JPS60127327A - 水中油型ポリオルガノシロキサンエマルジョン及びその製造方法 - Google Patents
水中油型ポリオルガノシロキサンエマルジョン及びその製造方法Info
- Publication number
- JPS60127327A JPS60127327A JP59217223A JP21722384A JPS60127327A JP S60127327 A JPS60127327 A JP S60127327A JP 59217223 A JP59217223 A JP 59217223A JP 21722384 A JP21722384 A JP 21722384A JP S60127327 A JPS60127327 A JP S60127327A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- polyol
- water
- emulsion
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 176
- 239000000839 emulsion Substances 0.000 title claims description 106
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000003921 oil Substances 0.000 claims description 182
- 239000004094 surface-active agent Substances 0.000 claims description 139
- 239000004530 micro-emulsion Substances 0.000 claims description 113
- 150000003077 polyols Chemical class 0.000 claims description 91
- 229920005862 polyol Polymers 0.000 claims description 90
- -1 amine salt Chemical class 0.000 claims description 89
- 239000002245 particle Substances 0.000 claims description 65
- 239000000203 mixture Substances 0.000 claims description 61
- 239000012141 concentrate Substances 0.000 claims description 60
- 238000000034 method Methods 0.000 claims description 40
- 239000000463 material Substances 0.000 claims description 21
- 239000004215 Carbon black (E152) Substances 0.000 claims description 18
- 229930195733 hydrocarbon Natural products 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 15
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- 239000010703 silicon Substances 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 9
- 125000001424 substituent group Chemical group 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 8
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical group [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 claims description 7
- 150000001408 amides Chemical class 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000002356 single layer Substances 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 235000011007 phosphoric acid Nutrition 0.000 claims description 4
- 150000001721 carbon Chemical group 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 150000003871 sulfonates Chemical class 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims 2
- 235000021317 phosphate Nutrition 0.000 claims 2
- 150000007942 carboxylates Chemical class 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical group [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Chemical group 0.000 claims 1
- 150000003254 radicals Chemical group 0.000 description 68
- 229920002545 silicone oil Polymers 0.000 description 39
- 229920001296 polysiloxane Polymers 0.000 description 31
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 25
- 238000007792 addition Methods 0.000 description 21
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 21
- 238000002360 preparation method Methods 0.000 description 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 19
- 125000004432 carbon atom Chemical group C* 0.000 description 15
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 12
- 239000002736 nonionic surfactant Substances 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- 230000008719 thickening Effects 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 8
- 125000005647 linker group Chemical group 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
- 238000010790 dilution Methods 0.000 description 7
- 239000012895 dilution Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- PLFJWWUZKJKIPZ-UHFFFAOYSA-N 2-[2-[2-(2,6,8-trimethylnonan-4-yloxy)ethoxy]ethoxy]ethanol Chemical compound CC(C)CC(C)CC(CC(C)C)OCCOCCOCCO PLFJWWUZKJKIPZ-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000002562 thickening agent Substances 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- 229920004896 Triton X-405 Polymers 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000003093 cationic surfactant Substances 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 229910000077 silane Inorganic materials 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 3
