KR102503085B1 - 리튬 고체 상태 전해질 계면 처리 - Google Patents

리튬 고체 상태 전해질 계면 처리 Download PDF

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KR102503085B1
KR102503085B1 KR1020197015050A KR20197015050A KR102503085B1 KR 102503085 B1 KR102503085 B1 KR 102503085B1 KR 1020197015050 A KR1020197015050 A KR 1020197015050A KR 20197015050 A KR20197015050 A KR 20197015050A KR 102503085 B1 KR102503085 B1 KR 102503085B1
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solid state
state electrolyte
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lithium
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KR20190088477A (ko
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리양빙 후
에릭 왁스만
쳉이 왕
윈후이 공
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유니버시티 오브 메릴랜드, 컬리지 파크
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562Solid materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00Compounds of niobium
    • C01G33/006Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • H01M2300/0071Oxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • H01M2300/0071Oxides
    • H01M2300/0074Ion conductive at high temperature
    • H01M2300/0077Ion conductive at high temperature based on zirconium oxide
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0088Composites
    • H01M2300/0094Composites in the form of layered products, e.g. coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Secondary Cells (AREA)
  • Conductive Materials (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
KR1020197015050A 2016-11-07 2017-11-07 리튬 고체 상태 전해질 계면 처리 Active KR102503085B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662418506P 2016-11-07 2016-11-07
US62/418,506 2016-11-07
PCT/US2017/060421 WO2018085847A1 (en) 2016-11-07 2017-11-07 Lithium solid state electrolyte interface treatment

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KR20190088477A KR20190088477A (ko) 2019-07-26
KR102503085B1 true KR102503085B1 (ko) 2023-02-23

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US (2) US20200052326A1 (enExample)
EP (1) EP3535796B1 (enExample)
JP (1) JP7299620B2 (enExample)
KR (1) KR102503085B1 (enExample)
WO (1) WO2018085847A1 (enExample)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3518251B1 (en) * 2016-09-21 2022-08-03 Murata Manufacturing Co., Ltd. Solid electrolyte and all-solid battery
CN110998923B (zh) * 2017-06-06 2023-08-08 密执安州立大学董事会 抑制固体电解质中金属扩散的方法
US10553874B2 (en) 2017-08-04 2020-02-04 Uchicago Argonne, Llc Protective coatings for lithium anodes
US11959166B2 (en) 2018-08-14 2024-04-16 Massachusetts Institute Of Technology Methods of fabricating thin films comprising lithium-containing materials
DE102018219925A1 (de) * 2018-11-21 2020-05-28 Robert Bosch Gmbh Kompositelektrode mit homogenem Abscheidungsverhalten
DE102018221164A1 (de) 2018-12-06 2020-06-10 Volkswagen Aktiengesellschaft Schutzschicht für eine Lithium-Metall-Anode einer Festkörperbatterie
TW202044646A (zh) * 2019-04-04 2020-12-01 美商希爾格得有限公司 用於高能量可充電鋰電池之聚醯胺—醯亞胺塗覆分隔件
CN110085910B (zh) * 2019-05-14 2021-02-02 中南大学 全固态锂电池、石榴石固态电解质及其制备方法
CN110504482A (zh) * 2019-08-08 2019-11-26 南开大学 固态锂电池石榴石型固态电解质材料的制备及表面处理方法与应用
JP7583730B2 (ja) 2019-09-27 2024-11-14 株式会社カネカ 酸化物、固体電解質、および全固体リチウムイオン二次電池
US11404698B2 (en) * 2019-10-30 2022-08-02 GM Global Technology Operations LLC Liquid metal interfacial layers for solid electrolytes and methods thereof
JP7540151B2 (ja) * 2019-12-19 2024-08-27 日本電気硝子株式会社 蓄電デバイス用部材及び蓄電デバイス
CN111087238B (zh) * 2019-12-30 2021-12-31 潍坊歌尔微电子有限公司 钛酸铋钠基无铅压电陶瓷及其制备方法
US12347830B2 (en) * 2020-02-07 2025-07-01 Uchicago Argonne, Llc Interface design for high current density cycling of solid state battery
JP7364804B2 (ja) 2020-04-14 2023-10-18 サン-ゴバン セラミックス アンド プラスティクス,インコーポレイティド イオン伝導性材料、イオン伝導性材料を含む電解質、およびその形成方法
US12266752B2 (en) 2020-04-22 2025-04-01 Uchicago Argonne, Llc Modification of lithium ion electrode materials via atomic layer deposition techniques
JP7395016B2 (ja) 2020-04-23 2023-12-08 サン-ゴバン セラミックス アンド プラスティクス,インコーポレイティド イオン伝導性層およびその形成方法
KR102538169B1 (ko) 2020-04-23 2023-05-31 세인트-고바인 세라믹스 앤드 플라스틱스, 인크. 이온 전도층 및 형성 방법
CN111710915B (zh) * 2020-06-28 2022-12-16 宜春清陶能源科技有限公司 一种固态锂离子电池
CN114256504A (zh) * 2020-09-23 2022-03-29 中国科学院上海硅酸盐研究所 一种固体电解质的表面修饰方法
CN112768753A (zh) * 2020-12-30 2021-05-07 广东微电新能源有限公司 固态电解质的制备方法、固态电池
US12270101B2 (en) 2021-03-19 2025-04-08 Uchicago Argonne, Llc Formation of lithium-metal-oxygen layer and removal of lithium carbonate on solid state electrolytes
US11414749B1 (en) 2021-03-19 2022-08-16 Uchicago Argonne, Llc Formation of lithium-metal-carbon protecting layer and removal of lithium carbonate on lithium metal
CN115732750A (zh) * 2021-08-31 2023-03-03 中国科学院化学研究所 一种表面修饰金属氧化物的固态电解质及其制备方法和应用
US20250105249A1 (en) * 2022-01-21 2025-03-27 University Of Maryland, College Park Lgps-based solid electrolyte
US20230361338A1 (en) * 2022-05-03 2023-11-09 Samsung Electronics Co., Ltd. Solid-state battery and method of manufacturing solid-state battery utilizing spray pyrolysis
KR20250034388A (ko) * 2022-07-12 2025-03-11 하이드로-퀘벡 표면 개질 고상 전해질, 이의 제조 방법, 및 이의 전기화학적 전지에서의 용도
KR102835018B1 (ko) * 2022-10-14 2025-07-15 삼성에스디아이 주식회사 고체 전해질 및 그 제조 방법
KR102885283B1 (ko) * 2023-07-11 2025-11-11 삼성에스디아이 주식회사 고체 전해질과 그 제조 방법 및 이를 포함하는 고체 전해질 막과 전고체 이차 전지
US20250062391A1 (en) * 2023-08-16 2025-02-20 GM Global Technology Operations LLC Lithium ion cells including coated solid-state electrolytes and methods of forming the same
CN119495806A (zh) * 2025-01-19 2025-02-21 吉林大学 一种具有界面修饰层的石榴石型固态电解质、制备方法及其在锂金属对称电池中的应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016069749A1 (en) * 2014-10-28 2016-05-06 University Of Maryland, College Park Interfacial layers for solid-state batteries methods of making same

