KR101527905B1 - 셀룰로오스에스테르 수지용 첨가제, 그것을 사용한 셀룰로오스에스테르 수지 조성물 및 필름 - Google Patents
셀룰로오스에스테르 수지용 첨가제, 그것을 사용한 셀룰로오스에스테르 수지 조성물 및 필름 Download PDFInfo
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- KR101527905B1 KR101527905B1 KR1020090102160A KR20090102160A KR101527905B1 KR 101527905 B1 KR101527905 B1 KR 101527905B1 KR 1020090102160 A KR1020090102160 A KR 1020090102160A KR 20090102160 A KR20090102160 A KR 20090102160A KR 101527905 B1 KR101527905 B1 KR 101527905B1
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- KR
- South Korea
- Prior art keywords
- film
- cellulose ester
- ester resin
- ester compound
- dicarboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920002678 cellulose Polymers 0.000 title claims abstract description 102
- 229920005989 resin Polymers 0.000 title claims abstract description 82
- 239000011347 resin Substances 0.000 title claims abstract description 82
- 239000000654 additive Substances 0.000 title claims abstract description 42
- 230000000996 additive effect Effects 0.000 title claims abstract description 35
- 239000011342 resin composition Substances 0.000 title claims description 28
- -1 aromatic dicarboxylic acid compound Chemical class 0.000 claims abstract description 217
- 239000012788 optical film Substances 0.000 claims abstract description 38
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 36
- 150000002148 esters Chemical class 0.000 claims abstract description 28
- HSSYVKMJJLDTKZ-UHFFFAOYSA-N 3-phenylphthalic acid Chemical compound OC(=O)C1=CC=CC(C=2C=CC=CC=2)=C1C(O)=O HSSYVKMJJLDTKZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000010408 film Substances 0.000 claims description 162
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 73
- 150000002009 diols Chemical class 0.000 claims description 52
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 28
- 235000013772 propylene glycol Nutrition 0.000 claims description 26
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 25
- 230000003287 optical effect Effects 0.000 abstract description 35
- 238000005886 esterification reaction Methods 0.000 abstract description 25
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- 238000004519 manufacturing process Methods 0.000 description 32
- 230000001681 protective effect Effects 0.000 description 32
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 29
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 26
- 239000003054 catalyst Substances 0.000 description 23
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- 230000000052 comparative effect Effects 0.000 description 21
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- 239000002253 acid Substances 0.000 description 20
- 238000000034 method Methods 0.000 description 20
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- 238000010992 reflux Methods 0.000 description 19
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- RLJWTAURUFQFJP-UHFFFAOYSA-N propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)O.CC(C)O.CC(C)O RLJWTAURUFQFJP-UHFFFAOYSA-N 0.000 description 16
- VXUYXOFXAQZZMF-UHFFFAOYSA-N tetraisopropyl titanate Substances CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 15
- 239000004014 plasticizer Substances 0.000 description 15
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 13
- 238000005259 measurement Methods 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 239000002904 solvent Substances 0.000 description 12
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 9
- 239000003960 organic solvent Substances 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- 238000005266 casting Methods 0.000 description 8
- 229920002301 cellulose acetate Polymers 0.000 description 8
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- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 8
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 8
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- 125000000217 alkyl group Chemical group 0.000 description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 5
- 239000002738 chelating agent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
- UNVGBIALRHLALK-UHFFFAOYSA-N 1,5-Hexanediol Chemical compound CC(O)CCCCO UNVGBIALRHLALK-UHFFFAOYSA-N 0.000 description 4
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 4
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 238000006359 acetalization reaction Methods 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 4
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 3
- 229920002284 Cellulose triacetate Polymers 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
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- 239000006224 matting agent Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- RUOPINZRYMFPBF-UHFFFAOYSA-N pentane-1,3-diol Chemical compound CCC(O)CCO RUOPINZRYMFPBF-UHFFFAOYSA-N 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 150000005846 sugar alcohols Chemical class 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 3
- 229940015975 1,2-hexanediol Drugs 0.000 description 2
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 2
