JPWO2010016612A1 - 色素増感型太陽電池用色素、半導体電極及び色素増感型太陽電池 - Google Patents
色素増感型太陽電池用色素、半導体電極及び色素増感型太陽電池 Download PDFInfo
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- JPWO2010016612A1 JPWO2010016612A1 JP2010523919A JP2010523919A JPWO2010016612A1 JP WO2010016612 A1 JPWO2010016612 A1 JP WO2010016612A1 JP 2010523919 A JP2010523919 A JP 2010523919A JP 2010523919 A JP2010523919 A JP 2010523919A JP WO2010016612 A1 JPWO2010016612 A1 JP WO2010016612A1
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- 239000000979 synthetic dye Substances 0.000 description 1
- 239000001040 synthetic pigment Substances 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical class CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- NLDYACGHTUPAQU-UHFFFAOYSA-N tetracyanoethylene Chemical group N#CC(C#N)=C(C#N)C#N NLDYACGHTUPAQU-UHFFFAOYSA-N 0.000 description 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical class CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 150000004961 triphenylmethanes Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- C07D209/56—Ring systems containing three or more rings
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Abstract
Description
中間体A;1.0g、中間体B;0.4g、酢酸アンモニウム0.05g、酢酸20mlを混合し、浴温120℃にて7時間加熱を行った。ついで室温まで冷却、そして析出した固体を濾取し、酢酸50ml、次いで水50ml、さらにメタノール20mlで洗浄後乾燥して、1.1gの粗生成物を得た。これをシリカゲルカラムクロマトグラフィー(展開溶媒:クロロホルム/メタノール=10/1(容量比))で精製して、0.9gの色素A−7を得た。
吸収極大(N,N−ジメチルホルムアミド溶液):485nm
中間体C;1.7g、中間体B;0.8g、酢酸アンモニウム0.05g、酢酸40mlを混合し、浴温120℃にて7時間加熱を行った。ついで室温まで冷却、そして析出した固体を濾取し、酢酸50ml、次いで水50ml、さらにメタノール20mlで洗浄後乾燥して、2.0gの粗生成物を得た。これをシリカゲルカラムクロマトグラフィー(展開溶媒:クロロホルム/メタノール=10/1(容量比))で精製して、1.6gの化合物A−3を得た。
吸収極大(メタノール溶液):490nm
中間体D;2.2g、中間体E;2.3g、酢酸アンモニウム0.1g、酢酸200mlを混合し、浴温120℃にて6時間加熱を行った。ついで室温まで冷却、そして析出した固体を濾取し、酢酸80ml、次いで水160ml、さらにメタノール140mlで洗浄後乾燥して、2.0gの粗生成物を得た。これをシリカゲルカラムクロマトグラフィー(展開溶媒:クロロホルム/メタノール=3/1(容量比))で精製して、1.6gの色素B−3を得た。
吸収極大(N,N−ジメチルホルムアミド溶液):530nm
中間体D;2.2g、中間体F;2.8g、酢酸アンモニウム0.1g、酢酸200mlを混合し、浴温120℃にて6時間加熱を行った。ついで室温まで冷却、そして析出した固体を濾取し、酢酸80ml、次いで水160ml、さらにメタノール140mlで洗浄後乾燥して、1.9gの粗生成物を得た。これをシリカゲルカラムクロマトグラフィー(展開溶媒:クロロホルム/メタノール=3/1(容量比))で精製して、1.5gの色素B−12を得た。
吸収極大(N,N−ジメチルホルムアミド溶液):530nm
中間体A;2.0g、中間体G;1.7g、酢酸アンモニウム0.1g、酢酸200mlを混合し、浴温120℃にて5時間加熱を行った。ついで室温まで冷却、そして析出した固体を濾取し、酢酸80ml、次いで水160ml、さらにメタノール140mlで洗浄後乾燥して、2.0gの粗生成物を得た。これをシリカゲルカラムクロマトグラフィー(展開溶媒:クロロホルム/メタノール=10/1(容量比))で精製して、1.7gの色素B−39を得た。
