JP5617162B2 - 多層フィルム - Google Patents
多層フィルム Download PDFInfo
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- JP5617162B2 JP5617162B2 JP2008300685A JP2008300685A JP5617162B2 JP 5617162 B2 JP5617162 B2 JP 5617162B2 JP 2008300685 A JP2008300685 A JP 2008300685A JP 2008300685 A JP2008300685 A JP 2008300685A JP 5617162 B2 JP5617162 B2 JP 5617162B2
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- JP
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- layer
- multilayer film
- resin material
- polycarbonate resin
- Prior art date
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- 229920000642 polymer Polymers 0.000 claims description 69
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- 239000000463 material Substances 0.000 claims description 56
- 239000002245 particle Substances 0.000 claims description 55
- 229920005668 polycarbonate resin Polymers 0.000 claims description 55
- 239000004431 polycarbonate resin Substances 0.000 claims description 55
- -1 phosphate ester Chemical class 0.000 claims description 53
- 229920000058 polyacrylate Polymers 0.000 claims description 30
- 229920000800 acrylic rubber Polymers 0.000 claims description 29
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 25
- 230000009477 glass transition Effects 0.000 claims description 22
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- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 238000005034 decoration Methods 0.000 claims description 6
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
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- VGFSOACUVJLBAA-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-3,3-dimethylbutan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C(C)(C)C)C1=CC=C(O)C=C1 VGFSOACUVJLBAA-UHFFFAOYSA-N 0.000 description 2
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- VHLLJTHDWPAQEM-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-4-methylpentan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(CC(C)C)C1=CC=C(O)C=C1 VHLLJTHDWPAQEM-UHFFFAOYSA-N 0.000 description 2
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- HTVITOHKHWFJKO-UHFFFAOYSA-N Bisphenol B Chemical compound C=1C=C(O)C=CC=1C(C)(CC)C1=CC=C(O)C=C1 HTVITOHKHWFJKO-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- IPRJXAGUEGOFGG-UHFFFAOYSA-N N-butylbenzenesulfonamide Chemical compound CCCCNS(=O)(=O)C1=CC=CC=C1 IPRJXAGUEGOFGG-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- ALOUNLDAKADEEB-UHFFFAOYSA-N dimethyl sebacate Chemical compound COC(=O)CCCCCCCCC(=O)OC ALOUNLDAKADEEB-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
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- 239000007788 liquid Substances 0.000 description 2
- YLYBTZIQSIBWLI-UHFFFAOYSA-N octyl acetate Chemical compound CCCCCCCCOC(C)=O YLYBTZIQSIBWLI-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
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- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
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- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- HSOOIVBINKDISP-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CCC)OC(=O)C(C)=C HSOOIVBINKDISP-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
