JPWO2007063698A1 - 太陽電池の保護カバー用塗料組成物 - Google Patents
太陽電池の保護カバー用塗料組成物 Download PDFInfo
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- JPWO2007063698A1 JPWO2007063698A1 JP2007547889A JP2007547889A JPWO2007063698A1 JP WO2007063698 A1 JPWO2007063698 A1 JP WO2007063698A1 JP 2007547889 A JP2007547889 A JP 2007547889A JP 2007547889 A JP2007547889 A JP 2007547889A JP WO2007063698 A1 JPWO2007063698 A1 JP WO2007063698A1
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- layer
- curable
- coating composition
- protective cover
- fluororesin
- Prior art date
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Abstract
Description
さらには、透明樹脂層(II)と該透明樹脂層に直接またはプライマー層(IV)を介して設けられているトップコート層(III)を含み、太陽電池モジュール(I)の太陽光照射面側に設ける保護カバー用積層フィルムであって、該トップコート層(III)が、前記硬化性含フッ素塗料組成物の硬化物層である太陽電池の保護カバー用積層フィルムにも関する。
本発明で用いる硬化性フッ素樹脂は、硬化性基を有するフッ素樹脂を単独で使用してもよいし、硬化性基を有するフッ素樹脂と非硬化性のフッ素樹脂および/または硬化性もしくは非硬化性の非フッ素樹脂とのブレンド物でもよい。また、非硬化性のフッ素樹脂と硬化性の非フッ素樹脂とのブレンド物でもよい。
フルオロオレフィン単位とビニルエーテル単位と硬化部位を有する単量体単位を有する共重合体、フルオロオレフィン単位とビニルエステル単位と硬化部位を有する単量体単位を有する共重合体などがあげられる。
TFE単位と炭化水素系単量体単位とビニルエステル単位と硬化部位を有する単量体単位を有する共重合体などがあげられる。
CTFE単位と硬化部位を有する単量体単位、さらに要すれば炭化水素系単量体単位および/またはビニルエーテル単位を有する共重合体などがあげられる。
VdF単位と硬化部位を有する単量体単位、さらに要すれば炭化水素系単量体単位、ビニルエステル単位および/またはビニルエーテル単位を有する共重合体などがあげられる。
非硬化性のフッ素樹脂としては、TFE系共重合体、CTFE系共重合体、VdF系共重合体などが使用できる。
硬化剤は、硬化性フッ素樹脂が有する硬化性基の種類に応じて最適なものを選択すればよい。
溶剤としては、透明樹脂層(II)を構成する透明樹脂を侵さない溶剤であればよく、塗料化、塗膜乾燥性、各種添加剤溶解性などが良好な点から弱溶剤が好ましい。
ユビナール3049、ユビナール3050(いずれもBASFジャパン(株)製);スミソーブ110、スミソーブ130、スミソーブ200(いずれも住友化学工業(株)製)
ベンゾトリアゾール系紫外線吸収剤:
チヌビン900、チヌビンPS、チヌビン384、チヌビン109、チヌビン928、チヌビン1130(いずれもチバ・スペシャリティ・ケミカルズ(株)製);スミソーブ250、スミソーブ300、スミソーブ320、スミソーブ340、スミソーブ350(いずれも住友化学工業(株)製);アデカスタブLA−32、アデカスタブLA−31(いずれも旭電化(株)製)
トリアジン系紫外線吸収剤:
チヌビン400、チヌビン405、チヌビン479(いずれもチバ・スペシャリティ・ケミカルズ(株)製)
ベンゾエート系紫外線吸収剤:
スミソーブ400(住友化学工業(株)製)
シアノアクリレート系紫外線吸収剤:
ユビナール3055、ユビナール3039(BASFジャパン(株)製)
その他の紫外線吸収剤:
プロパンジオイック酸[(4−メトキシフェニル)−メチレン]−ジメチルエステル
(II)透明樹脂:
ポリカーボネート
つぎの硬化性含フッ素塗料組成物の硬化物
前記(A1)の硬化性フッ素樹脂(特に、TFE/ビニルエステル/硬化部位(水酸基またはカルボキシル基)含有単量体の共重合体)
(B)硬化剤:
イソシアネート系
(C)溶剤:
第三種有機溶剤(特に、コールタールナフサ)
(D)添加剤:
親水化剤、紫外線吸収剤、シランカップリング剤
なし
(II)透明樹脂: ポリエチレンテレフタレート
