KR100743845B1 - 이온 그룹 또는 이온화 가능한 그룹을 함유하는 불소중합체 수지 및 이를 함유하는 제품 - Google Patents
이온 그룹 또는 이온화 가능한 그룹을 함유하는 불소중합체 수지 및 이를 함유하는 제품 Download PDFInfo
- Publication number
- KR100743845B1 KR100743845B1 KR1020017013043A KR20017013043A KR100743845B1 KR 100743845 B1 KR100743845 B1 KR 100743845B1 KR 1020017013043 A KR1020017013043 A KR 1020017013043A KR 20017013043 A KR20017013043 A KR 20017013043A KR 100743845 B1 KR100743845 B1 KR 100743845B1
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- South Korea
- Prior art keywords
- groups
- delete delete
- polymer
- vinyl
- acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000004811 fluoropolymer Substances 0.000 title claims abstract description 54
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 54
- 229920005989 resin Polymers 0.000 title claims abstract description 25
- 239000011347 resin Substances 0.000 title claims abstract description 25
- 125000003010 ionic group Chemical group 0.000 title claims description 29
- 239000012528 membrane Substances 0.000 claims abstract description 53
- 229920000642 polymer Polymers 0.000 claims abstract description 53
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 30
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 30
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 29
- -1 ionizable groups Polymers 0.000 claims abstract description 28
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 28
- 229920002959 polymer blend Polymers 0.000 claims abstract description 24
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 12
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 12
- 239000000178 monomer Substances 0.000 claims description 65
- 239000000203 mixture Substances 0.000 claims description 42
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 30
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 18
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 125000001153 fluoro group Chemical group F* 0.000 claims description 3
- 229920001484 poly(alkylene) Polymers 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 2
- 229920001567 vinyl ester resin Chemical class 0.000 claims description 2
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 claims description 2
- LNGKTPFIOZTXDP-UHFFFAOYSA-N 2-chloro-1,3,3,4,4,5,5,6,6,7,8,8,8-tridecafluoro-7-(trifluoromethyl)oct-1-ene Chemical compound FC(C(C(F)(F)F)(C(C(C(C(C(=CF)Cl)(F)F)(F)F)(F)F)(F)F)F)(F)F LNGKTPFIOZTXDP-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 235000013601 eggs Nutrition 0.000 claims 1
- 239000000446 fuel Substances 0.000 abstract description 31
- 238000000034 method Methods 0.000 abstract description 18
- 239000003014 ion exchange membrane Substances 0.000 abstract description 9
- 238000002360 preparation method Methods 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 239000008240 homogeneous mixture Substances 0.000 abstract description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 60
- 239000004816 latex Substances 0.000 description 29
- 229920000126 latex Polymers 0.000 description 29
- 239000002904 solvent Substances 0.000 description 18
- 238000002156 mixing Methods 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 238000006116 polymerization reaction Methods 0.000 description 16
- 239000006185 dispersion Substances 0.000 description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 13
- 238000010521 absorption reaction Methods 0.000 description 10
- 150000002500 ions Chemical class 0.000 description 10
- 239000002033 PVDF binder Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 7
- 229920000557 Nafion® Polymers 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- 229920000058 polyacrylate Polymers 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000005518 polymer electrolyte Substances 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 229920003303 ion-exchange polymer Polymers 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000006277 sulfonation reaction Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 241000220259 Raphanus Species 0.000 description 4
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000003456 ion exchange resin Substances 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 3
