KR101016891B1 - 산소 함유 탄화수소의 개질 촉매, 이를 사용한 수소 또는합성 가스의 제조방법 및 연료전지 시스템 - Google Patents

산소 함유 탄화수소의 개질 촉매, 이를 사용한 수소 또는합성 가스의 제조방법 및 연료전지 시스템 Download PDF

Info

Publication number
KR101016891B1
KR101016891B1 KR1020057022073A KR20057022073A KR101016891B1 KR 101016891 B1 KR101016891 B1 KR 101016891B1 KR 1020057022073 A KR1020057022073 A KR 1020057022073A KR 20057022073 A KR20057022073 A KR 20057022073A KR 101016891 B1 KR101016891 B1 KR 101016891B1
Authority
KR
South Korea
Prior art keywords
oxygen
reforming catalyst
reforming
catalyst
containing hydrocarbon
Prior art date
Application number
KR1020057022073A
Other languages
English (en)
Korean (ko)
Other versions
KR20060009366A (ko
Inventor
고이치 에구치
Original Assignee
이데미쓰 고산 가부시키가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이데미쓰 고산 가부시키가이샤 filed Critical 이데미쓰 고산 가부시키가이샤
Publication of KR20060009366A publication Critical patent/KR20060009366A/ko
Application granted granted Critical
Publication of KR101016891B1 publication Critical patent/KR101016891B1/ko

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/745Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005Spinels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32Manganese, technetium or rhenium
    • B01J23/34Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/86Chromium
    • B01J23/868Chromium copper and chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889Manganese, technetium or rhenium
    • B01J23/8892Manganese
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9016Oxides, hydroxides or oxygenated metallic salts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1076Copper or zinc-based catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
KR1020057022073A 2003-05-20 2004-05-14 산소 함유 탄화수소의 개질 촉매, 이를 사용한 수소 또는합성 가스의 제조방법 및 연료전지 시스템 KR101016891B1 (ko)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JPJP-P-2003-00142573 2003-05-20
JP2003142573 2003-05-20
JPJP-P-2003-00309696 2003-09-02
JP2003309696 2003-09-02
JP2003322949 2003-09-16
JPJP-P-2003-00322949 2003-09-16
JPJP-P-2004-00015343 2004-01-23
JP2004015343A JP4774197B2 (ja) 2003-05-20 2004-01-23 酸素含有炭化水素の改質触媒、それを用いた水素又は合成ガスの製造方法及び燃料電池システム

Publications (2)

Publication Number Publication Date
KR20060009366A KR20060009366A (ko) 2006-01-31
KR101016891B1 true KR101016891B1 (ko) 2011-02-22

Family

ID=33479782

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020057022073A KR101016891B1 (ko) 2003-05-20 2004-05-14 산소 함유 탄화수소의 개질 촉매, 이를 사용한 수소 또는합성 가스의 제조방법 및 연료전지 시스템

Country Status (4)

Country Link
JP (1) JP4774197B2 (ja)
KR (1) KR101016891B1 (ja)
TW (1) TW200500138A (ja)
WO (1) WO2004103555A1 (ja)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008142575A (ja) * 2005-03-28 2008-06-26 Tohoku Univ 複合酸化物を用いた高性能触媒及びその製造法
KR100732538B1 (ko) * 2005-08-24 2007-06-27 요업기술원 촉매를 활용하여 탄화수소로부터 수소를 직접 제조하는방법
JP4607715B2 (ja) * 2005-09-06 2011-01-05 株式会社東芝 触媒及び触媒の製造方法
KR100649737B1 (ko) * 2005-10-17 2006-11-27 삼성전기주식회사 박판 다층 형 수소 연료전지
JP2008221200A (ja) * 2007-02-16 2008-09-25 Japan Science & Technology Agency 酸素含有炭化水素の改質触媒、それを用いた水素又は合成ガスの製造方法及び燃料電池システム
WO2008126844A1 (ja) * 2007-04-11 2008-10-23 Japan Science And Technology Agency 酸素含有炭化水素の改質用触媒、それを用いた水素又は合成ガスの製造方法及び燃料電池システム
JP5178143B2 (ja) * 2007-04-11 2013-04-10 独立行政法人科学技術振興機構 酸素含有炭化水素の改質用触媒、それを用いた水素又は合成ガスの製造方法及び燃料電池システム
KR100938779B1 (ko) * 2007-12-04 2010-01-27 한국에너지기술연구원 메탄을 이용한 합성가스 및 수소의 제조방법
CN101965311B (zh) * 2008-02-25 2013-06-12 住友精化株式会社 氢的制造方法和装置
TWI451620B (zh) * 2008-05-14 2014-09-01 Nippon Oil Corp Desulfurization device, fuel cell system and modification system
JP4665044B2 (ja) * 2009-09-14 2011-04-06 株式会社東芝 燃料改質用触媒、改質器及び燃料電池システム
WO2012105355A1 (ja) * 2011-01-31 2012-08-09 住友精化株式会社 水素ガスの製造方法
JP5659067B2 (ja) * 2011-04-04 2015-01-28 住友精化株式会社 水素ガスの製造方法
JP5956377B2 (ja) * 2012-06-07 2016-07-27 株式会社豊田中央研究所 炭化水素改質用触媒の製造方法
KR101480801B1 (ko) 2013-05-08 2015-01-12 한국화학연구원 이산화탄소 개질반응용 모노리스 촉매, 이의 제조방법 및 이를 이용한 합성가스의 제조방법
CN104785269B (zh) * 2015-04-20 2017-04-26 广东石油化工学院 一种乙醇水蒸气重整制氢催化剂的制法
WO2016203371A1 (en) * 2015-06-15 2016-12-22 Clean Diesel Technologies, Inc. Performance improvement of copper and manganese containing ternary spinel as noble metal free three way catalysts
CN106391036B (zh) * 2016-10-28 2018-10-23 成都理工大学 一种乙酸自热重整制氢的固溶体催化剂及制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5227085A (en) 1975-08-27 1977-03-01 Nippon Soken Inc Catalyst for reforming of hydrocarbon fuel
WO2001098202A1 (es) * 2000-06-22 2001-12-27 Consejo Superior De Investigaciones Cientificas Procedimiento para la obtención de hidrógeno por oxidación parcial de metanol

