JPH10512010A - 生物学的に分解可能なポリマー混合物 - Google Patents
生物学的に分解可能なポリマー混合物Info
- Publication number
- JPH10512010A JPH10512010A JP8525223A JP52522396A JPH10512010A JP H10512010 A JPH10512010 A JP H10512010A JP 8525223 A JP8525223 A JP 8525223A JP 52522396 A JP52522396 A JP 52522396A JP H10512010 A JPH10512010 A JP H10512010A
- Authority
- JP
- Japan
- Prior art keywords
- polymer mixture
- acid
- polyester
- starch
- aliphatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2003/00—Use of starch or derivatives as moulding material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/12—Polyester-amides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.少なくとも1種の再生可能な原料をベースとして製造されたバイオポリマ ーを含む生物学的に分解可能なポリマー混合物において、バイオポリマーとして 少なくとも天然デンプンまたはその誘導体と、天然デンプンまたはその誘導体と の混合物に対して10〜40重量%の範囲の量の可塑剤または膨潤剤とを、水含 量<5%で混合することにより得られる熱可塑性デンプンが少なくとも存在し、 この場合可塑剤または膨潤剤はデンプンもしくは誘導体が少なくとも膨張し始め るまたは溶解し始めるのに適しており、かつポリマー混合物中に、以下のリスト : 芳香族ポリエステル、 脂肪族ならびに芳香族ブロックを有するポリエステル−コポリマー、 ポリエステルアミド、 ポリエチレンオキシドポリマーもしくはポリグリコール、 ポリエステルウレタン、 および/またはこれらの混合物 から選択されたポリマーが少なくとも1種使用されており、この際該ポリマー混 合物は、熱可塑性デンプンと少なくとも1種のポリマーとを、ポリマー混合物に 対して水含量<1重量%で混合することにより得られ ることを特徴とする、生物学的に分解可能なポリマー混合物。 2.熱可塑性デンプンが膨潤剤または可塑剤として少なくとも次の物質、つま りソルビトール、グリセリン、ヒドロキシ酸、例えば乳酸またはそのオリゴマー および/またはその塩、ポリビニルアルコール、脂肪族ポリエステル、例えば低 分子ポリ乳酸またはポリカプロラクトン、ポリエステルアミドおよび/またはこ れらの混合物を含有する、請求項1記載の生物学的に分解可能なポリマー混合物 。 3.ポリエステル−コポリマーがポリオールおよび芳香族または脂肪族ジ−カ ルボン酸から製造されている、請求項1または2記載の生物学的に分解可能なポ リマー混合物。 4.ポリエステル−コポリマーが以下の一般構造: を有し、この場合1およびmは変化してもよく、かつ分配され、ならびにその平 均値は反応混合物の組成により決まる、請求項1から3までのいずれか1項記載 の生物学的に分解可能なポリマー混合物。 5.ポリエステル−コポリマーが一方では一連の1,2−エタンジオール、1 ,3−プロパンジオール、 1,4−ブタンジオールおよび/または1,6−ヘキサンジオールからの少なく とも1種のジオールと、他方では少なくとも1種の芳香族ジ−カルボン酸、例え ばテレフタル酸、および場合により少なくとも1種の脂肪族ジ−カルボン酸、例 えばアジピン酸および/またはセバシン酸との重縮合により製造される、請求項 1から4までのいずれか1項記載の生物学的に分解可能なポリマー混合物。 6.ポリエステル−コポリマーがポリアルキレンテレフタレートまたはポリエ チレンテレフタレートである、請求項1から5までのいずれか1項記載の生物学 的に分解可能なポリマー混合物。 7.更なる成分として脂肪族ポリエステルもしくはコポリエステル、例えばポ リ乳酸、ポリヒドロキシ酪酸、ポリヒドロキシ安息香酸、ポリヒドロキシ酪酸− ヒドロキシ吉草酸−コポリマーまたはポリカプロラクトンを使用する、請求項1 から6までのいずれか1項記載の生物学的に分解可能なポリマー混合物。 8.熱可塑性デンプン、少なくとも1種のポリエチレンテレフタレートまたは ポリアルキレンテレフタレートならびにポリカプロラクトンを特徴とする、請求 項7記載の生物学的に分解可能なポリマー混合物。 9.混合物がデンプンまたは熱可塑性デンプンと少なくとも1種の以下のポリ マー: 脂肪族および芳香族ブロックを有するポリエステル −コポリマー、 芳香族ポリエステル、 脂肪族ポリエステル、 ポリエステルアミドおよび/または ポリエステルウレタン、 とを溶融物中で無水で混合し、かつ反応させることにより得られるブロックコポ リマーを相媒介剤として含有する、請求項1から8までのいずれか1項記載の生 物学的に分解可能なポリマー混合物。 10.少なくとも1種の別の成分、例えば添加剤、混和剤または充填剤、例え ば軟化剤、安定剤、難燃剤、生物学的に分解可能な別のバイオポリマー、例えば セルロースエステル、セルロース、ポリヒドロキシ酪酸、疎水性タンパク質、ポ リビニルアルコール、ゼラチン、ゼイン、多糖類、ポリラクチド、ポリビニルア セテート、ポリアクリレート、糖アルコール、セラック、カゼイン、脂肪酸誘導 体、植物繊維、レシチン、またはキトサンが含有されている、請求項1から9ま でのいずれか1項記載の生物学的に分解可能なポリマー混合物。 11.ポリマー混合物が、少なくとも1種の有機充填剤を、再生可能な原料、 例えば特にセルロース繊維から得る、請求項1から10までのいずれか1項記載 の生物学的に分解可能なポリマー混合物。 12.