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 238000010561 standard procedure Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- RCEJCSULJQNRQQ-UHFFFAOYSA-N 2-methylbutanenitrile Chemical compound CCC(C)C#N RCEJCSULJQNRQQ-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229920002274 Nalgene Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229920004896 Triton X-405 Polymers 0.000 description 2
- KYIKRXIYLAGAKQ-UHFFFAOYSA-N abcn Chemical compound C1CCCCC1(C#N)N=NC1(C#N)CCCCC1 KYIKRXIYLAGAKQ-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
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- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
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- 239000000843 powder Substances 0.000 description 2
- 238000000807 solvent casting Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical class OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 235000011044 succinic acid Nutrition 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 2
- IAXXETNIOYFMLW-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) 2-methylprop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C(=C)C)CC1C2(C)C IAXXETNIOYFMLW-UHFFFAOYSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- KQEIJFWAXDQUPR-UHFFFAOYSA-N 2,4-diaminophenol;hydron;dichloride Chemical compound Cl.Cl.NC1=CC=C(O)C(N)=C1 KQEIJFWAXDQUPR-UHFFFAOYSA-N 0.000 description 1
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 1
- FTALTLPZDVFJSS-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl prop-2-enoate Chemical compound CCOCCOCCOC(=O)C=C FTALTLPZDVFJSS-UHFFFAOYSA-N 0.000 description 1
- OLQFXOWPTQTLDP-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCO OLQFXOWPTQTLDP-UHFFFAOYSA-N 0.000 description 1
- PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- FRFUQJFVJRYYDZ-UHFFFAOYSA-N 2-methyl-n-(2-methylpropyl)prop-2-enamide Chemical compound CC(C)CNC(=O)C(C)=C FRFUQJFVJRYYDZ-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- GETJHIYPEXUGHO-UHFFFAOYSA-N 3-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCNC(=O)C=C GETJHIYPEXUGHO-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- 229920003934 Aciplex® Polymers 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- WXNOGBYAKIIZTE-UHFFFAOYSA-N CC(=C)C(O)=O.CO[SiH](OC)OC Chemical compound CC(=C)C(O)=O.CO[SiH](OC)OC WXNOGBYAKIIZTE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical group [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
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- RGBXDEHYFWDBKD-UHFFFAOYSA-N propan-2-yl propan-2-yloxy carbonate Chemical compound CC(C)OOC(=O)OC(C)C RGBXDEHYFWDBKD-UHFFFAOYSA-N 0.000 description 1
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- C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
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- C08F8/44—Preparation of metal salts or ammonium salts
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- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
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- H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
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- C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18273200P | 2000-02-15 | 2000-02-15 | |
| US60/182,732 | 2000-02-15 | ||
| US09/774,266 | 2001-01-30 | ||
| US09/774,266 US6780935B2 (en) | 2000-02-15 | 2001-01-30 | Fluoropolymer resins containing ionic or ionizable groups and products containing the same |
| PCT/US2001/004995 WO2001060872A1 (en) | 2000-02-15 | 2001-02-15 | Fluoropolymer resins containing ionic or ionizable groups and products containing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20020000798A KR20020000798A (ko) | 2002-01-05 |
| KR100743845B1 true KR100743845B1 (ko) | 2007-08-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020017013043A Expired - Lifetime KR100743845B1 (ko) | 2000-02-15 | 2001-02-15 | 이온 그룹 또는 이온화 가능한 그룹을 함유하는 불소중합체 수지 및 이를 함유하는 제품 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6780935B2 (enExample) |
| EP (1) | EP1177221A4 (enExample) |
| JP (1) | JP4837216B2 (enExample) |
| KR (1) | KR100743845B1 (enExample) |
| CN (1) | CN1142193C (enExample) |
| CA (1) | CA2369696C (enExample) |
| IL (1) | IL145673A (enExample) |
| MX (1) | MXPA01010408A (enExample) |
| RU (1) | RU2264420C2 (enExample) |
| TW (1) | TWI302540B (enExample) |
| WO (1) | WO2001060872A1 (enExample) |
Cited By (2)