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- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
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- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
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- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N Diethylhexyl phthalate Natural products CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 description 1
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- 239000007983 Tris buffer Substances 0.000 description 1
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
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- 125000003118 aryl group Chemical group 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
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- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- ZDWGXBPVPXVXMQ-UHFFFAOYSA-N bis(2-ethylhexyl) nonanedioate Chemical compound CCCCC(CC)COC(=O)CCCCCCCC(=O)OCC(CC)CCCC ZDWGXBPVPXVXMQ-UHFFFAOYSA-N 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229940031954 dibutyl sebacate Drugs 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 229940031769 diisobutyl adipate Drugs 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229940014772 dimethyl sebacate Drugs 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- DJDSLBVSSOQSLW-UHFFFAOYSA-N mono(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(O)=O DJDSLBVSSOQSLW-UHFFFAOYSA-N 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- BPJZKLBPJBMLQG-KWRJMZDGSA-N propanoyl (z,12r)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OC(=O)CC BPJZKLBPJBMLQG-KWRJMZDGSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 229910001927 ruthenium tetroxide Inorganic materials 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
Landscapes
- Injection Moulding Of Plastics Or The Like (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
Description
〔弾性重合体の層の平均粒子径の測定〕
アクリルゴム粒子をメタクリル樹脂と混合してフィルム化し、得られたフィルムを適当な大きさに切り出し、切片を0.5%四酸化ルテニウム水溶液に室温で15時間浸漬し、該ゴム粒子中の弾性重合体の層を染色した。さらに、ミクロトームを用いて約80nmの厚さにサンプルを切断した後、透過型電子顕微鏡で写真撮影を行った。この写真から無作為に100個の染色された弾性重合体の層を選択し、その各々の径を算出した後、その数平均値を求めた。
ポリカーボネート樹脂を75mmφ二軸押出機〔東芝機械(株)製〕で溶融させ、バレルの途中からポンプで液状の可塑剤(1)又は(2)を送り込み、ポリカーボネート樹脂と可塑剤(1)又は(2)とを表1に示す割合で混合し、ポリカーボネート樹脂組成物をペレットとして得た(実施例1〜10、比較例1〜3)。このポリカーボネート樹脂組成物のガラス転移温度を表1に示した。
JIS K5600−5−1:1999に従って、フィルムの耐屈曲性を評価し、試験片が破断せず、柔軟性が良好であるものを○、試験片が破断し、柔軟性に欠けるものを×とした。
JIS K5600−5−1:1999に従って、フィルムの耐屈曲性を評価し、試験片の屈曲部分が白化せずに透明であるものを○、試験片の屈曲部分が白化したものを×とした。
JIS K 5600−5−4に従って測定した。
フィルムから10×150mmの試験片を作成し、インストロン社のINSTRON5500Rを使用して、チャック間50mmにセットし、140℃において50mm/minの速度で、試験片が破断するまで延伸した。延伸中の最大応力(kgf)を表1に示した。なお、通常のインサート成形法において、真空成形や圧空成形などの予備成形時のフィルム表面の温度は140〜160℃であることから、140℃における延伸時の最大応力が小さいほど、成形が容易であると判断した。
メタクリル樹脂とアクリルゴム粒子(1)又は(2)とを、表1に示す割合でスーパーミキサーで混合し、二軸押出機にて溶融混錬して、メタクリル樹脂組成物をペレットとして得た。このメタクリル樹脂組成物のガラス転移温度を表1に示した。次いで、メタクリル樹脂組成物を、65mmφ一軸押出機〔東芝機械(株)製〕で溶融させ、設定温度265℃のT型ダイスを介して押し出し、得られるフィルム状物を、一対の表面が平滑な金属製のロールの間に挟み込んで成形した。こうして厚さ75μmの単層メタクリル樹脂フィルムを製造し、先と同様の評価を行い、結果を表1に示した。