吸収極大(N,N−ジメチルホルムアミド溶液):524nm
中間体A;2.0g、中間体H;2.4g、酢酸アンモニウム0.1g、酢酸200mlを混合し、浴温120℃にて6時間加熱を行った。ついで室温まで冷却、そして析出した固体を濾取し、酢酸80ml、次いで水160ml、さらにメタノール140mlで洗浄後乾燥して、2.0gの粗生成物を得た。これをシリカゲルカラムクロマトグラフィー(展開溶媒:クロロホルム/メタノール=10/1(容量比))で精製して、1.8gの色素B−41を得た。
吸収極大(N,N−ジメチルホルムアミド溶液):524nm
中間体C;2.0g、中間体I;2.2g、酢酸アンモニウム0.1g、酢酸400mlを混合し、浴温120℃にて10時間加熱を行った。ついで室温まで冷却、そして析出した固体を濾取し、酢酸80ml、次いで水160ml、さらにメタノール80mlで洗浄後乾燥して、3.1gの粗生成物を得た。これをシリカゲルカラムクロマトグラフィー(展開溶媒:クロロホルム/メタノール=3/1(容量比))で精製して、2.3gの色素C−8を得た。
吸収極大(N,N−ジメチルホルムアミド溶液):553nm
中間体A;2.0g、シアノ酢酸1.1g、ピペリジン0.8g、アセトニトリル80mlを混合し、浴温90℃にて5時間加熱還流した。ついで室温まで冷却、溶媒をデカンテーションして捨て、沈澱した油状物を取り出した。油状物をクロロホルム200mlに溶解し、1mol/lの塩酸20mlで洗浄した。クロロホルム溶液を分取し、水50mlで3回した後、無水硫酸マグネシウムで乾燥し、ロータリーエバポレーターでクロロホルムを減圧留去して1.8gの粗生成物を得た。これをシリカゲルカラムクロマトグラフィー(展開溶媒:クロロホルム/メタノール=3/1(容量比))で精製して、1.6gの色素D−7を得た。
吸収極大(メタノール溶液):415nm
中間体C;1.8g、シアノ酢酸1.1g、ピペリジン0.8g、アセトニトリル80mlを混合し、浴温90℃にて5時間加熱還流した。ついで室温まで冷却、溶媒をデカンテーションして捨て、沈澱した油状物を取り出した。油状物をクロロホルム200mlに溶解し、1mol/lの塩酸20mlで洗浄した。クロロホルム溶液を分取し、水50mlで3回した後、無水硫酸マグネシウムで乾燥し、ロータリーエバポレーターでクロロホルムを減圧留去して1.7gの粗生成物を得た。これをシリカゲルカラムクロマトグラフィー(展開溶媒:クロロホルム/メタノール=3/1(容量比))で精製して、1.5gの色素D−7を得た。
吸収極大(メタノール溶液):442nm
<色素増感型太陽電池の作製>
酸化チタン(日本アエロジル社製、商品名:P−25)2g、アセチルアセトン0.2g、界面活性剤(アルドリッチ社製、商品名:Triton X−100)0.3gを水6.5gと共にペイントコンディショナー(レッドデビル社製)で6時間分散処理を施した。さらに、この分散液4.0gに対して濃硝酸0.2ml、エタノール0.4ml、ポリエチレングリコール(#20,000)1.2gを加えてペーストを作製した。このペーストをFTOガラス基板上に膜厚10μmになるように塗布し、室温で乾燥後、100℃で1時間、さらに、550℃で1時間焼成し、半導体電極を得た。
色素増感型太陽電池の作用電極側から、光源としてソーラーシミュレーター(山下電装(株)製、装置名:YSS−40S)から発生した擬似太陽光(AM1.5G、照射強度100mW/cm2)を照射し、電気化学測定装置(ソーラートロン社製、装置名:SI−1280B)を用いて光電変換効率を評価した。結果を表3に示す。
色素増感型太陽電池を65℃環境下で14日間保存した後、光電変換効率を評価した。また、光電変換効率の維持率を求めた。光電変換効率の維持率は、保存前の光電変換効率に対する、保存後の光電変換効率の百分率として算出した。結果を表4に示す。
色素A−7をテトラヒドロフランに溶解し、0.3mMの濃度の色素溶液を作製した。この色素溶液に半導体電極を室温で8時間浸漬して吸着処理を施し、色素吸着半導体電極(作用電極)を作製した。この色素吸着半導体電極を電解質の溶媒である3−メトキシプロピオニトリル中に浸漬し、遮光、密閉かつ室温下で30日間保存した。保存した後の半導体電極上における色素の担持状態を目視で観察した。結果を表5に示す。
○:色素の溶出見られず。
△:色素の溶出が一部見られる。
色素A−7を、表3に示す色素に変更した以外は、実施例1同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表3〜5に示す。
色素A−7を、比較色素F−1〜F−6に変更した以外は、実施例1と同様にして色素増感型太陽電池の作製及び評価を実施した。結果を表3〜5に示す。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例1と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表6に示す。実施例1と比較して、開放電圧が+0.05V、短絡電流密度が−0.1mA/cm2、形状因子が+0.02変化しており、結果として、光電変換効率が+0.50%向上していた。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例2〜20と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表6に示す。表6には、開放電圧と光電変換効率について、実施例2〜20との差も示した。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、比較例1〜6と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表6に示す。表6には、開放電圧と光電変換効率について、比較例1〜6との差も示した。