- CSHOPPGMNYULAD-UHFFFAOYSA-N 1-tridecoxytridecane Chemical class CCCCCCCCCCCCCOCCCCCCCCCCCCC CSHOPPGMNYULAD-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- BEBAMNMBVKVURW-UHFFFAOYSA-N [ClH]1OCCCC1 Chemical compound [ClH]1OCCCC1 BEBAMNMBVKVURW-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000001257 hydrogen Chemical group 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 239000004147 Sorbitan trioleate Substances 0.000 description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229920004893 Triton X-165 Polymers 0.000 description 2
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001734 carboxylic acid salts Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 229910001651 emery Inorganic materials 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 150000003139 primary aliphatic amines Chemical class 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- BTJYKXPSPBJJDQ-UHFFFAOYSA-M sodium;1,4-bis(4-methylpentan-2-yloxy)-1,4-dioxobutane-2-sulfonate Chemical group [Na+].CC(C)CC(C)OC(=O)CC(S([O-])(=O)=O)C(=O)OC(C)CC(C)C BTJYKXPSPBJJDQ-UHFFFAOYSA-M 0.000 description 2
- 235000019337 sorbitan trioleate Nutrition 0.000 description 2
- 229960000391 sorbitan trioleate Drugs 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- YHBHQYRDAVETGQ-UHFFFAOYSA-N triton x 100 Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCCCCCCCCCO)C=C1 YHBHQYRDAVETGQ-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- RRPZHYWZRCTYBG-UHFFFAOYSA-N 18,18-dimethylnonadecan-1-amine Chemical compound CC(C)(C)CCCCCCCCCCCCCCCCCN RRPZHYWZRCTYBG-UHFFFAOYSA-N 0.000 description 1
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 1
- VYKGZYAKGHXTNC-UHFFFAOYSA-N 2-nonyl-2-phenyloxirane Chemical compound C=1C=CC=CC=1C1(CCCCCCCCC)CO1 VYKGZYAKGHXTNC-UHFFFAOYSA-N 0.000 description 1
- IYTZGAKTRXBTAI-UHFFFAOYSA-N 2-octadecylphenol;oxirane Chemical compound C1CO1.CCCCCCCCCCCCCCCCCCC1=CC=CC=C1O IYTZGAKTRXBTAI-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
- PBXYLMVLLSYZLN-UHFFFAOYSA-N 5beta-Ranol Natural products OC1CC2CC(O)CCC2(C)C2C1C1CCC(C(CCC(O)CCO)C)C1(C)C(O)C2 PBXYLMVLLSYZLN-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 125000006519 CCH3 Chemical group 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000238558 Eucarida Species 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910006127 SO3X Inorganic materials 0.000 description 1
- 229920004897 Triton X-45 Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 125000004799 bromophenyl group Chemical group 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- BASWCTFTZHOACJ-UHFFFAOYSA-L dipotassium;dodecylbenzene;sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1 BASWCTFTZHOACJ-UHFFFAOYSA-L 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- KBNXRWJNZDNESS-UHFFFAOYSA-N dodecan-1-ol;oxirane Chemical compound C1CO1.CCCCCCCCCCCCO KBNXRWJNZDNESS-UHFFFAOYSA-N 0.000 description 1
- DGSVFNZUDLUORY-UHFFFAOYSA-N dodecanoic acid;oxirane Chemical compound C1CO1.CCCCCCCCCCCC(O)=O DGSVFNZUDLUORY-UHFFFAOYSA-N 0.000 description 1
- 125000005066 dodecenyl group Chemical group C(=CCCCCCCCCCC)* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 150000002031 dolichols Chemical class 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- VPOQIALCYVGVOS-UHFFFAOYSA-N methyl(propoxy)silane Chemical compound CCCO[SiH2]C VPOQIALCYVGVOS-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- SDRIHQQYQSRQPG-UHFFFAOYSA-N octadecanoic acid;oxirane Chemical compound C1CO1.CCCCCCCCCCCCCCCCCC(O)=O SDRIHQQYQSRQPG-UHFFFAOYSA-N 0.000 description 1
- 229920002113 octoxynol Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- LFWKYFZACYOGGY-UHFFFAOYSA-N oxirane tetradecanoic acid Chemical compound C1CO1.C(CCCCCCCCCCCCC)(=O)O LFWKYFZACYOGGY-UHFFFAOYSA-N 0.000 description 1
- UWDGOZVDXHRSCU-UHFFFAOYSA-N oxirane;2-tetradecylphenol Chemical compound C1CO1.CCCCCCCCCCCCCCC1=CC=CC=C1O UWDGOZVDXHRSCU-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- LNIAEVLCVIKUGU-UHFFFAOYSA-M potassium;octadecane-1-sulfonate Chemical compound [K+].CCCCCCCCCCCCCCCCCCS([O-])(=O)=O LNIAEVLCVIKUGU-UHFFFAOYSA-M 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- PFMVLFSAAABWQD-UHFFFAOYSA-M potassium;octadecyl sulfate Chemical compound [K+].CCCCCCCCCCCCCCCCCCOS([O-])(=O)=O PFMVLFSAAABWQD-UHFFFAOYSA-M 0.000 description 1
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- RTVVXRKGQRRXFJ-UHFFFAOYSA-N sodium;2-sulfobutanedioic acid Chemical compound [Na].OC(=O)CC(C(O)=O)S(O)(=O)=O RTVVXRKGQRRXFJ-UHFFFAOYSA-N 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000008054 sulfonate salts Chemical class 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 150000004072 triols Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Colloid Chemistry (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US542639 | 1983-10-17 | ||
