KR890008249A - 이작용성 에폭시 수지, 다작용성 에폭시 수지, 이작용성 페놀 및 다작용성 페놀을 함유하는 경화성 조성물 - Google Patents

이작용성 에폭시 수지, 다작용성 에폭시 수지, 이작용성 페놀 및 다작용성 페놀을 함유하는 경화성 조성물 Download PDF

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KR890008249A
KR890008249A KR1019880005136A KR880005136A KR890008249A KR 890008249 A KR890008249 A KR 890008249A KR 1019880005136 A KR1019880005136 A KR 1019880005136A KR 880005136 A KR880005136 A KR 880005136A KR 890008249 A KR890008249 A KR 890008249A
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component
composition
phenolic hydroxyl
general formula
epoxy resin
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엘.위커 루이스
에이. 라슨 폴
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리챠드 지.웨터맨
더 다우 케미칼 캄파니
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02Polycondensates containing more than one epoxy group per molecule
    • C08G59/04Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32Epoxy compounds containing three or more epoxy groups
    • C08G59/3218Carbocyclic compounds
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62Alcohols or phenols
    • C08G59/621Phenols
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0313Organic insulating material
    • H05K1/032Organic insulating material consisting of one material
    • H05K1/0326Organic insulating material consisting of one material containing O
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • Y10T428/31515As intermediate layer
    • Y10T428/31522Next to metal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • Y10T428/31529Next to metal

