JPH11507696A - 改善された硬化性を有する熱可塑性エラストマー - Google Patents
改善された硬化性を有する熱可塑性エラストマーInfo
- Publication number
- JPH11507696A JPH11507696A JP9503236A JP50323697A JPH11507696A JP H11507696 A JPH11507696 A JP H11507696A JP 9503236 A JP9503236 A JP 9503236A JP 50323697 A JP50323697 A JP 50323697A JP H11507696 A JPH11507696 A JP H11507696A
- Authority
- JP
- Japan
- Prior art keywords
- elastomeric polymer
- range
- polymer
- thermoplastic elastomer
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 131
- 229920000642 polymer Polymers 0.000 claims abstract description 172
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 83
- 239000005977 Ethylene Substances 0.000 claims abstract description 83
- 229920001971 elastomer Polymers 0.000 claims abstract description 78
- 239000004711 α-olefin Substances 0.000 claims abstract description 57
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000000806 elastomer Substances 0.000 claims abstract description 43
- 230000006835 compression Effects 0.000 claims abstract description 26
- 238000007906 compression Methods 0.000 claims abstract description 26
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 23
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 22
- 239000004848 polyfunctional curative Substances 0.000 claims abstract description 10
- -1 polybutylene, ethylene Polymers 0.000 claims description 64
- 239000000203 mixture Substances 0.000 claims description 48
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- 239000004743 Polypropylene Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 33
- 229920001155 polypropylene Polymers 0.000 claims description 33
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 20
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 20
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 239000012190 activator Substances 0.000 claims description 8
- 229920003023 plastic Polymers 0.000 claims description 8
- 239000004033 plastic Substances 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 7
- 238000004898 kneading Methods 0.000 claims description 7
- 239000004952 Polyamide Substances 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 5
- YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 claims description 4
- 239000012298 atmosphere Substances 0.000 claims description 4
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229920001384 propylene homopolymer Polymers 0.000 claims description 2
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 abstract description 46
- 239000000178 monomer Substances 0.000 abstract description 37
- 230000032683 aging Effects 0.000 abstract description 3
- 238000010348 incorporation Methods 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000005060 rubber Substances 0.000 description 35
- 150000002978 peroxides Chemical class 0.000 description 29
- 239000003921 oil Substances 0.000 description 18
- 239000003054 catalyst Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- 229920000098 polyolefin Polymers 0.000 description 14
- 239000000945 filler Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 150000001450 anions Chemical class 0.000 description 9
- 239000012632 extractable Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 9
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 229920006126 semicrystalline polymer Polymers 0.000 description 8
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 7
- 239000000049 pigment Substances 0.000 description 7
- 239000004014 plasticizer Substances 0.000 description 7
- 239000010734 process oil Substances 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 6
- 230000004913 activation Effects 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 6