- WQHNZXURJISVCT-UHFFFAOYSA-N 1-butoxyethane-1,2-diol Chemical compound CCCCOC(O)CO WQHNZXURJISVCT-UHFFFAOYSA-N 0.000 description 2
- YPVUCEOTLGXCMA-UHFFFAOYSA-N 3-butylheptane-1,3-diol Chemical compound CCCCC(O)(CCO)CCCC YPVUCEOTLGXCMA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920008347 Cellulose acetate propionate Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
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- 125000004432 carbon atom Chemical group C* 0.000 description 2
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- 239000003607 modifier Substances 0.000 description 2
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- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- RGCVYEOTYJCNOS-UHFFFAOYSA-N (4-cyano-2-methylphenyl)boronic acid Chemical compound CC1=CC(C#N)=CC=C1B(O)O RGCVYEOTYJCNOS-UHFFFAOYSA-N 0.000 description 1
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- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- OWVAEQAOZDETGQ-UHFFFAOYSA-N 2,2-bis(benzoyloxymethyl)butyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC(COC(=O)C=1C=CC=CC=1)(CC)COC(=O)C1=CC=CC=C1 OWVAEQAOZDETGQ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B3/00—Preparation of cellulose esters of organic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
Landscapes
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Life Sciences & Earth Sciences (AREA)
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- Optics & Photonics (AREA)
- Polarising Elements (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
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| JP2008292087 | 2008-11-14 | ||
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| KR20100054721A KR20100054721A (ko) | 2010-05-25 |
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| JP (1) | JP5440082B2 (enExample) |
| KR (1) | KR101527905B1 (enExample) |
| CN (1) | CN101735477B (enExample) |
| TW (1) | TWI438234B (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| TWI452076B (zh) * | 2009-03-27 | 2014-09-11 | Dainippon Ink & Chemicals | Cellulose ester resin additives, cellulose ester resin compositions and optical films using the same |
| JP2013018895A (ja) * | 2010-07-20 | 2013-01-31 | Fujifilm Corp | 光学フィルム、位相差フィルム、偏光板及び液晶表示装置 |
| JP5821849B2 (ja) * | 2010-07-30 | 2015-11-24 | コニカミノルタ株式会社 | セルロースアセテートフィルムの製造方法 |
| JP2012177018A (ja) * | 2011-02-25 | 2012-09-13 | Dic Corp | セルロースエステル樹脂組成物及びそれを用いた光学フィルム |
| JP5873643B2 (ja) * | 2011-04-18 | 2016-03-01 | 富士フイルム株式会社 | セルロースエステルフィルム、偏光板、及び液晶表示装置 |
| WO2013027793A1 (ja) * | 2011-08-25 | 2013-02-28 | Dic株式会社 | 光学フィルム、位相差フィルム及び波長板 |
| JP5785894B2 (ja) * | 2011-09-16 | 2015-09-30 | 富士フイルム株式会社 | セルロースエステルフィルム、偏光板、及び液晶表示装置 |
| JP6046647B2 (ja) | 2013-01-18 | 2016-12-21 | 富士フイルム株式会社 | 光学フィルム、偏光板、及び画像表示装置 |
| JP5904311B2 (ja) * | 2013-09-30 | 2016-04-13 | Dic株式会社 | 光学材料用樹脂組成物、光学フィルム及び液晶表示装置 |
| CN105764972B (zh) * | 2013-11-21 | 2017-09-26 | Dic株式会社 | 纤维素酯树脂用改性剂、纤维素酯光学薄膜、偏光板用保护薄膜及液晶显示装置 |
| TWI662020B (zh) | 2014-10-03 | 2019-06-11 | 日商迪愛生股份有限公司 | 環氧酯化合物、纖維素酯樹脂組成物、光學膜及液晶顯示裝置 |
| JP2016098267A (ja) * | 2014-11-19 | 2016-05-30 | Dic株式会社 | セルロースエステル樹脂組成物、セルロースエステルフィルム、偏光板用保護フィルム及び液晶表示装置 |
| JP6836724B2 (ja) * | 2015-12-11 | 2021-03-03 | Dic株式会社 | セルロースエステル樹脂用改質剤、セルロースエステル樹脂組成物、光学フィルム及び液晶表示装置 |
| JP2017122854A (ja) * | 2016-01-08 | 2017-07-13 | コニカミノルタ株式会社 | 液晶表示装置 |
| JP6257680B2 (ja) * | 2016-03-31 | 2018-01-10 | 住友化学株式会社 | 偏光フィルムの製造方法、積層フィルム |
| CN106632697B (zh) * | 2016-12-16 | 2019-01-29 | 万华化学集团股份有限公司 | 一种制备高丁酰基含量的醋酸丁酸纤维素的方法 |
| JP2019006942A (ja) * | 2017-06-28 | 2019-01-17 | Dic株式会社 | 光学材料用樹脂組成物及び光学フィルム |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006282987A (ja) * | 2005-03-11 | 2006-10-19 | Dainippon Ink & Chem Inc | セルロースエステル樹脂用改質剤、及びそれを含有してなるフィルム |
| JP2007003679A (ja) * | 2005-06-22 | 2007-01-11 | Konica Minolta Opto Inc | 位相差板、偏光板及び液晶表示装置 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS61276836A (ja) * | 1985-05-31 | 1986-12-06 | Daihachi Kagaku Kogyosho:Kk | セルロ−ス誘導体樹脂組成物 |
| US20060181774A1 (en) * | 2005-02-16 | 2006-08-17 | Konica Minolta Opto, Inc. | Antireflection film, production method of the same, polarizing plate and display |
| TW200815508A (en) * | 2006-07-24 | 2008-04-01 | Fujifilm Corp | Cellulose acylate film, and polarizing plate and liquid crystal display device using the same |
-
2009
- 2009-10-07 JP JP2009233341A patent/JP5440082B2/ja active Active
- 2009-10-13 TW TW098134584A patent/TWI438234B/zh active
- 2009-10-27 KR KR1020090102160A patent/KR101527905B1/ko active Active
- 2009-11-13 CN CN2009102224519A patent/CN101735477B/zh active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006282987A (ja) * | 2005-03-11 | 2006-10-19 | Dainippon Ink & Chem Inc | セルロースエステル樹脂用改質剤、及びそれを含有してなるフィルム |
| JP2007003679A (ja) * | 2005-06-22 | 2007-01-11 | Konica Minolta Opto Inc | 位相差板、偏光板及び液晶表示装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI438234B (zh) | 2014-05-21 |
| KR20100054721A (ko) | 2010-05-25 |
| JP5440082B2 (ja) | 2014-03-12 |
| CN101735477B (zh) | 2013-06-12 |
| CN101735477A (zh) | 2010-06-16 |
| TW201018706A (en) | 2010-05-16 |
| JP2010138379A (ja) | 2010-06-24 |
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