JPS52120292A - Manufacture of paraadialkyllsubstituted benzene and catalysts therefor - Google Patents

Manufacture of paraadialkyllsubstituted benzene and catalysts therefor

Info

Publication number
JPS52120292A
JPS52120292A JP3555877A JP3555877A JPS52120292A JP S52120292 A JPS52120292 A JP S52120292A JP 3555877 A JP3555877 A JP 3555877A JP 3555877 A JP3555877 A JP 3555877A JP S52120292 A JPS52120292 A JP S52120292A
Authority
JP
Japan
Prior art keywords
paraadialkyllsubstituted
benzene
manufacture
catalysts therefor
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3555877A
Other languages
English (en)
Japanese (ja)
Other versions
JPS6247854B2 (xx
Inventor
Chin-Chiun Chu
Werner Otto Haag
David Harold Olson
Paul Gerhard Rodewald
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/672,194 external-priority patent/US4060568A/en
Priority claimed from US05/680,998 external-priority patent/US4011276A/en
Priority claimed from US05/726,091 external-priority patent/US4090981A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of JPS52120292A publication Critical patent/JPS52120292A/ja
Publication of JPS6247854B2 publication Critical patent/JPS6247854B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/34—Reaction with organic or organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP3555877A 1976-03-31 1977-03-31 Manufacture of paraadialkyllsubstituted benzene and catalysts therefor Granted JPS52120292A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US05/672,194 US4060568A (en) 1976-03-31 1976-03-31 Silica-modified zeolite catalyst and conversion therewith
US05/680,998 US4011276A (en) 1976-04-28 1976-04-28 Disproportionation of toluene
US68587276A 1976-05-12 1976-05-12
US68586976A 1976-05-12 1976-05-12
US05/726,091 US4090981A (en) 1976-09-23 1976-09-23 Catalyst for selective production of para dialkyl substituted benzenes

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP63264259A Division JPH0567613B1 (xx) 1976-03-31 1988-10-21

Publications (2)

Publication Number Publication Date
JPS52120292A true JPS52120292A (en) 1977-10-08
JPS6247854B2 JPS6247854B2 (xx) 1987-10-09

Family

ID=27542059

Family Applications (3)

Application Number Title Priority Date Filing Date
JP3555877A Granted JPS52120292A (en) 1976-03-31 1977-03-31 Manufacture of paraadialkyllsubstituted benzene and catalysts therefor
JP63264259A Pending JPH0567613B1 (xx) 1976-03-31 1988-10-21
JP63264259A Pending JPH01199920A (ja) 1976-03-31 1988-10-21 パラジアルキルベンゼンの製造法

Family Applications After (2)

Application Number Title Priority Date Filing Date
JP63264259A Pending JPH0567613B1 (xx) 1976-03-31 1988-10-21
JP63264259A Pending JPH01199920A (ja) 1976-03-31 1988-10-21 パラジアルキルベンゼンの製造法

Country Status (12)

Country Link
JP (3) JPS52120292A (xx)
BE (1) BE852865A (xx)
CS (1) CS218565B2 (xx)
DE (3) DE2760479C2 (xx)
FR (1) FR2357303A1 (xx)
GB (1) GB1574523A (xx)
IT (1) IT1075368B (xx)
NL (1) NL187424C (xx)
NO (1) NO149492C (xx)
NZ (1) NZ183608A (xx)
PL (1) PL115528B1 (xx)
SE (1) SE438606B (xx)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54122692A (en) * 1978-02-20 1979-09-22 Shell Int Research Hydrocarbon oil catalytic decomposition and decomposition catalyst
JPS55102440A (en) * 1979-01-31 1980-08-05 Mobil Oil Preparation of thermal stability* shape selective catalyst composition and hydrocarbon inverting method which use said composition
JPS5660644A (en) * 1979-10-12 1981-05-25 Mobil Oil Method of lengthening effective life of para selective denatured zeolite catalyst
JPS56133223A (en) * 1980-03-10 1981-10-19 Mobil Oil Corp Conversion of organic compound by alkali earth metal denatured zeolite catalyst
JPS56145227A (en) * 1980-04-07 1981-11-11 Mobil Oil Corp Conversion of organic compound by iv b group metal denatured zeolite catalyst
JPS5711927A (en) * 1980-05-19 1982-01-21 Mobil Oil Corp Conversion of organic compound using iron and/or cobalt-denatured zeolite catalyst
JPS57108023A (en) * 1980-12-26 1982-07-05 Toa Nenryo Kogyo Kk Oligomerization catalyst for isobutene
JPS5892461A (ja) * 1981-11-13 1983-06-01 アモコ　コーポレーション 水素処理、水添分解用触媒組成物及びその製法
JPS5931718A (ja) * 1982-08-17 1984-02-20 Toray Ind Inc パラジアルキルベンゼンの選択的製造法
JPS59107921A (ja) * 1982-12-10 1984-06-22 Idemitsu Kosan Co Ltd ｐ―キシレンの製造方法
JPS61221137A (ja) * 1985-03-28 1986-10-01 Teijin Yuka Kk Ｐ−キシレンの製造法
JPS6263528A (ja) * 1985-09-17 1987-03-20 Teijin Yuka Kk Ｐ−キシレンの製造法
JPS62115088A (ja) * 1985-11-13 1987-05-26 Res Assoc Util Of Light Oil 芳香族炭化水素の製造方法
JPS63274454A (ja) * 1987-04-08 1988-11-11 タイワン・スチアリ−ン・モノマ−・コ−ポレイシヨン 新規なＳｉ／ＨＺＳＭ−５触媒及びその製造方法並びに該触媒を利用するモノアルキルベンゼンからの高純度ｐ−ジアルキルベンゼンの合成方法
JPH01125333A (ja) * 1987-09-02 1989-05-17 Mobil Oil Corp トルエンの蒸気相不均化方法
JPH0567613B1 (xx) * 1976-03-31 1993-09-27 Mobil Oil
JPH0880438A (ja) * 1994-09-12 1996-03-26 Toray Ind Inc パラジアルキルベンゼンの製造用触媒及びその製造法及びパラキシレンを製造する方法
JPH10502330A (ja) * 1994-04-04 1998-03-03 モービル・オイル・コーポレイション 高純度パラキシレン供給原料からのパラキシレンの結晶化
JP2007517030A (ja) * 2003-12-31 2007-06-28 エクソンモービル・ケミカル・パテンツ・インク 芳香族のアルキル化プロセス
JP2010208948A (ja) * 2009-03-06 2010-09-24 Mitsui Chemicals Inc 芳香族炭化水素の製造方法およびその製造方法に使用される触媒

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL199748A1 (pl) * 1976-07-19 1978-04-24 Mobil Oil Corp Sposob selektywnego wytwarzania p-dwualkilobenzenow
US4104319A (en) * 1977-06-23 1978-08-01 Mobil Oil Corporation Ethylation of mono alkyl benzene
US4117024A (en) * 1977-07-29 1978-09-26 Mobil Oil Corporation Ethylation of aromatic compounds
FR2442881A2 (fr) * 1978-11-29 1980-06-27 Shell France Procede de craquage catalytique d'hydrocarbures, et catalyseur pour la mise en oeuvre du procede
US4357264A (en) 1980-03-10 1982-11-02 Mobil Oil Corporation Alkaline earth metal modified zeolite catalysts
EP0134076B1 (en) * 1983-08-19 1988-10-26 Mobil Oil Corporation A process for preparing a coked zeolite catalyst and a process for the selective disproportionation of toluene using said catalyst
ZA845190B (en) * 1983-08-19 1986-02-26 Mobil Oil Corp A process for preparing a coked zeolite catalyst and a process for the selective disproportionation of toluene using said catalyst
US4613717A (en) * 1984-06-25 1986-09-23 Research Association For Utilization Of Light Oil Process for producing a 1,4-dialkylbenzene
US4902841A (en) * 1987-03-11 1990-02-20 Nippon Petrochemicals Company, Ltd. Method for producing electrical insulating oil composition
JPH0788319B2 (ja) * 1987-09-09 1995-09-27 日本石油化学株式会社 ｍ−ベンジルトルエンの製造方法
JPH0810566B2 (ja) * 1988-03-09 1996-01-31 日本石油化学株式会社 改良された留分からなる電気絶縁油
US5109032A (en) * 1989-03-22 1992-04-28 Matsushita Refrigeration Co. Foamed heat insulation material
SG43877A1 (en) * 1989-12-13 1997-11-14 Mobil Oil Corp A process for the catalytic converson of a c9+ aromatics feed
DE19538799A1 (de) * 1995-10-18 1997-04-24 Sued Chemie Ag Wabenförmiger Katalysatorträger
US6316683B1 (en) * 1999-06-07 2001-11-13 Exxonmobil Chemical Patents Inc. Protecting catalytic activity of a SAPO molecular sieve
US6709570B1 (en) * 1999-09-27 2004-03-23 Shell Oil Company Method for preparing a catalyst
US7049260B2 (en) * 2003-06-03 2006-05-23 Chevron Phillips Chemical Company Lp Selective para-xylene production via methylation of toluene with methanol in the presence of modified HZSM-5 catalyst

