JP7299620B2 - リチウム固体電解質界面処理法 - Google Patents

リチウム固体電解質界面処理法 Download PDF

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JP7299620B2
JP7299620B2 JP2019523729A JP2019523729A JP7299620B2 JP 7299620 B2 JP7299620 B2 JP 7299620B2 JP 2019523729 A JP2019523729 A JP 2019523729A JP 2019523729 A JP2019523729 A JP 2019523729A JP 7299620 B2 JP7299620 B2 JP 7299620B2
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solid electrolyte
coating layer
lithium
metal
garnet
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JP2019534539A5 (enExample
JP2019534539A (ja
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リアンビン フー
エリック ワックスマン
チェンウェイ ワン
ユンフイ ゴン
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ユニバーシティ オブ メリーランド， カレッジ パーク
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00—Compounds of niobium
    • C01G33/006—Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/0071—Oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/0071—Oxides
    • H01M2300/0074—Ion conductive at high temperature
    • H01M2300/0077—Ion conductive at high temperature based on zirconium oxide
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0094—Composites in the form of layered products, e.g. coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Secondary Cells (AREA)
  • Conductive Materials (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
JP2019523729A 2016-11-07 2017-11-07 リチウム固体電解質界面処理法 Active JP7299620B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662418506P 2016-11-07 2016-11-07
US62/418,506 2016-11-07
PCT/US2017/060421 WO2018085847A1 (en) 2016-11-07 2017-11-07 Lithium solid state electrolyte interface treatment

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JP2019534539A JP2019534539A (ja) 2019-11-28
JP2019534539A5 JP2019534539A5 (enExample) 2020-12-17
JP7299620B2 true JP7299620B2 (ja) 2023-06-28

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US (2) US20200052326A1 (enExample)
EP (1) EP3535796B1 (enExample)
JP (1) JP7299620B2 (enExample)
KR (1) KR102503085B1 (enExample)
WO (1) WO2018085847A1 (enExample)