<色素増感型太陽電池の作製>
酸化チタン(日本アエロジル社製、商品名:P−25)2g、アセチルアセトン0.2g、界面活性剤(アルドリッチ社製、商品名:Triton X−100)0.3gを水6.5gと共にペイントコンディショナー(レッドデビル社製)で6時間分散処理を施した。さらに、この分散液4.0gに対して濃硝酸0.2ml、エタノール0.4ml、ポリエチレングリコール(#20,000)1.2gを加えてペーストを作製した。このペーストをFTOガラス基板上に膜厚12μmになるように塗布し、室温で乾燥後、100℃で1時間、さらに550℃で1時間焼成し、半導体電極を作製した。
評価1〜3を実施して、結果を表7〜9に示した。
色素B−3を、表7に示す色素に変更した以外は、実施例41と同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表7〜9に示す。
色素B−3を、比較色素F−7〜F−11に変更した以外は、実施例41と同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表7〜9に示す。
色素B−3を、表10に示す色素に変更し、ステロイド化合物E1をE2に変更した以外は、実施例41と同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表10〜12に示す。
色素B−3を、比較色素F−12〜F−17に変更し、ステロイド化合物E1をE2に変更した以外は、実施例41と同様にして、色素増感型太陽電池を作製して評価した。結果を表10〜12に示す。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例41と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表13に示す。実施例41と比較して、開放電圧が+0.06V、短絡電流密度が−0.1mA/cm2、形状因子が+0.03変化しており、結果として、光電変換効率が+0.80%向上していた。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例42〜92と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表13及び表14に示す。表13及び表14には、開放電圧と光電変換効率について、実施例42〜92との差も示した。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、比較例13〜23と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表13及び表14に示す。表13及び表14には、開放電圧と光電変換効率について、比較例13〜23との差も示した。
<色素増感型太陽電池の作製>
酸化チタン(日本アエロジル社製、商品名:P−25)2g、アセチルアセトン0.2g、界面活性剤(アルドリッチ社製、商品名:Triton X−100)0.3gを水6.5gと共にペイントコンディショナー(レッドデビル社製)で6時間分散処理を施した。さらに、この分散液4.0gに対して濃硝酸0.2ml、エタノール0.4ml、ポリエチレングリコール(#20,000)1.2gを加えてペーストを作製した。このペーストをFTOガラス基板上に膜厚10μmになるように塗布し、室温で乾燥後、100℃で1時間、さらに、550℃で1時間焼成し、半導体電極を得た。
評価1〜3を実施して、結果を表15〜17に示した。
色素C−8を、表15に示す色素に変更した以外は、実施例145同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表15〜17に示す。
色素C−8を、比較色素F−18〜F−22に変更した以外は、実施例145と同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表15〜17に示す。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例145と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表18に示す。実施例145と比較して、開放電圧が+0.05V、短絡電流密度が−0.1mA/cm2、形状因子が+0.02変化しており、結果として、光電変換効率が+0.64%向上していた。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例146〜164と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表18に示す。表18には、開放電圧と光電変換効率について、実施例146〜164との差も示した。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、比較例35〜39と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表18に示す。表18には、開放電圧と光電変換効率について、比較例35〜39との差も示した。