- 150000001451 organic peroxides Chemical class 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 239000002243 precursor Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 238000010057 rubber processing Methods 0.000 description 6
- 229920003031 santoprene Polymers 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 150000003623 transition metal compounds Chemical class 0.000 description 5
- 239000004636 vulcanized rubber Substances 0.000 description 5
- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 235000019241 carbon black Nutrition 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 229910052570 clay Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000035882 stress Effects 0.000 description 4
- 229910052723 transition metal Inorganic materials 0.000 description 4
- 150000003624 transition metals Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 3
- RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 description 3
- VSQLAQKFRFTMNS-UHFFFAOYSA-N 5-methylhexa-1,4-diene Chemical compound CC(C)=CCC=C VSQLAQKFRFTMNS-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920001748 polybutylene Polymers 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 241000566113 Branta sandvicensis Species 0.000 description 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 2
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 125000005626 carbonium group Chemical group 0.000 description 2
- 239000006231 channel black Substances 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000006232 furnace black Substances 0.000 description 2
- 239000002638 heterogeneous catalyst Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 150000007517 lewis acids Chemical class 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 2
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 2
- 150000002895 organic esters Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002952 polymeric resin Substances 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 239000012763 reinforcing filler Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000001374 small-angle light scattering Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000006234 thermal black Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 2
- JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 description 2
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- MYOQALXKVOJACM-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy pentaneperoxoate Chemical compound CCCCC(=O)OOOC(C)(C)C MYOQALXKVOJACM-UHFFFAOYSA-N 0.000 description 1
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 description 1
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- PBQSTXCCVHCVHS-UHFFFAOYSA-N 2-methylnona-2,7-diene Chemical compound CC=CCCCC=C(C)C PBQSTXCCVHCVHS-UHFFFAOYSA-N 0.000 description 1
- KUKRLSJNTMLPPK-UHFFFAOYSA-N 4,7,7-trimethylbicyclo[2.2.1]hept-2-ene Chemical compound C1CC2(C)C=CC1C2(C)C KUKRLSJNTMLPPK-UHFFFAOYSA-N 0.000 description 1
- YKZUNWLMLRCVCW-UHFFFAOYSA-N 4-[2-(4-bicyclo[2.2.1]hept-2-enyl)ethyl]bicyclo[2.2.1]hept-2-ene Chemical compound C1CC(C2)C=CC21CCC1(C=C2)CC2CC1 YKZUNWLMLRCVCW-UHFFFAOYSA-N 0.000 description 1
- TVEXGJYMHHTVKP-UHFFFAOYSA-N 6-oxabicyclo[3.2.1]oct-3-en-7-one Chemical compound C1C2C(=O)OC1C=CC2 TVEXGJYMHHTVKP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- GLVKGYRREXOCIB-UHFFFAOYSA-N Bornylene Natural products CC1CCC(C(C)(C)C)C=C1 GLVKGYRREXOCIB-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- SJLQDKKILMLGIT-UHFFFAOYSA-N C=CCCCC=CC.C=CCC=CC Chemical compound C=CCCCC=CC.C=CCC=CC SJLQDKKILMLGIT-UHFFFAOYSA-N 0.000 description 1