熱可塑性デンプンの疎水性特性をさらに減少 するために架橋剤、例えばジカルボン酸もしくはポリカルボン酸ならびにその無 水物、イソシアネート、ホルムアルデヒドおよびその誘導体、尿素−ホルムアル デヒド、メラミン−ホルムアルデヒドもしくはフェノール−ホルムアルデヒド− 樹脂、リン酸エステル、ポリリン酸エステルおよび/または式: のアルキルケテン二量体[式中、R=C12〜C24の範囲の線状飽和アルキル 基]を使用する、請求項1から11までのいずれか1項記載の生物学的に分解可 能なポリマー混合物。 13.可塑剤もしくは膨潤剤を含有する熱可塑性デンプンの割合が、混合物の 総重量に対して10〜95重量%である、請求項1から12までのいずれか1項 記載の生物学的に分解可能なポリマー混合物。 14.熱可塑性デンプンの割合が混合物中で40〜65重量%である、請求項 1から13までのいずれか1項記載の生物学的に分解可能なポリマー混合物。 15.熱可塑性デンプン、脂肪族および芳香族ブロックを有するポリエステル −コポリマーならびにエチレンアクリル酸−コポリマーおよびエチレンビニルア ルコール−コポリマーから選択されたコポリマーを特 徴とする、請求項1から5までのいずれか1項記載の生物学的に分解可能なポリ マー混合物。 16.天然デンプンまたはその誘導体の発熱性転換により得られる熱可塑性デ ンプンと、少なくとも1種の以下のポリマー: 芳香族ポリエステル、 芳香族および脂肪族ブロックを有するポリエステル−コポリマー、 ポリエステルアミド、 ポリエチレンオキシドポリマーもしくはポリグリコール、 ポリエステルウレタン、 および/または混合物とを混合し、この場合溶融物を混合し、その際混合の前 および/または混合の際に混合物の重量に対して水含量を<1.0重量%に減少 する、請求項1から15までのいずれか1項記載のポリマー混合物の製造方法。 17.溶融物に付加的に脂肪族ポリエステルを添加する、請求項16記載の方 法。 18.混合の前および/または混合の際の水含量を<0.5重量%、有利には <0.1重量%に減少する、請求項16または17記載の方法。 19.溶融物の混合を120〜260℃の温度範囲で行う、請求項16から1 8までのいずれか1項記載の方法。 20.混合を押出機またはニーダーで行い、かつダイからの溶融物の引き出し 後、これを水浴で冷却し、調整し、引き続き例えば造粒する、請求項16から1 9までのいずれか1項記載の方法。 21.例えば顆粒として存在するポリマー混合物を射出成形、押出成形または 吹込成形で加工する前に、軟化剤、例えばグリセリン、ソルビトールなど、およ び/または水で調整する、請求項1から15までのいずれか1項記載のポリマー 混合物の加工方法。 22.顆粒として存在するポリマー混合物を水含量1〜6重量%に調整し、か つ引き続き射出成形、押出成形、または吹込成形してフィルムにし、この場合製 造された射出成形パーツまたは押出物もしくはフィルムを有利には製造後直接相 対湿度>40%を有する比較的湿度の高い環境に貯蔵する、請求項21記載の方 法。 23.単層または多層フィルムを製造するための請求項1から15までのいず れか1項記載のポリマー混合物の使用。 24.吹込成形で製造した容器または瓶の製造のための、請求項1から15ま でのいずれか1項記載のポリマー混合物の使用。 25.繊維製品、例えば繊維、モノフィル、糸、ロープ、綱、フロック、詰綿 、織物、フェルト、フリースを製造するための、請求項1から15までのいずれ か1項記載のポリマー混合物の使用。 26.ポリマー混合物からなるフリースおよび/またはバックシートを少なく とも1つ有する衛生用品、例えばおむつ、包帯、失禁用製品、ベッド用詰め物な どを製造するための、請求項1から15までのいずれか1項記載のポリマー混合 物の使用。 27.接着剤の製造のための、請求項1から15までのいずれか1項記載のポ リマー混合物またはそのアルコール溶液の使用。 28.コーティング、例えば特に含浸剤の製造のための、請求項1から15ま でのいずれか1項記載のポリマー混合物またはそのアルコール溶液の使用。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1995113237 DE19513237A1 (de) | 1995-04-07 | 1995-04-07 | Biologisch abbaubare Polymermischung |
DE19513237.8 | 1995-04-07 | ||
DE19515013 | 1995-04-24 | ||
DE19515013.9 | 1995-04-24 | ||
PCT/IB1996/000275 WO1996031561A1 (de) | 1995-04-07 | 1996-04-02 | Biologisch abbaubare polymermischung |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH10512010A true JPH10512010A (ja) | 1998-11-17 |
JP3107830B2 JP3107830B2 (ja) | 2000-11-13 |
Family
ID=26014241
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP08525223A Expired - Lifetime JP3107830B2 (ja) | 1995-04-07 | 1996-04-02 | 生物学的に分解可能なポリマー混合物 |
Country Status (12)
Country | Link |
---|---|
US (2) | US6096809A (ja) |
EP (1) | EP0819147B1 (ja) |
JP (1) | JP3107830B2 (ja) |
CN (1) | CN1181098A (ja) |
AT (1) | ATE242295T1 (ja) |
AU (1) | AU705499B2 (ja) |
CA (1) | CA2217541A1 (ja) |
DE (1) | DE59610506D1 (ja) |
DK (1) | DK0819147T3 (ja) |
ES (1) | ES2201173T3 (ja) |
PT (1) | PT819147E (ja) |