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Abstract

내용 없음

Description

이작용성 에폭시 수지, 다작용성 에폭시 수지, 이작용성 페놀 및 다작용성 페놀을 함유하는 경화성 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. (A)필수적으로(1)분자당(평균)2개 이하의 인접한 에폭사이드 그룹을 갖는 하나 이상의 에폭시 수지 5 내지 96중량%: 및 (2)분자당(평균)2개 이상의 인접한 에폭사이드 그룹을 갖는 하나 이상의 에폭시 수지 95 내지 5중량%로 구성된 에폭시-함유 성분: 및 (B)필수적으로(1)분자당 평균 2개 이하의 페놀성 히드록실 그룹을 갖는 하나 이상의 페놀성 히드록실-함유 화합물 10 내지 70중량%: 및 (2)분자당 평균 2개 이상의 페놀성 히드록실 그룹을 갖는 하나 이상의 페놀성 히드록실-함유 화합물 90 내지 30중량%로 구성된 페놀성 히드록실-함유 성분으로 이루어지며, 성분(A) 및 (B)가 각각의 에폭시 그룹에 대한 페놀성 히드록실 그룹의 비가 0.75:1 내지 1.2:1이 되도록 하는 양으로 존재하는 조성물.
  2. 제1항에 있어서, (a)성분(A-1)이 하기 일반식(Ⅰ) 또는 (Ⅱ)의 에폭시 수지 또는 이러한 에폭시 수지의 혼합물이고, (b)성분(A-2)이 하기 일반식(Ⅲ) 또는 (Ⅳ)의 에폭시 수지 또는 이러한 에폭시 수지의 혼합물이며, (c)성분(B-1)이 하기 일반식(Ⅴ) 또는 (Ⅵ)의 페놀성 히드록실-함유 화합물 또는 이러한 페놀성 히드록실-함유 화합물의 혼합물이고, (d)성분(B-2)가 하기 일반식(Ⅶ) 또는 (Ⅷ)의 페녹성 히드록실-함유 화합물 또는 이러한 페놀성 히드록실-함유 화합물의 혼합물인 조성물.
    상기식에서 A는 각각 독립적으로 C1내지 C10의 2가 히드로카르빌그룹, -S-, -S-S-, -SO-, -SO2-, -CO- 또는 -O-이며, A'는 각각 독립적으로 C1내지 C10의 2가 히드로카르빌 그룹이고, R은 각각 독립적으로 수소 또는 C1내지 C3의 알킬그룹이며, R'는 각각 독립적으로 수소 또는 C1내지 C10의 히드로카르빌 그룹이고, x는 각각 독립적으로 수소, C1내지 C10의 알킬 그룹 또는 할로겐이며, m은 0,1 내지 7이고, m'는 0 내지 3이며, n은 각각 독립적으로 0 또는 1이고, n'는 0 내지 10이다.
  3. 제2항에 있어서, (a)성분(A-1)이 n이 1이고 n'가 0 내지 2인 일반식(Ⅱ)의 디글리시딜 에테르이고, (b)성분(A-2)가 m이 1 내지 5인 일반식(Ⅲ)의 폴리글리시딜 에테르이며, (c)성분(B-1)이 n이 1인 일반식(Ⅵ)의 페놀성 히드록실-함유 화합물이고, (d)성분(B-2)가 m이 0,1 내지 7인 일반식(Ⅶ)의 페놀성 히드록실-함유 화합물인 조성물.
  4. 제3항에 있어서, (a)성분(A-1)이 n이 1이고 n'가 0 내지 2인 일반식(Ⅱ)의 디글리시딜 에테르이고, (b)성분(A-2)가 페놀-포름알데히드 노볼락 에폭시 수지의폴리글리시딜 에테르이며, (c)성분(B-1)이 비스페놀 A또는 테트라브로모비스페놀 A이고, (d)성분(B-2)가 페놀-포름알데히드 노볼락 수지인 조성물.
  5. 제1항에 있어서, 성분(A)와 (B)의 반응을 수행하기 위한 하나 이상의 촉매(C)의 촉매량을 추가로 함유하는 조성물.
  6. 제5항에 있어서, 촉매가 포스포늄 화합물, 이미다졸 또는 이의 혼합물인 조성물.
  7. 제6항에 있어서, 촉매가 1:0.9 내지 1:1.25의 몰비의 4급 포스포늄 아세테이트, 아세트산 착물: 플루오로 붕산, 2-메틸이미다졸 또는 이의 혼합물인 조성물.
  8. 제1항에 있어서, 안정화제를 추가로 함유하는 조성물.
  9. 제5항 내지 제7항중 어느 한항에 있어서, 총 조성물의 1 내지 75중량%의 양으로 하나 이상의 용매(D)를 추가로 함유하는 조성물.
  10. 제5항 내지 제7항중 어느 한항의 조성물을 경화시켜 수득한 제품.
  11. 제9항의 조성물로 침지시킨 기질 재표의 하나 이상의 층을 경화시켜 수득한 적층판.
  12. 제11항에 있어서, 전기 전도성 재표의 외층을 갖는 적층판.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880005136A 1987-11-16 1988-05-03 이작용성 에폭시 수지, 다작용성 에폭시 수지, 이작용성 페놀 및 다작용성 페놀을 함유하는 경화성 조성물 KR920001742B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/121,329 US4868059A (en) 1987-11-16 1987-11-16 Curable composition containing a difunctional epoxy resin, a polyfunctional epoxy resin, a difunctional phenol and a polyfunctional phenol
US121,329 1987-11-16
US121329 1987-11-16

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KR890008249A true KR890008249A (ko) 1989-07-10
KR920001742B1 KR920001742B1 (ko) 1992-02-24

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Country Link
US (1) US4868059A (ko)
EP (1) EP0316509A3 (ko)
JP (1) JP2716726B2 (ko)
KR (1) KR920001742B1 (ko)
AU (1) AU607989B2 (ko)
BR (1) BR8802396A (ko)
CA (1) CA1333732C (ko)
IL (1) IL86138A (ko)
MX (1) MX165339B (ko)
MY (1) MY103263A (ko)

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JP2716726B2 (ja) 1998-02-18
IL86138A0 (en) 1988-11-15
AU1506788A (en) 1989-05-18
EP0316509A3 (en) 1989-10-18
MX165339B (es) 1992-11-05
IL86138A (en) 1991-08-16
US4868059A (en) 1989-09-19
CA1333732C (en) 1994-12-27
BR8802396A (pt) 1989-05-23
AU607989B2 (en) 1991-03-21
KR920001742B1 (ko) 1992-02-24
MY103263A (en) 1993-05-29
JPH01153715A (ja) 1989-06-15
EP0316509A2 (en) 1989-05-24

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