- 241000543381 Cliftonia monophylla Species 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000012668 chain scission Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 230000001814 effect on stress Effects 0.000 description 1
- 238000002091 elastography Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000010060 peroxide vulcanization Methods 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000011297 pine tar Substances 0.000 description 1
- 229940068124 pine tar Drugs 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- PIMBTRGLTHJJRV-UHFFFAOYSA-L zinc;2-methylprop-2-enoate Chemical compound [Zn+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O PIMBTRGLTHJJRV-UHFFFAOYSA-L 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/490,505 | 1995-06-14 | ||
| US08/490,505 US5656693A (en) | 1995-06-14 | 1995-06-14 | Thermoplastic elastomers having improved cure |
| PCT/US1996/009903 WO1997000288A1 (en) | 1995-06-14 | 1996-06-11 | Thermoplastic elastomers having improved cure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11507696A true JPH11507696A (ja) | 1999-07-06 |
| JPH11507696A5 JPH11507696A5 (enExample) | 2004-07-29 |
Family
ID=23948349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9503236A Pending JPH11507696A (ja) | 1995-06-14 | 1996-06-11 | 改善された硬化性を有する熱可塑性エラストマー |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5656693A (enExample) |
| EP (1) | EP0843698B1 (enExample) |
| JP (1) | JPH11507696A (enExample) |
| KR (1) | KR100411924B1 (enExample) |
| CN (1) | CN1081204C (enExample) |
| AU (1) | AU716677B2 (enExample) |
| BR (1) | BR9608988A (enExample) |
| CA (1) | CA2220668A1 (enExample) |
| DE (1) | DE69603737T2 (enExample) |
| ES (1) | ES2135904T3 (enExample) |
| IL (1) | IL118531A0 (enExample) |
| TW (1) | TW341586B (enExample) |
| WO (1) | WO1997000288A1 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001510629A (ja) * | 1997-06-05 | 2001-07-31 | エクソン・ケミカル・パテンツ・インク | エチレン、アルファ−オレフィン、ビニルノルボルネンエラストマー及びエチレンアルファ−オレフィンポリマーを含む電気装置 |
| JP2002515530A (ja) * | 1998-05-18 | 2002-05-28 | ザ ダウ ケミカル カンパニー | 照射および架橋エチレンポリマー製の高温弾性を有する製品ならびにその製造方法 |
| JP2008546575A (ja) * | 2005-06-27 | 2008-12-25 | アドバンスド エラストマー システムズ，エル．ピー． | 多軸スクリュー押出機における動的加硫による熱可塑性エラストマーの生成方法 |
| JP2014517165A (ja) * | 2011-04-29 | 2014-07-17 | アメリカン ビルトレイト （カナダ） リミテッド | 表面被覆材料および製品 |
| JP2020164700A (ja) * | 2019-03-29 | 2020-10-08 | 三井化学株式会社 | エチレン・α−オレフィン・ビニルノルボルネン共重合体組成物およびその架橋物 |
Families Citing this family (86)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2219052A1 (en) * | 1996-10-28 | 1998-04-28 | Mitsui Chemicals, Incorporated | Olefin thermoplastic elastomer composition |
| US5763533A (en) | 1996-12-10 | 1998-06-09 | Exxon Chemical Patents Inc. | Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers |
| US5965077A (en) * | 1997-10-16 | 1999-10-12 | Mercury Plastics, Inc. | Method of making an overmolded flexible valve |
| JP4233753B2 (ja) | 1997-11-20 | 2009-03-04 | アドバンスド エラストマー システムズ，エル．ピー． | エチレンの熱可塑性ランダムコポリマーによる熱可塑性加硫ゴムの改良 |
| US6288171B2 (en) * | 1998-07-01 | 2001-09-11 | Advanced Elastomer Systems, L.P. | Modification of thermoplastic vulcanizates using random propylene copolymers |
| PL200805B1 (pl) * | 1999-02-15 | 2009-02-27 | Polyone Corp | Termoplastyczny wulkanizat i sposób jego wytwarzania |
| US6281316B1 (en) | 1999-03-22 | 2001-08-28 | Union Carbide Chemicals & Plastics Technology Corporation | Enhanced crosslinking terpolymer |
| US6815062B2 (en) | 1999-06-21 | 2004-11-09 | Pirelli Cavi E Sistemi S.P.A. | Cable, in particular for electric energy transportation or distribution, and an insulating composition used therein |
| WO2000079543A1 (en) * | 1999-06-21 | 2000-12-28 | Pirelli Cavi E Sistemi S.P.A. | Cable, in particular for electric energy transportation or distribution, and an insulating composition used therein |