つぎの硬化性含フッ素塗料組成物の硬化物
前記(A1)の硬化性フッ素樹脂(特に、CTFE/ビニルエーテル/硬化部位(水酸基またはカルボキシル基)含有単量体の共重合体)
(B)硬化剤:
イソシアネート系
(C)溶剤:
第三種有機溶剤(特に、ミネラルスピリット)
(D)添加剤:
シランカップリング剤、紫外線吸収剤
なし
(II)透明樹脂:
アクリル樹脂
つぎの硬化性含フッ素塗料組成物の硬化物
前記(A1)の硬化性フッ素樹脂(特に、TFE/ビニルエステル/硬化部位(水酸基またはカルボキシル基)含有単量体の共重合体と硬化性アクリル樹脂との混合物)
(B)硬化剤:
イソシアネート系
(C)溶剤:
第三種有機溶剤(特に、コールタールナフサ)
(D)添加剤:
紫外線吸収剤
なし
(II)透明樹脂:
ポリカーボネート
つぎの硬化性含フッ素塗料組成物の硬化物
前記(A2)の硬化性フッ素樹脂(TFE/炭化水素系単量体/ビニルエステル/硬化部位(水酸基またはカルボキシル基)含有単量体の共重合体に代表される酢酸ブチルに溶解する硬化性フッ素樹脂)
(B)硬化剤:
イソシアネート系
(C)溶剤:
酢酸ブチル
(D)添加剤:
紫外線吸収剤、親水化剤
あり(非硬化性アクリル樹脂)
(II)透明樹脂:
ポリカーボネート
つぎの硬化性含フッ素塗料組成物の硬化物
前記(A2)の硬化性フッ素樹脂(TFE/炭化水素系単量体/ビニルエステル/硬化部位(水酸基またはカルボキシル基)含有単量体の共重合体に代表される酢酸ブチルに溶解する硬化性フッ素樹脂)
(B)硬化剤:
イソシアネート系
(C)溶剤:
酢酸ブチル
(D)添加剤:
紫外線吸収剤、親水化剤
あり(UV硬化性アクリル樹脂)
NMR測定装置:BRUKER社製
1H−NMR測定条件:300MHz(テトラメチルシラン=0ppm)
19F−NMR測定条件:282MHz(トリクロロフルオロメタン=0ppm)
測定装置:ジェイサイエンス(株)製のCHN CORDERとオリオリサーチ(株)製のイオナライザー901
NMRおよび元素分析法で求めた組成より計算した。
測定装置:東ソー(株)製のGPC(型式HLC−8020)
測定条件:カラムとしてTSKgel:GMHXLを3本、G2500HXLを1本、GRCXL−Lを1本使用する。溶離液としてはテトラヒドロフランを使用し、分子量の標準サンプルとしては分子量既知のポリスチレンを使用する。
ASTM E1356−98に従い、パーキンエルマー製のDSC測定装置7シリーズを使用し、2nd runにおいて中点法によりTgを決定する。
測定条件
昇温速度:10℃/min
試料量:10mg
ヒートサイクル:25℃〜150℃、昇温、冷却、昇温
「有機溶剤に可溶」とは、ある有機溶剤100gに温度20±5℃で10g以上溶解する(溶液が透明となる)ことをいう。塗料用組成物の調製や塗工が容易な点から、有機溶剤100gに100g以上溶解することが好ましい。
(株)東洋精機製作所製のヘイズガードIIを使用し、ASTM D1003に基づいて測定する。
容量6000mlのステンレス製オートクレーブに酢酸ブチル2500質量部、ベオバ9(以下、「VV9」という)554.5質量部、安息香酸ビニル(VBz)69.1質量部、4−ヒドロキシブチルビニルエーテル(HBVE)83.5質量部を仕込み、5℃に冷却したのち減圧窒素置換の操作を3回繰り返した。最後に再度減圧してテトラフルオロエチレン(TFE)280.0質量部を仕込んだ。撹拌下に62.0℃まで昇温し、パーブチルPV(商品名。日本油脂(株)製の過酸化物系重合開始剤)28.38質量部を仕込み重合を開始した。反応器内圧が1.0MPaGから0.4MPaGへ低下した時点で反応を停止した。重合収率は98.0%であった。得られた含フッ素共重合体を19F−NMR、1H−NMRおよび元素分析法で分析したところ、TFEが37モル%、VV9が45.2モル%、VBzが7.0モル%およびHBVEが10.8モル%からなる含フッ素共重合体(1−1)であり、数平均分子量Mnは9.0×1000であった。また、ガラス転移温度Tgは30℃であった。溶剤(コールタールナフサおよびミネラルスピリット)への溶解性は「可溶」であった。
硬化性含フッ素共重合体(1−1)100質量部をコールタールナフサ100質量部に溶解させて固形分50質量%の溶液とした。この溶液200質量部に、デュラネートTSA−100(商品名。旭化成(株)製のイソシアネート系硬化剤)を15.3質量部、ユピナール3039(商品名。BASF社製の紫外線吸収剤)を4.0質量部、カップリング剤としてγ-グリシドキシプロピルトリエトキシシランを10.0質量部、および追加溶剤としてコールタールナフサを50質量部加えてよく混合して塗料用組成物とした。
