) * 1994-01-27 1999-03-21 Kashima Oil Process for producing highly reactive modified phenolic resin

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EP0687703A3 (en) 1996-08-28
DE69528015D1 (de) 2002-10-10
US5614600A (en) 1997-03-25
KR0168714B1 (ko) 1999-01-15
EP0687703A2 (en) 1995-12-20
DE69528015T2 (de) 2003-04-30
EP0687703B1 (en) 2002-09-04

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