KR101620645B1 - 성형용 수지 시트 및 성형체 - Google Patents
성형용 수지 시트 및 성형체 Download PDFInfo
- Publication number
- KR101620645B1 KR101620645B1 KR1020107020875A KR20107020875A KR101620645B1 KR 101620645 B1 KR101620645 B1 KR 101620645B1 KR 1020107020875 A KR1020107020875 A KR 1020107020875A KR 20107020875 A KR20107020875 A KR 20107020875A KR 101620645 B1 KR101620645 B1 KR 101620645B1
- Authority
- KR
- South Korea
- Prior art keywords
- resin
- polycarbonate
- molding
- resin composition
- sheet
- Prior art date
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 78
- 239000011347 resin Substances 0.000 title claims abstract description 78
- 239000000203 mixture Substances 0.000 claims abstract description 57
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 52
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 52
- 125000003118 aryl group Chemical group 0.000 claims abstract description 45
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 42
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 42
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 41
- 239000004417 polycarbonate Substances 0.000 claims abstract description 41
- 230000009477 glass transition Effects 0.000 claims abstract description 33
- 239000010410 layer Substances 0.000 claims abstract description 30
- 229920000642 polymer Polymers 0.000 claims abstract description 23
- 239000000956 alloy Substances 0.000 claims abstract description 19
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 19
- 239000011247 coating layer Substances 0.000 claims abstract description 19
- 238000003856 thermoforming Methods 0.000 claims abstract description 10
- 239000000758 substrate Substances 0.000 claims abstract description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 36
- 229920000728 polyester Polymers 0.000 claims description 26
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 14
- -1 polyethylene terephthalate Polymers 0.000 claims description 12
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 10
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 7
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 claims description 4
- 229920005992 thermoplastic resin Polymers 0.000 claims 1
- 238000000465 moulding Methods 0.000 abstract description 52
- 238000005187 foaming Methods 0.000 abstract description 10
- 230000002087 whitening effect Effects 0.000 abstract description 8
- 238000005336 cracking Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 20
- 238000002156 mixing Methods 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 11
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 9
- 238000012695 Interfacial polymerization Methods 0.000 description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
- 150000002009 diols Chemical class 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000011342 resin composition Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 238000004898 kneading Methods 0.000 description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical compound O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 229920001515 polyalkylene glycol Polymers 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 230000003678 scratch resistant effect Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 description 1
- ZUHPIMDQNAGSOV-UHFFFAOYSA-N 2-benzyl-2-phenylpropanedioic acid Chemical compound C=1C=CC=CC=1C(C(=O)O)(C(O)=O)CC1=CC=CC=C1 ZUHPIMDQNAGSOV-UHFFFAOYSA-N 0.000 description 1
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229940117969 neopentyl glycol Drugs 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/14—Printing or colouring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/75—Printability
Landscapes
- Laminated Bodies (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JPJP-P-2008-038520 | 2008-02-20 | ||
| JP2008038520A JP4971218B2 (ja) | 2008-02-20 | 2008-02-20 | 成形用樹脂シート及び成形体 |
Related Child Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147021396A Division KR20140103186A (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