硬化性含フッ素共重合体(1−2)100質量部をミネラルスピリット100質量部に溶解させて固形分50質量%の溶液とした。この溶液200質量部に、デュラネートTSA−100を12.4質量部、ユピナール3039を4.0質量部、γ-グリシドキシプロピルトリエトキシシランを10.0質量部、および追加溶剤としてミネラルスピリットを50質量部加えてよく混合して塗料用組成物とした。
硬化性含フッ素共重合体(1−1)100質量部をコールタールナフサ100質量部に溶解させて固形分50質量%の溶液とした。この溶液200質量部に、デュラネートTSA−100を15.3質量部、ユピナール3039を4.0質量部、γ-グリシドキシプロピルトリエトキシシランを10.0質量部、ゼッフルGH700(商品名。ダイキン工業(株)製の親水化剤。フッ素含有アルキルシリケート)を5質量部および追加溶剤としてコールタールナフサを50質量部加えてよく混合して塗料用組成物とした。
硬化性含フッ素共重合体(1−1)50質量部とアクリル樹脂(メチルメタクリレート/シクロヘキシルメタクリレート/2−エチルヘキシルアクリレート/2−ヒロドキシエチルメタクリレート共重合体50質量部をコールタールナフサ100質量部に溶解させて固形分50質量%の透明な溶液とした。
硬化性含フッ素共重合体(1−1)100質量部をコールタールナフサ100質量部に溶解させて固形分50質量%の溶液とした。この溶液200質量部に、デュラネートTSA−100を15.3質量部、ユピナール3039を4.0質量部、ゼッフルGH700を5.0質量部、および追加溶剤としてコールタールナフサを50質量部加えてよく混合して塗料用組成物とした。
TFE系硬化性フッ素樹脂溶液(ダイキン工業(株)製のゼッフルGK510(商品名)。固形分50質量%、溶剤:酢酸ブチル、水酸基価60mgKOH/g、酸価9mgKOH/g。硬化性含フッ素共重合体1−3)200質量部に、スミジュールN3300(商品名。住化バイエルウレタン(株)製のイソシアネート系硬化剤)を21.0質量部、ユピナール3039を4.0質量部および追加溶剤として酢酸ブチルを50質量部加えてよく混合して塗料用組成物とした。
TFE系硬化性フッ素樹脂溶液(ダイキン工業(株)製のゼッフルGK570(商品名)。固形分65質量%、溶剤:酢酸ブチル、水酸基価60mgKOH/g、酸価3mgKOH/g。硬化性含フッ素共重合体1−4)154質量部に、スミジュールN3300を20.6質量部、ユピナール3039を4.0質量部、ゼッフルGH700を5.0質量部、および追加溶剤として酢酸ブチルを96質量部加えてよく混合して塗料用組成物とした。
VdF系非硬化性フッ素樹脂(ダイキン工業(株)製のゼッフルLC700(商品名)。VdF/TFE/CTFE共重合体。硬化性含フッ素共重合体1−5)60質量部とアクリル樹脂(メチルメタクリレート/シクロヘキシルメタクリレート/2−エチルヘキシルアクリレート/2−ヒロドキシエチルメタクリレート共重合体40質量部をコールタールナフサ100質量部に溶解させて固形分50質量%の透明な溶液とした。
ポリカーボネートフィルム(三菱エンジニアリングプラスチック(株)製のユーピロンフィルムFE−2000(商品名)。厚さ100μm)の表面を脱脂したのち、実施例1〜5でそれぞれ調製した塗料組成物をエアスプレーで乾燥膜厚が50μmとなるように塗装した。ついで、80℃にて20分間加熱し、乾燥硬化させて保護カバー用積層フィルムを作製した。
目視で評価する。
スーパーUVテスターW13型(商品名。岩崎電気(株)製の耐候性試験機)を用いて促進耐候試験を200時間行う。試験条件は照射11時間(照度:100mW/cm2、ブラックパネル温度:63℃、相対湿度:70%)、結露11時間(照度:0mW/cm2、ブラックパネル温度:室温、相対湿度:100%)、休止1時間(照度:0mW/cm2、ブラックパネル温度:63℃、相対湿度:85%)である。
雰囲気温度80℃で湿度85%の恒温恒湿器LH−20−01La((株)ナガノ科学機械製作所)内に試験板を吊り下げ1000時間試験を行ない、試験前後に光透過率、ヘイズ値を測定する。
JIS K5400に準じて碁盤目試験を行う。
大阪の工場地帯の4階建ての屋社の屋上で南に向かい、水平より30°の傾斜の曝露台に試験板を取り付け曝露試験を行う。1ヵ月間曝露し、試験板の色差の明度(L*値)を測定し、試験前後の差(−△L*)で評価する。
酢酸ブチルを含ませた綿布で塗膜を100回ラビングしたのちの塗膜表面の状態を目視によりつぎの基準で判定する。
A:異常がない。
B:多少つやびけがある。
C:塗膜が溶解したり膨潤したり顕著なつやびけがある。
ポリカーボネートフィルムに代えて、透明樹脂基材としてアクリル板(日本テストパネル(株)製のアクリル板。厚さ1mm)を用い、塗料組成物として実施例5の組成物を用いたほかは実施例9と同様にトップコート層を形成し、保護カバー用積層フィルムを作製した。