ポリカーボネート樹脂を75mmφ二軸押出機〔東芝機械(株)製〕で溶融させ、バレルの途中からポンプで液状の可塑剤(1)を送り込み、ポリカーボネート樹脂と可塑剤(1)とを表1に示す割合で混合し、ポリカーボネート樹脂組成物をペレットとして得た。このポリカーボネート樹脂組成物のガラス転移温度を表1に示した。次いで、ポリカーボネート樹脂組成物を、65mmφ一軸押出機〔東芝機械(株)製〕で溶融させ、設定温度275℃のT型ダイスを介して押し出し、得られるフィルム状物を、一対の表面が平滑な金属製のロールの間に挟み込んで成形した。こうして厚さ75μmの単層ポリカーボネート樹脂フィルムを製造し、先と同様の評価を行い、結果を表1に示した。
Claims (16)
- ポリカーボネート樹脂材料の層(A)の一方の面に、メタクリル樹脂85〜100重量部及びアクリルゴム粒子0〜15重量部を含有するメタクリル樹脂材料の層(B)が積層されてなる多層フィルムであって、前記ポリカーボネート樹脂材料が、ポリカーボネート樹脂70〜99重量部及び可塑剤1〜30重量部を含有するポリカーボネート樹脂組成物であり、前記ポリカーボネート樹脂材料のガラス転移温度TgA(℃)と前記メタクリル樹脂材料のガラス転移温度TgB(℃)とが式:TgA−TgB<25℃を満たし、TgAが130℃以下であり、層(A)面に加飾を施して用いられることを特徴とする多層フィルム。
- ポリカーボネート樹脂材料の層(A)の両方の面に、メタクリル樹脂85〜100重量部及びアクリルゴム粒子0〜15重量部を含有するメタクリル樹脂材料の層(B)が積層されてなる多層フィルムであって、前記ポリカーボネート樹脂材料のガラス転移温度TgA(℃)と前記メタクリル樹脂材料のガラス転移温度TgB(℃)とが式:TgA−TgB<25℃を満たし、TgAが130℃以下であることを特徴とする多層フィルム。
- ポリカーボネート樹脂材料が、ポリカーボネート樹脂70〜99重量部及び可塑剤1〜30重量部を含有するポリカーボネート樹脂組成物である請求項2に記載の多層フィルム。
- 可塑剤が、リン酸エステル系の可塑剤である請求項1又は3に記載の多層フィルム。
- メタクリル樹脂が、メタクリル酸アルキル、アクリル酸アルキル、及びこれら以外の単量体の合計100重量%を基準として、メタクリル酸アルキルを50〜100重量%、アクリル酸アルキルを0〜50重量%、及びこれら以外の単量体を0〜49重量%の割合で重合させてなる重合体である請求項1〜4のいずれかに記載の多層フィルム。
- アクリルゴム粒子が、アクリル酸アルキル、メタクリル酸アルキル、これら以外の単官能単量体、及び多官能単量体の合計100重量%を基準として、アクリル酸アルキルを50〜99.9重量%、メタクリル酸アルキルを0〜49.9重量%、これら以外の単官能単量体を0〜49.9重量%、及び多官能単量体を0.1〜10重量%の割合で重合させてなる弾性重合体を含有する粒子である請求項1〜5のいずれかに記載の多層フィルム。
- アクリルゴム粒子が、前記弾性重合体からなる層の外側に、メタクリル酸アルキル、アクリル酸アルキル、これら以外の単官能単量体、及び多官能単量体の合計100重量%を基準として、メタクリル酸アルキルを50〜100重量%、アクリル酸アルキルを0〜50重量%、これら以外の単官能単量体を0〜50重量%、及び多官能単量体を0〜10重量%の割合で重合させてなる重合体からなる層を有する多層構造の粒子である請求項6に記載の多層フィルム。
- アクリルゴムが、前記弾性重合体からなる層の内側に、メタクリル酸アルキル、アクリル酸アルキル、これら以外の単官能単量体、及び多官能単量体の合計100重量%を基準として、メタクリル酸アルキルを70〜100重量%、アクリル酸アルキルを0〜30重量%、これら以外の単官能単量体を0〜30重量%、及び多官能単量体を0〜10重量%の割合で重合させてなる重合体からなる層を有する多層構造の粒子である請求項6又は7に記載の多層フィルム。
- 全体の厚さが20〜200μmであり、層(A)の厚さが全体の厚さの10〜80%であり、かつ層(B)の厚さが10μm以上である請求項1〜8のいずれかに記載の多層フィルム。
- 層(A)及び/又は層(B)が有機系又は無機系の微粒子を含有する層である請求項1〜9のいずれかに記載の多層フィルム。
- ポリカーボネート樹脂材料とメタクリル樹脂材料とが共押出成形されてなる請求項1〜10のいずれかに記載の多層フィルム。
- 請求項1に記載の多層フィルムの層(A)側の面に、加飾が施されてなることを特徴とする加飾用フィルム。
- 請求項2に記載の多層フィルムの一方の面に、加飾が施されてなることを特徴とする加飾用フィルム。
- 請求項12又は13に記載の加飾用フィルムの加飾側の面に、熱可塑性樹脂シートが積層されてなることを特徴とする加飾用シート。
- 請求項12又は13に記載の加飾用フィルムの加飾側の面に、熱可塑性樹脂が射出成形されてなることを特徴とする加飾成形品。
- 請求項14に記載の加飾用シートの熱可塑性樹脂シート側の面に、熱可塑性樹脂が射出成形されてなることを特徴とする加飾成形品。
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JP5707191B2 (ja) * | 2011-03-18 | 2015-04-22 | 住友化学株式会社 | 積層板 |
JPWO2012147880A1 (ja) * | 2011-04-28 | 2014-07-28 | テクノポリマー株式会社 | 加飾樹脂シート |
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JP3457514B2 (ja) * | 1997-08-08 | 2003-10-20 | 株式会社クラレ | 積層板およびその製造方法 |
JP3638800B2 (ja) * | 1998-10-14 | 2005-04-13 | 出光興産株式会社 | ポリカーボネート樹脂組成物及びその製造方法 |
JP2000302960A (ja) * | 1999-04-19 | 2000-10-31 | Kanegafuchi Chem Ind Co Ltd | 光学フィルム |
JP2007160627A (ja) * | 2005-12-12 | 2007-06-28 | Fujifilm Corp | 熱可塑性樹脂フィルム及びその製造方法並びに装置 |
JP4720832B2 (ja) * | 2007-01-31 | 2011-07-13 | 住友化学株式会社 | 積層フィルム |
JP2008238618A (ja) * | 2007-03-28 | 2008-10-09 | Nippon A & L Kk | 加飾用多層フィルム |
JP2008273028A (ja) * | 2007-04-27 | 2008-11-13 | Nippon Shokubai Co Ltd | 積層体 |
JP4971218B2 (ja) * | 2008-02-20 | 2012-07-11 | 三菱樹脂株式会社 | 成形用樹脂シート及び成形体 |
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