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WO2018056082A1 (ja) * 2016-09-21 2018-03-29 株式会社村田製作所 固体電解質及び全固体電池
KR102786914B1 (ko) * 2017-06-06 2025-03-25 더 리젠츠 오브 더 유니버시티 오브 미시건 고체 전해질에서 금속 확산을 억제하기 위한 방법
US10553874B2 (en) 2017-08-04 2020-02-04 Uchicago Argonne, Llc Protective coatings for lithium anodes
WO2020036936A1 (en) 2018-08-14 2020-02-20 Massachusetts Institute Of Technology Methods of fabricating thin films comprising lithium-containing materials
DE102018219925A1 (de) * 2018-11-21 2020-05-28 Robert Bosch Gmbh Kompositelektrode mit homogenem Abscheidungsverhalten
DE102018221164A1 (de) 2018-12-06 2020-06-10 Volkswagen Aktiengesellschaft Schutzschicht für eine Lithium-Metall-Anode einer Festkörperbatterie
TW202044646A (zh) * 2019-04-04 2020-12-01 美商希爾格得有限公司 用於高能量可充電鋰電池之聚醯胺—醯亞胺塗覆分隔件
CN110085910B (zh) * 2019-05-14 2021-02-02 中南大学 全固态锂电池、石榴石固态电解质及其制备方法
CN110504482A (zh) * 2019-08-08 2019-11-26 南开大学 固态锂电池石榴石型固态电解质材料的制备及表面处理方法与应用
CN114466822B (zh) * 2019-09-27 2024-07-09 株式会社钟化 氧化物、固体电解质、及全固态锂离子二次电池
US11404698B2 (en) * 2019-10-30 2022-08-02 GM Global Technology Operations LLC Liquid metal interfacial layers for solid electrolytes and methods thereof
JP7540151B2 (ja) * 2019-12-19 2024-08-27 日本電気硝子株式会社 蓄電デバイス用部材及び蓄電デバイス
CN111087238B (zh) * 2019-12-30 2021-12-31 潍坊歌尔微电子有限公司 钛酸铋钠基无铅压电陶瓷及其制备方法
US12347830B2 (en) * 2020-02-07 2025-07-01 Uchicago Argonne, Llc Interface design for high current density cycling of solid state battery
KR102856486B1 (ko) 2020-04-14 2025-09-09 세인트-고바인 세라믹스 앤드 플라스틱스, 인크. 이온 전도성 재료, 이온 전도성 재료를 포함하는 전해질 및 형성 방법
US12266752B2 (en) 2020-04-22 2025-04-01 Uchicago Argonne, Llc Modification of lithium ion electrode materials via atomic layer deposition techniques
KR102957965B1 (ko) 2020-04-23 2026-04-28 세인트-고바인 세라믹스 앤드 플라스틱스, 인크. 이온 전도층 및 형성 방법
US12095089B2 (en) 2020-04-23 2024-09-17 Saint-Gobain Ceramics & Plastics, Inc. Ion conductive layer and methods of forming
CN111710915B (zh) * 2020-06-28 2022-12-16 宜春清陶能源科技有限公司 一种固态锂离子电池
CN114256504A (zh) * 2020-09-23 2022-03-29 中国科学院上海硅酸盐研究所 一种固体电解质的表面修饰方法
CN112768753A (zh) * 2020-12-30 2021-05-07 广东微电新能源有限公司 固态电解质的制备方法、固态电池
US12270101B2 (en) 2021-03-19 2025-04-08 Uchicago Argonne, Llc Formation of lithium-metal-oxygen layer and removal of lithium carbonate on solid state electrolytes
US11414749B1 (en) 2021-03-19 2022-08-16 Uchicago Argonne, Llc Formation of lithium-metal-carbon protecting layer and removal of lithium carbonate on lithium metal
CN115732750A (zh) * 2021-08-31 2023-03-03 中国科学院化学研究所 一种表面修饰金属氧化物的固态电解质及其制备方法和应用
WO2023140861A1 (en) * 2022-01-21 2023-07-27 University Of Maryland, College Park Lgps-based solid electrolyte
US20230361338A1 (en) * 2022-05-03 2023-11-09 Samsung Electronics Co., Ltd. Solid-state battery and method of manufacturing solid-state battery utilizing spray pyrolysis
EP4555569A4 (en) * 2022-07-12 2026-07-22 Hydro Quebec Surface-modified solid-state electrolytes, their preparation processes and their use in electrochemical cells
KR102835018B1 (ko) * 2022-10-14 2025-07-15 삼성에스디아이 주식회사 고체 전해질 및 그 제조 방법
US12586787B2 (en) 2023-02-06 2026-03-24 Uchicago Argonne, Llc Shelf-life enhanced lithium hydroxide via the surface protection and the improved metal-doped cathode materials using the same
CN116914236A (zh) * 2023-06-02 2023-10-20 常州工学院 一种亲锂性合金界面层修饰的固态电解质、应用及其制备方法
KR102885283B1 (ko) * 2023-07-11 2025-11-11 삼성에스디아이 주식회사 고체 전해질과 그 제조 방법 및 이를 포함하는 고체 전해질 막과 전고체 이차 전지
US20250062391A1 (en) * 2023-08-16 2025-02-20 GM Global Technology Operations LLC Lithium ion cells including coated solid-state electrolytes and methods of forming the same
WO2025100789A1 (ko) * 2023-11-09 2025-05-15 주식회사 엘지에너지솔루션 전고체 전지용 양극 활물질, 이의 제조방법, 이를 포함하는 전고체 전지용 양극 및 전고체 전지
CN117878391A (zh) * 2024-01-19 2024-04-12 中南大学 一种化学浴沉积金属氧化物的固态电解质-负极界面修饰方法
CN119495806A (zh) * 2025-01-19 2025-02-21 吉林大学 一种具有界面修饰层的石榴石型固态电解质、制备方法及其在锂金属对称电池中的应用

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KR20190088477A (ko) 2019-07-26
EP3535796A4 (en) 2020-06-10
US20240222691A1 (en) 2024-07-04
KR102503085B1 (ko) 2023-02-23
US20200052326A1 (en) 2020-02-13
WO2018085847A1 (en) 2018-05-11
EP3535796A1 (en) 2019-09-11
EP3535796B1 (en) 2022-06-15
JP2019534539A (ja) 2019-11-28

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