| CA2292387A1 (en) | 1999-12-17 | 2001-06-17 | Bayer Inc. | Process for producing olefin polymer with long chain branching |
| DE60124342T2 (de) * | 2000-06-20 | 2007-05-31 | Jsr Corp. | Polymerisches Material für Laserbearbeitung |
| US6667364B2 (en) * | 2000-12-29 | 2003-12-23 | Advanced Elastomer Systems Lp | Processable polyethylene/EPDM thermoplastic vulcanizates |
| US6451915B1 (en) | 2000-12-29 | 2002-09-17 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved processing and physical property balance |
| US6433090B1 (en) | 2001-01-26 | 2002-08-13 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved set foams made therefrom |
| US7021633B2 (en) * | 2001-09-11 | 2006-04-04 | Gorman Company, Inc. | Low friction fluid seal device with additive to rubber compound |
| EP1591458B8 (en) * | 2002-01-15 | 2010-06-02 | Advanced Elastomer Systems, L.P. | Thermoplastic Elastomers |
| CZ2004577A3 (cs) * | 2002-01-15 | 2004-11-10 | Advanced Elastomer Systems, L.P. | Termoplastické elastomery a způsob jejich výroby |
| JP2005517755A (ja) * | 2002-02-11 | 2005-06-16 | ディーエスエム アイピー アセッツ ビー．ブイ． | 熱可塑性エラストマー組成物 |
| US6806336B2 (en) | 2002-06-19 | 2004-10-19 | Exxonmobil Chemical Patents Inc. | Process for polymerizing ethylene, higher alpha-olefin comonomer and dienes, especially vinyl norbornene; polymers made using such processes; and articles made from such polymers |
| US6790911B2 (en) * | 2002-12-26 | 2004-09-14 | Advanvced Elastomer Systems, L.P. | Thermoplastic elastomers having improved adhesive proterties |
| US7737205B2 (en) * | 2003-07-28 | 2010-06-15 | Dow Global Technologies Inc | Thermoplastic vulcanizates and process to prepare them |
| US7868096B2 (en) * | 2003-09-17 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates and processes for making the same |
| WO2005049670A1 (en) * | 2003-11-14 | 2005-06-02 | Exxonmobil Chemical Patents Inc. | Propylene-based elastomers and uses thereof |
| US20060014903A1 (en) | 2004-07-14 | 2006-01-19 | Thierry Vromman | Thermoplastic vulcanizates with enhanced cooling and articles made therefrom |
| US20060052540A1 (en) * | 2004-09-09 | 2006-03-09 | Maria Ellul | Thermoplastic vulcanizates |
| US7193018B2 (en) * | 2004-09-15 | 2007-03-20 | Advanced Elastomer Systems, Lp. | Slip-coat compositions and polymeric laminates |
| US7829623B2 (en) * | 2004-11-05 | 2010-11-09 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates having improved fabricability |
| US8076416B2 (en) | 2005-02-04 | 2011-12-13 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates and their use |
| US20070021564A1 (en) * | 2005-07-13 | 2007-01-25 | Ellul Maria D | Peroxide-cured thermoplastic vulcanizates |
| US7872075B2 (en) * | 2005-10-07 | 2011-01-18 | Exxonmobil Chemical Patents Inc. | Peroxide-cured thermoplastic vulcanizates and process for making the same |
| US20070112139A1 (en) * | 2005-11-14 | 2007-05-17 | Ellul Maria D | Peroxide-cured thermoplastic vulcanizates and process for making the same |
| EP1957548B1 (en) * | 2005-12-06 | 2013-08-07 | ExxonMobil Chemical Patents Inc. | Ethylene elastomer compositions |
| US7709577B2 (en) | 2005-12-07 | 2010-05-04 | Exxonmobil Chemical Patents Inc. | Process of making polymer blends |
| US7812093B2 (en) * | 2005-12-19 | 2010-10-12 | Exxonmobil Chemical Patents Inc. | Peroxide-cured thermoplastic vulcanizates and medical devices made therewith |
| DE102006003194A1 (de) * | 2006-01-24 | 2007-08-02 | Elringklinger Ag | Radialdichtung |
| US7504458B2 (en) * | 2006-04-12 | 2009-03-17 | Advanced Elastomer Systems, Llp | Method for improving compression set in thermoplastic vulcanizates |
| US20070244263A1 (en) * | 2006-04-13 | 2007-10-18 | Burrowes Thomas G | Elastomeric composition for transmission belt |
| US7985804B2 (en) | 2006-11-06 | 2011-07-26 | Exxonmobil Chemical Patents Inc. | Rubber toughened compositions, articles, films, and methods of making the same |
| US7955540B2 (en) * | 2007-01-19 | 2011-06-07 | Exxonmobil Chemical Patents Inc. | Extrusion of thermoplastic elastomers |
| WO2008134173A1 (en) * | 2007-05-01 | 2008-11-06 | Advanced Elastomer Systems, L.P. | Method for preparing thermoplastic vulcanizates |
| WO2009020720A1 (en) * | 2007-08-06 | 2009-02-12 | Advance Elastomer Systems, L.P. | Peroxide-cured thermoplastic vulcanizates prepared with ultrahigh molecular weight plastics |
| US9234093B2 (en) * | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| US8877867B2 (en) * | 2008-11-06 | 2014-11-04 | Exxonmobil Chemical Patents Inc. | Process for forming thermoplastic vulcanizates and extruded articles therefrom |
| US20100119855A1 (en) * | 2008-11-10 | 2010-05-13 | Trazollah Ouhadi | Thermoplastic Elastomer with Excellent Adhesion to EPDM Thermoset Rubber and Low Coefficient of Friction |
| US8829349B2 (en) * | 2008-12-18 | 2014-09-09 | Exxonmobil Chemical Patents Inc. | Oxides for protection against electrochemical oxidation and ionic contamination in medium-voltage power-cable insulation |
| US8969481B2 (en) * | 2008-12-18 | 2015-03-03 | Exxonmobil Chemical Patent Inc. | Peroxide cured TPV |
| BRPI1010079B1 (pt) | 2009-07-15 | 2019-10-08 | Dow Global Technologies Llc | Composição polimérica e artigo |
| US8865838B2 (en) * | 2009-12-30 | 2014-10-21 | Exxonmobil Chemical Patents Inc. | Process for forming thermoplastic vulcanizates |
| US8557906B2 (en) | 2010-09-03 | 2013-10-15 | Exxonmobil Chemical Patents Inc. | Flame resistant polyolefin compositions and methods for making the same |
| US10072146B2 (en) | 2010-12-30 | 2018-09-11 | Dow Global Technologies Llc | Compositions, methods of making the same, and articles prepared from the same |
| EP2574635A1 (en) | 2011-09-28 | 2013-04-03 | Lanxess Inc. | Process for continuous production of halogen-free thermoplastic elastomer compositions |
| US10266683B2 (en) | 2012-05-10 | 2019-04-23 | Exxonmobil Chemical Patents Inc. | Compositions and methods for making them |
| EP2885326B1 (en) | 2012-08-16 | 2019-11-27 | ExxonMobil Chemical Patents Inc. | Highly branched compositions and processes for the production thereof |
| KR20160119079A (ko) * | 2014-02-07 | 2016-10-12 | 제너럴 케이블 테크놀로지즈 코오포레이션 | 개선된 외피를 가지는 케이블 형성방법 |
| US10414881B2 (en) | 2014-11-25 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Method of making thermoplastic vulcanizates and thermoplastic vulcanizates made therefrom |
| KR101820319B1 (ko) * | 2014-12-05 | 2018-01-19 | 요코하마 고무 가부시키가이샤 | 접착 방법 및 컨베이어 벨트 |
| US10730206B2 (en) | 2015-02-26 | 2020-08-04 | Exxonmobil Chemical Patents Inc. | Process for forming thermoplastic vulcanizates and thermoplastic vulcanizates made therefrom |
| US10790404B2 (en) | 2016-03-30 | 2020-09-29 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions for photovoltaic cell applications |
| US11192992B2 (en) | 2016-12-29 | 2021-12-07 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates for foaming applications |
| US10508179B2 (en) | 2017-02-28 | 2019-12-17 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized EPDM |
| EP3676068A1 (en) | 2017-08-31 | 2020-07-08 | ExxonMobil Chemical Patents Inc. | Methods of making thermoplastic vulcanizates (tpv) |
| CA3076459C (en) | 2017-11-03 | 2021-03-16 | American Biltrite (Canada) Ltd. | Resilient surface coverings and methods of making and using thereof |
| US11447624B2 (en) | 2017-12-06 | 2022-09-20 | Celanese International Corporation | Low density foamed thermoplastic vulcanizate compositions |