WO (1) | WO1996031561A1 (ja) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6515054B1 (en) | 1999-11-02 | 2003-02-04 | Nippon Shokubai Co., Ltd. | Biodegradable resin composition and its molded product |
JP2006526064A (ja) * | 2003-06-06 | 2006-11-16 | ザ プロクター アンド ギャンブル カンパニー | ヒドロキシル・ポリマーのための架橋系 |
JP2008536961A (ja) * | 2005-03-18 | 2008-09-11 | ノバモント・ソシエタ・ペル・アチオニ | 生分解性の脂肪−芳香族ポリエステル |
JP2009511765A (ja) * | 2005-10-11 | 2009-03-19 | ザ プロクター アンド ギャンブル カンパニー | デンプンを含む水安定性繊維及び物品並びにその製造方法 |
JP2009155531A (ja) * | 2007-12-27 | 2009-07-16 | Mitsubishi Chemicals Corp | 樹脂組成物及びその製造方法並びに該樹脂組成物からなるフィルム |
JP2011500934A (ja) * | 2007-10-22 | 2011-01-06 | バイオ−テック ビオローギッシュ ナチューフェアパックンゲン ゲーエムベーハー ウント コンパニ カーゲー | ポリマー材料およびその生産のための方法 |
JP2011516719A (ja) * | 2009-03-31 | 2011-05-26 | 武▲漢華麗▼生物材料有限公司 | 環境分解性高分子複合材料及びその製造方法 |
JP4809215B2 (ja) * | 2003-06-03 | 2011-11-09 | ビオテック ビオローギッシュ ナチューフェアパックンゲン ゲーエムベーハー ウント コンパニ カーゲー | 生分解性重合体又は重合体ブレンドで被覆又は含浸された繊維シート |
JP2015518499A (ja) * | 2012-03-28 | 2015-07-02 | テューリンギッシェス・インスティトゥート・フューア・テクスティル−ウント・クンストストッフ−フォルシュング・エー・ファウ | 液体形態で適用することができる多官能性コーティングフィルム |
Families Citing this family (175)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69732371T2 (de) | 1996-11-05 | 2005-06-30 | Novamont S.P.A. | Biologisch abbaubare Polymerzusammensetzungen, die Stärke und ein thermoplastisches Polymer enthalten |
ATE237656T1 (de) * | 1997-06-20 | 2003-05-15 | Biotec Biolog Naturverpack | Verschleissartikel in der wehr- bzw. pyrotechnik sowie faltfeststrassen, überfahr- und gehhilfen aus biologisch abbaubaren werkstoffen |
DE19822979A1 (de) * | 1998-05-25 | 1999-12-02 | Kalle Nalo Gmbh & Co Kg | Folie mit Stärke oder Stärkederivaten und Polyesterurethanen sowie Verfahren zu ihrer Herstellung |
AU4054199A (en) * | 1998-06-17 | 2000-01-05 | Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg | Foamed thermoplastic film made from biodegradable materials |
ITTO980524A1 (it) * | 1998-06-17 | 1999-12-17 | Novamont Spa | Composizioni contenenti amido aventi elevata resistenza all'invecchiam ento. |
DE19860836C1 (de) * | 1998-12-30 | 2000-05-18 | Haller Formholz | Verfahren und Vorrichtung zum kontinuierlichen Herstellen von Formkörpern |
US6440364B1 (en) * | 1999-02-16 | 2002-08-27 | Ethicon, Inc. | Method of degassing absorbable suture products |
DE60019994T2 (de) * | 1999-03-08 | 2006-01-19 | The Procter & Gamble Company, Cincinnati | Absorbierende und flexible Struktur mit Stärkefasern |
US6632925B1 (en) * | 1999-05-04 | 2003-10-14 | Iowa State University Research Foundation, Inc. | Biodegradable plant protein composites and related methods |
US6231970B1 (en) * | 2000-01-11 | 2001-05-15 | E. Khashoggi Industries, Llc | Thermoplastic starch compositions incorporating a particulate filler component |
KR20010081685A (ko) * | 2000-02-18 | 2001-08-29 | 윤여생 | 생분해성 방습 플라스틱 용기 |