<色素増感型太陽電池の作製>
酸化チタン(日本アエロジル社製、商品名:P−25)2g、アセチルアセトン0.2g、界面活性剤(アルドリッチ社製、商品名:Triton X−100)0.3gを水6.5gと共にペイントコンディショナー(レッドデビル社製)で6時間分散処理を施した。さらに、この分散液4.0gに対して濃硝酸0.2ml、エタノール0.4ml、ポリエチレングリコール(#20,000)1.2gを加えてペーストを作製した。このペーストをFTOガラス基板上に膜厚10μmになるように塗布し、室温で乾燥後、100℃で1時間、さらに、550℃で1時間焼成し、半導体電極を得た。
評価1〜3を実施して、結果を表19〜21に示した。
色素D−7を、表19に示す色素に変更した以外は、実施例185と同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表19〜21に示す。
色素D−7を、比較色素F−23〜F−27に変更した以外は、実施例185と同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表19〜21に示す。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例185と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表22に示す。実施例185と比較して、開放電圧が+0.05V、短絡電流密度が−0.1mA/cm2、形状因子が+0.02変化しており、結果として、光電変換効率が+0.67%向上していた。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例186〜204と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表22に示す。表22には、開放電圧と光電変換効率について、実施例186〜204との差も示した。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、比較例45〜49と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表22に示す。表22には、開放電圧と光電変換効率について、比較例45〜49との差も示した。
<色素増感型太陽電池の作製>
酸化チタン(日本アエロジル社製、商品名:P−25)2g、アセチルアセトン0.2g、界面活性剤(アルドリッチ社製、商品名:Triton X−100)0.3gを水6.5gと共にペイントコンディショナー(レッドデビル社製)で6時間分散処理を施した。さらに、この分散液4.0gに対して濃硝酸0.2ml、エタノール0.4ml、ポリエチレングリコール(#20,000)1.2gを加えてペーストを作製した。このペーストをFTOガラス基板上に膜厚6μmになるように塗布し、室温で乾燥後、100℃で1時間、さらに、550℃で1時間焼成し、半導体電極を得た。
評価1〜3を実施して、結果を表23〜25に示した。
色素D−9をテトラヒドロフランに溶解し、0.3mMの濃度の色素溶液を作製した。この色素溶液に、実施例225と同様にして作製した半導体電極を室温で3時間浸漬して吸着処理を施し、色素吸着半導体電極(作用電極)を作製した。対極にはチタニウム板上に白金をスパッタリングしたものを使用した。両電極を互いに向かい合うように配置し、それらの間に電解液を注入して色素増感型太陽電池を作製した。電解液はヨウ化リチウム0.1M、ヨウ素0.05M、ヨウ化1,2−ジメチル−3−n−プロピルイミダゾリウム0.5M、4−t−ブチルピリジン0.05Mの3−メトキシプロピオニトリル溶液を使用した。
評価1〜3を実施して、結果を表23〜25に示した。
色素B−12を、比較色素F−28またはF−29に変更した以外は、実施例225と同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表23〜25に示す。
色素D−9を、比較色素F−30またはF−31に変更した以外は、実施例226と同様にして、色素増感型太陽電池の作製及び評価を実施した。結果を表23〜25に示す。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例225と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表26に示す。実施例225と比較して、開放電圧が+0.05V、短絡電流密度が−0.1mA/cm2、形状因子が+0.01変化しており、結果として、光電変換効率が+0.50%向上していた。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、実施例226と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表26に示す。表26には、開放電圧と光電変換効率について、実施例226との差も示した。