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO146046L (ja) * 1980-03-28
DE19739773A1 (de) * 1997-09-10 1999-03-11 Basf Ag Verfahren und Katalysator zur Dampfreformierung von Methanol
JP2003010685A (ja) * 2001-06-27 2003-01-14 Nkk Corp 水素製造触媒およびその製造方法ならびに水素を製造する方法
JP2003033656A (ja) * 2001-07-25 2003-02-04 Nkk Corp 合成ガス製造触媒および合成ガスの製造方法
JP4022615B2 (ja) * 2002-05-01 2007-12-19 独立行政法人産業技術総合研究所 水性ガスシフト反応及びメタノール水蒸気改質反応用触媒
DE10225945A1 (de) * 2002-06-11 2003-12-24 Basf Ag Verfahren zur Herstellung von wasserstoffhaltigen Gasen

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5227085A (en) 1975-08-27 1977-03-01 Nippon Soken Inc Catalyst for reforming of hydrocarbon fuel
WO2001098202A1 (es) * 2000-06-22 2001-12-27 Consejo Superior De Investigaciones Cientificas Procedimiento para la obtención de hidrógeno por oxidación parcial de metanol

Also Published As

Publication number Publication date
TW200500138A (en) 2005-01-01
JP4774197B2 (ja) 2011-09-14
TWI351312B (ja) 2011-11-01
KR20060009366A (ko) 2006-01-31
JP2005342543A (ja) 2005-12-15
WO2004103555A1 (ja) 2004-12-02

Similar Documents

Publication Publication Date Title
KR101016891B1 (ko) 산소 함유 탄화수소의 개질 촉매, 이를 사용한 수소 또는합성 가스의 제조방법 및 연료전지 시스템
KR20090115709A (ko) 산소 함유 탄화수소의 개질 촉매, 그것을 이용한 수소 또는합성 가스의 제조 방법 및 연료 전지 시스템
KR101484793B1 (ko) 촉매 전구체 물질 및 그것을 이용한 촉매
Usman et al. Recent advances in the methanol synthesis via methane reforming processes
JPWO2006101079A1 (ja) 脱硫剤及びこれを用いた脱硫方法
US11795055B1 (en) Systems and methods for processing ammonia
US8016899B2 (en) Composite fuels for hydrogen generation
KR100782383B1 (ko) 알칼리 붕소수소화물 용액을 이용한 수소 방출 반응용코발트-붕소 촉매 및 그 제조 방법
JP4398670B2 (ja) 酸素含有炭化水素の改質触媒、それを用いた水素又は合成ガスの製造方法及び燃料電池システム
KR101486095B1 (ko) 산소 함유 탄화수소의 개질용 촉매, 그것을 이용한 수소 또는 합성 가스의 제조 방법 및 연료 전지 시스템
KR20070084220A (ko) 산소 함유 탄화수소의 개질 촉매, 이를 이용한 수소 또는합성 가스의 제조 방법 및 연료 전지 시스템
JP2018204433A (ja) 内燃機関
JP2005007383A (ja) 硫黄化合物除去用吸着剤及び燃料電池用水素の製造方法
JP2021195316A (ja) Coの選択的酸化触媒を備えたco2メタネーション反応装置およびガス中のcoの除去方法
JP4127685B2 (ja) 一酸化炭素選択メタン化器、一酸化炭素シフト反応器及び燃料電池システム
JP4328941B2 (ja) 水素含有ガスの製造方法
JP2006043587A (ja) 酸素含有炭化水素の改質触媒、それを用いた酸素含有炭化水素の改質方法及び燃料電池システム
JP2009119307A (ja) 触媒の再生方法
JP5275113B2 (ja) 炭化水素用脱硫剤前駆体及びその製造方法、炭化水素用脱硫剤焼成前駆体及びその製造方法、炭化水素用脱硫剤及びその製造方法、炭化水素の脱硫方法並びに燃料電池システム
RU2677875C1 (ru) Катализатор и способ получения обогащенной по водороду газовой смеси из диметилового эфира и воздуха
Navarro Jaen et al. Catalytic Technologies for Clean Hydrogen Production
JP2007301452A (ja) 酸素含有炭化水素改質用触媒、それを用いた水素又は合成ガスの製造方法、及び燃料電池システム
JP2007137749A (ja) 酸素含有炭化水素化合物からの水素の製造装置、該製造装置を用いる水素の製造方法及び燃料電池システム
JP4359748B2 (ja) 水素含有ガスの製造方法
JP2006339119A (ja) 液化石油ガス型燃料電池用の燃料補給方法

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee