JPS6257985B2 - - Google Patents
Info
- Publication number
- JPS6257985B2 JPS6257985B2 JP55040997A JP4099780A JPS6257985B2 JP S6257985 B2 JPS6257985 B2 JP S6257985B2 JP 55040997 A JP55040997 A JP 55040997A JP 4099780 A JP4099780 A JP 4099780A JP S6257985 B2 JPS6257985 B2 JP S6257985B2
- Authority
- JP
- Japan
- Prior art keywords
- compound
- group
- dir
- silver halide
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 74
- 150000001875 compounds Chemical class 0.000 claims description 41
- 229910052709 silver Inorganic materials 0.000 claims description 34
- 239000004332 silver Substances 0.000 claims description 34
- 239000000839 emulsion Substances 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 239000003112 inhibitor Substances 0.000 claims description 22
- 230000008878 coupling Effects 0.000 claims description 21
- 238000010168 coupling process Methods 0.000 claims description 21
- 238000005859 coupling reaction Methods 0.000 claims description 21
- 238000011161 development Methods 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 21
- 239000010410 layer Substances 0.000 description 26
- 230000000694 effects Effects 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 239000000975 dye Substances 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 108010010803 Gelatin Proteins 0.000 description 5
- 229920000159 gelatin Polymers 0.000 description 5
- 239000008273 gelatin Substances 0.000 description 5
- 235000019322 gelatine Nutrition 0.000 description 5
- 235000011852 gelatine desserts Nutrition 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 230000027756 respiratory electron transport chain Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 2
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910021612 Silver iodide Inorganic materials 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- LGRLWUINFJPLSH-UHFFFAOYSA-N methanide Chemical compound [CH3-] LGRLWUINFJPLSH-UHFFFAOYSA-N 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 229940045105 silver iodide Drugs 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- BAXOFTOLAUCFNW-UHFFFAOYSA-N 1H-indazole Chemical compound C1=CC=C2C=NNC2=C1 BAXOFTOLAUCFNW-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical compound SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- PMWJOLLLHRDHNP-UHFFFAOYSA-N 2,3-dioctylbenzene-1,4-diol Chemical compound CCCCCCCCC1=C(O)C=CC(O)=C1CCCCCCCC PMWJOLLLHRDHNP-UHFFFAOYSA-N 0.000 description 1
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- MKCXKSFGLFQLSA-UHFFFAOYSA-N N-[4-[2,4-bis(2-methylbutan-2-yl)phenoxy]butyl]naphthalene-2-carboxamide Chemical compound C1=C(C=CC2=CC=CC=C12)C(=O)NCCCCOC1=C(C=C(C=C1)C(C)(C)CC)C(C)(C)CC MKCXKSFGLFQLSA-UHFFFAOYSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- KPYMODXRSSIYIB-UHFFFAOYSA-N ortho-quinone methide Chemical compound CC(=O)C1=C(O)C(=C)C(=O)C(C)=C1 KPYMODXRSSIYIB-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 125000005328 phosphinyl group Chemical group [PH2](=O)* 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- USFMMZYROHDWPJ-UHFFFAOYSA-N trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium Chemical compound CC(=C)C(=O)OCC[N+](C)(C)C USFMMZYROHDWPJ-UHFFFAOYSA-N 0.000 description 1
- HERBOKBJKVUALN-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]acetate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O HERBOKBJKVUALN-UHFFFAOYSA-K 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/305—Substances liberating photographically active agents, e.g. development-inhibiting releasing couplers
- G03C7/30594—Combination of substances liberating photographically active agents
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
〠ç£æ¥äžã®å©çšåé
æ¬çºæã¯é®®éæ§ãæ¹è¯ãããæ°èŠãªããã²ã³å
éã«ã©ãŒåçæå ææã«é¢ãããã®ã§ããã ã åŸæ¥æè¡ äžè¬ã«å€å±€ããã²ã³åéã«ã©ãŒåçæå ææã«
ãããŠãã®ç»åã«çš®ã ã®ç¹æ§ãèŠæ±ãããããã®
äžã€ã¯ç»åã®èŒªéãé®®æãããã埮现ãªåããŒã
ããããšãªãæåãããããšãå³ã¡é®®éæ§ãè¯å¥œ
ãªããšã§ãããå¥ã®ç¹æ§ã¯äžã€ã®æè²æ§å±€ãè²çŽ
ç»åã圢æããæãããã§çæããã«ã©ãŒçŸåäž»
è¬ã®é žåäœã«ãã€ãŠä»ã®æè²æ§å±€ãçºè²ããŠè²ã
æ¿ããªãããšãå³ã¡è²çŽåºŠã®é«ãããšã§ããã åãç¹ã«ãã¬ãã€ãææã§ã¯åºãé²å ç¯å²ãå¿
å®ã«åçŸããããšãå³ã¡é²å 蚱容床ãåºãããšã
éèŠãªç¹æ§ã®ïŒã€ã§ãããæŽã«å¥ã®ç¹æ§ã¯ç»åã
ãªãããã§ããã€ããªãããšãå³ã¡ç²ç¶æ§ãè¯å¥œ
ã§ããããšã§ããã ãããã®ç¹æ§ãããã²ã³åéå€å±€ã«ã©ãŒåçæ
å ææã«ä»äžããããã«åŸæ¥çš®ã ã®å·¥å€«ããªãã
ãŠãããæªã ååã§ãããšã¯ãããªãã ç»åã®é®®é床ã¯é£æ¥å¹æã«ããåäžããããšã¯
è¯ãç¥ãããŠããããã®å¹æã¯çŸåæã®æå¶æ§ç©
質ã®æ¿åºŠåŸé ãå©çšãããã®ã§çŸå液ãæ°Žã§åžé
ããæ¹æ³ãçŸåäžã«æªæã匱ãè¡ãªãæ¹æ³çãã
ãããçŸåé žåç©ãšåå¿ããŠæå¶å€ãæŸåºããå
åç©ãæå ææã«å«ãŸããæ¹æ³ã¯ç¹ã«æ¹åå¹æã
èããããã®çš®ã®ååç©ãšããŠã¯ãäŸãã°ç±³åœç¹
蚱第3148062å·åã³å第3227554å·åæ现æžã«èšèŒ
ãããŠããåŠãçºè²çŸåäž»è¬ã®é žåäœãšã«ãããª
ã³ã°ããŠè²çŽ ãçæãçŸåæå¶å€ãæŸåºããåå
ç©ïŒä»¥äžDIRã«ãã©ãŒãšããïŒããããã¯ç±³åœç¹
蚱第3632345å·æ现æžã«èšèŒãããŠããåŠãçºè²
çŸåäž»è¬ã®é žåäœãšã®ã«ãããªã³ã°ã«ãã€ãŠçŸå
æå¶å€ãæŸåºãè²çŽ ã圢æããªãååç©ïŒä»¥äž
DIRç©è³ªãšããïŒãç¥ãããŠããã 以äžDIRã«ãã©ãŒããã³DIRç©è³ªã䜵ããŠDIR
ååç©ãšç·ç§°ããã ãããã®DIRååç©ã®ç¹åŸŽã¯ãçºè²çŸåäž»è¬ã®
é žåäœãšåå¿ããŠã«ãããªã³ã°äœçœ®ããæå¶å€ã
çŽæ¥æŸåºãããšããã«ããããããçšããããšã«
ãã€ãŠç²ç¶æ§ããã³é²å 蚱容床ã«ã€ããŠã¯æ¹è¯ã
ãããã®ã®ãé®®éæ§ã«ã€ããŠã¯ãã®å¹æã¯ååã§