ポリカーボネートフィルム(三菱エンジニアリングプラスチック(株)製のユーピロンフィルムFE−2000(商品名)。厚さ100μm)の表面を脱脂したのち、アクリル樹脂系プライマー((メチルメタクリレート/エチルアクリレート/メタクリル酸共重合体。数平均分子量4万、Tg=45℃、酸価:12mgKOH/g)20質量部のイソプロパノール56質量部およびn−酢酸プロピル24質量部の混合溶剤溶液)をバーコーター(安田精機(株)製)#18により乾燥膜厚が5μmとなるように塗布し、80℃にて20分間加熱してプライマー層を形成した。
TFE系硬化性フッ素樹脂溶液(ダイキン工業(株)製のゼッフルGK570(商品名)。硬化性含フッ素共重合体1−4)154質量部に、スミジュールN3300を20.6質量部、チヌビン479(チバ・スペシャリティ・ケミカルズ(株)製のトリアジン系紫外線吸収剤)を2.0質量部、チヌビン400(チバ・スペシャリティ・ケミカルズ(株)製のトリアジン系紫外線吸収剤)を2.0質量部、および追加溶剤として酢酸ブチルを96質量部加えてよく混合して塗料用組成物とした。
TFE系硬化性フッ素樹脂溶液(ダイキン工業(株)製のゼッフルGK570(商品名)。硬化性含フッ素共重合体1−4)154質量部に、スミジュールN3300を20.6質量部、チヌビン479を2.0質量部、チヌビン400を2.0質量部、ゼッフルGH700を5.0質量部、および追加溶剤として酢酸ブチルを96質量部加えてよく混合して塗料用組成物とした。
ポリカーボネートフィルム(三菱エンジニアリングプラスチック(株)製のユーピロンフィルムFE−2000(商品名)。厚さ100μm)の表面を脱脂したのち、アクリル樹脂系プライマー(メチルメタクリレート/エチルアクリレート/メタクリル酸共重合体。数平均分子量4万、Tg=45℃、酸価:12mgKOH/g)20質量部のイソプロパノール56質量部およびn−酢酸プロピル24質量部の混合溶剤溶液)をバーコーター(安田精機(株)製)#18により乾燥膜厚が5μmとなるように塗布し、80℃にて20分間加熱してプライマー層を形成した。
Claims (10)
- (A)硬化性フッ素樹脂と(B)硬化剤と(C)溶剤を含む硬化性含フッ素塗料組成物であって、太陽電池モジュール(I)の太陽光照射面側に設けられている透明樹脂層(II)に直接またはプライマー層(IV)を介して設けられるフッ素樹脂硬化物のトップコート層(III)の形成に用いる太陽電池の保護カバー用塗料組成物。
- 前記硬化性フッ素樹脂(A)が、第三種有機溶剤に可溶な硬化性フッ素樹脂(A1)である請求の範囲第1項記載の保護カバー用塗料組成物。
- 前記硬化性フッ素樹脂(A1)が、水酸基価が5mgKOH/gを超え、かつ水酸基価と酸価の合計が30mgKOH/gを超える水酸基含有含フッ素共重合体である請求の範囲第2項記載の保護カバー用塗料組成物。
- 前記溶剤(C)が非極性炭化水素系有機溶剤である請求の範囲第1項〜第3項のいずれかに記載の保護カバー用塗料組成物。
- 前記硬化剤(B)が、イソシアネート系硬化剤またはアミノ樹脂系硬化剤である請求の範囲第1項〜第4項のいずれかに記載の保護カバー用塗料組成物。
- 前記フッ素樹脂硬化物のトップコート層(III)が、透明樹脂層(II)に直接設けられている請求の範囲第1項〜第5項のいずれかに記載の保護カバー用塗料組成物。
- 前記透明樹脂層(II)の光線透過率が80%以上である請求の範囲第1項〜第6項のいずれかに記載の保護カバー用塗料組成物。
- 前記透明樹脂層(II)が、ポリカーボネート層、ポリエチレンテレフタレート層またはアクリル樹脂層である請求の範囲第1項〜第7項のいずれかに記載の保護カバー用塗料組成物。
- 太陽電池モジュール(I)と該モジュールの太陽光照射面側に設けられている透明樹脂層(II)と該透明樹脂層に直接またはプライマー層(IV)を介して設けられているトップコート層(III)を含む太陽電池であって、該トップコート層(III)が、請求の範囲第1項〜第8項のいずれかに記載の保護カバー用塗料組成物の硬化物層である太陽電池。
- 透明樹脂層(II)と該透明樹脂層に直接またはプライマー層(IV)を介して設けられているトップコート層(III)を含み、太陽電池モジュール(I)の太陽光照射面側に設ける保護カバー用積層フィルムであって、該トップコート層(III)が、請求の範囲第1項〜第8項のいずれかに記載の硬化性含フッ素塗料組成物の硬化物層である太陽電池の保護カバー用積層フィルム。
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PCT/JP2006/322635 WO2007063698A1 (ja) | 2005-11-30 | 2006-11-14 | 太陽電池の保護カバー用塗料組成物 |
