IT1166581B - Membrane cationiche a base di copolimeri solfonati di stirene divinilbenzene e 2- o 4-vinilpiridina o acido acrilico, procedimento per la loro preparazione ed uso in celle di elettrolisi - Google Patents
Membrane cationiche a base di copolimeri solfonati di stirene divinilbenzene e 2- o 4-vinilpiridina o acido acrilico, procedimento per la loro preparazione ed uso in celle di elettrolisiInfo
- Publication number
- IT1166581B IT1166581B IT19354/79A IT1935479A IT1166581B IT 1166581 B IT1166581 B IT 1166581B IT 19354/79 A IT19354/79 A IT 19354/79A IT 1935479 A IT1935479 A IT 1935479A IT 1166581 B IT1166581 B IT 1166581B
- Authority
- IT
- Italy
- Prior art keywords
- vinylpyridine
- preparation
- acrylic acid
- electrolysis cells
- procedure
- Prior art date
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title abstract 3
- 239000012528 membrane Substances 0.000 title abstract 3
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 title abstract 2
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 title abstract 2
- 238000005868 electrolysis reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 title 1
- 229920001577 copolymer Polymers 0.000 title 1
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 238000006277 sulfonation reaction Methods 0.000 abstract 1
- 229920001897 terpolymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2287—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2339/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Derivatives of such polymers
- C08J2339/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08J2339/08—Homopolymers or copolymers of vinyl-pyridine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT19354/79A IT1166581B (it) | 1979-01-17 | 1979-01-17 | Membrane cationiche a base di copolimeri solfonati di stirene divinilbenzene e 2- o 4-vinilpiridina o acido acrilico, procedimento per la loro preparazione ed uso in celle di elettrolisi |
| US06/013,829 US4246090A (en) | 1979-01-17 | 1979-02-22 | Novel cationic membranes |
| CA322,382A CA1130515A (en) | 1979-01-17 | 1979-02-27 | Cationic membranes |
| DE7979100598T DE2967209D1 (en) | 1979-01-17 | 1979-02-28 | A fluid impermeable cation exchange membrane, process for its preparation, electrochemical cell comprising said membrane and an electrolytic process using said membrane |
| JP2204579A JPS5597255A (en) | 1979-01-17 | 1979-02-28 | Cation exchange membrane |
| EP79100598A EP0013677B1 (en) | 1979-01-17 | 1979-02-28 | A fluid impermeable cation exchange membrane, process for its preparation, electrochemical cell comprising said membrane and an electrolytic process using said membrane |
| US06/133,521 US4295952A (en) | 1979-01-17 | 1980-03-24 | Novel cationic membranes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT19354/79A IT1166581B (it) | 1979-01-17 | 1979-01-17 | Membrane cationiche a base di copolimeri solfonati di stirene divinilbenzene e 2- o 4-vinilpiridina o acido acrilico, procedimento per la loro preparazione ed uso in celle di elettrolisi |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IT7919354A0 IT7919354A0 (it) | 1979-01-17 |
| IT1166581B true IT1166581B (it) | 1987-05-05 |
Family
ID=11156986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT19354/79A IT1166581B (it) | 1979-01-17 | 1979-01-17 | Membrane cationiche a base di copolimeri solfonati di stirene divinilbenzene e 2- o 4-vinilpiridina o acido acrilico, procedimento per la loro preparazione ed uso in celle di elettrolisi |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US4246090A (it) |
| EP (1) | EP0013677B1 (it) |
| JP (1) | JPS5597255A (it) |
| CA (1) | CA1130515A (it) |
| DE (1) | DE2967209D1 (it) |
| IT (1) | IT1166581B (it) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55160028A (en) * | 1979-05-31 | 1980-12-12 | Asahi Chem Ind Co Ltd | Improved fluorinated cation exchange membrane and production thereof |
| US4462877A (en) * | 1980-06-11 | 1984-07-31 | The Dow Chemical Company | Composite ion exchange membranes |
| US4414090A (en) * | 1981-10-01 | 1983-11-08 | Rai Research Corporation | Separator membranes for redox-type electrochemical cells |
| EP0082355B1 (de) * | 1981-12-21 | 1986-06-11 | Aligena Ag | Semipermeable Membranen aus modifizierten Polystyrolen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US4627899A (en) * | 1985-02-15 | 1986-12-09 | The United States Of America As Represented By The Secretary Of The Interior | Electrolytic cell and methods combining electrowinning and electrochemical reactions employing a membrane or diaphragm |