WO2001074555A1 (en) * | 2000-03-31 | 2001-10-11 | Holy Norman L | Compostable, degradable plastic compositions and articles thereof |
DE10027905A1 (de) * | 2000-06-06 | 2001-12-13 | Bayer Ag | Biologisch abbaubare Formmassen mit sehr guter Fließfähigkeit sowie deren Herstellung und Verwendung |
WO2002014430A2 (de) * | 2000-08-11 | 2002-02-21 | Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg | Biologisch abbaubarer polymerblend |
US6573340B1 (en) | 2000-08-23 | 2003-06-03 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | Biodegradable polymer films and sheets suitable for use as laminate coatings as well as wraps and other packaging materials |
JP2002088161A (ja) * | 2000-09-14 | 2002-03-27 | Sony Corp | 生分解性樹脂組成物の弾性率向上方法 |
US7402618B2 (en) * | 2000-11-23 | 2008-07-22 | Hao Xu | Biodegradable composition for the preparation of tableware, drink container, mulching film and package and method for preparing the same |
CN1121452C (zh) * | 2000-11-23 | 2003-09-17 | 许浩 | 生物降解环保型餐具的配方及生产工艺 |
US7029620B2 (en) * | 2000-11-27 | 2006-04-18 | The Procter & Gamble Company | Electro-spinning process for making starch filaments for flexible structure |
US6811740B2 (en) | 2000-11-27 | 2004-11-02 | The Procter & Gamble Company | Process for making non-thermoplastic starch fibers |
US20030203196A1 (en) * | 2000-11-27 | 2003-10-30 | Trokhan Paul Dennis | Flexible structure comprising starch filaments |
US7297394B2 (en) * | 2002-03-01 | 2007-11-20 | Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg | Biodegradable films and sheets suitable for use as coatings, wraps and packaging materials |
US7241832B2 (en) * | 2002-03-01 | 2007-07-10 | bio-tec Biologische Naturverpackungen GmbH & Co., KG | Biodegradable polymer blends for use in making films, sheets and other articles of manufacture |
EP1392770A4 (en) * | 2001-04-18 | 2004-07-14 | Plantic Technologies Ltd | BIODEGRADABLE POLYMER |
US20030077444A1 (en) | 2001-05-10 | 2003-04-24 | The Procter & Gamble Company | Multicomponent fibers comprising starch and polymers |
US6946506B2 (en) | 2001-05-10 | 2005-09-20 | The Procter & Gamble Company | Fibers comprising starch and biodegradable polymers |
US6743506B2 (en) | 2001-05-10 | 2004-06-01 | The Procter & Gamble Company | High elongation splittable multicomponent fibers comprising starch and polymers |
US20020168518A1 (en) * | 2001-05-10 | 2002-11-14 | The Procter & Gamble Company | Fibers comprising starch and polymers |
US20020168912A1 (en) * | 2001-05-10 | 2002-11-14 | Bond Eric Bryan | Multicomponent fibers comprising starch and biodegradable polymers |
US6623854B2 (en) | 2001-05-10 | 2003-09-23 | The Procter & Gamble Company | High elongation multicomponent fibers comprising starch and polymers |
