KR101395478B1 - 비수계 전해질 2차 전지용 정극 활물질과 그의 제조 방법, 및 상기 정극 활물질을 이용한 비수계 전해질 2차 전지 - Google Patents
비수계 전해질 2차 전지용 정극 활물질과 그의 제조 방법, 및 상기 정극 활물질을 이용한 비수계 전해질 2차 전지 Download PDFInfo
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- KR101395478B1 KR101395478B1 KR1020137009483A KR20137009483A KR101395478B1 KR 101395478 B1 KR101395478 B1 KR 101395478B1 KR 1020137009483 A KR1020137009483 A KR 1020137009483A KR 20137009483 A KR20137009483 A KR 20137009483A KR 101395478 B1 KR101395478 B1 KR 101395478B1
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- Prior art keywords
- positive electrode
- active material
- electrode active
- secondary battery
- electrolyte secondary
- Prior art date
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- 239000011255 nonaqueous electrolyte Substances 0.000 title claims abstract description 51
- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 238000000034 method Methods 0.000 title claims description 20
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 137
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- 239000003513 alkali Substances 0.000 claims abstract description 56
- 239000011164 primary particle Substances 0.000 claims abstract description 50
- 239000010419 fine particle Substances 0.000 claims abstract description 47
- 239000011163 secondary particle Substances 0.000 claims abstract description 20
- 239000011244 liquid electrolyte Substances 0.000 claims abstract description 15
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 13
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- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 10
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- 239000000243 solution Substances 0.000 claims description 58
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 38
- 239000010937 tungsten Substances 0.000 claims description 37
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- 239000011737 fluorine Substances 0.000 description 5
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- 229910052715 tantalum Inorganic materials 0.000 description 5
- 229910052723 transition metal Inorganic materials 0.000 description 5
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- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 3
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- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- CKFRRHLHAJZIIN-UHFFFAOYSA-N cobalt lithium Chemical compound [Li].[Co] CKFRRHLHAJZIIN-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
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- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 2
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- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
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- 238000004438 BET method Methods 0.000 description 1
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- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
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- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
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- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 description 1
- 238000009831 deintercalation Methods 0.000 description 1
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- PFPDWGGTEJAIIG-UHFFFAOYSA-L sodium nickel(2+) sulfate Chemical compound [Ni+2].S(=O)(=O)([O-])[O-].[Na+] PFPDWGGTEJAIIG-UHFFFAOYSA-L 0.000 description 1
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- 238000001291 vacuum drying Methods 0.000 description 1
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
