KR890008249A - 이작용성 에폭시 수지, 다작용성 에폭시 수지, 이작용성 페놀 및 다작용성 페놀을 함유하는 경화성 조성물 - Google Patents
이작용성 에폭시 수지, 다작용성 에폭시 수지, 이작용성 페놀 및 다작용성 페놀을 함유하는 경화성 조성물 Download PDFInfo
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- KR890008249A KR890008249A KR1019880005136A KR880005136A KR890008249A KR 890008249 A KR890008249 A KR 890008249A KR 1019880005136 A KR1019880005136 A KR 1019880005136A KR 880005136 A KR880005136 A KR 880005136A KR 890008249 A KR890008249 A KR 890008249A
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- phenolic hydroxyl
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- epoxy resin
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- 239000000203 mixture Substances 0.000 title claims 17
- 239000003822 epoxy resin Substances 0.000 title claims 8
- 229920000647 polyepoxide Polymers 0.000 title claims 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims 6
- 230000001588 bifunctional effect Effects 0.000 title 2
- 150000001875 compounds Chemical class 0.000 claims 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims 2
- 150000002118 epoxides Chemical group 0.000 claims 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 claims 2
- 229920001568 phenolic resin Polymers 0.000 claims 2
- -1 phenoxy hydroxyl Chemical group 0.000 claims 2
- RILZRCJGXSFXNE-UHFFFAOYSA-N 2-[4-(trifluoromethoxy)phenyl]ethanol Chemical compound OCCC1=CC=C(OC(F)(F)F)C=C1 RILZRCJGXSFXNE-UHFFFAOYSA-N 0.000 claims 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 239000004020 conductor Substances 0.000 claims 1
- 125000003700 epoxy group Chemical group 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 229920003986 novolac Polymers 0.000 claims 1
- 239000004843 novolac epoxy resin Substances 0.000 claims 1
- TWWBIMNLBUYJKB-UHFFFAOYSA-N phosphanyl acetate Chemical group CC(=O)OP TWWBIMNLBUYJKB-UHFFFAOYSA-N 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
- C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
- C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3218—Carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
- C08G59/621—Phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/032—Organic insulating material consisting of one material
- H05K1/0326—Organic insulating material consisting of one material containing O
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
- Y10T428/31522—Next to metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31529—Next to metal
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Epoxy Resins (AREA)
- Laminated Bodies (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- (A)필수적으로(1)분자당(평균)2개 이하의 인접한 에폭사이드 그룹을 갖는 하나 이상의 에폭시 수지 5 내지 96중량%: 및 (2)분자당(평균)2개 이상의 인접한 에폭사이드 그룹을 갖는 하나 이상의 에폭시 수지 95 내지 5중량%로 구성된 에폭시-함유 성분: 및 (B)필수적으로(1)분자당 평균 2개 이하의 페놀성 히드록실 그룹을 갖는 하나 이상의 페놀성 히드록실-함유 화합물 10 내지 70중량%: 및 (2)분자당 평균 2개 이상의 페놀성 히드록실 그룹을 갖는 하나 이상의 페놀성 히드록실-함유 화합물 90 내지 30중량%로 구성된 페놀성 히드록실-함유 성분으로 이루어지며, 성분(A) 및 (B)가 각각의 에폭시 그룹에 대한 페놀성 히드록실 그룹의 비가 0.75:1 내지 1.2:1이 되도록 하는 양으로 존재하는 조성물.
- 제1항에 있어서, (a)성분(A-1)이 하기 일반식(Ⅰ) 또는 (Ⅱ)의 에폭시 수지 또는 이러한 에폭시 수지의 혼합물이고, (b)성분(A-2)이 하기 일반식(Ⅲ) 또는 (Ⅳ)의 에폭시 수지 또는 이러한 에폭시 수지의 혼합물이며, (c)성분(B-1)이 하기 일반식(Ⅴ) 또는 (Ⅵ)의 페놀성 히드록실-함유 화합물 또는 이러한 페놀성 히드록실-함유 화합물의 혼합물이고, (d)성분(B-2)가 하기 일반식(Ⅶ) 또는 (Ⅷ)의 페녹성 히드록실-함유 화합물 또는 이러한 페놀성 히드록실-함유 화합물의 혼합물인 조성물.상기식에서 A는 각각 독립적으로 C1내지 C10의 2가 히드로카르빌그룹, -S-, -S-S-, -SO-, -SO2-, -CO- 또는 -O-이며, A'는 각각 독립적으로 C1내지 C10의 2가 히드로카르빌 그룹이고, R은 각각 독립적으로 수소 또는 C1내지 C3의 알킬그룹이며, R'는 각각 독립적으로 수소 또는 C1내지 C10의 히드로카르빌 그룹이고, x는 각각 독립적으로 수소, C1내지 C10의 알킬 그룹 또는 할로겐이며, m은 0,1 내지 7이고, m'는 0 내지 3이며, n은 각각 독립적으로 0 또는 1이고, n'는 0 내지 10이다.
- 제2항에 있어서, (a)성분(A-1)이 n이 1이고 n'가 0 내지 2인 일반식(Ⅱ)의 디글리시딜 에테르이고, (b)성분(A-2)가 m이 1 내지 5인 일반식(Ⅲ)의 폴리글리시딜 에테르이며, (c)성분(B-1)이 n이 1인 일반식(Ⅵ)의 페놀성 히드록실-함유 화합물이고, (d)성분(B-2)가 m이 0,1 내지 7인 일반식(Ⅶ)의 페놀성 히드록실-함유 화합물인 조성물.