ã¯ãªãäžã€è²çŽåºŠã®æ¹è¯ã«ã¯äœãå¹æããªãã åãç¹éæ54â145135å·å ¬å ±ã«ã¯ãçºè²çŸåäž»
è¬ã®é žåäœãšåå¿ããŠååå æ±æ žçœ®æåå¿ã«ãã
ã¹ããªãããªãååç©ãæŸåºããDIRååç©ã
åãç¹é¡æ55â17644å·æ现æžïŒç¹éæ56â
114946å·ïŒã«ã¯å ±åœ¹éã«æ²¿ã€ãé»å移åã«ããé
æ¥çã«æå¶å€ãæŸåºããããDIRååç©ãèšèŒã
ããŠããããã®çš®ã®ååç©ãçšãããšãçŸåãã
ãããã²ã³éç²åããç¹å®ã®è·é¢ã ãé¢ããäœçœ®
ã§æå¶å€ã®å¹æãçºæ®ããããããšãå¯èœãªã
ããããããå±€éå¹æã«åºãè²çŽåºŠã倧ããåäž
ãããåãæ·»å å±€ã®é®®é床åã³é£æ¥å¹æã«åºã¥ã
é£æ¥å±€ã®é®®é床ãåäžãããããããååã§ã¯ãª
ããäžã€ç²ç¶æ§æ¹åå¹æã¯å°ãããšããæ¬ ç¹ãæ
ããŠããã ã çºæã®ç®ç æ¬çºæã®ç®çã¯ããã®ãããªåŸæ¥æè¡ã®æ¬ ç¹ã®
æ¹åãããããã²ã³åéã«ã©ãŒåçæå ææãæ
äŸããããšã§ããã詳ããã¯ãèããé®®éæ§ã®æ¹
åãããããã²ã³åéã«ã©ãŒåçæå ææãæäŸ
ããããšã§ããã æ¬çºæã®ä»ã®ç®çã¯ç²ç¶æ§ãšè²çŽåºŠã®åªããã
ãã²ã³åéã«ã©ãŒåçæå ææãæäŸããããšã§
ããã æ¬çºæã®ç®çã¯æ¯æäœäžã®ããã²ã³åéä¹³å€å±€
äžã«ãçºè²çŸåäž»è¬ã®é žåäœãšã«ãããªã³ã°ãã
ãæåãšè©²é žåäœãšã«ãããªã³ã°ããŠæŸåºããã
çŸåæå¶å€ãšãªãåºãšãæãã該ã«ãããªã³ã°ã
ããæåãšè©²æå¶å€ãšãªãåºãšã®éã«ã¿ã€ãã³ã°
åºãæããååç©ããã³çºè²çŸåäž»è¬ã®é žåäœãš
ã«ãããªã³ã°ãããæåãšè©²é žåäœãšã«ãããªã³
ã°ããŠæŸåºãããçŸåæå¶å€ãšãªãåºãæãã該
ã«ãããªã³ã°ãããæåãšè©²æå¶å€ãšã®éã«ã¿ã€
ãã³ã°åºãæããªãååç©ãå«ãããã²ã³åéã«
ã©ãŒåçæå ææã«ãã€ãŠéæãããã ã çºæã®æ§æåã³ãã®äœçšå¹æ æ¬çºæã«çšããããçºè²çŸåäž»è¬ã®é žåäœãšã«
ãããªã³ã°ãããæåãšçºè²çŸåäž»è¬ã®é žåäœãš
ã«ãããªã³ã°ããŠæŸåºãããæå¶å€ãšãªãåºãšã
æãã該æåãšè©²åºãšã®éã«ã¿ã€ãã³ã°åºãæã
ãååç©å³ã¡ã¿ã€ãã³ã°åºãæããDIRååç©
ã¯ã次ã®ãããªäžè¬åŒ(1)ã§è¡šããããšãã§ããã äžè¬åŒ(1) âTIMEâ åŒäžãã¯çºè²çŸåäž»è¬ã®é žåäœãšåå¿ããã
ã«ãããªã³ã°æåã§ãçºè²çŸåäž»è¬ã®é žåäœãšå
å¿ããŠTIMEâåºãæŸåºããããšãã§ããã®ã§
ãããªãã°ã©ã®ãããªæåã§ãã€ãŠãè¯ãã TIMEã¯ã¿ã€ãã³ã°åºãã¯çŸåæå¶å€ãšãªã
åºã§ãããTIMEã®å ·äœäŸã¯ç¹éæ54â145135å·
å ¬å ±ã«èšèŒãããŠããåŠãååå æ±æ žçœ®æåå¿ã«
ãããã®ã§ãç¹é¡æ55â17644å·æ现æžïŒç¹éæ
56â114946å·ïŒã«èšèŒãããŠããåŠãå ±åœ¹éã«æ²¿
ã€ãé»å移åã«ãããã®ã§ãè¯ãã æ¬çºæã«ä¿ãã¿ã€ãã³ã°åºãæããDIRååç©
ã¯ãèŠããã«å§ãã«ïŒ¡âTIMEã®çµåãåããŠ
TIMEâåºãæŸåºãããããåŸã«TIMEâã®
çµåãåããŠïŒºãæŸåºããååç©ã§ããã°è¯ãã
ã«ã¯ãªãµãŒããã€ã¹ã¯ããŒãžã€ãŒïŒResearch
DisclosureïŒ176å·» No.17643 Dec.1978ïŒä»¥äžæ
ç®ïŒãšããïŒã«èšèŒãããŠããåŠãçŸåæå¶å€ãš
ãªãåºãå«ãŸãã奜ãŸããã¯ã¡ã«ã«ããããã©ãŸ
ãŒã«ãã»ã¬ãããã©ãŸãŒã«ãã¡ã«ã«ãããã³ãŸã
ã¢ãŸãŒã«ãã»ã¬ããã³ãŸãã¢ãŸãŒã«ãã¡ã«ã«ãã
ãã³ãŸãªããµãŸãŒã«ãã»ã¬ããã³ãŸãªããµãŸãŒ
ã«ãã¡ã«ã«ãããã³ãºã€ãããŸãŒã«ãã»ã¬ããã³
ãºã€ãããŸãŒã«ããã³ãŸããªã¢ãŸãŒã«ããã³ãŸãž
ã¢ãŸãŒã«ãåã³ãããã®èªå°äœãšãªãåºã§ããã
æ¬çºæã«çšããããã¿ã€ãã³ã°åºãæããDIR
ååç©ã¯ãæŽã«å ·äœçã«ã¯äžè¬åŒ(2)ã(5)ãŸãã¯(6)
ã§ç€ºãããååç©ãå å«ããã äžè¬åŒ(2) åŒäžããšïŒºã¯äžè¬åŒ(1)ã®å Žåãšå矩ã§ããã
ã¯çœ®æåºããã€ãŠããããã³ãŒã³ç°ãŸãã¯ãã
ã¿ã¬ã³ç°ãå®æããã«å¿ èŠãªåå矀ãè¡šããã
R1ãšR2ã¯æ°ŽçŽ ååãã¢ã«ãã«åºããŸãã¯ã¢ãªãŒ
ã«åºã瀺ãããŸã
éã«ã©ãŒåçæå ææã«é¢ãããã®ã§ããã ã åŸæ¥æè¡ äžè¬ã«å€å±€ããã²ã³åéã«ã©ãŒåçæå ææã«
ãããŠãã®ç»åã«çš®ã ã®ç¹æ§ãèŠæ±ãããããã®
äžã€ã¯ç»åã®èŒªéãé®®æãããã埮现ãªåããŒã
ããããšãªãæåãããããšãå³ã¡é®®éæ§ãè¯å¥œ
ãªããšã§ãããå¥ã®ç¹æ§ã¯äžã€ã®æè²æ§å±€ãè²çŽ
ç»åã圢æããæãããã§çæããã«ã©ãŒçŸåäž»
è¬ã®é žåäœã«ãã€ãŠä»ã®æè²æ§å±€ãçºè²ããŠè²ã
æ¿ããªãããšãå³ã¡è²çŽåºŠã®é«ãããšã§ããã åãç¹ã«ãã¬ãã€ãææã§ã¯åºãé²å ç¯å²ãå¿
å®ã«åçŸããããšãå³ã¡é²å 蚱容床ãåºãããšã
éèŠãªç¹æ§ã®ïŒã€ã§ãããæŽã«å¥ã®ç¹æ§ã¯ç»åã
ãªãããã§ããã€ããªãããšãå³ã¡ç²ç¶æ§ãè¯å¥œ
ã§ããããšã§ããã ãããã®ç¹æ§ãããã²ã³åéå€å±€ã«ã©ãŒåçæ
å ææã«ä»äžããããã«åŸæ¥çš®ã ã®å·¥å€«ããªãã
ãŠãããæªã ååã§ãããšã¯ãããªãã ç»åã®é®®é床ã¯é£æ¥å¹æã«ããåäžããããšã¯
è¯ãç¥ãããŠããããã®å¹æã¯çŸåæã®æå¶æ§ç©
質ã®æ¿åºŠåŸé ãå©çšãããã®ã§çŸå液ãæ°Žã§åžé
ããæ¹æ³ãçŸåäžã«æªæã匱ãè¡ãªãæ¹æ³çãã
ãããçŸåé žåç©ãšåå¿ããŠæå¶å€ãæŸåºããå
åç©ãæå ææã«å«ãŸããæ¹æ³ã¯ç¹ã«æ¹åå¹æã
èããããã®çš®ã®ååç©ãšããŠã¯ãäŸãã°ç±³åœç¹
蚱第3148062å·åã³å第3227554å·åæ现æžã«èšèŒ
ãããŠããåŠãçºè²çŸåäž»è¬ã®é žåäœãšã«ãããª
ã³ã°ããŠè²çŽ ãçæãçŸåæå¶å€ãæŸåºããåå
ç©ïŒä»¥äžDIRã«ãã©ãŒãšããïŒããããã¯ç±³åœç¹
蚱第3632345å·æ现æžã«èšèŒãããŠããåŠãçºè²
çŸåäž»è¬ã®é žåäœãšã®ã«ãããªã³ã°ã«ãã€ãŠçŸå
æå¶å€ãæŸåºãè²çŽ ã圢æããªãååç©ïŒä»¥äž
DIRç©è³ªãšããïŒãç¥ãããŠããã 以äžDIRã«ãã©ãŒããã³DIRç©è³ªã䜵ããŠDIR
ååç©ãšç·ç§°ããã ãããã®DIRååç©ã®ç¹åŸŽã¯ãçºè²çŸåäž»è¬ã®
é žåäœãšåå¿ããŠã«ãããªã³ã°äœçœ®ããæå¶å€ã
çŽæ¥æŸåºãããšããã«ããããããçšããããšã«
ãã€ãŠç²ç¶æ§ããã³é²å 蚱容床ã«ã€ããŠã¯æ¹è¯ã
ãããã®ã®ãé®®éæ§ã«ã€ããŠã¯ãã®å¹æã¯ååã§
ã¯ãªãäžã€è²çŽåºŠã®æ¹è¯ã«ã¯äœãå¹æããªãã åãç¹éæ54â145135å·å ¬å ±ã«ã¯ãçºè²çŸåäž»
è¬ã®é žåäœãšåå¿ããŠååå æ±æ žçœ®æåå¿ã«ãã
ã¹ããªãããªãååç©ãæŸåºããDIRååç©ã
åãç¹é¡æ55â17644å·æ现æžïŒç¹éæ56â
114946å·ïŒã«ã¯å ±åœ¹éã«æ²¿ã€ãé»å移åã«ããé
æ¥çã«æå¶å€ãæŸåºããããDIRååç©ãèšèŒã
ããŠããããã®çš®ã®ååç©ãçšãããšãçŸåãã
ãããã²ã³éç²åããç¹å®ã®è·é¢ã ãé¢ããäœçœ®
ã§æå¶å€ã®å¹æãçºæ®ããããããšãå¯èœãªã
ããããããå±€éå¹æã«åºãè²çŽåºŠã倧ããåäž
ãããåãæ·»å å±€ã®é®®é床åã³é£æ¥å¹æã«åºã¥ã
é£æ¥å±€ã®é®®é床ãåäžãããããããååã§ã¯ãª
ããäžã€ç²ç¶æ§æ¹åå¹æã¯å°ãããšããæ¬ ç¹ãæ
ããŠããã ã çºæã®ç®ç æ¬çºæã®ç®çã¯ããã®ãããªåŸæ¥æè¡ã®æ¬ ç¹ã®
æ¹åãããããã²ã³åéã«ã©ãŒåçæå ææãæ
äŸããããšã§ããã詳ããã¯ãèããé®®éæ§ã®æ¹
åãããããã²ã³åéã«ã©ãŒåçæå ææãæäŸ
ããããšã§ããã æ¬çºæã®ä»ã®ç®çã¯ç²ç¶æ§ãšè²çŽåºŠã®åªããã
ãã²ã³åéã«ã©ãŒåçæå ææãæäŸããããšã§
ããã æ¬çºæã®ç®çã¯æ¯æäœäžã®ããã²ã³åéä¹³å€å±€
äžã«ãçºè²çŸåäž»è¬ã®é žåäœãšã«ãããªã³ã°ãã
ãæåãšè©²é žåäœãšã«ãããªã³ã°ããŠæŸåºããã
çŸåæå¶å€ãšãªãåºãšãæãã該ã«ãããªã³ã°ã
ããæåãšè©²æå¶å€ãšãªãåºãšã®éã«ã¿ã€ãã³ã°
åºãæããååç©ããã³çºè²çŸåäž»è¬ã®é žåäœãš
ã«ãããªã³ã°ãããæåãšè©²é žåäœãšã«ãããªã³
ã°ããŠæŸåºãããçŸåæå¶å€ãšãªãåºãæãã該
ã«ãããªã³ã°ãããæåãšè©²æå¶å€ãšã®éã«ã¿ã€
ãã³ã°åºãæããªãååç©ãå«ãããã²ã³åéã«
ã©ãŒåçæå ææã«ãã€ãŠéæãããã ã çºæã®æ§æåã³ãã®äœçšå¹æ æ¬çºæã«çšããããçºè²çŸåäž»è¬ã®é žåäœãšã«
ãããªã³ã°ãããæåãšçºè²çŸåäž»è¬ã®é žåäœãš