電解液の4−t−ブチルピリジンの濃度を0.5Mに変更した以外は、比較例55〜58と同様にして、色素増感型太陽電池を作製して、光電変換効率を評価した。結果を表26に示す。表26には、開放電圧と光電変換効率について、比較例55〜58との差も示した。
Claims (3)
- 下記一般式[I]、[II]、[III]または[IV]で示される色素増感型太陽電池用色素。
- 請求項1記載の色素増感型太陽電池用色素により増感された半導体電極。
- 請求項2記載の半導体電極を用いてなる色素増感型太陽電池。
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Family Cites Families (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3824099A (en) | 1973-01-15 | 1974-07-16 | Ibm | Sensitive electrophotographic plates |
US4123269A (en) | 1977-09-29 | 1978-10-31 | Xerox Corporation | Electrostatographic photosensitive device comprising hole injecting and hole transport layers |
US4150987A (en) | 1977-10-17 | 1979-04-24 | International Business Machines Corporation | Hydrazone containing charge transport element and photoconductive process of using same |
JPS56123544A (en) | 1980-03-03 | 1981-09-28 | Hitachi Ltd | Composite type electrophotographic plate and electrophotographic method using it |
JPS57207982A (en) | 1981-06-16 | 1982-12-20 | Canon Inc | Information output device |
JPS5865440A (ja) | 1981-09-18 | 1983-04-19 | Konishiroku Photo Ind Co Ltd | 電子写真感光体 |
JPS6024553A (ja) | 1983-07-20 | 1985-02-07 | Mitsubishi Paper Mills Ltd | 電子写真用感光体 |
JPS6098437A (ja) | 1983-11-04 | 1985-06-01 | Ricoh Co Ltd | 電子写真用感光体 |
JPS60182542A (ja) | 1984-02-29 | 1985-09-18 | Otani Denki Kk | リ−ル台のブレ−キ装置 |
JP2659561B2 (ja) | 1988-08-12 | 1997-09-30 | 三菱製紙株式会社 | 電子写真感光体 |
JPH0296767A (ja) | 1988-10-03 | 1990-04-09 | Mitsubishi Paper Mills Ltd | 電子写真感光体 |
JP2690541B2 (ja) | 1989-01-09 | 1997-12-10 | 三菱製紙株式会社 | 電子写真感光体 |
JPH02226160A (ja) | 1989-02-27 | 1990-09-07 | Mitsubishi Paper Mills Ltd | 電子写真感光体 |
JP2812729B2 (ja) | 1989-08-17 | 1998-10-22 | 三菱製紙株式会社 | 電子写真感光体 |
US5679795A (en) | 1995-02-28 | 1997-10-21 | Eastman Kodak Company | Method of synthesizing dyes and precursor compounds therefor |
JP2955646B2 (ja) | 1996-09-12 | 1999-10-04 | 工業技術院長 | 有機色素増感型酸化物半導体電極及びそれを含む太陽電池 |
JP4201095B2 (ja) | 1998-02-20 | 2008-12-24 | 富士フイルム株式会社 | 光電変換素子および光電気化学電池 |
JP2001076773A (ja) | 1999-08-31 | 2001-03-23 | Fuji Photo Film Co Ltd | 光電変換素子および光電気化学電池ならびに新規スクアリリウムシアニン色素 |
JP2002045199A (ja) | 2000-07-31 | 2002-02-12 | Olympus Optical Co Ltd | 変異原性解析方法 |
JP5142307B2 (ja) | 2000-11-28 | 2013-02-13 | 独立行政法人産業技術総合研究所 | 有機色素を光増感剤とする半導体薄膜電極、光電変換素子 |