| US11359083B2 (en) | 2018-01-18 | 2022-06-14 | Celanese International Corporation | Thermoplastic vulcanizates |
| WO2019143419A1 (en) | 2018-01-18 | 2019-07-25 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| EP3774256A4 (en) | 2018-04-05 | 2022-03-09 | ExxonMobil Chemical Patents Inc. | IMPROVEMENT OF CROSSLINKED RUBBER DISPERSION IN THERMOPLASTIC VULCANIZATE |
| WO2019199486A1 (en) | 2018-04-10 | 2019-10-17 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizale compositions |
| EP3827033B1 (en) | 2018-07-23 | 2025-01-01 | ExxonMobil Chemical Patents Inc. | Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom |
| WO2020055704A1 (en) | 2018-09-14 | 2020-03-19 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions in polymeric inner / pressure sheaths of flexible pipes for oil & gas applications |
| WO2020068409A1 (en) | 2018-09-24 | 2020-04-02 | Exxonmobil Chemical Patents Inc. | Crosslinked elastomer-polymer blends |
| US20210355255A1 (en) * | 2019-01-30 | 2021-11-18 | Sumitomo Chemical Company, Limited | Rubber composition |
| WO2020191393A1 (en) | 2019-03-21 | 2020-09-24 | Exxonmobil Chemical Patents Inc. | Pipe including a thermoplastic vulcanizate composition |
| US11413800B2 (en) | 2019-05-20 | 2022-08-16 | Kraton Polymers Llc | Molding compositions and articles made thereof |
| CN113853403B (zh) | 2019-06-13 | 2024-04-16 | 国际人造丝公司 | 用热塑性硫化橡胶组合物形成的汽车挡风雨密封件 |
| WO2020257630A1 (en) | 2019-06-21 | 2020-12-24 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions |
| US20220299154A1 (en) | 2019-08-26 | 2022-09-22 | Celanese International Corporation | Thermoplastic Vulcanizate Compositions and Thermoplastic Olefinic Compositions as Insulating Layers in Non-Flexible Pipes |
| US20220306849A1 (en) | 2019-10-22 | 2022-09-29 | Celanese International Corporation | Thermoplastic Vulcanizate Compositions and Processes for the Production Thereof |
| WO2021188361A1 (en) | 2020-03-20 | 2021-09-23 | Exxonmobil Chemical Patents Inc. | Linear alpha-olefin copolymers and impact copolymers thereof |
| EP4146735A1 (en) | 2020-05-05 | 2023-03-15 | Celanese International Corporation | Pipe including a polymethylpentene thermoplastic polymer |
| US11674024B2 (en) | 2020-05-29 | 2023-06-13 | Exxonmobil Chemical Patents Inc. | Sequential, double elastomer vulcanization system, method and composition |
| WO2021242636A1 (en) | 2020-05-29 | 2021-12-02 | Exxonmobil Chemical Patents Inc. | Processes for producing cyclic olefins from polymers and re-polymerization thereof |
| CN115916892A (zh) | 2020-07-02 | 2023-04-04 | 国际人造丝公司 | 含有茂金属多峰共聚物橡胶的热塑性硫化橡胶组合物及其制造方法 |
| JP2022047722A (ja) * | 2020-09-14 | 2022-03-25 | 豊田合成株式会社 | 架橋ゴム組成物及びその製造方法 |
| WO2022093448A1 (en) | 2020-10-30 | 2022-05-05 | Celanese International Corporation | Thermoplastic vulcanizate compositions and articles containing the same |
| WO2022132268A1 (en) | 2020-12-16 | 2022-06-23 | Celanese International Corporation | Extrusion molded thermoplastic vulcanizate gaskets and methods of making such gaskets |
| US20230374285A1 (en) | 2022-05-18 | 2023-11-23 | Mcpp Innovation Llc | Split-proof automotive corner molding compound |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1018778A (en) * | 1962-08-09 | 1966-02-02 | Montedison Spa | Olefin copolymers |
| DE1595440B2 (de) * | 1966-08-18 | 1973-05-24 | Chemische Werke Hüls AG, 4370 Mari | Verfahren zur herstellung von vulkanisierbaren, ungesaettigten copolymeren |
| CA920742A (en) * | 1969-01-15 | 1973-02-06 | Du Pont Of Canada Limited | Copolymers of ethylene and bicyclo-(2,2,1)-2-heptenes with improved physical properties |
| GB1311946A (en) * | 1969-09-05 | 1973-03-28 | Montedison Spa | Ethylene propylene copolymers |