ã«ãããªã³ã°ããŠæŸåºãããæå¶å€ãšãªãåºãšã
æãã該æåãšè©²åºãšã®éã«ã¿ã€ãã³ã°åºãæã
ãååç©å³ã¡ã¿ã€ãã³ã°åºãæããDIRååç©
ã¯ã次ã®ãããªäžè¬åŒ(1)ã§è¡šããããšãã§ããã äžè¬åŒ(1) âTIMEâ åŒäžãã¯çºè²çŸåäž»è¬ã®é žåäœãšåå¿ããã
ã«ãããªã³ã°æåã§ãçºè²çŸåäž»è¬ã®é žåäœãšå
å¿ããŠTIMEâåºãæŸåºããããšãã§ããã®ã§
ãããªãã°ã©ã®ãããªæåã§ãã€ãŠãè¯ãã TIMEã¯ã¿ã€ãã³ã°åºãã¯çŸåæå¶å€ãšãªã
åºã§ãããTIMEã®å ·äœäŸã¯ç¹éæ54â145135å·
å ¬å ±ã«èšèŒãããŠããåŠãååå æ±æ žçœ®æåå¿ã«
ãããã®ã§ãç¹é¡æ55â17644å·æ现æžïŒç¹éæ
56â114946å·ïŒã«èšèŒãããŠããåŠãå ±åœ¹éã«æ²¿
ã€ãé»å移åã«ãããã®ã§ãè¯ãã æ¬çºæã«ä¿ãã¿ã€ãã³ã°åºãæããDIRååç©
ã¯ãèŠããã«å§ãã«ïŒ¡âTIMEã®çµåãåããŠ
TIMEâåºãæŸåºãããããåŸã«TIMEâã®
çµåãåããŠïŒºãæŸåºããååç©ã§ããã°è¯ãã
ã«ã¯ãªãµãŒããã€ã¹ã¯ããŒãžã€ãŒïŒResearch
DisclosureïŒ176å·» No.17643 Dec.1978ïŒä»¥äžæ
ç®ïŒãšããïŒã«èšèŒãããŠããåŠãçŸåæå¶å€ãš
ãªãåºãå«ãŸãã奜ãŸããã¯ã¡ã«ã«ããããã©ãŸ
ãŒã«ãã»ã¬ãããã©ãŸãŒã«ãã¡ã«ã«ãããã³ãŸã
ã¢ãŸãŒã«ãã»ã¬ããã³ãŸãã¢ãŸãŒã«ãã¡ã«ã«ãã
ãã³ãŸãªããµãŸãŒã«ãã»ã¬ããã³ãŸãªããµãŸãŒ
ã«ãã¡ã«ã«ãããã³ãºã€ãããŸãŒã«ãã»ã¬ããã³
ãºã€ãããŸãŒã«ããã³ãŸããªã¢ãŸãŒã«ããã³ãŸãž
ã¢ãŸãŒã«ãåã³ãããã®èªå°äœãšãªãåºã§ããã
æ¬çºæã«çšããããã¿ã€ãã³ã°åºãæããDIR
ååç©ã¯ãæŽã«å ·äœçã«ã¯äžè¬åŒ(2)ã(5)ãŸãã¯(6)
ã§ç€ºãããååç©ãå å«ããã äžè¬åŒ(2) åŒäžããšïŒºã¯äžè¬åŒ(1)ã®å Žåãšå矩ã§ããã
ã¯çœ®æåºããã€ãŠããããã³ãŒã³ç°ãŸãã¯ãã
ã¿ã¬ã³ç°ãå®æããã«å¿ èŠãªåå矀ãè¡šããã
R1ãšR2ã¯æ°ŽçŽ ååãã¢ã«ãã«åºããŸãã¯ã¢ãªãŒ
ã«åºã瀺ãããŸã
ãåŒããªãåºã¯ïŒ¯ååã«å¯Ÿ
ãããªã«ããŸãã¯ãã©äœã«çœ®æãããŠããã
äžèšäžè¬åŒ(2)ã§ç€ºãããååç©ã¯ãçºè²çŸåäž»
è¬ã®é žåäœãšåå¿ãããšéè£ããŠå ã¥äžèšäžè¬åŒ
(3)ã§ç€ºãããæåãçæãããã®æå(3)ã¯åŒç¶ã
ãŠå ±åœ¹ç³»ã«æ²¿ã€ãé»å移åã«ãã€ãŠåã³éè£ããŠ
äžèšäžè¬åŒ(4)ã«ãŠç€ºãããååç©ãçæãåæã«
ãæŸåºããã äžèšäžè¬åŒ(4)ã§ç€ºãããååç©ã¯ããã³ã¡ãã
ãŸãã¯ãããããã³ã¡ãããšåŒã°ããååç©ã§ã
ãã 次ã«ãæ¬çºæã«çšããããäžè¬åŒ(2)ã§ç€ºããã
ã¿ã€ãã³ã°åºãæããDIRååç©ãšè©²ååç©ãšçº
è²çŸåäž»è¬ã®é žåäœãšã®åå¿æ©æ§ãååŠåå¿åŒ
ããã¿ã€ãã³ã°åºãšããŠããã³ã¡ãã圢æåºããŸ
ããšããŠããšãã«ã¡ã«ã«ããããã©ãŸãŒã«ãšãª
ãåºãçšããååç©ã䜿ã€ãŠèª¬æããã äžèšåå¿åŒã«ãããŠCDâ²ã¯çºè²çŸåäž»è¬ã®é žå
äœãè¡šããïŒä»¥äžã®åå¿åŒã«ãããŠãåãïŒã
ã¯çºè²çŸåäž»è¬ã®é žåäœãšåå¿ãããã«ãããªã³
ã°æåãè¡šãããŠããããããŠãã¿ã€ãã³ã°åº
ã¯ãäžèšã«ãããªã³ã°æåãçºè²çŸåäž»è¬ã®é žå
äœãšåå¿ãåŸãäœçœ®ã§çµåãããŠããã äžèšåå¿åŒã§ç€ºãããã«ãã¿ã€ãã³ã°åºãæã
ãDIRååç©ãCDâ²ãšã®åå¿ã«ãã€ãŠéè£ããç
æããçŸåæå¶æåãçµåããã¿ã€ãã³ã°åºãã
ç¢å°ã§ç€ºãããããã«å ±åœ¹ç³»ã«æ²¿ã€ãé»å移åã«
ãã€ãŠãªã«ãããã³ã¡ãããçæãããšå ±ã«çŸå
æå¶å€ãæŸåºããã äžè¬åŒ(5) åŒäžãããã³ïŒºã¯äžè¬åŒ(1)ãšå矩ã§ãããäž
è¬åŒ(5)ã§ç€ºãããã¿ã€ãã³ã°åºãæããDIRåå
ç©ãšCDâ²ãšã®ååŠåå¿åŒã以äžã«èª¬æããã äžèšåå¿åŒã«ãããŠïŒ¡ãšCDâ²ã¯åèšãšåæ§ã®åº
ã瀺ãããã®å Žåã«ãããŠãCDâ²ãšåå¿åŸãéè£
ãããã©ã°ã¡ã³ãã®é žçŽ ååäžã®äžå¯Ÿé»åã¯ã«ã«
ããã«éšåã®Ïé»åãšå ±åœ¹é¢ä¿ã«ããã 次ã«ãååå æ±æ žçœ®æã«ããçŸåæå¶å€ãæŸåº
ããåã®DIRååç©ã®äŸãäžè¬åŒ(6)ã§ç€ºãã äžè¬åŒ(6) åŒäžããšïŒºã¯äžè¬åŒ(1)ãšå矩ã§ãããNuâ
âãTIMEã«çžåœãããNuã¯é»åã®è±å¯ãªé ž
çŽ ãç¡«é»åã¯çªçŽ ååãæããŠããæ±æ žåºã§ã
ããã¯é»åã®äžååãªã«ã«ããã«åºãããªã«ã«
ããã«åºããã¹ãã€ãã«åºåã¯ããªãã¹ãã€ãã«
åºãæããŠããæ±é»ååºã§ããããã®æ±é»ååºã¯
ã«çµåããŠãããã¯Nuåã³ïŒ¥ãç«äœçã«é¢
ä¿ã¥ããŠããŠïŒ¡ããNuãæŸåºããããããåŸã
ïŒå¡ç°ãªããïŒå¡ç°ã®åœ¢æã䌎ãååå æ±æ žçœ®æ
åå¿ã被ãããã€ããã«ãã€ãŠïŒºãæŸåºããããš
ã®ã§ããçµååºã§ããã 次ã«äžè¬åŒ(6)ã§ç€ºãããã¿ã€ãã³ã°åºãæãã
DIRååç©ãšCDâ²ãšã®åå¿æ©æ§ãäžäŸãšããŠã
ãšããŠããšãã«ã¡ã«ã«ããããã©ãŸãŒã«ãšãªãåº
ã䜿çšããååç©ãçšããŠäžèšã«ãã説æããã äžèšã¿ã€ãã³ã°åºãæããDIRååç©ã¯ãäžè¬
åŒ(6)ã«ãããNuïŒïŒ¥åã³ïŒžãããããé žçŽ ã
è¬ã®é žåäœãšåå¿ãããšéè£ããŠå ã¥äžèšäžè¬åŒ
(3)ã§ç€ºãããæåãçæãããã®æå(3)ã¯åŒç¶ã
ãŠå ±åœ¹ç³»ã«æ²¿ã€ãé»å移åã«ãã€ãŠåã³éè£ããŠ
äžèšäžè¬åŒ(4)ã«ãŠç€ºãããååç©ãçæãåæã«
ãæŸåºããã äžèšäžè¬åŒ(4)ã§ç€ºãããååç©ã¯ããã³ã¡ãã
ãŸãã¯ãããããã³ã¡ãããšåŒã°ããååç©ã§ã
ãã 次ã«ãæ¬çºæã«çšããããäžè¬åŒ(2)ã§ç€ºããã
ã¿ã€ãã³ã°åºãæããDIRååç©ãšè©²ååç©ãšçº
è²çŸåäž»è¬ã®é žåäœãšã®åå¿æ©æ§ãååŠåå¿åŒ
ããã¿ã€ãã³ã°åºãšããŠããã³ã¡ãã圢æåºããŸ
ããšããŠããšãã«ã¡ã«ã«ããããã©ãŸãŒã«ãšãª
ãåºãçšããååç©ã䜿ã€ãŠèª¬æããã äžèšåå¿åŒã«ãããŠCDâ²ã¯çºè²çŸåäž»è¬ã®é žå
äœãè¡šããïŒä»¥äžã®åå¿åŒã«ãããŠãåãïŒã
ã¯çºè²çŸåäž»è¬ã®é žåäœãšåå¿ãããã«ãããªã³
ã°æåãè¡šãããŠããããããŠãã¿ã€ãã³ã°åº
ã¯ãäžèšã«ãããªã³ã°æåãçºè²çŸåäž»è¬ã®é žå
äœãšåå¿ãåŸãäœçœ®ã§çµåãããŠããã äžèšåå¿åŒã§ç€ºãããã«ãã¿ã€ãã³ã°åºãæã
ãDIRååç©ãCDâ²ãšã®åå¿ã«ãã€ãŠéè£ããç
æããçŸåæå¶æåãçµåããã¿ã€ãã³ã°åºãã
ç¢å°ã§ç€ºãããããã«å ±åœ¹ç³»ã«æ²¿ã€ãé»å移åã«
ãã€ãŠãªã«ãããã³ã¡ãããçæãããšå ±ã«çŸå
æå¶å€ãæŸåºããã äžè¬åŒ(5) åŒäžãããã³ïŒºã¯äžè¬åŒ(1)ãšå矩ã§ãããäž
è¬åŒ(5)ã§ç€ºãããã¿ã€ãã³ã°åºãæããDIRåå
ç©ãšCDâ²ãšã®ååŠåå¿åŒã以äžã«èª¬æããã äžèšåå¿åŒã«ãããŠïŒ¡ãšCDâ²ã¯åèšãšåæ§ã®åº
ã瀺ãããã®å Žåã«ãããŠãCDâ²ãšåå¿åŸãéè£
ãããã©ã°ã¡ã³ãã®é žçŽ ååäžã®äžå¯Ÿé»åã¯ã«ã«
ããã«éšåã®Ïé»åãšå ±åœ¹é¢ä¿ã«ããã 次ã«ãååå æ±æ žçœ®æã«ããçŸåæå¶å€ãæŸåº
ããåã®DIRååç©ã®äŸãäžè¬åŒ(6)ã§ç€ºãã äžè¬åŒ(6) åŒäžããšïŒºã¯äžè¬åŒ(1)ãšå矩ã§ãããNuâ
âãTIMEã«çžåœãããNuã¯é»åã®è±å¯ãªé ž
çŽ ãç¡«é»åã¯çªçŽ ååãæããŠããæ±æ žåºã§ã
ããã¯é»åã®äžååãªã«ã«ããã«åºãããªã«ã«
ããã«åºããã¹ãã€ãã«åºåã¯ããªãã¹ãã€ãã«
åºãæããŠããæ±é»ååºã§ããããã®æ±é»ååºã¯
ã«çµåããŠãããã¯Nuåã³ïŒ¥ãç«äœçã«é¢
ä¿ã¥ããŠããŠïŒ¡ããNuãæŸåºããããããåŸã
ïŒå¡ç°ãªããïŒå¡ç°ã®åœ¢æã䌎ãååå æ±æ žçœ®æ
åå¿ã被ãããã€ããã«ãã€ãŠïŒºãæŸåºããããš
ã®ã§ããçµååºã§ããã 次ã«äžè¬åŒ(6)ã§ç€ºãããã¿ã€ãã³ã°åºãæãã
DIRååç©ãšCDâ²ãšã®åå¿æ©æ§ãäžäŸãšããŠã
ãšããŠããšãã«ã¡ã«ã«ããããã©ãŸãŒã«ãšãªãåº
ã䜿çšããååç©ãçšããŠäžèšã«ãã説æããã äžèšã¿ã€ãã³ã°åºãæããDIRååç©ã¯ãäžè¬
åŒ(6)ã«ãããNuïŒïŒ¥åã³ïŒžãããããé žçŽ ã
ãåŒãåºåã³ããšãã¬ã³åºã§ããåå
ç©ã§ããã
äžèšåå¿åŒã§ç€ºãããã«ãã¿ã€ãã³ã°åºãæã
ãDIRååç©ã¯ãçºè²çŸåå€ã®é žåäœãšåå¿ããŠ
éè£ããååå æ±æ žçœ®æåå¿ã«ãã€ãŠçŸåæå¶å€
ãæŸåºããã 次ã«ãæ¬çºæã«çšããããã¿ã€ãã³ã°åºãæã
ãDIRååç©ã®å ·äœç代衚äŸã瀺ããæ¬çºæã«çš