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Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8168297B2 (en) * | 2007-04-23 | 2012-05-01 | E. I. Du Pont De Nemours And Company | Fluoropolymer coated film, process for forming the same, and fluoropolymer liquid composition |
JP2009024145A (ja) * | 2007-07-24 | 2009-02-05 | Asahi Glass Co Ltd | 塗料用フッ素樹脂組成物およびこれを用いた物品 |
AU2009263416B2 (en) * | 2008-06-23 | 2014-07-17 | Asahi Glass Company, Limited | Backsheet for solar cell module and solar cell module |
DE102008043713A1 (de) * | 2008-11-13 | 2010-05-20 | Evonik Röhm Gmbh | Herstellung von Solarzellenmodulen |
TW201034218A (en) * | 2008-12-26 | 2010-09-16 | Lintec Corp | Rear surface protective sheet for solar cell module |
KR101069732B1 (ko) * | 2009-03-31 | 2011-10-05 | (주)삼일물산 | 태양전지의 백시트용 불소화 우레탄 필름 조성물 및 그의 제조방법 |
JP2011018872A (ja) * | 2009-06-11 | 2011-01-27 | Dainichiseika Color & Chem Mfg Co Ltd | 太陽電池モジュールおよびプライマー組成物 |
JP2011023601A (ja) * | 2009-07-16 | 2011-02-03 | Ohbayashi Corp | 太陽電池ユニット、及び、施工方法 |
JP2011023602A (ja) * | 2009-07-16 | 2011-02-03 | Ohbayashi Corp | 太陽電池モジュール、及び、施工方法 |
MX2012009871A (es) | 2010-02-26 | 2012-09-12 | Asahi Glass Co Ltd | Composicion de recubrimiento para reflector recolector de calor solar y reflector recolector de calor solar y procedimiento para su produccion. |
WO2011108497A1 (ja) * | 2010-03-03 | 2011-09-09 | 旭硝子株式会社 | 太陽熱集熱用反射板用の塗料組成物、ならびに太陽熱集熱用反射板およびその製造方法 |
JP5575680B2 (ja) | 2010-03-09 | 2014-08-20 | 富士フイルム株式会社 | ポリエステル樹脂組成物及びその製造方法、ポリエステルフィルム、並びに太陽電池発電モジュール |
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US20120063952A1 (en) * | 2010-09-10 | 2012-03-15 | Hong Keith C | Uv resistant clear laminates |
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WO2013080918A1 (ja) * | 2011-12-02 | 2013-06-06 | ダイキン工業株式会社 | 塗料、塗膜、太陽電池モジュールのバックシート、及び、太陽電池モジュール |
US8691915B2 (en) | 2012-04-23 | 2014-04-08 | Sabic Innovative Plastics Ip B.V. | Copolymers and polymer blends having improved refractive indices |
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DE102013204395A1 (de) * | 2013-03-13 | 2014-09-18 | Evonik Industries Ag | Oberflächenvergütung auf Basis von vernetzbaren Fluorpolymeren |