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0029316A1 (en) * | 1979-11-09 | 1981-05-27 | Kureha Kagaku Kogyo Kabushiki Kaisha | Vinylidene chloride copolymer resin composition, packaging film prepared therefrom and food packages using the film |
| US5510160A (en) * | 1993-08-04 | 1996-04-23 | Huels Aktiengesellschaft | Thermoplastic multilayer composites |
| US5554426A (en) * | 1994-03-24 | 1996-09-10 | Huels Aktiengesellschaft | Multilayer plastic pipe |
| US5962140A (en) * | 1996-06-25 | 1999-10-05 | Acushnet Company | Golf ball comprising fluoropolymer |
Family Cites Families (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1810528A (en) | 1929-06-12 | 1931-06-16 | Hotchkiss Co E H | Stapling machine |
| US1996222A (en) | 1933-09-01 | 1935-04-02 | Vogel Max | Stapling machine |
| DE1078329B (de) | 1955-04-27 | 1960-03-24 | Du Pont | Verfahren zur Herstellung eines elastischen Mischpolymerisats aus Vinylidenfluorid und einem anderen Fluorolefin |
| US2987729A (en) | 1959-02-10 | 1961-06-13 | Melpar Inc | Stapling device |
| GB975031A (en) * | 1960-02-01 | 1964-11-11 | American Mach & Foundry | Ion permeable membranes |
| US3178399A (en) | 1961-08-10 | 1965-04-13 | Minnesota Mining & Mfg | Fluorine-containing polymers and preparation thereof |
| US3475396A (en) | 1966-07-06 | 1969-10-28 | Diamond Shamrock Corp | Process for polymerizing vinylidene fluoride |
| US3504837A (en) | 1968-04-24 | 1970-04-07 | Werner Schafroth | Stapling machine and method of forming staples |
| DE1959147C3 (de) * | 1968-11-26 | 1979-12-06 | E.I. Du Pont De Nemours And Co., Wilmington, Del. (V.St.A.) | Oberflächenaktiver Fluorkohlenstoffpolymerisat-Gegenstand |
| US3642187A (en) | 1970-05-14 | 1972-02-15 | Flynn & Emrich Co | Stitching head |
| US3857827A (en) | 1974-01-25 | 1974-12-31 | Pennwalt Corp | Method of preparing high-quality vinylidene fluoride polymer in aqueous emulsion |
| JPS551351B2 (enExample) * | 1974-03-07 | 1980-01-12 | ||
| FR2268094B1 (enExample) | 1974-04-16 | 1976-10-08 | Rhone Poulenc Textile | |
| US4191811A (en) * | 1977-03-01 | 1980-03-04 | Ionics, Incorported | Ion exchange membranes based upon polyphenylene sulfide and fluorocarbon polymeric binder |
| JPS6053059B2 (ja) * | 1978-07-11 | 1985-11-22 | 旭化成株式会社 | 改良された陽イオン交換膜の製法 |
| IT1166581B (it) | 1979-01-17 | 1987-05-05 | Oronzio De Nora Impianti | Membrane cationiche a base di copolimeri solfonati di stirene divinilbenzene e 2- o 4-vinilpiridina o acido acrilico, procedimento per la loro preparazione ed uso in celle di elettrolisi |
| US4318555A (en) | 1980-01-15 | 1982-03-09 | Eastman Kodak Company | Stapler |
| US4421264A (en) | 1981-06-26 | 1983-12-20 | International Business Machines Corporation | Variable thickness set compensation for stapler |
| US4583276A (en) | 1983-06-23 | 1986-04-22 | Swingline, Inc. | Method of forming and driving staples |
| US4569978A (en) | 1984-07-25 | 1986-02-11 | Pennwalt Corporation | Emulsion polymerization of vinylidene fluoride polymers in the presence of trichlorofluoromethane as chain transfer agent |
| DE3533840A1 (de) | 1985-09-23 | 1987-04-02 | Bosch Gmbh Robert | Kraftbetriebenes einschlaggeraet, insbesondere fuer heftklammern |
| FR2600265B1 (fr) * | 1986-06-20 | 1991-09-06 | Rhone Poulenc Rech | Membranes semi-permeables sechables et hydrophiles a base de polyfluorure de vinylidene |
| US5007483A (en) | 1988-02-03 | 1991-04-16 | Mcguire Douglas K | Hoof-buffing tool kit for farriers |
| US5093427A (en) | 1990-05-10 | 1992-03-03 | Atochem North America, Inc. | Copolymers of vinylidene fluoride and hexafluoropropylene and process for preparing the same |
| JP3128938B2 (ja) * | 1992-03-27 | 2001-01-29 | ジェイエスアール株式会社 | 水系フッ素重合体分散液の製造方法 |
| US5272186A (en) | 1992-05-01 | 1993-12-21 | E. I. Du Pont De Nemours And Company | Concentration of fluoropolymer dispersions using acrylic polymers of high acid content |
| SE500140C2 (sv) | 1992-06-30 | 1994-04-25 | Isaberg Ab | Häftapparat med flatläggningsmekanism |
| DE4243995C2 (de) * | 1992-12-23 | 1996-07-25 | Gore W L & Ass Gmbh | Permanente hydrophile Modifizierung für Fluorpolymere und Verfahren zur Erzeugung der Modifizierung |
| JP3345788B2 (ja) * | 1993-12-26 | 2002-11-18 | ジャパンゴアテックス株式会社 | 電気化学反応装置用セパレータ |
| JPH07187487A (ja) | 1993-12-28 | 1995-07-25 | Toshiba Corp | ステイプル装置及びステイプル装置を有した画像形成装置 |