JP2004011555A (ja) | 2002-06-07 | 2004-01-15 | Hitachi Unisia Automotive Ltd | タービン型燃料ポンプ |
US20040256002A1 (en) | 2002-07-29 | 2004-12-23 | Tamotsu Horiuchi | Organic dye, photoelectric transducing material, semiconductor electrode, and photoelectric transducing device |
DE60333014D1 (de) * | 2002-07-29 | 2010-07-29 | Mitsubishi Paper Mills Ltd | Organischer farbstoff, photoelektrisch signalgebendes material, halbleiterelektrode sowie photoelektrischer signalgeber |
JP4326272B2 (ja) | 2003-06-26 | 2009-09-02 | 三菱製紙株式会社 | 色素増感型太陽電池用色素 |
JP2006156212A (ja) * | 2004-11-30 | 2006-06-15 | Mitsubishi Paper Mills Ltd | 半導体電極並びにそれを用いた光電変換素子 |
JP5185503B2 (ja) | 2005-03-07 | 2013-04-17 | 三菱製紙株式会社 | 光電変換材料、半導体電極並びにそれを用いた光電変換素子 |
JP2007027171A (ja) * | 2005-07-12 | 2007-02-01 | Mitsubishi Paper Mills Ltd | 光電変換素子 |
JP2007048672A (ja) | 2005-08-11 | 2007-02-22 | Mitsubishi Paper Mills Ltd | 光電変換材料、半導体電極並びにそれを用いた光電変換素子 |
JP2007048680A (ja) | 2005-08-12 | 2007-02-22 | Mitsubishi Paper Mills Ltd | 光電変換材料、半導体電極並びにそれを用いた光電変換素子 |
JP5185517B2 (ja) | 2005-09-22 | 2013-04-17 | 三菱製紙株式会社 | 光電変換材料、半導体電極並びにそれを用いた光電変換素子 |
JP2007095584A (ja) | 2005-09-29 | 2007-04-12 | Mitsubishi Paper Mills Ltd | 光電変換材料、半導体電極並びにそれを用いた光電変換素子 |
JP2007231171A (ja) * | 2006-03-01 | 2007-09-13 | Mitsubishi Paper Mills Ltd | 増感色素単量体、増感色素重合体、光電変換材料、半導体電極及び光電変換素子 |
JP5166708B2 (ja) | 2006-07-07 | 2013-03-21 | 三菱製紙株式会社 | 光電変換材料および半導体電極 |
JP5238168B2 (ja) * | 2006-09-12 | 2013-07-17 | 三菱製紙株式会社 | 光電変換材料および半導体電極 |
JP2008091137A (ja) * | 2006-09-29 | 2008-04-17 | Mitsubishi Paper Mills Ltd | 光電変換材料、半導体電極並びにそれを用いた光電変換素子 |
JP2008277206A (ja) | 2007-05-07 | 2008-11-13 | Konica Minolta Holdings Inc | 光電変換材料用半導体、光電変換素子及び太陽電池 |
JP2009176526A (ja) | 2008-01-23 | 2009-08-06 | Mitsubishi Paper Mills Ltd | 色素増感太陽電池 |
JP2009187738A (ja) | 2008-02-05 | 2009-08-20 | Mitsubishi Paper Mills Ltd | 光電変換材料、半導体電極およびそれを用いた光電変換素子 |
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- 2009-08-05 WO PCT/JP2009/064213 patent/WO2010016612A1/ja active Application Filing
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EP2309584A1 (en) | 2011-04-13 |
JP5416118B2 (ja) | 2014-02-12 |
CN102171885A (zh) | 2011-08-31 |
WO2010016612A1 (ja) | 2010-02-11 |
US8383831B2 (en) | 2013-02-26 |
EP2309584A4 (en) | 2012-08-15 |
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