CN105683305B (zh) | 2013-06-26 | 2018-11-13 | 3M创新有限公司 | 耐污染性微球体制品 |
EP3085747B1 (en) * | 2013-12-17 | 2019-06-26 | Korea Research Institute of Chemical Technology | Solar cell fluorinated coating composition, fluorinated multilayer film, and solar cell comprising same |
KR101512435B1 (ko) * | 2013-12-17 | 2015-04-16 | 한국화학연구원 | 태양전지용 백시트 및 이를 포함하는 태양전지 |
CN106029363B (zh) | 2014-02-13 | 2018-01-16 | 3M创新有限公司 | 双重固化耐污微球体制品 |
CN104673013A (zh) * | 2015-01-23 | 2015-06-03 | 长兴化学工业(中国)有限公司 | 含氟聚合物、水性含氟组合物、背板及其制造方法以及太阳能电池模组 |
EP3497174A4 (en) * | 2016-08-10 | 2020-04-22 | 3M Innovative Properties Company | FLUORED PRESSURE SENSITIVE ADHESIVE |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6392064A (ja) * | 1986-10-07 | 1988-04-22 | Matsushita Electric Ind Co Ltd | 太陽電池モジユ−ル |
JPH06334207A (ja) * | 1993-05-27 | 1994-12-02 | Canon Inc | 太陽電池モジュール |
JPH06350117A (ja) * | 1993-06-14 | 1994-12-22 | Canon Inc | 太陽電池モジュール |
JPH07122770A (ja) * | 1993-08-31 | 1995-05-12 | Canon Inc | 光電変換装置及びモジュール |
JPH07169984A (ja) * | 1993-09-30 | 1995-07-04 | Canon Inc | 太陽電池モジュール |
JPH09137113A (ja) * | 1995-11-15 | 1997-05-27 | Central Glass Co Ltd | フッ素樹脂塗料用組成物 |
JP2000138391A (ja) * | 1998-10-29 | 2000-05-16 | Dainippon Printing Co Ltd | 太陽電池モジュ−ル用表面保護シ−トおよびそれを使用した太陽電池モジュ−ル |
JP2001177124A (ja) * | 1999-12-17 | 2001-06-29 | Dainippon Printing Co Ltd | 太陽電池モジュ−ル |
JP2004277553A (ja) * | 2003-03-14 | 2004-10-07 | Asahi Glass Co Ltd | 塗料用組成物および塗料 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5396088A (en) | 1977-02-01 | 1978-08-22 | Asahi Glass Co Ltd | Preparation of fluorine-containing copolymer |
JPS6021686B2 (ja) | 1980-08-08 | 1985-05-29 | 旭硝子株式会社 | 常温硬化可能な含フツ素共重合体 |
JPS59198773A (ja) | 1983-04-25 | 1984-11-10 | Shimizu Constr Co Ltd | 太陽電池 |
JPS6157609A (ja) * | 1984-08-30 | 1986-03-24 | Central Glass Co Ltd | 含フツ素共重合体 |
JPH0662719B2 (ja) | 1984-12-18 | 1994-08-17 | 大日本インキ化学工業株式会社 | 硬化可能なフルオロオレフイン共重合体及びその製造法 |
JPH0662910B2 (ja) | 1985-03-28 | 1994-08-17 | 大日本インキ化学工業株式会社 | 塗料用樹脂組成物 |