- 제3항에 있어서, (a)성분(A-1)이 n이 1이고 n'가 0 내지 2인 일반식(Ⅱ)의 디글리시딜 에테르이고, (b)성분(A-2)가 페놀-포름알데히드 노볼락 에폭시 수지의폴리글리시딜 에테르이며, (c)성분(B-1)이 비스페놀 A또는 테트라브로모비스페놀 A이고, (d)성분(B-2)가 페놀-포름알데히드 노볼락 수지인 조성물.
- 제1항에 있어서, 성분(A)와 (B)의 반응을 수행하기 위한 하나 이상의 촉매(C)의 촉매량을 추가로 함유하는 조성물.
- 제5항에 있어서, 촉매가 포스포늄 화합물, 이미다졸 또는 이의 혼합물인 조성물.
- 제6항에 있어서, 촉매가 1:0.9 내지 1:1.25의 몰비의 4급 포스포늄 아세테이트, 아세트산 착물: 플루오로 붕산, 2-메틸이미다졸 또는 이의 혼합물인 조성물.
- 제1항에 있어서, 안정화제를 추가로 함유하는 조성물.
- 제5항 내지 제7항중 어느 한항에 있어서, 총 조성물의 1 내지 75중량%의 양으로 하나 이상의 용매(D)를 추가로 함유하는 조성물.
- 제5항 내지 제7항중 어느 한항의 조성물을 경화시켜 수득한 제품.
- 제9항의 조성물로 침지시킨 기질 재표의 하나 이상의 층을 경화시켜 수득한 적층판.
- 제11항에 있어서, 전기 전도성 재표의 외층을 갖는 적층판.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/121,329 US4868059A (en) | 1987-11-16 | 1987-11-16 | Curable composition containing a difunctional epoxy resin, a polyfunctional epoxy resin, a difunctional phenol and a polyfunctional phenol |
US121,329 | 1987-11-16 | ||
US121329 | 1987-11-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890008249A true KR890008249A (ko) | 1989-07-10 |
KR920001742B1 KR920001742B1 (ko) | 1992-02-24 |
Family
ID=22395980
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880005136A KR920001742B1 (ko) | 1987-11-16 | 1988-05-03 | 이작용성 에폭시 수지, 다작용성 에폭시 수지, 이작용성 페놀 및 다작용성 페놀을 함유하는 경화성 조성물 |
Country Status (10)
Country | Link |
---|---|
US (1) | US4868059A (ko) |
EP (1) | EP0316509A3 (ko) |
JP (1) | JP2716726B2 (ko) |
KR (1) | KR920001742B1 (ko) |
AU (1) | AU607989B2 (ko) |
BR (1) | BR8802396A (ko) |
CA (1) | CA1333732C (ko) |
IL (1) | IL86138A (ko) |
MX (1) | MX165339B (ko) |
MY (1) | MY103263A (ko) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0487164A3 (en) * | 1985-11-26 | 1992-06-24 | Sumitomo Chemical Company, Limited | Thermosetting resin composition and a composite material comprising the cured product of the resin composition as its matrix |
AU608627B2 (en) * | 1987-08-10 | 1991-04-11 | Dow Chemical Company, The | Curing agent compositions, laminating varnishes containing same and laminates prepared therefrom |
US5066735A (en) * | 1987-11-16 | 1991-11-19 | The Dow Chemical Company | Curable composition containing a difunctional epoxy resin, a polyfunctional epoxy resin, a difunctional phenol and a polyfunctional phenol |
JPH0627181B2 (ja) * | 1988-02-16 | 1994-04-13 | ソマール株式会社 | 可とう性エポキシ樹脂組成物 |
US4874669A (en) * | 1988-08-15 | 1989-10-17 | The Dow Chemical Company | Curable compositions containing an epoxy resin, a difunctional phenol and a polyfunctional phenol |
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-
1987
- 1987-11-16 US US07/121,329 patent/US4868059A/en not_active Expired - Fee Related
-
1988
- 1988-04-19 MY MYPI88000390A patent/MY103263A/en unknown
- 1988-04-20 IL IL86138A patent/IL86138A/xx not_active IP Right Cessation
- 1988-04-20 EP EP88106276A patent/EP0316509A3/en not_active Withdrawn
- 1988-04-20 CA CA000564596A patent/CA1333732C/en not_active Expired - Fee Related
- 1988-04-21 AU AU15067/88A patent/AU607989B2/en not_active Ceased
- 1988-05-02 JP JP63107736A patent/JP2716726B2/ja not_active Expired - Lifetime
- 1988-05-03 KR KR1019880005136A patent/KR920001742B1/ko not_active IP Right Cessation
- 1988-05-11 BR BR8802396A patent/BR8802396A/pt not_active Application Discontinuation
- 1988-05-12 MX MX011444A patent/MX165339B/es unknown
Also Published As
Publication number | Publication date |
---|---|
JP2716726B2 (ja) | 1998-02-18 |
IL86138A0 (en) | 1988-11-15 |
AU1506788A (en) | 1989-05-18 |
EP0316509A3 (en) | 1989-10-18 |
MX165339B (es) | 1992-11-05 |
IL86138A (en) | 1991-08-16 |
US4868059A (en) | 1989-09-19 |
CA1333732C (en) | 1994-12-27 |
BR8802396A (pt) | 1989-05-23 |
AU607989B2 (en) | 1991-03-21 |
KR920001742B1 (ko) | 1992-02-24 |
MY103263A (en) | 1993-05-29 |
JPH01153715A (ja) | 1989-06-15 |
EP0316509A2 (en) | 1989-05-24 |
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