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| PCT/JP2011/072519 WO2012043783A1 (ja) | 2010-09-30 | 2011-09-30 | 非水系電解質二次電池用正極活物質とその製造方法、および該正極活物質を用いた非水系電解質二次電池 |
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| JP5370515B2 (ja) * | 2012-02-22 | 2013-12-18 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極材料とその製造方法、および該正極材料を用いた非水系電解質二次電池 |
| CA2794290A1 (en) | 2012-10-22 | 2014-04-22 | Hydro-Quebec | Method of producing electrode material for lithium-ion secondary battery and lithium-ion secondary battery using such electrode material |
| KR101613862B1 (ko) | 2013-10-10 | 2016-04-20 | 미쓰이금속광업주식회사 | 리튬 과잉형 층상 리튬 금속 복합 산화물의 제조 방법 |
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| WO2018160023A1 (ko) | 2017-02-28 | 2018-09-07 | 주식회사 엘지화학 | 리튬 이차전지용 양극 활물질, 그 제조방법 및 이를 포함하는 리튬 이차전지 |
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| KR102007565B1 (ko) * | 2017-09-28 | 2019-08-06 | 포항공과대학교 산학협력단 | 리튬 이차 전지용 리튬 니켈 망간 복합 산화물의 제조 방법 |
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| KR102165119B1 (ko) * | 2017-10-20 | 2020-10-14 | 주식회사 엘지화학 | 이차전지용 양극활물질 제조방법 및 이를 이용하는 이차전지 |
| JP7220851B2 (ja) * | 2017-10-31 | 2023-02-13 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質とその製造方法、及び正極活物質を用いた非水系電解質二次電池 |
| JP6791112B2 (ja) * | 2017-12-25 | 2020-11-25 | 日亜化学工業株式会社 | 非水系二次電池用正極材料の製造方法 |
| CN117185362A (zh) * | 2017-12-28 | 2023-12-08 | 松下知识产权经营株式会社 | 非水电解质二次电池用正极活性物质的制造方法 |
| CN108598379A (zh) * | 2018-02-08 | 2018-09-28 | 中南大学 | 一种钨酸锂包覆镍钴铝酸锂复合材料及其制备方法和应用 |
| JP7232814B2 (ja) | 2018-03-13 | 2023-03-03 | 三洋電機株式会社 | 非水電解質二次電池 |
| JP2019160573A (ja) * | 2018-03-13 | 2019-09-19 | 住友化学株式会社 | リチウム金属複合酸化物粉末、リチウム二次電池用正極活物質、正極、及びリチウム二次電池 |
| JP6962838B2 (ja) * | 2018-03-13 | 2021-11-05 | 住友化学株式会社 | リチウム金属複合酸化物粉末、リチウム二次電池用正極活物質、正極、及びリチウム二次電池 |
| KR102746636B1 (ko) * | 2018-03-21 | 2024-12-24 | 바스프 에스이 | 적어도 부분적으로 코팅된 전극 활물질의 제조 방법 |
| CN111919317B (zh) | 2018-03-29 | 2024-02-09 | 住友金属矿山株式会社 | 非水电解质二次电池用正极活性物质 |
| JP7028073B2 (ja) * | 2018-05-31 | 2022-03-02 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質、非水系電解質二次電池 |
| JP7203360B2 (ja) | 2018-06-28 | 2023-01-13 | パナソニックIpマネジメント株式会社 | 電極構造体及び非水電解質二次電池 |
| CN109879330A (zh) * | 2019-02-26 | 2019-06-14 | 哈尔滨工业大学(深圳) | 一种锂离子电池正极材料及其制作方法 |
| JP7357499B2 (ja) * | 2019-09-26 | 2023-10-06 | パナソニックホールディングス株式会社 | 非水電解質二次電池用正極活物質、及び非水電解質二次電池 |
| US12159996B2 (en) | 2020-03-25 | 2024-12-03 | Samsung Sdi Co., Ltd. | Positive electrode active material, positive electrode including the same, and lithium secondary battery employing the positive electrode |
| WO2024090405A1 (ja) * | 2022-10-26 | 2024-05-02 | 三井金属鉱業株式会社 | タングステン酸リチウム分散液およびその製造方法 |
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| JP2010040383A (ja) * | 2008-08-06 | 2010-02-18 | Sony Corp | 正極活物質の製造方法および正極活物質 |
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| JP2000149948A (ja) | 1998-11-12 | 2000-05-30 | Toshiba Corp | 正極活物質、リチウムイオン二次電池およびその正極活物質の製造方法 |
| JP2002075367A (ja) | 2000-09-04 | 2002-03-15 | Mitsui Chemicals Inc | リチウム電池用正極活物質、その製法およびそれを用いた二次電池 |
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| US9406928B2 (en) | 2016-08-02 |
| KR20130051012A (ko) | 2013-05-16 |
| CN103155240A (zh) | 2013-06-12 |
| US9130212B1 (en) | 2015-09-08 |
| WO2012043783A1 (ja) | 2012-04-05 |
| JP2012079464A (ja) | 2012-04-19 |
| US20150228974A1 (en) | 2015-08-13 |
| EP2624342B1 (en) | 2016-11-09 |
| CN103155240B (zh) | 2015-08-19 |
| EP2624342A1 (en) | 2013-08-07 |
| JP5035712B2 (ja) | 2012-09-26 |
| EP2624342A4 (en) | 2014-01-15 |
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