| US3637617A (en) * | 1969-09-08 | 1972-01-25 | Copolymer Rubber & Chem Corp | Minimizing compression set of curable rubbers |
| US3806558A (en) * | 1971-08-12 | 1974-04-23 | Uniroyal Inc | Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic |
| GB1402049A (en) * | 1972-12-22 | 1975-08-06 | Stamicarbon | Polypropylene compositions having mechanical properties |
| US4130535A (en) * | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
| US4031169A (en) * | 1975-09-11 | 1977-06-21 | Uniroyal Inc. | Thermoplastic elastomeric polymer blend |
| GB1597833A (en) * | 1977-03-05 | 1981-09-09 | Treacy T P | Shoring assembly for a trench or hole |
| DE2822815C2 (de) * | 1977-05-26 | 1994-02-17 | Mitsui Petrochemical Ind | Verfahren zur Herstellung einer teilweise vulkanisierten thermoplastischen Masse |
| US4311628A (en) * | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
| US4220579A (en) * | 1978-04-17 | 1980-09-02 | Uniroyal, Inc. | Thermoplastic elastomeric blend of monoolefin copolymer rubber, amorphous polypropylene resin and crystalline polyolefin resin |
| JPS58191705A (ja) * | 1982-05-06 | 1983-11-09 | Mitsui Petrochem Ind Ltd | エチレン共重合ゴム |
| JPS6040141A (ja) * | 1983-08-16 | 1985-03-02 | Mitsui Petrochem Ind Ltd | 硫黄加硫可能な低比重ゴム組成物 |
| JPS61151758A (ja) * | 1984-12-26 | 1986-07-10 | Nec Corp | メモリバツクアツプ方式 |
| JPH0627129B2 (ja) * | 1985-10-31 | 1994-04-13 | 三井石油化学工業株式会社 | 塩素化ゴム |
| US5177147A (en) * | 1986-03-03 | 1993-01-05 | Advanced Elastomer Systems, Lp | Elastomer-plastic blends |
| JPS62210169A (ja) * | 1986-03-10 | 1987-09-16 | Nissan Motor Co Ltd | 車両用実舵角制御装置 |
| JPH0730217B2 (ja) * | 1986-05-08 | 1995-04-05 | 住友化学工業株式会社 | 熱可塑性エラストマ−組成物 |
| IN167956B (enExample) * | 1986-05-23 | 1991-01-12 | Uniroyal Chem Co Inc | |
| EP0275925B1 (en) * | 1987-01-19 | 1995-04-05 | Sumitomo Chemical Company, Limited | Rubbery copolymers of ethylene, propylene and a nonconjugated polyene and their use |
| JPS63265940A (ja) * | 1987-04-24 | 1988-11-02 | Nippon Oil Co Ltd | 熱可塑性エラストマ−組成物 |
| JP2546849B2 (ja) * | 1987-08-26 | 1996-10-23 | 三井石油化学工業株式会社 | 熱可塑性樹脂用改質剤 |
| EP0366411A3 (en) * | 1988-10-28 | 1991-04-24 | Exxon Chemical Patents Inc. | Graft polymers of ethylene-propylene-diene monomer polymers with propylene, means of preparation, and use of polypropylene compositions |
| US5292811A (en) * | 1988-11-21 | 1994-03-08 | Mitsui Petrochemical Industries, Ltd. | Process for preparing thermoplastic elastomers |
| US4985502A (en) * | 1988-12-23 | 1991-01-15 | Showa Denko K.K. | Thermoplastic elastomer |
| US5157081A (en) * | 1989-05-26 | 1992-10-20 | Advanced Elastomer Systems, L.P. | Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix |
| JP3031022B2 (ja) * | 1991-12-19 | 2000-04-10 | 住友化学工業株式会社 | 熱可塑性エラストマー組成物の製造方法 |
| US5288806A (en) * | 1992-09-22 | 1994-02-22 | Exxon Chemical Patents Inc. | Thermoplastic olefins with low viscosity |
-
1995
- 1995-06-14 US US08/490,505 patent/US5656693A/en not_active Expired - Lifetime
-
1996
- 1996-06-02 IL IL11853196A patent/IL118531A0/xx unknown
- 1996-06-06 TW TW085106757A patent/TW341586B/zh active
- 1996-06-11 ES ES96918426T patent/ES2135904T3/es not_active Expired - Lifetime
- 1996-06-11 AU AU61095/96A patent/AU716677B2/en not_active Ceased
- 1996-06-11 WO PCT/US1996/009903 patent/WO1997000288A1/en not_active Ceased
- 1996-06-11 BR BR9608988A patent/BR9608988A/pt not_active IP Right Cessation
- 1996-06-11 JP JP9503236A patent/JPH11507696A/ja active Pending
- 1996-06-11 KR KR1019970709395A patent/KR100411924B1/ko not_active Expired - Fee Related
- 1996-06-11 CN CN96195416A patent/CN1081204C/zh not_active Expired - Fee Related