JPS62174213A (ja) | 1985-10-15 | 1987-07-31 | Daikin Ind Ltd | 含フツ素共重合体およびフツ素樹脂塗料 |
JPH0832847B2 (ja) | 1987-02-17 | 1996-03-29 | 旭硝子株式会社 | 塗料用組成物 |
JPH0619061B2 (ja) | 1988-04-15 | 1994-03-16 | 新日鐵化学株式会社 | 太陽熱遮蔽塗料組成物及び被覆構造物 |
JP2692185B2 (ja) | 1988-11-02 | 1997-12-17 | 旭硝子株式会社 | 太陽電池 |
JPH06184243A (ja) | 1992-12-22 | 1994-07-05 | Daikin Ind Ltd | 含フッ素共重合体 |
JPH06271807A (ja) | 1993-03-22 | 1994-09-27 | Central Glass Co Ltd | 含フッ素樹脂塗料組成物 |
WO1995002645A1 (fr) * | 1993-07-14 | 1995-01-26 | Asahi Glass Company Ltd. | Composition resineuse de revetement |
JPH07216291A (ja) * | 1994-01-31 | 1995-08-15 | Asahi Glass Co Ltd | 塗料用被覆組成物 |
CN1097626C (zh) | 1995-02-20 | 2003-01-01 | 大金工业株式会社 | 污染附着防止剂及含有该防止剂的非水性涂料用组合物 |
JP3387741B2 (ja) * | 1995-07-19 | 2003-03-17 | キヤノン株式会社 | 半導体素子用保護材、該保護材を有する半導体素子、該素子を有する半導体装置 |
JPH0955530A (ja) * | 1995-08-14 | 1997-02-25 | Sunstar Eng Inc | 太陽電池モジュールおよびその製造法 |
JPH09277377A (ja) * | 1996-04-18 | 1997-10-28 | Daicel Chem Ind Ltd | フィルム被覆化粧材とその製法 |
JP3122375B2 (ja) | 1996-10-18 | 2001-01-09 | 富士チタン工業株式会社 | 赤外線遮蔽材 |
JPH10256580A (ja) * | 1997-03-13 | 1998-09-25 | Daikin Ind Ltd | 太陽電池用材料 |
JP3262098B2 (ja) | 1998-03-16 | 2002-03-04 | 住友金属鉱山株式会社 | 熱線遮蔽材料とこれを用いた熱線遮蔽器材並びに塗布液および熱線遮蔽膜 |
DE19814652A1 (de) * | 1998-04-01 | 1999-10-07 | Bayer Ag | Photovoltaik-Module mit Verbundfolien |
US5994641A (en) * | 1998-04-24 | 1999-11-30 | Ase Americas, Inc. | Solar module having reflector between cells |
JP2000301054A (ja) * | 1999-04-20 | 2000-10-31 | Daikin Ind Ltd | 表面親水化塗料で被覆されたプラスチック成形品 |
WO2003106516A1 (ja) * | 2002-06-14 | 2003-12-24 | ダイキン工業株式会社 | 含フッ素共重合体および塗料用組成物 |
US20050257558A1 (en) * | 2002-11-26 | 2005-11-24 | Daikin Industries, Ltd. | Heat exchanger for air and freezer device |
JP2004204173A (ja) | 2002-12-26 | 2004-07-22 | Catalysts & Chem Ind Co Ltd | 赤外線遮蔽膜形成用塗料および赤外線遮蔽膜付基材 |
JP2004277716A (ja) * | 2003-02-28 | 2004-10-07 | Asahi Glass Co Ltd | 塗料用含フッ素共重合体、塗料用組成物および塗料 |
JP2004307666A (ja) * | 2003-04-08 | 2004-11-04 | Asahi Glass Co Ltd | 塗料用含フッ素共重合体、塗料用組成物および塗料 |
JP2005248157A (ja) * | 2003-12-05 | 2005-09-15 | Daikin Ind Ltd | 常温硬化性水性組成物 |