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US2722504A (en) * 1950-12-04 1955-11-01 Union Oil Co Silicone coated catalyst and use thereof
US3417157A (en) * 1967-12-28 1968-12-17 Universal Oil Prod Co Transalkylation of toluene and catalyst therefor
US3525775A (en) * 1968-03-29 1970-08-25 Union Carbide Corp Catalytic xylene isomerization process and catalyst therefor
US3651162A (en) * 1969-02-27 1972-03-21 Standard Oil Co Isomerization and disproportionation of alkyl aromatics
US3658696A (en) * 1969-06-17 1972-04-25 Texaco Inc Selected adsorption with a silanized crystalline alumino-silicate
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3790471A (en) * 1969-10-10 1974-02-05 Mobil Oil Corp Conversion with zsm-5 family of crystalline aluminosilicate zeolites
US3682996A (en) 1970-02-24 1972-08-08 Mobil Oil Corp Zeolite esters
US3832449A (en) * 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
US3698157A (en) * 1971-06-01 1972-10-17 Mobil Oil Corp Separation of mixtures with modified zeolites
GB1403329A (en) * 1972-04-28 1975-08-28 Mobil Oil Corp Vapour-phase alkylation in presence of crystalline alumino silicate catalyst
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US3808284A (en) * 1972-09-11 1974-04-30 Texaco Inc Process for disproportionating hydrocarbons
US3894104A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3890218A (en) * 1974-03-29 1975-06-17 Mobil Oil Corp Upgrading aliphatic naphthas to higher octane gasoline
CA1062285A (en) * 1974-04-24 1979-09-11 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures
US3980586A (en) * 1974-08-28 1976-09-14 Mobil Oil Corporation Modified solid catalyst materials
NZ178543A (en) * 1974-09-23 1978-04-03 Mobil Oil Corp Conversion catalyst, crystalline alumin osilicate zeolite containing phosphorus
US4016218A (en) * 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
US4086262A (en) * 1976-09-20 1978-04-25 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0567613B1 (xx) * 1976-03-31 1993-09-27 Mobil Oil
JPS6255897B2 (xx) * 1978-02-20 1987-11-21
JPS54122692A (en) * 1978-02-20 1979-09-22 Shell Int Research Hydrocarbon oil catalytic decomposition and decomposition catalyst
JPH0140656B2 (xx) * 1979-01-31 1989-08-30 Mobil Oil
JPS55102440A (en) * 1979-01-31 1980-08-05 Mobil Oil Preparation of thermal stability* shape selective catalyst composition and hydrocarbon inverting method which use said composition
JPH0138534B2 (xx) * 1979-10-12 1989-08-15 Mobil Oil
JPS5660644A (en) * 1979-10-12 1981-05-25 Mobil Oil Method of lengthening effective life of para selective denatured zeolite catalyst
JPS56133223A (en) * 1980-03-10 1981-10-19 Mobil Oil Corp Conversion of organic compound by alkali earth metal denatured zeolite catalyst