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6955866B2 (en) * 1998-09-03 2005-10-18 Polyplus Battery Company Coated lithium electrodes
KR100659816B1 (ko) * 2002-04-26 2006-12-19 미츠이 마이닝 & 스멜팅 콤파니 리미티드 비수 전해액 이차전지용 음극 및 그 제조방법 그리고 비수전해액 이차전지
KR100477751B1 (ko) * 2002-11-16 2005-03-21 삼성에스디아이 주식회사 비수계 전해액 및 이를 채용한 리튬 전지
US20130216910A1 (en) * 2010-11-09 2013-08-22 3M Innovative Properties Company High capacity alloy anodes and lithium-ion electrochemical cells containing same
KR101382869B1 (ko) * 2012-06-04 2014-04-08 현대자동차주식회사 배터리용 복합형 고체 고이온전도체 및 이를 이용한 리튬황배터리
WO2014153534A1 (en) * 2013-03-21 2014-09-25 University Of Maryland, College Park Ion-conducting batteries with solid state electrolyte materials
US8940446B1 (en) * 2013-08-06 2015-01-27 Quantumscape Corporation Solid state lithium-air based battery cell
JP6165546B2 (ja) * 2013-08-09 2017-07-19 株式会社日立製作所 固体電解質および全固体リチウムイオン二次電池
JP6028694B2 (ja) 2013-08-23 2016-11-16 株式会社豊田中央研究所 ガーネット型イオン伝導性酸化物の製造方法及び複合体の製造方法
US11043696B2 (en) * 2016-04-29 2021-06-22 University Of Maryland, College Park Metal alloy layers on substrates, methods of making same, and uses thereof
EP3523847A4 (en) * 2016-10-07 2020-08-12 The Regents of The University of Michigan STABILIZATION COATINGS FOR MONOLITHIC BATTERIES
KR102650938B1 (ko) * 2017-03-31 2024-03-25 더 리젠츠 오브 더 유니버시티 오브 미시건 고체 상태 전해질을 갖는 용이한 리튬 금속 애노드 계면의 형성을 위한 시스템 및 방법
JP7209636B2 (ja) * 2017-03-31 2023-01-20 ザ リージェンツ オブ ザ ユニバーシティ オブ ミシガン 固体電解質の表面を処理するためのシステム及び方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016069749A1 (en) * 2014-10-28 2016-05-06 University Of Maryland, College Park Interfacial layers for solid-state batteries methods of making same

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EP3535796B1 (en) 2022-06-15
JP2019534539A (ja) 2019-11-28
WO2018085847A1 (en) 2018-05-11
US20240222691A1 (en) 2024-07-04
US20200052326A1 (en) 2020-02-13
EP3535796A4 (en) 2020-06-10
KR20190088477A (ko) 2019-07-26
JP7299620B2 (ja) 2023-06-28
EP3535796A1 (en) 2019-09-11

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