| AU570847B2 (en) * | 1985-05-17 | 1988-03-24 | Dow Chemical Company, The | Electrochemical cell component, process for preparing same and processes utilising the component |
| US4795536A (en) * | 1985-07-10 | 1989-01-03 | Allied-Signal Inc. | Hydrogen separation and electricity generation using novel three-component membrane |
| US4795533A (en) * | 1985-07-10 | 1989-01-03 | Allied-Signal Inc. | Gas detection apparatus and method with novel three-component membrane |
| US4714482A (en) * | 1985-07-11 | 1987-12-22 | Uop Inc. | Thin film polymer blend membranes |
| US4664757A (en) * | 1985-12-27 | 1987-05-12 | Uop Inc. | Method and apparatus for gas detection using proton-conducting polymers |
| US4664761A (en) * | 1985-12-27 | 1987-05-12 | Uop Inc. | Electrochemical method and apparatus using proton-conducting polymers |
| US6780935B2 (en) | 2000-02-15 | 2004-08-24 | Atofina Chemicals, Inc. | Fluoropolymer resins containing ionic or ionizable groups and products containing the same |
| WO2003062493A1 (en) * | 2002-01-23 | 2003-07-31 | Polyfuel, Inc. | Acid-base proton conducting polymer blend membrane |
| US20040175625A1 (en) * | 2003-03-06 | 2004-09-09 | Lotfi Hedhli | Non-perfluorinated resins containing ionic or ionizable groups and products containing the same |
| US7449111B2 (en) * | 2003-07-30 | 2008-11-11 | Arkema Inc. | Resins containing ionic or ionizable groups with small domain sizes and improved conductivity |
| US8039160B2 (en) * | 2004-07-14 | 2011-10-18 | Arkema Inc. | Multi-layer polyelectrolyte membrane |
| FR2909906B1 (fr) | 2006-12-13 | 2009-02-06 | Inst Francais Du Petrole | Procede d'isomerisation des composes c8 aromatiques en presence d'un catalyseur comprenant une zeolithe euo modifiee |
| TWI398353B (zh) * | 2009-03-02 | 2013-06-11 | Ind Tech Res Inst | 奈米纖維材料與脫鹽過濾材料 |
| EP2535325B1 (en) * | 2010-02-09 | 2018-04-25 | Chiyoda Corporation | Method for enhancing the carbonylation rate of methanol |
| US20190233788A1 (en) * | 2016-07-05 | 2019-08-01 | Korea Advanced Institute Of Science And Technology | Production Method For And Use Of Polymer Thin-Film Culture Plat For Production Method For And Application Of Cell Sheet |
| US10741812B2 (en) * | 2017-06-19 | 2020-08-11 | GM Global Technology Operations LLC | Acid-scavenging functional separators for power performance of lithium ion electrochemical cells |
| CN114597348B (zh) | 2020-12-02 | 2024-06-11 | 通用汽车环球科技运作有限责任公司 | 通过轧制制得电极的制造方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3562139A (en) * | 1968-08-05 | 1971-02-09 | Ionics | Cationic-anionic ion-exchange membrane |
| US3657104A (en) * | 1970-11-05 | 1972-04-18 | Ionics | Bifunctional cation exchange membranes and their use in electrolyticcells |
| JPS5140556B2 (it) * | 1971-11-26 | 1976-11-04 | ||
| US3887499A (en) * | 1971-12-06 | 1975-06-03 | Ionics | Cation exchange membranes having carboxylic and sulfonic acid functionality |
| US3976549A (en) * | 1973-02-26 | 1976-08-24 | Hooker Chemicals & Plastics Corporation | Electrolysis method |
| US4166014A (en) * | 1973-12-27 | 1979-08-28 | Tokuyama Soda Kabushiki Kaisha | Electrolytic diaphragms, and method of electrolysis using the same |
| IN143622B (it) * | 1974-10-16 | 1978-01-07 | Diamond Shamrock Corp | |
| JPS52145397A (en) * | 1976-03-31 | 1977-12-03 | Asahi Chem Ind Co Ltd | Electrolysis |
| US4100113A (en) * | 1976-04-01 | 1978-07-11 | Diamond Shamrock Corporation | Electrolytic cell membrane and method of preparation by plasma polymerization of polyamide or polytetrafluoroethylene thin films onto polymeric substrates |
| US4101395A (en) * | 1976-08-30 | 1978-07-18 | Tokuyama Soda Kabushiki Kaisha | Cathode-structure for electrolysis |
-
1979
- 1979-01-17 IT IT19354/79A patent/IT1166581B/it active
- 1979-02-22 US US06/013,829 patent/US4246090A/en not_active Expired - Lifetime
- 1979-02-27 CA CA322,382A patent/CA1130515A/en not_active Expired
- 1979-02-28 EP EP79100598A patent/EP0013677B1/en not_active Expired
- 1979-02-28 DE DE7979100598T patent/DE2967209D1/de not_active Expired
- 1979-02-28 JP JP2204579A patent/JPS5597255A/ja active Pending
-
1980
- 1980-03-24 US US06/133,521 patent/US4295952A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US4246090A (en) | 1981-01-20 |
| DE2967209D1 (en) | 1984-10-18 |
| EP0013677A1 (en) | 1980-08-06 |
| CA1130515A (en) | 1982-08-31 |
| IT7919354A0 (it) | 1979-01-17 |
| EP0013677B1 (en) | 1984-09-12 |
| US4295952A (en) | 1981-10-20 |
| JPS5597255A (en) | 1980-07-24 |
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