JPS56145227A (en) * 1980-04-07 1981-11-11 Mobil Oil Corp Conversion of organic compound by iv b group metal denatured zeolite catalyst
JPS5711927A (en) * 1980-05-19 1982-01-21 Mobil Oil Corp Conversion of organic compound using iron and/or cobalt-denatured zeolite catalyst
JPS6241574B2 (xx) * 1980-12-26 1987-09-03 Toa Nenryo Kogyo Kk
JPS57108023A (en) * 1980-12-26 1982-07-05 Toa Nenryo Kogyo Kk Oligomerization catalyst for isobutene
JPS5892461A (ja) * 1981-11-13 1983-06-01 アモコ　コーポレーション 水素処理、水添分解用触媒組成物及びその製法
JPS6349542B2 (xx) * 1981-11-13 1988-10-05 Standard Oil Co
JPS5931718A (ja) * 1982-08-17 1984-02-20 Toray Ind Inc パラジアルキルベンゼンの選択的製造法
JPS6317814B2 (xx) * 1982-08-17 1988-04-15 Toray Industries
JPS59107921A (ja) * 1982-12-10 1984-06-22 Idemitsu Kosan Co Ltd ｐ―キシレンの製造方法
JPH0123448B2 (xx) * 1982-12-10 1989-05-02 Idemitsu Kosan Co
JPS61221137A (ja) * 1985-03-28 1986-10-01 Teijin Yuka Kk Ｐ−キシレンの製造法
JPH0324456B2 (xx) * 1985-03-28 1991-04-03 Teijin Yuka Kk
JPH0366293B2 (xx) * 1985-09-17 1991-10-16 Teijin Yuka Kk
JPS6263528A (ja) * 1985-09-17 1987-03-20 Teijin Yuka Kk Ｐ−キシレンの製造法
JPS62115088A (ja) * 1985-11-13 1987-05-26 Res Assoc Util Of Light Oil 芳香族炭化水素の製造方法
JPH0535755B2 (xx) * 1985-11-13 1993-05-27 Keishitsu Ryubun Shinyoto Kaihatsu Gijutsu Kenkyu Kumiai
JPS63274454A (ja) * 1987-04-08 1988-11-11 タイワン・スチアリ−ン・モノマ−・コ−ポレイシヨン 新規なＳｉ／ＨＺＳＭ−５触媒及びその製造方法並びに該触媒を利用するモノアルキルベンゼンからの高純度ｐ−ジアルキルベンゼンの合成方法
JPH01125333A (ja) * 1987-09-02 1989-05-17 Mobil Oil Corp トルエンの蒸気相不均化方法
JPH10502330A (ja) * 1994-04-04 1998-03-03 モービル・オイル・コーポレイション 高純度パラキシレン供給原料からのパラキシレンの結晶化
JPH0880438A (ja) * 1994-09-12 1996-03-26 Toray Ind Inc パラジアルキルベンゼンの製造用触媒及びその製造法及びパラキシレンを製造する方法
JP2007517030A (ja) * 2003-12-31 2007-06-28 エクソンモービル・ケミカル・パテンツ・インク 芳香族のアルキル化プロセス
JP4843501B2 (ja) * 2003-12-31 2011-12-21 エクソンモービル・ケミカル・パテンツ・インク 芳香族のアルキル化プロセス
JP2010208948A (ja) * 2009-03-06 2010-09-24 Mitsui Chemicals Inc 芳香族炭化水素の製造方法およびその製造方法に使用される触媒

Also Published As

Publication number Publication date
NO149492B (no) 1984-01-23
NL187424B (nl) 1991-05-01
PL115528B1 (en) 1981-04-30
GB1574523A (en) 1980-09-10
SE438606B (sv) 1985-04-29
DE2760481C2 (xx) 1993-07-15
JPH0567613B1 (xx) 1993-09-27
NL187424C (nl) 1991-10-01
JPH01199920A (ja) 1989-08-11
NL7703484A (nl) 1977-10-04
IT1075368B (it) 1985-04-22
DE2714239C2 (xx) 1993-07-22
SE7703593L (sv) 1977-10-01
NZ183608A (en) 1978-12-18
DE2760479C2 (xx) 1993-08-12
JPS6247854B2 (xx) 1987-10-09
DE2714239A1 (de) 1977-10-20
CS218565B2 (en) 1983-02-25
NO149492C (no) 1984-05-09
FR2357303A1 (fr) 1978-02-03
FR2357303B1 (xx) 1984-06-01
BE852865A (fr) 1977-09-26
NO771085L (no) 1977-10-03

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