| US06/542,639 US4620878A (en) | 1983-10-17 | 1983-10-17 | Method of preparing polyorganosiloxane emulsions having small particle size |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4210322A Division JPH0778123B2 (ja) | 1983-10-17 | 1992-08-06 | ポリオルガノシロキサン油濃厚物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60127327A true JPS60127327A (ja) | 1985-07-08 |
| JPH058737B2 JPH058737B2 (show.php) | 1993-02-03 |
Family
ID=24164695
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59217223A Granted JPS60127327A (ja) | 1983-10-17 | 1984-10-16 | 水中油型ポリオルガノシロキサンエマルジョン及びその製造方法 |
| JP4210322A Expired - Lifetime JPH0778123B2 (ja) | 1983-10-17 | 1992-08-06 | ポリオルガノシロキサン油濃厚物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4210322A Expired - Lifetime JPH0778123B2 (ja) | 1983-10-17 | 1992-08-06 | ポリオルガノシロキサン油濃厚物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4620878A (show.php) |
| EP (1) | EP0138192B1 (show.php) |
| JP (2) | JPS60127327A (show.php) |
| KR (1) | KR910007587B1 (show.php) |
| AU (1) | AU564821B2 (show.php) |
| CA (1) | CA1250684A (show.php) |
| DE (1) | DE3475201D1 (show.php) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63125530A (ja) * | 1986-11-13 | 1988-05-28 | Shin Etsu Chem Co Ltd | オルガノポリシロキサンエマルジヨンの製造方法 |
| JPS63130512A (ja) * | 1986-11-18 | 1988-06-02 | Toray Silicone Co Ltd | 化粧料 |
| JPS63130517A (ja) * | 1986-11-04 | 1988-06-02 | ダウ コーニング コーポレーション | 整髪料組成物 |
| JPS6414378A (en) * | 1986-07-24 | 1989-01-18 | Toray Silicone Co | Fiber treatment agent |
| JPH08325456A (ja) * | 1995-04-05 | 1996-12-10 | Dow Corning Corp | ポリシロキサンエマルションの製造方法 |
| JPH11323135A (ja) * | 1998-03-20 | 1999-11-26 | Dow Corning Corp | 塩に安定なシリコ―ン含有水中油型カチオンマイクロエマルション |
| JP2002102667A (ja) * | 2000-09-29 | 2002-04-09 | Dow Corning Toray Silicone Co Ltd | 連続乳化装置および水性エマルジョンの連続的製造方法 |
| JP2016534178A (ja) * | 2013-07-26 | 2016-11-04 | ザ プロクター アンド ギャンブル カンパニー | アミノシリコーンナノエマルション |
| US9605151B2 (en) | 2012-10-23 | 2017-03-28 | Shin-Etsu Chemical Co., Ltd. | Microemulsion composition and a fiber treating agent |
| US9949520B2 (en) | 2013-05-09 | 2018-04-24 | Chuo Bohshi Co., Ltd. | Folding hat |
Families Citing this family (132)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4620878A (en) * | 1983-10-17 | 1986-11-04 | Dow Corning Corporation | Method of preparing polyorganosiloxane emulsions having small particle size |
| USRE34584E (en) | 1984-11-09 | 1994-04-12 | The Procter & Gamble Company | Shampoo compositions |
| DE3520710A1 (de) * | 1985-06-10 | 1986-12-11 | Henkel KGaA, 4000 Düsseldorf | Waschverfahren fuer empfindliche textilien |
| US4797272A (en) * | 1985-11-15 | 1989-01-10 | Eli Lilly And Company | Water-in-oil microemulsions for cosmetic uses |
| CA1328139C (en) * | 1985-12-12 | 1994-03-29 | Daniel Graiver | Methods for making polydiorganosiloxane microemulsions |
| US4999398A (en) * | 1985-12-12 | 1991-03-12 | Dow Corning Corporation | Methods for making polydiorganosiloxane microemulsions |
| US4891245A (en) * | 1986-03-21 | 1990-01-02 | Koh-I-Noor Rapidograph, Inc. | Electrophoretic display particles and a process for their preparation |
| EP0242069A3 (en) * | 1986-04-14 | 1988-08-03 | Dow Corning Corporation | Semipermeable composite membranes produced from silicone water based emulsions applied to porous substrates |
| JPS63153108A (ja) * | 1986-07-22 | 1988-06-25 | Toray Silicone Co Ltd | 離型剤 |
| US4784665A (en) * | 1986-07-24 | 1988-11-15 | Toray Silicone Co., Ltd. | Agent for the treatment of fibers |
| US4749732A (en) * | 1987-01-02 | 1988-06-07 | Dow Corning Corporation | Hair care composition containing modified aminoalkyl substituted polydiorganosiloxane |
| US4842766A (en) * | 1987-02-17 | 1989-06-27 | Dow Corning Corporation | Silane microemulsions |
| JP2538246B2 (ja) * | 1987-04-24 | 1996-09-25 | 東レ・ダウコーニング・シリコーン株式会社 | 繊維処理剤 |
| DE3723697A1 (de) * | 1987-04-24 | 1988-11-17 | Pfersee Chem Fab | Waessrige, feinteilige bis optisch klare, thermisch und mechanisch stabile silikonemulsionen, verfahren zu deren herstellung und deren verwendung |
| US4935464A (en) * | 1987-04-30 | 1990-06-19 | Toray Silicone Company Limited | Organopolysiloxane microemulsion, process for its production and application thereof |
| US4945121A (en) * | 1987-08-18 | 1990-07-31 | Koh-I-Noor Radiograph, Inc. | Thermosetting dyed latex colorant dispersions |
| GB8729489D0 (en) * | 1987-12-18 | 1988-02-03 | Dow Corning Ltd | Polyorganosiloxane emulsions |
| US4824877A (en) * | 1988-02-02 | 1989-04-25 | Dow Corning Corporation | High polymer content silicone emulsions |
| US4824890A (en) * | 1988-02-02 | 1989-04-25 | Dow Corning Corporation | Film forming silicone microemulsions |
| GB8819569D0 (en) * | 1988-08-17 | 1988-09-21 | Dow Corning Ltd | Emulsions for treating fibrous materials |
| JP2750899B2 (ja) * | 1989-06-19 | 1998-05-13 | 東レ・ダウコーニング・シリコーン株式会社 | シクロヘキシルアミノ基合有オルガノポリシロキサンマイクロエマルジョンの製造方法 |
| DE4007136A1 (de) * | 1989-08-05 | 1991-09-12 | Pfersee Chem Fab | Zusammensetzung in form einer waessrigen dispersion und verfahren zur behandlung von fasermaterialien |
| DE4026029A1 (de) * | 1989-09-07 | 1992-02-20 | Sandoz Ag | Waessrige aminopolysiloxanmikroemulsionen, deren herstellung und verwendung |
| DE3930410A1 (de) * | 1989-09-12 | 1991-03-14 | Bayer Ag | Silicon-emulsionen |
| US5145907A (en) * | 1989-09-25 | 1992-09-08 | Dow Corning Corporation | Precured silicone emulsion |
| US5017221A (en) * | 1989-12-05 | 1991-05-21 | Dow Corning Corporation | Polymethylalkylsiloxane emulsions and methods |
| FR2658094A1 (fr) * | 1990-02-14 | 1991-08-16 | Rhone Poulenc Chimie | Procede de preparation d'emulsions, du type huile dans eau, monodisperses. |
| DE4004946A1 (de) * | 1990-02-16 | 1991-08-22 | Wacker Chemie Gmbh | Feinteilige organopolysiloxanemulsionen |
| US4999120A (en) * | 1990-02-26 | 1991-03-12 | E. I. Du Pont De Nemours And Company | Aqueous emulsion finish for spandex fiber treatment comprising a polydimethyl siloxane and an ethoxylated long-chained alkanol |
| DE4010393A1 (de) * | 1990-03-30 | 1991-10-02 | Henkel Kgaa | Verfahren zur herstellung von oel-in-wasser-cremes |
| CA2041599A1 (en) | 1990-06-01 | 1991-12-02 | Michael Gee | Method for making polysiloxane emulsions |
| CA2043282A1 (en) * | 1990-06-07 | 1991-12-08 | Ronald P. Gee | Process for making polysiloxane emulsions |
| CA2042693A1 (en) * | 1990-06-07 | 1991-12-08 | Daniel J. Halloran | Silicone mechanical emulsions for hair care |
| US5258451A (en) * | 1990-06-07 | 1993-11-02 | Shin-Etsu Chemical Co., Ltd. | Method for the preparation of an aqueous emulsion of organopolysiloxane |
| US5135742A (en) * | 1990-07-06 | 1992-08-04 | Dow Corning Corporation | Hair fixatives comprising silanes containing a silsesquioxane characteristic |
| US5108738A (en) * | 1990-07-06 | 1992-04-28 | Dow Corning Corporation | Organosilicon hair care products |
| US5173201A (en) * | 1990-07-23 | 1992-12-22 | The Proctor & Gamble Company | Microemulsified amine functional silicone in liquid fabric softeners for reducing fiber-fiber and yarn-yarn friction in fabrics |
| US5071573A (en) * | 1990-07-23 | 1991-12-10 | The Procter & Gamble Company | Microemulsified silicones in liquid fabric care compositions containing dye |
| US5174912A (en) * | 1990-07-23 | 1992-12-29 | The Procter & Gamble Company | Microemulsified silicones in liquid fabric care compositions containing dye |
| US5152984A (en) * | 1990-11-20 | 1992-10-06 | Dow Corning Corporation | Hair fixatives |
| CA2068124A1 (en) * | 1991-05-24 | 1992-11-25 | Daniel J. Halloran | Optically clear hair care compositions containing amino-functional silicone microemulsions |
| DE4117864A1 (de) * | 1991-05-31 | 1992-12-03 | Pfersee Chem Fab | Waessrige dispersionen von polysiloxanen |
| US5178668A (en) * | 1991-09-06 | 1993-01-12 | General Electric Company | Aqueous water repellent compositions |
| US5556629A (en) * | 1991-09-13 | 1996-09-17 | General Electric Company | Method of preparing microemulsions |
| US5244598A (en) * | 1991-09-13 | 1993-09-14 | General Electric Company | Method of preparing amine functional silicone microemulsions |
| DE4133358A1 (de) * | 1991-10-09 | 1993-04-15 | Pfersee Chem Fab | Waessrige zusammensetzungen mit stickstoffhaltigen polysiloxanen |
| WO1993008006A1 (en) * | 1991-10-15 | 1993-04-29 | Ppg Industries, Inc. | Stable aqueous solutions containing siloxanes for treating cellulosic substrates |
| JPH07501077A (ja) * | 1991-11-22 | 1995-02-02 | リチャードソン、ビックス、インコーポレーテッド | 組合せパーソナルクレンジング及びモイスチャライジング組成物 |
| US5234495A (en) * | 1991-12-02 | 1993-08-10 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the emulsification of polydimethyl siloxane oils, organomodified siloxane oils and organic oil using non-ionic surfactants |
| US5338352A (en) * | 1991-12-02 | 1994-08-16 | Osi Specialties, Inc. | Process for the emulsification of polydimethyl siloxane oils, organomodified siloxane oils and organic oil using non-ionic surfactants |
| US5312559A (en) * | 1992-07-07 | 1994-05-17 | The Procter & Gamble Company | Personal cleanser with moisturizer |
| DE4222483A1 (de) * | 1992-07-09 | 1994-01-13 | Pfersee Chem Fab | Organosiloxane mit Stickstoff enthaltenden und mit Äthergruppierungen enthaltenden Resten |
| CA2106173A1 (en) * | 1992-09-23 | 1994-03-24 | Kalliopi S. Haley | Fabric finish stiffening composition |
| US5326483A (en) * | 1993-02-19 | 1994-07-05 | Dow Corning Corporation | Method of making clear shampoo products |
| JP3398171B2 (ja) * | 1993-03-15 | 2003-04-21 | 株式会社資生堂 | 水中油型乳化組成物 |
| DE4318794A1 (de) * | 1993-06-07 | 1994-12-08 | Pfersee Chem Fab | Substituierte 1.3.5-Triazin-Einheiten enthaltende Organopolysiloxane |
| ES2125483T3 (es) * | 1993-08-18 | 1999-03-01 | Unilever Nv | Composicion para el afeitado. |
| DE4328917A1 (de) * | 1993-08-27 | 1995-03-02 | Wacker Chemie Gmbh | Herstellung von Organopolysiloxan-Microemulsionen |
| US5518716A (en) * | 1994-03-31 | 1996-05-21 | General Electric Company | Composition and method of preparing microemulsion blends |
| US6180117B1 (en) | 1994-05-27 | 2001-01-30 | General Electric Company | Method of preparing microemulsions of amino silicone fluids and MQ resin mixtures |
| US5578298A (en) * | 1994-05-27 | 1996-11-26 | General Electric Company | Microemulsions for high viscosity amino silicone fluids and gums and their preparation |
| US5683625A (en) * | 1994-05-27 | 1997-11-04 | General Electric Company | Method of preparing microemulsions |
| DE4443825A1 (de) * | 1994-12-09 | 1996-06-13 | Huels Chemische Werke Ag | Wasserbasierende Organopolysiloxan-haltige Zusammensetzungen, Verfahren zu deren Herstellung und deren Verwendung |
| DE4443824A1 (de) * | 1994-12-09 | 1996-06-13 | Huels Chemische Werke Ag | Organopolysiloxan-haltige Zusammensetzungen auf Wasserbasis, Verfahren zu deren Herstellung sowie deren Verwendung |
| US5665374A (en) * | 1995-06-05 | 1997-09-09 | Whitehill Oral Technologies, Inc. | Ultramulsion containing interdental delivery devices |
| US5733529A (en) * | 1995-06-05 | 1998-03-31 | Whitehill Oral Technologies, Inc. | Ultramulsion based antigingivitis toothpaste compositions |
| US5711936A (en) * | 1995-06-05 | 1998-01-27 | Whitehill Oral Technologies, Inc. | Ultramulsion based ingestible compositions |
| US5645841A (en) * | 1995-06-05 | 1997-07-08 | Whitehill Oral Technologies, Inc. | Ultramulsion based oral care rinse compositions |
| US5730967A (en) * | 1995-06-05 | 1998-03-24 | Whitehill Oral Technologies, Inc. | Ultramulsion based skin care compositions |
| US5733536A (en) * | 1995-06-05 | 1998-03-31 | Whitehill Oral Technologies, Inc. | Ultramulsion based hair care compositions |
| US5651959A (en) * | 1995-06-05 | 1997-07-29 | Whitehill Oral Technologies, Inc. | Ultramulsion based oral care compositions |
| FR2742676B1 (fr) * | 1995-12-21 | 1998-02-06 | Oreal | Nanoemulsion transparente a base de tensioactifs silicones et utilisation en cosmetique ou en dermopharmacie |
| US5777026A (en) * | 1995-12-28 | 1998-07-07 | Dow Corning Corporation | Surface modified silicone elastomers from aqueous silicone emulsions |
| GB9619761D0 (en) * | 1996-09-23 | 1996-11-06 | Unilever Plc | Shampoo composition |
| US5707435A (en) * | 1996-10-16 | 1998-01-13 | Dow Corning Corporation | Ammonium siloxane emulsions and their use as fiber treatment agents |
| DE19649953A1 (de) * | 1996-12-03 | 1998-06-04 | Huels Chemische Werke Ag | Fluoralkyl-funktionelle Organopolysiloxan-haltige Zusammensetzungen auf Wasserbasis, Verfahren zu deren Herstellung sowie deren Verwendung |
| DE19652524C2 (de) * | 1996-12-17 | 2003-08-14 | Rudolf Gmbh & Co Kg Chem Fab | Organopolysiloxane enthaltende Emulsionen, deren Herstellung und Verwendung in wäßrigen Systemen |
| US5840813A (en) * | 1997-01-03 | 1998-11-24 | Dow Corning Corporation | Homopolymerization of acrylate or methacrylate endblocked polydiorganosiloxanes |
| JP2000096454A (ja) * | 1998-09-25 | 2000-04-04 | Dow Corning Toray Silicone Co Ltd | 水系繊維処理剤 |
| US6528121B2 (en) * | 1998-11-19 | 2003-03-04 | Dow Corning Toray Silicone Co., Ltd. | Aqueous treatment agent for wiping paper |
| US6451905B2 (en) * | 1999-02-16 | 2002-09-17 | Crompton Corporation | Shear stable aminosilicone emulsions |
| US6207720B1 (en) | 1999-06-25 | 2001-03-27 | Crompton Corporation | Hydrolyzable silane emulsions and method for preparing the same |
| US6106607A (en) * | 1999-09-10 | 2000-08-22 | Dow Corning Corporation | Composition for hydrophobing gypsum and methods for the preparation and use thereof |
| DE10034831A1 (de) * | 2000-07-18 | 2002-01-31 | Ciba Sc Pfersee Gmbh | Gemische von Polysiloxanemulsionen |
| US6475974B1 (en) * | 2000-09-01 | 2002-11-05 | Dow Corning Corporation | Mechanical microemulsions of blended silicones |
| US6632420B1 (en) | 2000-09-28 | 2003-10-14 | The Gillette Company | Personal care product |
| FR2818989B1 (fr) * | 2000-12-29 | 2004-03-19 | Rhodia Chimie Sa | Utilisation d'un polyorganosiloxane fonctionnalise epoxy et/ou carboxy, a titre de matiere active dans une composition silicone liquide d'hydrofugation de materiaux de construction |
| EP1264863A1 (de) * | 2001-06-08 | 2002-12-11 | Ciba Spezialitätenchemie Pfersee GmbH | Zusammensetzungen mit Polysiloxanen und weiteren Polymeren |
| US6498197B1 (en) * | 2001-07-25 | 2002-12-24 | Dow Corning Corporation | Temperature insensitive one-phase microemulsions |
| DE10139126A1 (de) | 2001-08-09 | 2003-02-20 | Ciba Sc Pfersee Gmbh | Zusammensetzungen aus Polysiloxanen, Fluorpolymeren und Extendern |
| WO2003026599A1 (en) * | 2001-09-26 | 2003-04-03 | The Procter & Gamble Company | Personal cleansing compositions comprising silicone resin-containing adhesives |
| US20030118761A1 (en) * | 2001-12-21 | 2003-06-26 | Kimberly-Clark Worldwide, Inc. | Elastomeric articles having improved chemical resistance |
| US6664299B2 (en) | 2002-02-14 | 2003-12-16 | Dow Corning Corporation | Masterbatch method for economically and efficiently producing soap dispersions in textile fluids for synthetic fiber treatment |
| DE60328365D1 (de) * | 2002-03-21 | 2009-08-27 | Ciba Holding Inc | Zusammensetzungen enthaltend nicht-vernetzte polysiloxane |
| GB0209136D0 (en) * | 2002-04-22 | 2002-05-29 | Procter & Gamble | Durable hair treatment composition |
| US6770123B2 (en) | 2002-07-23 | 2004-08-03 | Clariant Finance (Bvi) Limited | Protective coatings having branched trimethylsilylated alkylsilsesquioxane emulsions |
| AU2003302035A1 (en) * | 2002-11-04 | 2004-06-15 | Ge Bayer Silicones Gmbh And Co. Kg | Formulations used for the treatment of substrate surfaces |
| DE10253152A1 (de) | 2002-11-14 | 2004-06-03 | Rudolf Gmbh & Co. Kg Chemische Fabrik | Teilquaternierte, aminofunktionelle Organopolysiloxane und deren Verwendung in wässrigen Systemen |
| US20040110870A1 (en) * | 2002-12-04 | 2004-06-10 | Liu Matthew T. | Fire protection coating composition |
| US6737444B1 (en) * | 2003-01-16 | 2004-05-18 | Dow Corning Corporation | Method of making silicone resin emulsions |
| US7052642B2 (en) | 2003-06-11 | 2006-05-30 | Kimberly-Clark Worldwide, Inc. | Composition for forming an elastomeric article |
| US8012544B2 (en) | 2003-10-08 | 2011-09-06 | Dow Corning Corporation | Silicone MQ resin reinforced silicone elastomer emulsions |
| JP4516310B2 (ja) * | 2003-12-26 | 2010-08-04 | ライオン株式会社 | 変性シリコーンエマルション及びその製造方法、並びに衣料用柔軟仕上げ剤 |
| EP1591102A1 (en) * | 2004-04-30 | 2005-11-02 | The Procter & Gamble Company | Process and kit-of-parts for improved hair conditioning after coloring, bleaching or perming |
| JP2008516923A (ja) * | 2004-10-15 | 2008-05-22 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | アミノ官能性ポリオルガノシロキサンを含むヘアケア配合物 |
| JP2008534714A (ja) * | 2005-03-22 | 2008-08-28 | バイオセーフ インク． | 優れた持続性の抗菌特性を有する、無溶媒のシリコン含有第４級アンモニウムを含むポリマー抗菌剤の作製法 |
| GB0518059D0 (en) * | 2005-09-06 | 2005-10-12 | Dow Corning | Delivery system for releasing active ingredients |
| JP4972317B2 (ja) * | 2006-01-23 | 2012-07-11 | 富士フイルム株式会社 | インク組成物、インクセット、記録方法及びそれによる記録物 |
| US20080095727A1 (en) * | 2006-10-19 | 2008-04-24 | L'oreal | Aqueous systems containing fatty monoamine, surfactant and phosphate ester for water- insoluble materials |
| WO2008085713A1 (en) * | 2007-01-05 | 2008-07-17 | Xo Armor, Lp | Chemical composition and method of applying same to enhance the adhesive bonding of glass laminates |
| EP2276796B1 (en) * | 2008-04-14 | 2012-12-05 | Dow Corning Corporation | Emulsions of boron crosslinked organopolysiloxanes and their use in personal care compositions |
| EP2276818B1 (en) * | 2008-04-14 | 2013-03-13 | Dow Corning Corporation | Emulsions of boron crosslinked organopolysiloxanes |
| JP2011517725A (ja) * | 2008-04-14 | 2011-06-16 | ダウ・コーニング・コーポレイション | ダイラタント・オルガノポリシロキサンのエマルジョン |
| WO2009128883A1 (en) * | 2008-04-16 | 2009-10-22 | Dow Corning Corporation | Preparation of silicone microemulsions |
| GB0811302D0 (en) * | 2008-06-20 | 2008-07-30 | Dow Corning | Shampoo compositions |
| WO2011042409A2 (en) | 2009-10-05 | 2011-04-14 | Momentive Performance Materials Gmbh | Aqueous emulsions of polyorganosiloxanes |
| JP5702926B2 (ja) * | 2009-10-16 | 2015-04-15 | 東レ・ダウコーニング株式会社 | 拭取り紙用処理剤組成物 |
| CN102199352A (zh) * | 2010-03-25 | 2011-09-28 | 日照岚星化工工业有限公司 | 一种水溶性有机硅乳液脱模剂的制备方法 |
| US20110274627A1 (en) | 2010-05-06 | 2011-11-10 | Ali Abdelaziz Alwattari | Method Of Making An Aerosol Shave Composition Comprising A Hydrophobical Agent Forming At Least One Microdroplet |
| US20110272320A1 (en) | 2010-05-06 | 2011-11-10 | Ali Abdelaziz Alwattari | Aerosol Shave Composition Comprising A Hydrophobical Agent Forming At Least One Microdroplet |
| DE102011078382A1 (de) | 2011-06-30 | 2013-01-03 | Evonik Goldschmidt Gmbh | Mikroemulsion von quaternären Ammoniumgruppen enthaltenden Polysiloxanen, derenHerstellung und Verwendung |
| WO2013025891A1 (en) | 2011-08-16 | 2013-02-21 | The Gillette Company | An aerosol shave composition comprising a hydrophobical agent forming at least one microdroplet and an anti-irritation agent |
| WO2013082112A1 (en) | 2011-11-29 | 2013-06-06 | Dow Corning Corporation | Aminofunctional silicone emulsions |
| EP2906194B1 (en) | 2012-10-11 | 2018-06-06 | Dow Corning Corporation | Aqueous silicone polyether microemulsions |
| WO2014143728A1 (en) | 2013-03-15 | 2014-09-18 | Dow Corning Corporation | Cosmetic compositions containing silicone resin emulsions |
| USRE49528E1 (en) | 2013-04-26 | 2023-05-16 | Biointeractions Ltd. | Bioactive coatings |
| US10206945B2 (en) | 2013-04-26 | 2019-02-19 | Biointeractions Ltd. | Bioactive coatings |
| US9717676B2 (en) | 2013-07-26 | 2017-08-01 | The Procter & Gamble Company | Amino silicone nanoemulsion |
| EP2980125B1 (en) * | 2014-07-28 | 2017-06-14 | Wacker Chemie AG | Process for making an aminosiloxane polymer nanoemulsion |
| WO2016123002A1 (en) | 2015-01-28 | 2016-08-04 | The Procter & Gamble Company | Silicone nanoemulsion comprising c3-c6 alkylene glycol alkyl ether |
| DE102016207060A1 (de) * | 2016-04-26 | 2017-10-26 | Wacker Chemie Ag | Wässrige Emulsionen aus Carbamato-funktionalisierten Organopolysiloxanen |
| DE102016207603A1 (de) | 2016-05-03 | 2017-11-09 | Wacker Chemie Ag | Wässrige Emulsionen enthaltend aminofunktionelle Organopolysiloxane und nicht-ionische Emulgatoren |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1191289A (en) * | 1966-08-19 | 1970-05-13 | Shinetsu Chem Ind Co | Method of Emulsifying Highly Viscous Organopolysiloxane Oils in Water |
| US3975294A (en) * | 1972-11-03 | 1976-08-17 | Rhone-Poulenc S.A. | Surface active composition |
| US4052331A (en) * | 1972-11-03 | 1977-10-04 | Rhone-Poulenc S.A. | Surface active composition |
| JPS53119955A (en) * | 1977-03-28 | 1978-10-19 | Toshiba Silicone | Silicone emulsion composition |
| GB2036052A (en) * | 1978-11-08 | 1980-06-25 | Dow Corning Ltd | Organosilicon Polymers |
| JPS57111354A (en) * | 1980-12-29 | 1982-07-10 | Toray Silicone Co Ltd | Organopolysiloxane composition |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1338009A (fr) * | 1961-10-13 | 1963-09-20 | Bayer Ag | Nouvelles émulsions d'huiles d'organopolysiloxanes stables à la dilution |
| NL133796C (show.php) * | 1965-01-21 | 1900-01-01 | ||
| US4146499A (en) * | 1976-09-18 | 1979-03-27 | Rosano Henri L | Method for preparing microemulsions |
| DE2730923C3 (de) * | 1977-07-08 | 1981-10-22 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von wäßrigen feindispersen, lagerstabilen Polysiloxanolemulsionen |
| JPS597832B2 (ja) * | 1979-05-17 | 1984-02-21 | ト−レ・シリコ−ン株式会社 | 繊維処理剤 |
| CA1211595A (en) * | 1980-07-01 | 1986-09-16 | General Electric Company | Transparent silicone emulsions |
| GB2092608B (en) * | 1981-01-28 | 1985-02-27 | Gen Electric | Water-based resin emulsions |
| JPS5857459A (ja) * | 1981-10-01 | 1983-04-05 | Nippon Saafuakutanto Kogyo Kk | 自己乳化性シリコ−ン組成物 |
| US4620878A (en) * | 1983-10-17 | 1986-11-04 | Dow Corning Corporation | Method of preparing polyorganosiloxane emulsions having small particle size |
-
1983
- 1983-10-17 US US06/542,639 patent/US4620878A/en not_active Expired - Lifetime
-
1984
- 1984-08-22 CA CA000461507A patent/CA1250684A/en not_active Expired
- 1984-10-11 DE DE8484112174T patent/DE3475201D1/de not_active Expired
- 1984-10-11 EP EP84112174A patent/EP0138192B1/en not_active Expired
- 1984-10-16 AU AU34286/84A patent/AU564821B2/en not_active Ceased
- 1984-10-16 JP JP59217223A patent/JPS60127327A/ja active Granted
- 1984-10-17 KR KR1019840006440A patent/KR910007587B1/ko not_active Expired
-
1992
- 1992-08-06 JP JP4210322A patent/JPH0778123B2/ja not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1191289A (en) * | 1966-08-19 | 1970-05-13 | Shinetsu Chem Ind Co | Method of Emulsifying Highly Viscous Organopolysiloxane Oils in Water |
| US3975294A (en) * | 1972-11-03 | 1976-08-17 | Rhone-Poulenc S.A. | Surface active composition |
| US4052331A (en) * | 1972-11-03 | 1977-10-04 | Rhone-Poulenc S.A. | Surface active composition |
| JPS53119955A (en) * | 1977-03-28 | 1978-10-19 | Toshiba Silicone | Silicone emulsion composition |
| GB2036052A (en) * | 1978-11-08 | 1980-06-25 | Dow Corning Ltd | Organosilicon Polymers |
| JPS57111354A (en) * | 1980-12-29 | 1982-07-10 | Toray Silicone Co Ltd | Organopolysiloxane composition |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6414378A (en) * | 1986-07-24 | 1989-01-18 | Toray Silicone Co | Fiber treatment agent |
| JPS63130517A (ja) * | 1986-11-04 | 1988-06-02 | ダウ コーニング コーポレーション | 整髪料組成物 |
| JPS63125530A (ja) * | 1986-11-13 | 1988-05-28 | Shin Etsu Chem Co Ltd | オルガノポリシロキサンエマルジヨンの製造方法 |
| JPS63130512A (ja) * | 1986-11-18 | 1988-06-02 | Toray Silicone Co Ltd | 化粧料 |
| JPH08325456A (ja) * | 1995-04-05 | 1996-12-10 | Dow Corning Corp | ポリシロキサンエマルションの製造方法 |
| JPH11323135A (ja) * | 1998-03-20 | 1999-11-26 | Dow Corning Corp | 塩に安定なシリコ―ン含有水中油型カチオンマイクロエマルション |
| JP2002102667A (ja) * | 2000-09-29 | 2002-04-09 | Dow Corning Toray Silicone Co Ltd | 連続乳化装置および水性エマルジョンの連続的製造方法 |
| US9605151B2 (en) | 2012-10-23 | 2017-03-28 | Shin-Etsu Chemical Co., Ltd. | Microemulsion composition and a fiber treating agent |
| US9949520B2 (en) | 2013-05-09 | 2018-04-24 | Chuo Bohshi Co., Ltd. | Folding hat |
| JP2016534178A (ja) * | 2013-07-26 | 2016-11-04 | ザ プロクター アンド ギャンブル カンパニー | アミノシリコーンナノエマルション |
Also Published As
| Publication number | Publication date |
|---|---|
| AU3428684A (en) | 1985-04-26 |
| JPH058737B2 (show.php) | 1993-02-03 |
| DE3475201D1 (en) | 1988-12-22 |
| US4620878A (en) | 1986-11-04 |
| JPH0778123B2 (ja) | 1995-08-23 |
| CA1250684A (en) | 1989-02-28 |
| AU564821B2 (en) | 1987-08-27 |
| KR910007587B1 (ko) | 1991-09-28 |
| EP0138192B1 (en) | 1988-11-17 |
| JPH05186601A (ja) | 1993-07-27 |
| KR850003334A (ko) | 1985-06-17 |
| EP0138192A1 (en) | 1985-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS60127327A (ja) | 水中油型ポリオルガノシロキサンエマルジョン及びその製造方法 | |
| JP2693374B2 (ja) | オルガノポリシロキサンおよびアルキルポリグリコシドを基礎とする水性乳濁液 | |
| JP2591912B2 (ja) | オルガノポリシロキサン−マイクロエマルジョンの製造法 | |
| JP3247444B2 (ja) | アミノ官能性シリコーンミクロエマルジョンの製造法 | |
| JP4299145B2 (ja) | 水中シリコーン油型エマルション、塩、アルコール、および溶媒を含有する組成物 | |
| JPH05139941A (ja) | ポリオルガノシロキサンマイクロエマルシヨンを含有する配合物、並びにその製造及び毛髪処理方法 | |
| EP2273971B1 (en) | Oil-in-water organopolysiloxane emulsion composition, cosmetic ingredient comprising this composition, and method of producing a hair cosmetic using this composition | |
| US4501619A (en) | Aqueous emulsions of carboxyl-containing silicone fluids and a method for their preparation | |
| CN103687896B (zh) | 有机聚硅氧烷乳浊液组合物的制造方法 | |
| US5683625A (en) | Method of preparing microemulsions | |
| JP2002080603A (ja) | マイクロエマルジョンおよびその製造方法 | |
| US5518716A (en) | Composition and method of preparing microemulsion blends | |
| EP1069149B1 (en) | Emulsion containing silicone particles of large size | |
| JPH033695B2 (show.php) | ||
| WO2017038936A1 (ja) | オルガノポリシロキサンエマルション組成物の製造方法 | |
| JP3495109B2 (ja) | アミノ基含有オルガノポリシロキサンマイクロエマルジョンおよびその製造方法 | |
| JPH09316331A (ja) | 水中油型オルガノポリシロキサン乳化物及びその製造方法 | |
| JP6390798B2 (ja) | オルガノポリシロキサンエマルション組成物の製造方法 | |
| CN1330687C (zh) | 高浓度水包油聚硅氧烷乳液 | |
| JPH0873747A (ja) | アミノ基含有オルガノポリシロキサンマイクロエマルジョンおよびその製法 | |
| JP2001089316A (ja) | 化粧品原料 | |
| CN105051093B (zh) | 形成抗水解水性乳液的方法 | |
| JP6387930B2 (ja) | オルガノポリシロキサンエマルション組成物の製造方法 | |
| JPH04285665A (ja) | オルガノポリシロキサンエマルジョン組成物 |