KR101074948B1 (ko) * | 2003-12-17 | 2011-10-18 | 가부시키가이샤 브리지스톤 | 반사 방지 필름, 전자파 실드성 광 투과창재, 가스 방전형발광 패널, 플랫 디스플레이 패널, 진열창재 및 태양 전지모듈 |
US20060145598A1 (en) * | 2004-12-30 | 2006-07-06 | Macpherson Charles D | Electronic devices and process for forming the same |
-
2006
- 2006-11-14 WO PCT/JP2006/322635 patent/WO2007063698A1/ja active Application Filing
- 2006-11-14 EP EP13184135.5A patent/EP2682991A3/en not_active Withdrawn
- 2006-11-14 US US12/095,556 patent/US20100180938A1/en not_active Abandoned
- 2006-11-14 EP EP06832597A patent/EP1956657A4/en not_active Withdrawn
- 2006-11-14 CN CN201110436056.8A patent/CN102544149B/zh active Active
- 2006-11-14 JP JP2007547889A patent/JPWO2007063698A1/ja active Pending
-
2012
- 2012-08-27 JP JP2012186814A patent/JP2012251162A/ja active Pending
-
2013
- 2013-03-25 US US13/850,242 patent/US20130213468A1/en not_active Abandoned
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6392064A (ja) * | 1986-10-07 | 1988-04-22 | Matsushita Electric Ind Co Ltd | 太陽電池モジユ−ル |
JPH06334207A (ja) * | 1993-05-27 | 1994-12-02 | Canon Inc | 太陽電池モジュール |
JPH06350117A (ja) * | 1993-06-14 | 1994-12-22 | Canon Inc | 太陽電池モジュール |
JPH07122770A (ja) * | 1993-08-31 | 1995-05-12 | Canon Inc | 光電変換装置及びモジュール |
JPH07169984A (ja) * | 1993-09-30 | 1995-07-04 | Canon Inc | 太陽電池モジュール |
JPH09137113A (ja) * | 1995-11-15 | 1997-05-27 | Central Glass Co Ltd | フッ素樹脂塗料用組成物 |
JP2000138391A (ja) * | 1998-10-29 | 2000-05-16 | Dainippon Printing Co Ltd | 太陽電池モジュ−ル用表面保護シ−トおよびそれを使用した太陽電池モジュ−ル |
JP2001177124A (ja) * | 1999-12-17 | 2001-06-29 | Dainippon Printing Co Ltd | 太陽電池モジュ−ル |
JP2004277553A (ja) * | 2003-03-14 | 2004-10-07 | Asahi Glass Co Ltd | 塗料用組成物および塗料 |
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US20130213468A1 (en) | 2013-08-22 |
CN102544149B (zh) | 2016-07-20 |
EP1956657A4 (en) | 2010-04-14 |
EP1956657A1 (en) | 2008-08-13 |
EP2682991A3 (en) | 2014-05-21 |
CN102544149A (zh) | 2012-07-04 |
EP2682991A2 (en) | 2014-01-08 |
JP2012251162A (ja) | 2012-12-20 |
US20100180938A1 (en) | 2010-07-22 |
WO2007063698A1 (ja) | 2007-06-07 |
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