| KR1020137026104A Division KR101484875B1 (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
| KR1020147021398A Division KR20140104051A (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20100116670A KR20100116670A (ko) | 2010-11-01 |
| KR101620645B1 true KR101620645B1 (ko) | 2016-05-12 |
Family
ID=40985287
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147021398A KR20140104051A (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
| KR1020107020875A KR101620645B1 (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
| KR1020137026104A KR101484875B1 (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
| KR1020147021396A KR20140103186A (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147021398A KR20140104051A (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137026104A KR101484875B1 (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
| KR1020147021396A KR20140103186A (ko) | 2008-02-20 | 2009-02-19 | 성형용 수지 시트 및 성형체 |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP4971218B2 (ja) |
| KR (4) | KR20140104051A (ja) |
| CN (3) | CN104325766A (ja) |
| TW (1) | TWI438087B (ja) |
| WO (1) | WO2009104399A1 (ja) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5544686B2 (ja) * | 2008-03-28 | 2014-07-09 | 住友化学株式会社 | 射出成形同時貼合用多層フィルム |
| JP5544685B2 (ja) * | 2008-03-28 | 2014-07-09 | 住友化学株式会社 | 射出成形同時貼合用多層フィルム |
| JP5617162B2 (ja) * | 2008-11-26 | 2014-11-05 | 住友化学株式会社 | 多層フィルム |
| WO2011021720A1 (ja) * | 2009-08-21 | 2011-02-24 | 帝人株式会社 | 射出成形用加飾シート |
| JP2011093258A (ja) * | 2009-10-30 | 2011-05-12 | Sumitomo Chemical Co Ltd | 艶消し樹脂フィルム |
| JP5586261B2 (ja) * | 2010-02-12 | 2014-09-10 | 三菱化学株式会社 | 多層体 |
| CN106003958A (zh) * | 2010-03-03 | 2016-10-12 | 三菱化学株式会社 | 层积体 |
| JP5634089B2 (ja) * | 2010-03-24 | 2014-12-03 | 信越ポリマー株式会社 | 多層シート、加飾シートおよび加飾成形体 |
| WO2012018099A1 (ja) * | 2010-08-04 | 2012-02-09 | 帝人化成株式会社 | 多層フィルム、加飾成形用フィルムおよび成形体 |
| JP5639837B2 (ja) * | 2010-10-04 | 2014-12-10 | 帝人株式会社 | 多層シート |
| JP5335126B1 (ja) * | 2012-03-30 | 2013-11-06 | 日新製鋼株式会社 | 塗装金属素形材と熱可塑性樹脂組成物の成形体とが接合された複合体およびその製造方法 |
| JP5988719B2 (ja) * | 2012-06-15 | 2016-09-07 | 三菱瓦斯化学株式会社 | 二次元曲げされたハードコートシートの製造方法 |
| WO2014005848A1 (de) * | 2012-07-04 | 2014-01-09 | Evonik Industries Ag | Vakuumtiefziehprozess und verwendung |
| TWI598392B (zh) | 2012-09-21 | 2017-09-11 | Mitsubishi Gas Chemical Co | Synthetic resin laminate |
| JP6167712B2 (ja) * | 2013-07-16 | 2017-07-26 | 三菱ケミカル株式会社 | 耐擦傷性樹脂積層体 |
| KR101800482B1 (ko) * | 2013-10-31 | 2017-12-21 | (주)엘지하우시스 | 고경도 다층시트 |
| JP6030590B2 (ja) * | 2014-02-28 | 2016-11-24 | 三菱化学株式会社 | 多層体 |
| CN106687290A (zh) * | 2014-09-30 | 2017-05-17 | 可隆工业株式会社 | 透明塑料片材 |
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| US20220274384A1 (en) * | 2019-07-25 | 2022-09-01 | Mitsubishi Gas Chemical Company, Inc. | Transparent resin multilayer body, and transparent substrate material and transparent protective material each using same |
| EP4011622A4 (en) | 2019-08-09 | 2022-08-24 | Mitsubishi Gas Chemical Company, Inc. | RESIN FILM FOR MOLDING AND MOLDING ARTICLES WITH IT |
| JP7318408B2 (ja) * | 2019-08-09 | 2023-08-01 | 三菱瓦斯化学株式会社 | 貼り合わせ用粘着シート、多層体および多層体の製造方法 |
| CN115666945A (zh) | 2020-06-05 | 2023-01-31 | 三菱瓦斯化学株式会社 | 成型用树脂片和使用该成型用树脂片的成型品 |
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| JP2007045067A (ja) * | 2005-08-11 | 2007-02-22 | Mitsubishi Plastics Ind Ltd | 意匠性被覆用積層シートおよび積層シート被覆金属板 |
| JP2007160892A (ja) * | 2005-12-16 | 2007-06-28 | Mitsubishi Gas Chem Co Inc | 多層シートおよび成形体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009196153A (ja) | 2009-09-03 |
| KR20140104051A (ko) | 2014-08-27 |
| CN104325766A (zh) | 2015-02-04 |
| KR20130119008A (ko) | 2013-10-30 |
| JP4971218B2 (ja) | 2012-07-11 |
| KR20100116670A (ko) | 2010-11-01 |
| CN103465579A (zh) | 2013-12-25 |
| TW200940334A (en) | 2009-10-01 |
| KR101484875B1 (ko) | 2015-01-22 |
| KR20140103186A (ko) | 2014-08-25 |
| CN101952119A (zh) | 2011-01-19 |
| WO2009104399A1 (ja) | 2009-08-27 |
| TWI438087B (zh) | 2014-05-21 |
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