| ZA952384B (en) * | 1994-04-13 | 1996-09-23 | Nat Power Plc | Cation exchange membranes and method for the preparation of such membranes |
| US5468574A (en) | 1994-05-23 | 1995-11-21 | Dais Corporation | Fuel cell incorporating novel ion-conducting membrane |
| US5795668A (en) | 1994-11-10 | 1998-08-18 | E. I. Du Pont De Nemours And Company | Fuel cell incorporating a reinforced membrane |
| US5599614A (en) * | 1995-03-15 | 1997-02-04 | W. L. Gore & Associates, Inc. | Integral composite membrane |
| US5880204A (en) | 1995-09-27 | 1999-03-09 | Alliedsignal Inc. | Room temperature coalescable aqueous fluoropolymer dispersions and method for their manufacture |
| CA2252679C (en) | 1996-04-30 | 2003-10-28 | W. L. Gore & Associates, Inc. | Integral multi-layered ion-exchange composite membranes |
| JPH108009A (ja) * | 1996-06-26 | 1998-01-13 | Elf Atochem Japan Kk | フッ化ビニリデン系樹脂の金属への接着方法およびフッ化ビニリデン系樹脂からなる金属接着性複合材料 |
| US6033804A (en) | 1996-11-01 | 2000-03-07 | E. I. Du Pont De Nemours And Company | Highly conductive ion exchange polymer and process |
| US6444343B1 (en) * | 1996-11-18 | 2002-09-03 | University Of Southern California | Polymer electrolyte membranes for use in fuel cells |
| US6025092A (en) * | 1998-02-13 | 2000-02-15 | E. I. Du Pont De Nemours And Company | Fluorinated ionomers and their uses |
| JP4150867B2 (ja) * | 1998-05-13 | 2008-09-17 | ダイキン工業株式会社 | 燃料電池に使用するのに適した固体高分子電解質用材料 |
| US6076720A (en) | 1998-07-22 | 2000-06-20 | Deng; Jinn-Yi | Stapler with staples of different sizes |
| DK1176655T3 (da) * | 1998-12-22 | 2003-07-07 | David Fuel Cell Components S L | Membranelektrode aggregat og produktionsproces |
| US6423784B1 (en) * | 1999-12-15 | 2002-07-23 | 3M Innovative Properties Company | Acid functional fluoropolymer membranes and method of manufacture |
-
2001
- 2001-01-30 US US09/774,266 patent/US6780935B2/en not_active Expired - Lifetime
- 2001-02-15 WO PCT/US2001/004995 patent/WO2001060872A1/en not_active Ceased
- 2001-02-15 CA CA2369696A patent/CA2369696C/en not_active Expired - Lifetime
- 2001-02-15 KR KR1020017013043A patent/KR100743845B1/ko not_active Expired - Lifetime
- 2001-02-15 JP JP2001560254A patent/JP4837216B2/ja not_active Expired - Lifetime
- 2001-02-15 EP EP01916103A patent/EP1177221A4/en not_active Withdrawn
- 2001-02-15 MX MXPA01010408A patent/MXPA01010408A/es active IP Right Grant
- 2001-02-15 CN CNB018002137A patent/CN1142193C/zh not_active Expired - Lifetime
- 2001-02-15 RU RU2001130757/04A patent/RU2264420C2/ru active
- 2001-03-08 TW TW090103434A patent/TWI302540B/zh not_active IP Right Cessation
- 2001-09-25 IL IL145673A patent/IL145673A/en active IP Right Grant
-
2003
- 2003-09-24 US US10/670,095 patent/US6872781B2/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0029316A1 (en) * | 1979-11-09 | 1981-05-27 | Kureha Kagaku Kogyo Kabushiki Kaisha | Vinylidene chloride copolymer resin composition, packaging film prepared therefrom and food packages using the film |
| US5510160A (en) * | 1993-08-04 | 1996-04-23 | Huels Aktiengesellschaft | Thermoplastic multilayer composites |
| US5554426A (en) * | 1994-03-24 | 1996-09-10 | Huels Aktiengesellschaft | Multilayer plastic pipe |
| US5962140A (en) * | 1996-06-25 | 1999-10-05 | Acushnet Company | Golf ball comprising fluoropolymer |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101547409B1 (ko) | 2010-12-15 | 2015-08-25 | 솔베이 (차이나) 컴퍼니, 리미티드 | 플루오로중합체 조성물 |
| KR101282028B1 (ko) * | 2011-04-18 | 2013-07-04 | 한국화학연구원 | 태양전지 모듈 백시트의 내후성 코팅용 불소고분자-퍼플루오로알킬기 함유 아크릴 입자 |
Also Published As
| Publication number | Publication date |
|---|---|
| US6872781B2 (en) | 2005-03-29 |
| JP4837216B2 (ja) | 2011-12-14 |
| CA2369696A1 (en) | 2001-08-23 |
| CN1362971A (zh) | 2002-08-07 |
| IL145673A (en) | 2009-09-22 |
| US6780935B2 (en) | 2004-08-24 |
| EP1177221A1 (en) | 2002-02-06 |
| CA2369696C (en) | 2011-12-13 |
| KR20020000798A (ko) | 2002-01-05 |
| WO2001060872A1 (en) | 2001-08-23 |
| US20040092661A1 (en) | 2004-05-13 |
| TWI302540B (en) | 2008-11-01 |
| EP1177221A4 (en) | 2006-11-08 |
| RU2264420C2 (ru) | 2005-11-20 |
| MXPA01010408A (es) | 2002-05-06 |
| JP2003523419A (ja) | 2003-08-05 |
| US20030064267A1 (en) | 2003-04-03 |
| CN1142193C (zh) | 2004-03-17 |
| IL145673A0 (en) | 2002-06-30 |
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