- 1996-06-11 CA CA002220668A patent/CA2220668A1/en not_active Abandoned
- 1996-06-11 DE DE69603737T patent/DE69603737T2/de not_active Revoked
- 1996-06-11 EP EP96918426A patent/EP0843698B1/en not_active Revoked
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001510629A (ja) * | 1997-06-05 | 2001-07-31 | エクソン・ケミカル・パテンツ・インク | エチレン、アルファ−オレフィン、ビニルノルボルネンエラストマー及びエチレンアルファ−オレフィンポリマーを含む電気装置 |
| JP2002515530A (ja) * | 1998-05-18 | 2002-05-28 | ザ ダウ ケミカル カンパニー | 照射および架橋エチレンポリマー製の高温弾性を有する製品ならびにその製造方法 |
| JP2008546575A (ja) * | 2005-06-27 | 2008-12-25 | アドバンスド エラストマー システムズ，エル．ピー． | 多軸スクリュー押出機における動的加硫による熱可塑性エラストマーの生成方法 |
| JP2014517165A (ja) * | 2011-04-29 | 2014-07-17 | アメリカン ビルトレイト （カナダ） リミテッド | 表面被覆材料および製品 |
| JP2020164700A (ja) * | 2019-03-29 | 2020-10-08 | 三井化学株式会社 | エチレン・α−オレフィン・ビニルノルボルネン共重合体組成物およびその架橋物 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0843698B1 (en) | 1999-08-11 |
| KR100411924B1 (ko) | 2004-02-18 |
| KR19990022926A (ko) | 1999-03-25 |
| CA2220668A1 (en) | 1997-01-03 |
| ES2135904T3 (es) | 1999-11-01 |
| TW341586B (en) | 1998-10-01 |
| US5656693A (en) | 1997-08-12 |
| DE69603737T2 (de) | 2000-03-16 |
| AU716677B2 (en) | 2000-03-02 |
| EP0843698A1 (en) | 1998-05-27 |
| DE69603737D1 (de) | 1999-09-16 |
| IL118531A0 (en) | 1996-10-16 |
| AU6109596A (en) | 1997-01-15 |
| BR9608988A (pt) | 1999-06-29 |
| CN1081204C (zh) | 2002-03-20 |
| CN1190420A (zh) | 1998-08-12 |
| WO1997000288A1 (en) | 1997-01-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH11507696A (ja) | 改善された硬化性を有する熱可塑性エラストマー | |
| KR100392552B1 (ko) | 열경화성탄성중합체 | |
| EP1219679B1 (en) | Thermoplastic elastomers having improved processing and physical property balance | |
| US6121383A (en) | Thermosplastic vulcanizates from blends of a polypropylene and elastic α-olefin/cyclic olefin copolymers | |
| US9234093B2 (en) | Thermoplastic vulcanizates | |
| CN114341255B (zh) | 用于层状制品的基于乙烯的共聚物和丙烯-α-烯烃-二烯组合物 | |
| JP2002544344A (ja) | 高結晶性ｅａｏｄｍインターポリマー | |
| WO2017206009A1 (en) | Ethylene/alpha-olefin/diene interpolymers compositions | |
| US4722973A (en) | Thermoplastic elastomer composition | |
| WO2019182949A1 (en) | Elastomeric propylene-alpha-olefin-diene terpolymer compositions | |
| CN112703210A (zh) | 制备双峰橡胶、热塑性硫化橡胶和由其制成的制品 | |
| US8183328B2 (en) | Compositions comprising grafted and crosslinked LLDPE's, Methods for making same, and articles made therefrom | |
| US20070287804A1 (en) | Thermoplastic elastomer composition and laminate | |
| US8211985B2 (en) | Silicon-containing ethylene-based polymer blends, methods for making same, and articles made therefrom | |
| JPS626585B2 (enExample) | ||
| JP2004067798A (ja) | 芳香族ビニル系水素添加ゴム組成物 | |
| JP2023532133A (ja) | メタロセン多峰性コポリマーゴムを含有する熱可塑性加硫物組成物およびその製造方法 | |
| JP3552360B2 (ja) | オレフィン系熱可塑性エラストマー組成物、該組成物からなるシート及び該シートからなる積層体 | |
| JPH09104720A (ja) | 過酸化物改質エチレン・α−オレフィン系共重合体エラストマーおよび樹脂組成物 | |
| US12378391B2 (en) | Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates | |
| WO2021188361A1 (en) | Linear alpha-olefin copolymers and impact copolymers thereof | |
| JP2001206994A (ja) | 熱可塑性エラストマー組成物及び成形体 | |
| JPH0848827A (ja) | 透明性の改良されたエチレン系樹脂組成物 | |
| JPS63165416A (ja) | 架橋されたオレフイン系ブロツク共重合体の製造法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20051115 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20050830 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20060213 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20060403 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20060515 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20061024 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070221 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20070510 |
|
| A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20070531 |