ããããååç©ã¯ãããã«éå®ããããã®ã§ã¯ãª
ãã äŸç€ºååç© åŒäžã®ïŒ¹ïŒïŒ·ïŒïœåã³R3ã¯ãããããäžèšã®
éãã§ããã
ãDIRååç©ã¯ãçºè²çŸåå€ã®é žåäœãšåå¿ããŠ
éè£ããååå æ±æ žçœ®æåå¿ã«ãã€ãŠçŸåæå¶å€
ãæŸåºããã 次ã«ãæ¬çºæã«çšããããã¿ã€ãã³ã°åºãæã
ãDIRååç©ã®å ·äœç代衚äŸã瀺ããæ¬çºæã«çš
ããããååç©ã¯ãããã«éå®ããããã®ã§ã¯ãª
ãã äŸç€ºååç© åŒäžã®ïŒ¹ïŒïŒ·ïŒïœåã³R3ã¯ãããããäžèšã®
éãã§ããã
ãè¡šã
ãè¡šã
æ¬çºæã«çšããããã¿ã€ãã³ã°åºãæããDIR
ååç©ã®åææ³ã¯ç¹éæ54â145135å·å ¬å ±ãç¹é¡
æ55â17644å·æ现æžïŒç¹éæ56â114946å·ïŒç
ã«èšèŒãããŠããã æ¬çºæã«çšãããããçºè²çŸåäž»è¬ã®é žåäœãš
ã«ãããªã³ã°ãããæåãšè©²é žåäœãšã«ãããªã³
ã°ããŠæŸåºãããçŸåæå¶å€ãšãªãåºãšãæã該
ã«ãããªã³ã°ãããæåãšè©²æå¶å€ãšãªãåºãšã®
éã«ã¿ã€ãã³ã°åºãæããªãååç©ãå³ã¡ã¿ã€ã
ã³ã°åºãæããªãDIRååç©ã¯DIRã«ãã©ãŒãš
DIRç©è³ªãšãå å«ããã ã¿ã€ãã³ã°åºãæããªãDIRã«ãã©ãŒãšããŠã¯
äŸãã°ç±³åœç¹èš±ç¬¬3227554å·ãå第3773201å·ãè±
åœç¹èš±ç¬¬2010818å·æ现æžã«èšèŒããããã®ãæ
ãããããåææ³ããããæ现æžã«èšèŒãããŠã
ãã ã¿ã€ãã³ã°åºãæããªãDIRç©è³ªã¯ç±³åœç¹èš±ç¬¬
3958993å·ãå第3961959å·ãå第3938996å·æ现
æžãç¹éæ50â147716å·ãå50â152731å·ãå51
â105819å·ãå51â6724å·ãå52â14817å·ãå
52â49030å·å ¬å ±ãç±³åœç¹èš±ç¬¬3928041å·ãå第
3632345å·æ现æžçã«èšèŒããããã®ãæãã
ããåææ³ããããæ现æžã«èšèŒãããŠããã 次ã«ãæ¬çºæã«ãããŠçšããããã¿ã€ãã³ã°åº
ãæããªãDIRååç©ã®å ·äœç代衚äŸã瀺ããæ¬
çºæã«çšããããååç©ã¯ãããã«éå®ãããã
ã®ã§ã¯ãªãã æ¬çºæã«çšããããã¿ã€ãã³ã°åºãæããDIR
ååç©ãšã¿ã€ãã³ã°åºãæããªãDIRååç©ã¯ã
äž¡è ãããã²ã³åéä¹³å€å±€ã®å°ãªããšãïŒå±€ã«å«
æãããã°ãããäŸãã°éææ§ä¹³å€å±€ãç·ææ§ä¹³
å€å±€ããã³èµ€ææ§ä¹³å€å±€ãæããéåžžã®å€å±€ãã
ã²ã³åéã«ã©ãŒåçæå ææã«é©çšããå Žåã«
ã¯ããããã®ïŒå±€ãããã¯ïŒå±€ä»¥äžã«å«æããã
ã°ããããå°ãªããšãç·ææ§ä¹³å€å±€ã«å«æããã
ããšã奜ãŸããããŸããåäžã®æè²æ§ãæããã
ãã²ã³åéä¹³å€å±€ãæ床ãç°ã«ããè€æ°ã®å±€ãã
ãªãå Žåã«ã¯ããããã®ïŒå±€ãŸãã¯ïŒå±€ä»¥äžã«å«
æãããã°ãããåå¥ã ã®å±€ã«å«æãããŠããã
ããå°ãªããšãäœæ床乳å€å±€ã«å«æãããããšã
奜ãŸããã æ¬çºæã«ä¿ãããã²ã³åéã«ã©ãŒåçæå ææ
ã«ãããŠã¿ã€ãã³ã°åºãæããªãDIRååç©ãšã¿
ã€ãã³ã°åºãæããDIRååç©ã®ç·éã¯ä¹³å€äžã®
ããã²ã³åéïŒã¢ã«ã«å¯ŸããŠ0.0005ãªãã0.10ã¢
ã«ã®ç¯å²ã奜ãŸãããç¹ã«å¥œãŸããã¯0.001ãªã
ã0.01ã¢ã«ã®ç¯å²ã§ããã æ¬çºæã«çšããããã¿ã€ãã³ã°åºãæããDIR
ååç©ãšã¿ã€ãã³ã°åºãæããªãDIRååç©ã®æ¯
çã¯ä»»æã«éžã¶ããšãã§ããããã¿ã€ãã³ã°åºã
æããªãDIRååç©ã«å¯ŸããŠã¿ã€ãã³ã°åºãæã
ãDIRååç©ã0.02ãªãã50ã¢ã«ã®ç¯å²ã奜ãŸã
ããç¹ã«0.1ãªãã5.0ã¢ã«ã®ç¯å²ã奜ãŸããã æ¬çºæã«ä¿ãããã²ã³åéã«ã©ãŒåçæå ææ
ã«çšããããã«ãã©ãŒããªãã¡çºè²çŸåäž»è¬ã®é ž
åç©ãšåå¿ããŠè²çŽ ã圢æããååç©ã¯ååäžã«
ãã©ã¹ãåºãšãã°ããçæ°Žåºãæããéæ£æ§ã®ã
ãã®ãæãŸãããã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒåœ
éæ§ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããã ãŸããã«ãã©ãŒã®åœ¢æ ãšããŠäœååéã®ãã®ã§
ãè¯ãããããããããªã¡ãªãã¯ã«ãã©ãŒã§ãè¯
ãã ã€ãšããŒã«ãã©ãŒãšããŠã¯å ¬ç¥ã®ééã±ãã¡ã
ã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ããããããã®
ãã¡ãã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»åã³ãããã€ã«
ã¢ã»ãã¢ããªãç³»ååç©ãæçšã§ããã ããŒã³ã¿ã«ãã©ãŒãšããŠã¯ãã©ãŸãã³ç³»åå
ç©ãã€ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«åå
ç©ãã·ã¢ã³ã«ãã©ãŒãšããŠã¯ããšããŒã«ç³»åå
ç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ã
ãã ãããã®ã«ãã©ãŒã¯ãäžè¬ã«ä¹³å€å±€äžã®éïŒã¢
ã«åœãïŒÃ10-3ã¢ã«ãªããïŒÃ10-1ã¢ã«ã奜ãŸã
ãã¯ïŒÃ10-2ã¢ã«ãªããïŒÃ10-1ã¢ã«æ·»å ããã æ¬çºæã«ããã¿ã€ãã³ã°åºãæããDIRååç©
ãšã¿ã€ãã³ã°åºãæããªãDIRååç©ãããã²ã³
åéæå ææã«å«æãããã«ã¯åçš®ã®æ¹æ³ããã
ããã©ããã¯ã¹åæ£æ³ãæ°Žäžæ²¹æ»Žåä¹³ååæ£æ³ã
ç¹ã«æå¹ã§ããããããã®åæ£æ¹æ³ã¯åŸæ¥ããã
ãç¥ãããŠãããã©ããã¯ã¹åæ£æ³ããã³ãã®å¹
æã¯ãç¹éæ49â74538å·ãå51â59943å·ãå54
â32552å·åå ¬å ±ããªãµãŒãã»ãã¹ã¯ããŒãžã€ãŒ
ïŒResearch DisclosureïŒã1976幎ïŒæãNo.
14850ã77ã79é ã«èšèŒãããŠããã é©åœãªã©ããã¯ã¹ã¯ãäŸãã°ã¹ãã¬ã³ããšãã«
ã¢ã¯ãªã¬ãŒããïœâããã«ã¢ã¯ãªã¬ãŒããïœâã
ãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâã¢ã»ãã¢ã»ããã·ãšã
ã«ã¡ã¿ã¯ãªã¬ãŒããïŒâïŒã¡ã¿ã¯ãªãã€ã«ãªã
ã·ïŒãšãã«ããªã¡ãã«ã¢ã³ã¢ããŠã ã¡ããµã«ããš
ãŒãïŒâïŒã¡ã¿ã¯ãªãã€ã«ãªãã·ïŒãããã³âïŒ
âã¹ã«ãã³é žãããªãŠã å¡©ãâã€ãœãããã«ã¢
ã¯ãªã«ã¢ãããâãïŒâïŒïŒâã¡ãã«âïŒâãªã
ãœãã³ãã«ïŒãã¢ã¯ãªã«ã¢ãããïŒâã¢ã¯ãªã«ã¢
ããâïŒâã¡ãã«ãããã³ã¹ã«ãã³é žãªã©ã®ãã
ãªã¢ãããŒã®ãã¢ããªããŒãã³ããªããŒããã³ã¿
ãŒããªããŒã§ãããæ¬çºæã«ä¿ãDIRååç©ã¯è©²
ããªããŒé¡ã«åæ£ããŠããã²ã³åéä¹³å€äžã«æ·»å
ããããæ°Žäžæ²¹æ»Žåä¹³ååæ£æ³ã¯ãã«ãã©ãŒçã®
çæ°Žæ§æ·»å ç©ããŒã©ãã³çãžåæ£ãããåŸæ¥å ¬ç¥
ã®æ¹æ³ãé©çšã§ãããæ¬çºæã«çšããããäžèšïŒ
çš®ã®DIRååç©ã¯ãã«ãã©ãŒãšåæã«åæ£ããã
ã²ã³åéä¹³å€äžã«æ·»å ããŠãè¯ãããç¬ç«ã«äžèš
ïŒçš®ã®DIRååç©ãåæ£ããä¹³å€äžã«ç¬ç«ã«å ã
ãŠãè¯ãã ãŸããåæ°ãŸãã¯è€æ°ã®ã¹ã«ãã³ãžã€ãŒå±€ãæ
å ææã®æ§æå±€ã®é©åœãªäœçœ®ã«ä»åšãããããšã«
ãã€ãŠãäžèšæŸåºãããçŸåæå¶å€ã®åœ±é¿ãåã
ãå±€ãšåããªãå±€ãšã«ã³ã³ãããŒã«ããããšãã§
ããã æ¬çºæã®ããã²ã³åéåçæå ææã«äœ¿çšãã
ãããã²ã³åéä¹³å€ãšããŠã¯ãåœæ¥çã«ãããŠäœ¿
çšãããä»»æã®ããã²ã³åéä¹³å€ãé©çšãããã
äŸãã°ãå¡©åéãèåéãæ²èåéãå¡©æ²èå
éãå¡©æ²åéãããã¯å¡©æ²èåéã®çµæ¶åã¯ãã
ãã®çµæ¶ã®æ··åç©ãå«ãããšãã§ããã該ããã²
ã³åéä¹³å€ã¯å€§ç²åã§ãå°ç²åã§ãããããããŠ
ååæ£ã§ãå€åæ£ã§ãããããŸãããããã²ã³å
éçµæ¶ã¯ç«æ¹æ¶ãå «é¢äœããšãã¿ãã·ã€ã«æ··æçµ
æ¶çã®äœãã§ãããã該乳å€ã¯ãã¬ä¹³å€ãããã¯
çŽæ¥ããžä¹³å€ãšããããšãã§ããããããã¯äž»ãš
ããŠããã²ã³åéç²åã®è¡šé¢ã«æœåã圢æããè¡š
é¢æœååä¹³å€ãããã²ã³åéç²åã®å éšã«æœåå
ä¹³å€ãŸãã¯è¡šé¢æœååä¹³å€ãšå éšæœååä¹³å€ãšã®
æ··åç©ã䜿çšã§ããã ãããã®ããã²ã³åéã¯ã掻æ§ãŒã©ãã³ïŒç¡«é»
å¢æå€äŸãã°ã¢ãªã«ããªã«ã«ããããããªå°¿çŽ ã
ã·ã¹ãã³çïŒã»ã¬ã³å¢æå€ïŒéå å¢æå€äŸãã°ç¬¬
ïŒã¹ãºå¡©ãäºé žåããªå°¿çŽ ãããªã¢ãã³çïŒè²Žé
å±å¢æå€äŸãã°éå¢æå€å ·äœçã«ã¯ã«ãªãŠã ãªãŒ
ãªããªã·ã¢ããŒããã«ãªãŠã ã¯ãããªãŒã¬ãŒãã
ïŒâãªãŒãã¹ã«ããã³ãŸãã¢ãŸãŒã«ã¡ãã¯ãã©ã€
ãçãããã¯äŸãã°ã«ãããŠã ãããžãŠã ãã€ãª
ãžãŠã çã®æ°Žæº¶æ§å¡©ã®å¢æå€ãå ·äœçã«ã¯ã¢ã³ã¢
ããŠã ã¯ãããã©ããŒããã«ãªãŠã ã¯ãããã©ã
ãªãŒãããã³ãããªãŠã ã¯ãããã©ãã€ãçïŒã
ããã®æãçš®ã®ãã®ã¯éã®å€§å°ã«ãã€ãŠå¢æå€ã
ããã¯ã«ããªæå¶å€çãšããŠäœçšãããïŒïŒçã«
ããåç¬ã§ãããã¯é©å®äœµçšïŒäŸãã°éå¢æå€ãš
ç¡«é»å¢æå€ã®äœµçšãéå¢æå€ãšã»ã¬ã³å¢æå€ãšã®
䜵çšçãïŒããŠååŠçã«å¢æãããŠããŠãããã ããã«ãã®ããã²ã³åéã¯ææã®æ³¢é·åã«å åŠ
çã«å¢æããããšãã§ããäŸãã°ãŒãã¡ãã³è²çŽ
ã¢ãã¡ãã³è²çŽ ããžã¡ãã³è²çŽ ãããªã¡ãã³è²çŽ
çã®ã·ã¢ãã³è²çŽ ãããã¯ã¡ãã·ã¢ãã³è²çŽ çã®
å åŠå¢æå€ã§åç¬ã«ãããã¯äœµçšããŠïŒäŸãã°è¶
è²å¢æïŒå åŠçã«å¢æããããšãã§ããã æ¬çºæã®ããã²ã³åéåçæå ææã®ãã®ä»ã®
å ·äœçãªæ§æçã¯æç®ïŒããªãµãŒãã»ãã€ã¹ã¯ã
ãŒãžã€ãŒNo.18431ã«èšèŒãããŠããå 容ãé©çšã§
ãããäžèšæ¬çºæã®ããã²ã³åéåçæå ææ
ã¯ãå ¬ç¥ã®åŠçæ¹æ³äŸãã°çºè²çŸåãæŒçœå®çã
æ°ŽæŽãå®å®ã®å·¥çšãå«ãæ¹æ³ã§åŠçãããããã®
çºè²çŸåã¯çºè²çŸåäž»è¬ãå«æããã¢ã«ã«ãªæ§æ°Ž
溶液ã§ãããçºè²çŸåäž»è¬ã¯ãããã²ã³åéã«ã©
ãŒåçæå ææã®çŸåçšãšããŠäœ¿çšãããä»»æã®
çºè²çŸåäž»è¬ãé©çšã§ããäŸãã°æç®ïŒã«èšèŒã
ããŠããåŠããâããšãã¬ã³ãžã¢ãã³åã³ïŒ°â
ã¢ããããšããŒã«ã®ãããªè³éŠæ第ïŒçŽã¢ãã³ã
é©çšã§ããã äžèšæŒçœå®çã¯ããšãã¬ã³ãžã¢ãã³ïŒé ¢é žé
ïŒïŒå¡©ã®åŠã第ïŒéå¡©ãšãã€ãã®åŠãããªç¡«é ž
å¡©ãå«æããæŒçœå®ç液ã§ããã第ïŒéå¡©ãšããª
ç¡«é žå¡©ãšãå¥ã ã®åŠç液ãšããŠãåŠçã§ããã ã å®æœäŸ 以äžãå®æœäŸã«ãããŠãæ¬çºæãããã«å ·äœç
ã«èª¬æããã¿ã€ãã³ã°åºãæããDIRååç©ãšæ
ããªãDIRååç©ãšãçµåããããšã«ãã€ãŠãã
ãããåç¬ã®å Žåã«æ¯ãèããé®®éæ§çãåäžã
ãããšãäŸèšŒããã ãªããç»åé®®éæ§ã®æ¹è¯å¹æã®æ€åºã¯MTF
ïŒModulation Transfer FunctionïŒãæ±ãã空é
åšæ³¢æ°ã10æ¬ïŒmmããã³30æ¬ïŒmmã§ã®MTFã®å€§
ãããæ¯èŒããããšã«ããè¡ãªã€ãã ãŸããç²ç¶æ§ïŒRMSïŒã¯å圢走æ»å£åŸã25ÎŒ
ã®ãã¯ããã³ã·ãã¡ãŒã¿ãŒã§èµ°æ»ãããšãã«çã
ãæ¿åºŠå€ã®å€åã®æšåå·®ã®1000åå€ãæ¯èŒããã
ãšã«ããè¡ãªã€ãã å®æœäŸ ïŒ ããŒã³ã¿ã«ãã©ãŒãšããŠïŒâïŒïŒïŒïŒïŒïŒâã
ãªã¯ããããšãã«ïŒâïŒâãïŒâïŒïŒïŒïŒâãžâïœ
âã¢ãã«ããšããã·ã¢ã»ãã¢ããïŒãã³ãã¢ã
ããâïŒâãã©ãŸãã³15ïœãé ¢é žãšãã«30mlåã³
ãžããã«ãã¿ã¬ãŒã15mlã«æº¶è§£ãããããã¢ã«ã«
ããŒã«ïŒ¢ïŒã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ãããŒããã
ãŠãã³ç€Ÿè£œïŒã®10ïŒ æ°Žæº¶æ¶²20mlåã³ïŒïŒ ãŒã©ãã³
氎溶液200mlãšæ··åããã³ãã€ããã«ã«ãŠä¹³åå
æ£ããããããã®ã¡ããã®åæ£æ¶²ãç·ææ§æ²èå
éä¹³å€ïŒ6.0ã¢ã«ïŒ æ²åéå«æïŒïŒKgã«æ·»å ããŠ
ãã¬ãŒã·ãšã³é²æ¢å±€ãæããããªã¢ã»ããŒãããŒ
ã¹äžã«ééã20mgïŒïœm2ãšãªãããå¡åžãã也ç¥
ããã ãããè©Šæ(1)ãšããã äžèšè©Šæ(1)ãšåæ§ã«ããŠãäœãäžèšã®åŠãïŒçš®
ã®DIRååç©ïŒ¡ïŒïŒ¢ãäžèšã®ç¬¬ïŒè¡šã«èšèŒããæ·»
å éã«åŸã€ãŠä¹³å€äžã«æ·»å ããŠè©Šæ(2)ïŒ(3)ïŒ(4)å
ã³(5)ãäœè£œããã  äŸç€ºååç©ïŒ€â64ïŒã¿ã€ãã³ã°åºããããªã
DIRååç©ïŒ  äŸç€ºååç©ïŒŽâ36ïŒã¿ã€ãã³ã°åºãæãã
DIRååç©ïŒ
ååç©ã®åææ³ã¯ç¹éæ54â145135å·å ¬å ±ãç¹é¡
æ55â17644å·æ现æžïŒç¹éæ56â114946å·ïŒç
ã«èšèŒãããŠããã æ¬çºæã«çšãããããçºè²çŸåäž»è¬ã®é žåäœãš
ã«ãããªã³ã°ãããæåãšè©²é žåäœãšã«ãããªã³
ã°ããŠæŸåºãããçŸåæå¶å€ãšãªãåºãšãæã該
ã«ãããªã³ã°ãããæåãšè©²æå¶å€ãšãªãåºãšã®
éã«ã¿ã€ãã³ã°åºãæããªãååç©ãå³ã¡ã¿ã€ã
ã³ã°åºãæããªãDIRååç©ã¯DIRã«ãã©ãŒãš
DIRç©è³ªãšãå å«ããã ã¿ã€ãã³ã°åºãæããªãDIRã«ãã©ãŒãšããŠã¯
äŸãã°ç±³åœç¹èš±ç¬¬3227554å·ãå第3773201å·ãè±
åœç¹èš±ç¬¬2010818å·æ现æžã«èšèŒããããã®ãæ
ãããããåææ³ããããæ现æžã«èšèŒãããŠã
ãã ã¿ã€ãã³ã°åºãæããªãDIRç©è³ªã¯ç±³åœç¹èš±ç¬¬
3958993å·ãå第3961959å·ãå第3938996å·æ现
æžãç¹éæ50â147716å·ãå50â152731å·ãå51
â105819å·ãå51â6724å·ãå52â14817å·ãå
52â49030å·å ¬å ±ãç±³åœç¹èš±ç¬¬3928041å·ãå第
3632345å·æ现æžçã«èšèŒããããã®ãæãã
ããåææ³ããããæ现æžã«èšèŒãããŠããã 次ã«ãæ¬çºæã«ãããŠçšããããã¿ã€ãã³ã°åº
ãæããªãDIRååç©ã®å ·äœç代衚äŸã瀺ããæ¬
çºæã«çšããããååç©ã¯ãããã«éå®ãããã
ã®ã§ã¯ãªãã æ¬çºæã«çšããããã¿ã€ãã³ã°åºãæããDIR
ååç©ãšã¿ã€ãã³ã°åºãæããªãDIRååç©ã¯ã
äž¡è ãããã²ã³åéä¹³å€å±€ã®å°ãªããšãïŒå±€ã«å«
æãããã°ãããäŸãã°éææ§ä¹³å€å±€ãç·ææ§ä¹³
å€å±€ããã³èµ€ææ§ä¹³å€å±€ãæããéåžžã®å€å±€ãã
ã²ã³åéã«ã©ãŒåçæå ææã«é©çšããå Žåã«
ã¯ããããã®ïŒå±€ãããã¯ïŒå±€ä»¥äžã«å«æããã
ã°ããããå°ãªããšãç·ææ§ä¹³å€å±€ã«å«æããã
ããšã奜ãŸããããŸããåäžã®æè²æ§ãæããã
ãã²ã³åéä¹³å€å±€ãæ床ãç°ã«ããè€æ°ã®å±€ãã
ãªãå Žåã«ã¯ããããã®ïŒå±€ãŸãã¯ïŒå±€ä»¥äžã«å«
æãããã°ãããåå¥ã ã®å±€ã«å«æãããŠããã
ããå°ãªããšãäœæ床乳å€å±€ã«å«æãããããšã
奜ãŸããã æ¬çºæã«ä¿ãããã²ã³åéã«ã©ãŒåçæå ææ
ã«ãããŠã¿ã€ãã³ã°åºãæããªãDIRååç©ãšã¿
ã€ãã³ã°åºãæããDIRååç©ã®ç·éã¯ä¹³å€äžã®
ããã²ã³åéïŒã¢ã«ã«å¯ŸããŠ0.0005ãªãã0.10ã¢
ã«ã®ç¯å²ã奜ãŸãããç¹ã«å¥œãŸããã¯0.001ãªã
ã0.01ã¢ã«ã®ç¯å²ã§ããã æ¬çºæã«çšããããã¿ã€ãã³ã°åºãæããDIR
ååç©ãšã¿ã€ãã³ã°åºãæããªãDIRååç©ã®æ¯
çã¯ä»»æã«éžã¶ããšãã§ããããã¿ã€ãã³ã°åºã
æããªãDIRååç©ã«å¯ŸããŠã¿ã€ãã³ã°åºãæã
ãDIRååç©ã0.02ãªãã50ã¢ã«ã®ç¯å²ã奜ãŸã
ããç¹ã«0.1ãªãã5.0ã¢ã«ã®ç¯å²ã奜ãŸããã æ¬çºæã«ä¿ãããã²ã³åéã«ã©ãŒåçæå ææ
ã«çšããããã«ãã©ãŒããªãã¡çºè²çŸåäž»è¬ã®é ž
åç©ãšåå¿ããŠè²çŽ ã圢æããååç©ã¯ååäžã«
ãã©ã¹ãåºãšãã°ããçæ°Žåºãæããéæ£æ§ã®ã
ãã®ãæãŸãããã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒåœ
éæ§ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããã ãŸããã«ãã©ãŒã®åœ¢æ ãšããŠäœååéã®ãã®ã§
ãè¯ãããããããããªã¡ãªãã¯ã«ãã©ãŒã§ãè¯
ãã ã€ãšããŒã«ãã©ãŒãšããŠã¯å ¬ç¥ã®ééã±ãã¡ã
ã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ããããããã®
ãã¡ãã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»åã³ãããã€ã«
ã¢ã»ãã¢ããªãç³»ååç©ãæçšã§ããã ããŒã³ã¿ã«ãã©ãŒãšããŠã¯ãã©ãŸãã³ç³»åå
ç©ãã€ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«åå
ç©ãã·ã¢ã³ã«ãã©ãŒãšããŠã¯ããšããŒã«ç³»åå
ç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ã
ãã ãããã®ã«ãã©ãŒã¯ãäžè¬ã«ä¹³å€å±€äžã®éïŒã¢
ã«åœãïŒÃ10-3ã¢ã«ãªããïŒÃ10-1ã¢ã«ã奜ãŸã
ãã¯ïŒÃ10-2ã¢ã«ãªããïŒÃ10-1ã¢ã«æ·»å ããã æ¬çºæã«ããã¿ã€ãã³ã°åºãæããDIRååç©
ãšã¿ã€ãã³ã°åºãæããªãDIRååç©ãããã²ã³
åéæå ææã«å«æãããã«ã¯åçš®ã®æ¹æ³ããã
ããã©ããã¯ã¹åæ£æ³ãæ°Žäžæ²¹æ»Žåä¹³ååæ£æ³ã
ç¹ã«æå¹ã§ããããããã®åæ£æ¹æ³ã¯åŸæ¥ããã
ãç¥ãããŠãããã©ããã¯ã¹åæ£æ³ããã³ãã®å¹
æã¯ãç¹éæ49â74538å·ãå51â59943å·ãå54
â32552å·åå ¬å ±ããªãµãŒãã»ãã¹ã¯ããŒãžã€ãŒ
ïŒResearch DisclosureïŒã1976幎ïŒæãNo.
14850ã77ã79é ã«èšèŒãããŠããã é©åœãªã©ããã¯ã¹ã¯ãäŸãã°ã¹ãã¬ã³ããšãã«
ã¢ã¯ãªã¬ãŒããïœâããã«ã¢ã¯ãªã¬ãŒããïœâã
ãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâã¢ã»ãã¢ã»ããã·ãšã
ã«ã¡ã¿ã¯ãªã¬ãŒããïŒâïŒã¡ã¿ã¯ãªãã€ã«ãªã
ã·ïŒãšãã«ããªã¡ãã«ã¢ã³ã¢ããŠã ã¡ããµã«ããš
ãŒãïŒâïŒã¡ã¿ã¯ãªãã€ã«ãªãã·ïŒãããã³âïŒ
âã¹ã«ãã³é žãããªãŠã å¡©ãâã€ãœãããã«ã¢
ã¯ãªã«ã¢ãããâãïŒâïŒïŒâã¡ãã«âïŒâãªã
ãœãã³ãã«ïŒãã¢ã¯ãªã«ã¢ãããïŒâã¢ã¯ãªã«ã¢
ããâïŒâã¡ãã«ãããã³ã¹ã«ãã³é žãªã©ã®ãã
ãªã¢ãããŒã®ãã¢ããªããŒãã³ããªããŒããã³ã¿
ãŒããªããŒã§ãããæ¬çºæã«ä¿ãDIRååç©ã¯è©²
ããªããŒé¡ã«åæ£ããŠããã²ã³åéä¹³å€äžã«æ·»å
ããããæ°Žäžæ²¹æ»Žåä¹³ååæ£æ³ã¯ãã«ãã©ãŒçã®
çæ°Žæ§æ·»å ç©ããŒã©ãã³çãžåæ£ãããåŸæ¥å ¬ç¥
ã®æ¹æ³ãé©çšã§ãããæ¬çºæã«çšããããäžèšïŒ
çš®ã®DIRååç©ã¯ãã«ãã©ãŒãšåæã«åæ£ããã
ã²ã³åéä¹³å€äžã«æ·»å ããŠãè¯ãããç¬ç«ã«äžèš
ïŒçš®ã®DIRååç©ãåæ£ããä¹³å€äžã«ç¬ç«ã«å ã
ãŠãè¯ãã ãŸããåæ°ãŸãã¯è€æ°ã®ã¹ã«ãã³ãžã€ãŒå±€ãæ
å ææã®æ§æå±€ã®é©åœãªäœçœ®ã«ä»åšãããããšã«
ãã€ãŠãäžèšæŸåºãããçŸåæå¶å€ã®åœ±é¿ãåã
ãå±€ãšåããªãå±€ãšã«ã³ã³ãããŒã«ããããšãã§
ããã æ¬çºæã®ããã²ã³åéåçæå ææã«äœ¿çšãã
ãããã²ã³åéä¹³å€ãšããŠã¯ãåœæ¥çã«ãããŠäœ¿
çšãããä»»æã®ããã²ã³åéä¹³å€ãé©çšãããã
äŸãã°ãå¡©åéãèåéãæ²èåéãå¡©æ²èå
éãå¡©æ²åéãããã¯å¡©æ²èåéã®çµæ¶åã¯ãã
ãã®çµæ¶ã®æ··åç©ãå«ãããšãã§ããã該ããã²
ã³åéä¹³å€ã¯å€§ç²åã§ãå°ç²åã§ãããããããŠ
ååæ£ã§ãå€åæ£ã§ãããããŸãããããã²ã³å
éçµæ¶ã¯ç«æ¹æ¶ãå «é¢äœããšãã¿ãã·ã€ã«æ··æçµ
æ¶çã®äœãã§ãããã該乳å€ã¯ãã¬ä¹³å€ãããã¯
çŽæ¥ããžä¹³å€ãšããããšãã§ããããããã¯äž»ãš
ããŠããã²ã³åéç²åã®è¡šé¢ã«æœåã圢æããè¡š
é¢æœååä¹³å€ãããã²ã³åéç²åã®å éšã«æœåå
ä¹³å€ãŸãã¯è¡šé¢æœååä¹³å€ãšå éšæœååä¹³å€ãšã®
æ··åç©ã䜿çšã§ããã ãããã®ããã²ã³åéã¯ã掻æ§ãŒã©ãã³ïŒç¡«é»
å¢æå€äŸãã°ã¢ãªã«ããªã«ã«ããããããªå°¿çŽ ã
ã·ã¹ãã³çïŒã»ã¬ã³å¢æå€ïŒéå å¢æå€äŸãã°ç¬¬
ïŒã¹ãºå¡©ãäºé žåããªå°¿çŽ ãããªã¢ãã³çïŒè²Žé
å±å¢æå€äŸãã°éå¢æå€å ·äœçã«ã¯ã«ãªãŠã ãªãŒ
ãªããªã·ã¢ããŒããã«ãªãŠã ã¯ãããªãŒã¬ãŒãã
ïŒâãªãŒãã¹ã«ããã³ãŸãã¢ãŸãŒã«ã¡ãã¯ãã©ã€
ãçãããã¯äŸãã°ã«ãããŠã ãããžãŠã ãã€ãª
ãžãŠã çã®æ°Žæº¶æ§å¡©ã®å¢æå€ãå ·äœçã«ã¯ã¢ã³ã¢
ããŠã ã¯ãããã©ããŒããã«ãªãŠã ã¯ãããã©ã
ãªãŒãããã³ãããªãŠã ã¯ãããã©ãã€ãçïŒã
ããã®æãçš®ã®ãã®ã¯éã®å€§å°ã«ãã€ãŠå¢æå€ã
ããã¯ã«ããªæå¶å€çãšããŠäœçšãããïŒïŒçã«
ããåç¬ã§ãããã¯é©å®äœµçšïŒäŸãã°éå¢æå€ãš
ç¡«é»å¢æå€ã®äœµçšãéå¢æå€ãšã»ã¬ã³å¢æå€ãšã®
䜵çšçãïŒããŠååŠçã«å¢æãããŠããŠãããã ããã«ãã®ããã²ã³åéã¯ææã®æ³¢é·åã«å åŠ
çã«å¢æããããšãã§ããäŸãã°ãŒãã¡ãã³è²çŽ
ã¢ãã¡ãã³è²çŽ ããžã¡ãã³è²çŽ ãããªã¡ãã³è²çŽ
çã®ã·ã¢ãã³è²çŽ ãããã¯ã¡ãã·ã¢ãã³è²çŽ çã®
å åŠå¢æå€ã§åç¬ã«ãããã¯äœµçšããŠïŒäŸãã°è¶
è²å¢æïŒå åŠçã«å¢æããããšãã§ããã æ¬çºæã®ããã²ã³åéåçæå ææã®ãã®ä»ã®
å ·äœçãªæ§æçã¯æç®ïŒããªãµãŒãã»ãã€ã¹ã¯ã
ãŒãžã€ãŒNo.18431ã«èšèŒãããŠããå 容ãé©çšã§
ãããäžèšæ¬çºæã®ããã²ã³åéåçæå ææ
ã¯ãå ¬ç¥ã®åŠçæ¹æ³äŸãã°çºè²çŸåãæŒçœå®çã
æ°ŽæŽãå®å®ã®å·¥çšãå«ãæ¹æ³ã§åŠçãããããã®
çºè²çŸåã¯çºè²çŸåäž»è¬ãå«æããã¢ã«ã«ãªæ§æ°Ž
溶液ã§ãããçºè²çŸåäž»è¬ã¯ãããã²ã³åéã«ã©
ãŒåçæå ææã®çŸåçšãšããŠäœ¿çšãããä»»æã®
çºè²çŸåäž»è¬ãé©çšã§ããäŸãã°æç®ïŒã«èšèŒã
ããŠããåŠããâããšãã¬ã³ãžã¢ãã³åã³ïŒ°â
ã¢ããããšããŒã«ã®ãããªè³éŠæ第ïŒçŽã¢ãã³ã
é©çšã§ããã äžèšæŒçœå®çã¯ããšãã¬ã³ãžã¢ãã³ïŒé ¢é žé
ïŒïŒå¡©ã®åŠã第ïŒéå¡©ãšãã€ãã®åŠãããªç¡«é ž
å¡©ãå«æããæŒçœå®ç液ã§ããã第ïŒéå¡©ãšããª
ç¡«é žå¡©ãšãå¥ã ã®åŠç液ãšããŠãåŠçã§ããã ã å®æœäŸ 以äžãå®æœäŸã«ãããŠãæ¬çºæãããã«å ·äœç
ã«èª¬æããã¿ã€ãã³ã°åºãæããDIRååç©ãšæ
ããªãDIRååç©ãšãçµåããããšã«ãã€ãŠãã
ãããåç¬ã®å Žåã«æ¯ãèããé®®éæ§çãåäžã
ãããšãäŸèšŒããã ãªããç»åé®®éæ§ã®æ¹è¯å¹æã®æ€åºã¯MTF
ïŒModulation Transfer FunctionïŒãæ±ãã空é
åšæ³¢æ°ã10æ¬ïŒmmããã³30æ¬ïŒmmã§ã®MTFã®å€§
ãããæ¯èŒããããšã«ããè¡ãªã€ãã ãŸããç²ç¶æ§ïŒRMSïŒã¯å圢走æ»å£åŸã25ÎŒ
ã®ãã¯ããã³ã·ãã¡ãŒã¿ãŒã§èµ°æ»ãããšãã«çã
ãæ¿åºŠå€ã®å€åã®æšåå·®ã®1000åå€ãæ¯èŒããã
ãšã«ããè¡ãªã€ãã å®æœäŸ ïŒ ããŒã³ã¿ã«ãã©ãŒãšããŠïŒâïŒïŒïŒïŒïŒïŒâã
ãªã¯ããããšãã«ïŒâïŒâãïŒâïŒïŒïŒïŒâãžâïœ
âã¢ãã«ããšããã·ã¢ã»ãã¢ããïŒãã³ãã¢ã
ããâïŒâãã©ãŸãã³15ïœãé ¢é žãšãã«30mlåã³
ãžããã«ãã¿ã¬ãŒã15mlã«æº¶è§£ãããããã¢ã«ã«
ããŒã«ïŒ¢ïŒã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ãããŒããã
ãŠãã³ç€Ÿè£œïŒã®10ïŒ æ°Žæº¶æ¶²20mlåã³ïŒïŒ ãŒã©ãã³
氎溶液200mlãšæ··åããã³ãã€ããã«ã«ãŠä¹³åå
æ£ããããããã®ã¡ããã®åæ£æ¶²ãç·ææ§æ²èå
éä¹³å€ïŒ6.0ã¢ã«ïŒ æ²åéå«æïŒïŒKgã«æ·»å ããŠ
ãã¬ãŒã·ãšã³é²æ¢å±€ãæããããªã¢ã»ããŒãããŒ
ã¹äžã«ééã20mgïŒïœm2ãšãªãããå¡åžãã也ç¥
ããã ãããè©Šæ(1)ãšããã äžèšè©Šæ(1)ãšåæ§ã«ããŠãäœãäžèšã®åŠãïŒçš®
ã®DIRååç©ïŒ¡ïŒïŒ¢ãäžèšã®ç¬¬ïŒè¡šã«èšèŒããæ·»
å éã«åŸã€ãŠä¹³å€äžã«æ·»å ããŠè©Šæ(2)ïŒ(3)ïŒ(4)å
ã³(5)ãäœè£œããã  äŸç€ºååç©ïŒ€â64ïŒã¿ã€ãã³ã°åºããããªã
DIRååç©ïŒ  äŸç€ºååç©ïŒŽâ36ïŒã¿ã€ãã³ã°åºãæãã
DIRååç©ïŒ
ãè¡šã
äžèšïŒçš®é¡ã®è©ŠæããŠãšããžé²å
ããäžèšçµæ
ã®çºè²çŸå液ãçšã38âã§ïŒåéçºè²çŸåãè¡
ããæŒçœãå®çãè¡ã€ãŠããæ°ŽæŽããã ïŒçºè²çŸå液çµæïŒ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âããããã·ãšãã«ïŒâã¢ããªã³ã»ç¡«é žå¡©
4.75ïœ ç¡æ°Žäºç¡«é žãããªãŠã 4.25ïœ ããããã·ã«ã¢ãã³ïŒïŒïŒç¡«é žå¡© 2.0ïœ ç¡æ°Žçé žã«ãªãŠã 37.5ïœ èåãããªãŠã 1.3ïœ ãããªãããªé ¢é žã»ïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
2.5ïœ æ°Žé žåã«ãªãŠã 1.0ïœ æ°Žãå ããŠïŒãšãæ°Žé žåã«ãªãŠã ãçšããŠPH
10.0ã«èª¿æŽããã åŸãããçµæãäžèšç¬¬ïŒè¡šã«ç€ºãã
ã®çºè²çŸå液ãçšã38âã§ïŒåéçºè²çŸåãè¡
ããæŒçœãå®çãè¡ã€ãŠããæ°ŽæŽããã ïŒçºè²çŸå液çµæïŒ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âããããã·ãšãã«ïŒâã¢ããªã³ã»ç¡«é žå¡©
4.75ïœ ç¡æ°Žäºç¡«é žãããªãŠã 4.25ïœ ããããã·ã«ã¢ãã³ïŒïŒïŒç¡«é žå¡© 2.0ïœ ç¡æ°Žçé žã«ãªãŠã 37.5ïœ èåãããªãŠã 1.3ïœ ãããªãããªé ¢é žã»ïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
2.5ïœ æ°Žé žåã«ãªãŠã 1.0ïœ æ°Žãå ããŠïŒãšãæ°Žé žåã«ãªãŠã ãçšããŠPH
10.0ã«èª¿æŽããã åŸãããçµæãäžèšç¬¬ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šããã察ç
§è©Šæ(1)以å€ã¯æ¯æ床ãã¬ã³ã
ã®å€ã¯ã»ãŒåäžã§ãããå³ã¡DIRååç©ã«ããçº
è²æ¿åºŠã®äœäžã¯åãã§ããã«ãé¢ããããšïŒ¢ã
çµåããŠäœ¿çšããååç©æ¬çºæè©Šæã®(3)ïŒ(4)ã¯å
åç©ïŒ¡ãšïŒ¢ãããããåç¬ã«äœ¿çšããå Žåã«æ¯ã
MTFå€ãèãã倧ããé®®éæ§ãæ¹åãããããš
ããããããŸãRMSå€ãå¯Ÿç §è©Šæ(1)ãšæ¯ãèã
ãå°ãªãå€ã瀺ããŠãããå³ã¡ç²ç¶æ§ãæ¹åãã
ãŠããããšã瀺ããŠããã å®æœäŸïŒ ïŒéå±€å¹æïŒ ããªã¢ã»ããŒãããŒã¹äžã«ä»¥äžã®é åºã§éå±€å¡
åžãè¡ã€ãŠäžèšã®ïŒçš®é¡ã®è©Šæãäœæããã 第ïŒå±€ ã·ã¢ã³ã«ãã©ãŒãšããŠïŒâããããã·â
âãïŒâïŒïŒïŒïŒâãžâïœâã¢ãã«ããšãã
ã·ïŒããã«ãâïŒâãããã¢ãã10.6ïœãå®æœ
äŸ(1)ãšåæ§ã«åæ£ããèµ€ææ§æ²èåéä¹³å€
ïŒ3.0ã¢ã«ïŒ æ²åéå«æïŒïŒKgã«æ·»å å¡åžä¹Ÿç¥ã
ãã 第ïŒå±€ ãŒã©ãã³0.5ïœïŒm2ããã³ïŒïŒïŒâtert
âãžãªã¯ãã«ãã€ããããã³0.1ïœïŒm2ãå«æ
ãããŒã©ãã³äžéå±€ã 第ïŒå±€ å®æœäŸïŒã«ãããã®ãšåæ§ãªïŒçš®é¡ã®ç·
ææ§æ²èåéä¹³å€å±€ã å®æœäŸ(1)ã®è©Šæ(1)ïŒ(2)ïŒ(3)ïŒ(4)ããã³(5)ã«å¯Ÿå¿
ããè©Šæãããããè©Šæ(6)ïŒ(7)ïŒ(8)ïŒ(9)ããã³(10)
ãšããã åè©Šæãç·è²å ã§ãŠãšããžãä»ããŠé²å ããåŸ
ã«ãèµ€è²å ã®é²å ã®ã¿ã§ã¯èµ€æ¿åºŠã2.0ãšãªãã
ããªé²å éã§èµ€è²å ãåäžé²å ããåŸã«å®æœäŸ(1)
ãšåæ§ã«çŸååŠçããã åŸãããçµæã第ïŒè¡šã«ç€ºãã
ã®å€ã¯ã»ãŒåäžã§ãããå³ã¡DIRååç©ã«ããçº
è²æ¿åºŠã®äœäžã¯åãã§ããã«ãé¢ããããšïŒ¢ã
çµåããŠäœ¿çšããååç©æ¬çºæè©Šæã®(3)ïŒ(4)ã¯å
åç©ïŒ¡ãšïŒ¢ãããããåç¬ã«äœ¿çšããå Žåã«æ¯ã
MTFå€ãèãã倧ããé®®éæ§ãæ¹åãããããš
ããããããŸãRMSå€ãå¯Ÿç §è©Šæ(1)ãšæ¯ãèã
ãå°ãªãå€ã瀺ããŠãããå³ã¡ç²ç¶æ§ãæ¹åãã
ãŠããããšã瀺ããŠããã å®æœäŸïŒ ïŒéå±€å¹æïŒ ããªã¢ã»ããŒãããŒã¹äžã«ä»¥äžã®é åºã§éå±€å¡
åžãè¡ã€ãŠäžèšã®ïŒçš®é¡ã®è©Šæãäœæããã 第ïŒå±€ ã·ã¢ã³ã«ãã©ãŒãšããŠïŒâããããã·â
âãïŒâïŒïŒïŒïŒâãžâïœâã¢ãã«ããšãã
ã·ïŒããã«ãâïŒâãããã¢ãã10.6ïœãå®æœ
äŸ(1)ãšåæ§ã«åæ£ããèµ€ææ§æ²èåéä¹³å€
ïŒ3.0ã¢ã«ïŒ æ²åéå«æïŒïŒKgã«æ·»å å¡åžä¹Ÿç¥ã
ãã 第ïŒå±€ ãŒã©ãã³0.5ïœïŒm2ããã³ïŒïŒïŒâtert
âãžãªã¯ãã«ãã€ããããã³0.1ïœïŒm2ãå«æ
ãããŒã©ãã³äžéå±€ã 第ïŒå±€ å®æœäŸïŒã«ãããã®ãšåæ§ãªïŒçš®é¡ã®ç·
ææ§æ²èåéä¹³å€å±€ã å®æœäŸ(1)ã®è©Šæ(1)ïŒ(2)ïŒ(3)ïŒ(4)ããã³(5)ã«å¯Ÿå¿
ããè©Šæãããããè©Šæ(6)ïŒ(7)ïŒ(8)ïŒ(9)ããã³(10)
ãšããã åè©Šæãç·è²å ã§ãŠãšããžãä»ããŠé²å ããåŸ
ã«ãèµ€è²å ã®é²å ã®ã¿ã§ã¯èµ€æ¿åºŠã2.0ãšãªãã
ããªé²å éã§èµ€è²å ãåäžé²å ããåŸã«å®æœäŸ(1)
ãšåæ§ã«çŸååŠçããã åŸãããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šãããDIRååç©ãå«æããè©Šæ(7)ïŒ
(8)ïŒ(9)ããã³(10)ã®æ床ãã¬ã³ãã¯ã»ãŒåäžã§ã
ãã äžæ¹ãèµ€æ¿åºŠã¯ãŠãšããžãä»ããªãã§é²å ãã
ã®ã§ããããæ¬æ¥ã¯2.0ã®ã¯ãã§ããããçŸåæ
ã®éå±€å¹æãããããã€ã³ã¿ãŒã€ã¡ãŒãžãšããšã¯
ãïŒä»¥äžIIEãšç¥èšããïŒã®ããã«ç·æå±€ã§çŸå
ãããæ¿åºŠã«å¿ããŠèµ€æå±€ã®çŸåãæå¶ãããŠèµ€
æ¿åºŠãD1ã«äœäžããã ç·è²æ¿åºŠãæ倧ã®ãšãã®èµ€æ¿åºŠãD1ãšãããš
IIEã®åŒ·ããÎïŒïŒ2.0âD1ïŒïŒ2.0ã§è¡šãããã
å³ã¡Îã®å€ã倧ãããã°IIEã¯åŒ·ããè²çŽåºŠã
é«ããããšãã§ãããå³ã¡ãæ¬çºæè©Šæ(8)ïŒ(9)ã¯
æ¯èŒè©Šæ(6)ã«æ¯ãã倧ããªIIEã瀺ããŠããããš
ããããã å®æœäŸ ïŒ ã·ã¢ã³ã«ãã©ãŒãšããŠïŒâããããã·ââ
ãïŒâïŒïŒïŒïŒâãžâïœâã¢ãã«ããšããã·ïŒãã
ã«ãâïŒâãããã¢ãã10.6ïœããã³ç¬¬ïŒè¡šã«ç€º
ãDIRååç©ãå®æœäŸïŒãšåæ§ã«ããŠç·ææ§æ²è
åéä¹³å€ã«åæ£ãå¡åžãè©Šæ11ïŒ12ããã³13ãäœ
æããã  äŸç€ºååç©ïŒ€â67ïŒã¿ã€ãã³ã°åºãå«æããª
ãDIRååç©ïŒ  äŸç€ºååç©ïŒŽâ35ïŒã¿ã€ãã³ã°åºãæãã
DIRååç©ïŒ
(8)ïŒ(9)ããã³(10)ã®æ床ãã¬ã³ãã¯ã»ãŒåäžã§ã
ãã äžæ¹ãèµ€æ¿åºŠã¯ãŠãšããžãä»ããªãã§é²å ãã
ã®ã§ããããæ¬æ¥ã¯2.0ã®ã¯ãã§ããããçŸåæ
ã®éå±€å¹æãããããã€ã³ã¿ãŒã€ã¡ãŒãžãšããšã¯
ãïŒä»¥äžIIEãšç¥èšããïŒã®ããã«ç·æå±€ã§çŸå
ãããæ¿åºŠã«å¿ããŠèµ€æå±€ã®çŸåãæå¶ãããŠèµ€
æ¿åºŠãD1ã«äœäžããã ç·è²æ¿åºŠãæ倧ã®ãšãã®èµ€æ¿åºŠãD1ãšãããš
IIEã®åŒ·ããÎïŒïŒ2.0âD1ïŒïŒ2.0ã§è¡šãããã
å³ã¡Îã®å€ã倧ãããã°IIEã¯åŒ·ããè²çŽåºŠã
é«ããããšãã§ãããå³ã¡ãæ¬çºæè©Šæ(8)ïŒ(9)ã¯
æ¯èŒè©Šæ(6)ã«æ¯ãã倧ããªIIEã瀺ããŠããããš
ããããã å®æœäŸ ïŒ ã·ã¢ã³ã«ãã©ãŒãšããŠïŒâããããã·ââ
ãïŒâïŒïŒïŒïŒâãžâïœâã¢ãã«ããšããã·ïŒãã
ã«ãâïŒâãããã¢ãã10.6ïœããã³ç¬¬ïŒè¡šã«ç€º
ãDIRååç©ãå®æœäŸïŒãšåæ§ã«ããŠç·ææ§æ²è
åéä¹³å€ã«åæ£ãå¡åžãè©Šæ11ïŒ12ããã³13ãäœ
æããã  äŸç€ºååç©ïŒ€â67ïŒã¿ã€ãã³ã°åºãå«æããª
ãDIRååç©ïŒ  äŸç€ºååç©ïŒŽâ35ïŒã¿ã€ãã³ã°åºãæãã
DIRååç©ïŒ
ãè¡šã
è©Šæ(11)ïŒ(12)ïŒïŒ13ïŒãå®æœäŸïŒãšåæ§ã«åŠçã
ããåŸãããçµæã第ïŒè¡šã«ç€ºãã
ããåŸãããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šãããæ¬çºæã«ä¿ãååç©ãçµåãããŠ
çšããããšã«ããããããåç¬ã«äœ¿çšããå Žåã
ããèããMTFå€ã倧ãããªãããšå³ã¡ãç»å
ã®é®®é床ãèããåäžããããšããããã å®æœäŸ ïŒ ã€ãšããŒã«ãã©ãŒãšããŠÎ±âãããã€ã«âïŒâ
ãγâïŒïŒïŒïŒâãžâïœâã¢ãã«ããšããã·ïŒâã
ãã«ã¢ãããâïŒâã¯ããã¢ã»ãã¢ãã©ã€ã12.7
ïœãšäžèšDIRååç©ïŒ¥ïŒïŒŠãäžèšç¬¬ïŒè¡šã«èšèŒã
ãæ·»å éã«åŸã€ãŠæ·»å ããå®æœäŸïŒãšåæ§ã«å¡åž
也ç¥ãè©ŠæïŒ14ïŒïŒïŒ15ïŒïŒïŒ16ïŒãäœè£œããã  äŸç€ºååç©ïŒ€â69ïŒã¿ã€ãã³ã°åºãæããªã
DIRååç©ïŒ  äŸç€ºååç©ïŒŽâïŒïŒã¿ã€ãã³ã°åºãæãã
DIRååç©ïŒ
çšããããšã«ããããããåç¬ã«äœ¿çšããå Žåã
ããèããMTFå€ã倧ãããªãããšå³ã¡ãç»å
ã®é®®é床ãèããåäžããããšããããã å®æœäŸ ïŒ ã€ãšããŒã«ãã©ãŒãšããŠÎ±âãããã€ã«âïŒâ
ãγâïŒïŒïŒïŒâãžâïœâã¢ãã«ããšããã·ïŒâã
ãã«ã¢ãããâïŒâã¯ããã¢ã»ãã¢ãã©ã€ã12.7
ïœãšäžèšDIRååç©ïŒ¥ïŒïŒŠãäžèšç¬¬ïŒè¡šã«èšèŒã
ãæ·»å éã«åŸã€ãŠæ·»å ããå®æœäŸïŒãšåæ§ã«å¡åž
也ç¥ãè©ŠæïŒ14ïŒïŒïŒ15ïŒïŒïŒ16ïŒãäœè£œããã  äŸç€ºååç©ïŒ€â69ïŒã¿ã€ãã³ã°åºãæããªã
DIRååç©ïŒ  äŸç€ºååç©ïŒŽâïŒïŒã¿ã€ãã³ã°åºãæãã
DIRååç©ïŒ
ãè¡šã
åŸãããè©Šæãå®æœäŸïŒãšåæ§ã«é²å
ïŒçŸåã
ããåŸãããçµæã第ïŒè¡šã«ç€ºãã
ããåŸãããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šããæãããªããã«ãæ¬çºæã«ä¿ãåå
ç©ãçµåããŠçšããããšã«ãããããããåç¬ã«
䜿çšããå ŽåãããèããMTFå€ã倧ãããªã
ããšãå³ã¡ç»åã®é®®é床ãèããåäžããã
ç©ãçµåããŠçšããããšã«ãããããããåç¬ã«
䜿çšããå ŽåãããèããMTFå€ã倧ãããªã
ããšãå³ã¡ç»åã®é®®é床ãèããåäžããã
Claims (1)
- ïŒ æ¯æäœäžã®ããã²ã³åéä¹³å€å±€äžã«ãçºè²çŸ
象䞻è¬ã®é žåäœãšã«ãããªã³ã°ãããæåãšè©²é ž
åäœãšã«ãããªã³ã°ããŠæŸåºãããŠçŸè±¡æå¶å€ãš
ãªãåºãšãæãã該ã«ãããªã³ã°ãããæåãšè©²
æå¶å€ãšãªãåºãšã®éã«ã¿ã€ãã³ã°åºãæããå
åç©ããã³çºè²çŸåäž»è¬ã®é žåäœãšã«ãããªã³ã°
ãããæåãšè©²é žåäœãšã«ãããªã³ã°ããŠæŸåºã
ããçŸåæå¶å€ãšãªãåºãšãæãã該ã«ãããªã³
ã°ãããæåãšè©²æå¶å€ãšã®éã«ã¿ã€ãã³ã°åºã
æããªãååç©ãå«æããããšãç¹åŸŽãšãããã
ã²ã³åéã«ã©ãŒåçæå ææã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4099780A JPS56137353A (en) | 1980-03-29 | 1980-03-29 | Multilayered color photographic sensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4099780A JPS56137353A (en) | 1980-03-29 | 1980-03-29 | Multilayered color photographic sensitive material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56137353A JPS56137353A (en) | 1981-10-27 |
| JPS6257985B2 true JPS6257985B2 (ja) | 1987-12-03 |
Family
ID=12596058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4099780A Granted JPS56137353A (en) | 1980-03-29 | 1980-03-29 | Multilayered color photographic sensitive material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56137353A (ja) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58100847A (ja) * | 1981-12-12 | 1983-06-15 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©ãŒåçæå ææ |
| JPS58111941A (ja) * | 1981-12-16 | 1983-07-04 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPS58132233A (ja) * | 1982-01-30 | 1983-08-06 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPS58140740A (ja) * | 1982-02-15 | 1983-08-20 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
| JPS58154844A (ja) * | 1982-02-27 | 1983-09-14 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| AU568488B2 (en) * | 1982-02-24 | 1988-01-07 | Konishiroku Photo Industry Co., Ltd. | Light-sensitive silver halide colour photographic material |
| JPS5990848A (ja) * | 1982-11-16 | 1984-05-25 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
| JPS59149359A (ja) * | 1983-02-15 | 1984-08-27 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
| JPS61255342A (ja) | 1985-05-09 | 1986-11-13 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPH0619528B2 (ja) * | 1986-06-19 | 1994-03-16 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3703375A (en) * | 1968-04-01 | 1972-11-21 | Eastman Kodak Co | Photographic processes and materials |
| DE2322165A1 (de) * | 1972-05-02 | 1973-11-08 | Eastman Kodak Co | Farbphotographisches aufzeichnungsmaterial |
| US3892572A (en) * | 1973-06-29 | 1975-07-01 | Fuji Photo Film Co Ltd | Multilayer color photographic material |
| JPS51146828A (en) * | 1975-06-11 | 1976-12-16 | Fuji Photo Film Co Ltd | Photographic colour coupler |
| GB1460991A (en) * | 1973-05-04 | 1977-01-06 | Fuji Photo Film Co Ltd | Multi-layer colour photographic light-sensitive materials |
| JPS54145135A (en) * | 1977-12-23 | 1979-11-13 | Eastman Kodak Co | Novel photographic coupler and photographic element using same coupler and method of using same |
-
1980
- 1980-03-29 JP JP4099780A patent/JPS56137353A/ja active Granted
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3703375A (en) * | 1968-04-01 | 1972-11-21 | Eastman Kodak Co | Photographic processes and materials |
| DE2322165A1 (de) * | 1972-05-02 | 1973-11-08 | Eastman Kodak Co | Farbphotographisches aufzeichnungsmaterial |
| GB1460991A (en) * | 1973-05-04 | 1977-01-06 | Fuji Photo Film Co Ltd | Multi-layer colour photographic light-sensitive materials |
| US3892572A (en) * | 1973-06-29 | 1975-07-01 | Fuji Photo Film Co Ltd | Multilayer color photographic material |
| JPS51146828A (en) * | 1975-06-11 | 1976-12-16 | Fuji Photo Film Co Ltd | Photographic colour coupler |
| JPS54145135A (en) * | 1977-12-23 | 1979-11-13 | Eastman Kodak Co | Novel photographic coupler and photographic element using same coupler and method of using same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56137353A (en) | 1981-10-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0336205B2 (ja) | ||
| JP2630432B2 (ja) | æ°èŠãªã·ã¢ã³ã«ãã©ãŒãå«æããããã²ã³åéã«ã©ãŒåçæå ææ | |
| JPH0369090B2 (ja) | ||
| US4490459A (en) | Multi-layered color photo-sensitive material | |
| JPS6257985B2 (ja) | ||
| JPH05694B2 (ja) | ||
| JPS6356970B2 (ja) | ||
| JPH0440701B2 (ja) | ||
| JPH0614176B2 (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPH0123777B2 (ja) | ||
| EP0174871A2 (en) | Silver halide color photographic material | |
| JPS6358347B2 (ja) | ||
| JPH0454938B2 (ja) | ||
| JPH0415933B2 (ja) | ||
| JPH0341816B2 (ja) | ||
| JPH0439064B2 (ja) | ||
| JP2566393B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH0434733B2 (ja) | ||
| JPH037098B2 (ja) | ||
| JPH0640208B2 (ja) | å€å±€ã«ã©âåçææ | |
| JPS6349216B2 (ja) | ||
| JP2613371B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH044579B2 (ja) | ||
| JPS6358346B2 (ja) | ||
| JPH05693B2 (ja) |