US20030148690A1 (en) * | 2001-05-10 | 2003-08-07 | Bond Eric Bryan | Multicomponent fibers comprising a dissolvable starch component, processes therefor, and fibers therefrom |
US6783854B2 (en) * | 2001-05-10 | 2004-08-31 | The Procter & Gamble Company | Bicomponent fibers comprising a thermoplastic polymer surrounding a starch rich core |
US7276201B2 (en) * | 2001-09-06 | 2007-10-02 | The Procter & Gamble Company | Process for making non-thermoplastic starch fibers |
US7071249B2 (en) * | 2001-10-05 | 2006-07-04 | William Ho | Biodegradable starch resin and method for making same |
US7077994B2 (en) * | 2001-10-19 | 2006-07-18 | The Procter & Gamble Company | Polyhydroxyalkanoate copolymer/starch compositions for laminates and films |
DE10214327A1 (de) | 2001-10-23 | 2003-05-22 | Innogel Ag Zug | Netzwerk auf Polysaccharidbasis und Verfahren zu dessen Herstellung |
US6723160B2 (en) * | 2002-02-01 | 2004-04-20 | The Procter & Gamble Company | Non-thermoplastic starch fibers and starch composition for making same |
US7005137B1 (en) * | 2002-06-21 | 2006-02-28 | Advanceed Cardiovascular Systems, Inc. | Coating for implantable medical devices |
US7217426B1 (en) | 2002-06-21 | 2007-05-15 | Advanced Cardiovascular Systems, Inc. | Coatings containing polycationic peptides for cardiovascular therapy |
US6821538B2 (en) * | 2002-07-09 | 2004-11-23 | T.F.H. Publications, Inc. | Blends of starch and aliphatic-aromatic based polyester resins |
US6830810B2 (en) * | 2002-11-14 | 2004-12-14 | The Procter & Gamble Company | Compositions and processes for reducing water solubility of a starch component in a multicomponent fiber |
DE10258227A1 (de) * | 2002-12-09 | 2004-07-15 | Biop Biopolymer Technologies Ag | Biologisch abbaubare Mehrschichtfolie |
DE10261786A1 (de) * | 2002-12-23 | 2004-07-01 | Fritz Häcker GmbH + Co.KG | Schmelzbarer Klebstoff auf Gelatinebasis |
US8791171B2 (en) | 2003-05-01 | 2014-07-29 | Abbott Cardiovascular Systems Inc. | Biodegradable coatings for implantable medical devices |
US7098292B2 (en) * | 2003-05-08 | 2006-08-29 | The Procter & Gamble Company | Molded or extruded articles comprising polyhydroxyalkanoate copolymer and an environmentally degradable thermoplastic polymer |
US6706942B1 (en) | 2003-05-08 | 2004-03-16 | The Procter & Gamble Company | Molded or extruded articles comprising polyhydroxyalkanoate copolymer compositions having short annealing cycle times |
US7879440B2 (en) * | 2003-11-25 | 2011-02-01 | Asahi Kasei Life & Living Corporation | Matte film |
US7160977B2 (en) * | 2003-12-22 | 2007-01-09 | Eastman Chemical Company | Polymer blends with improved notched impact strength |
US7368503B2 (en) * | 2003-12-22 | 2008-05-06 | Eastman Chemical Company | Compatibilized blends of biodegradable polymers with improved rheology |
US7368511B2 (en) * | 2003-12-22 | 2008-05-06 | Eastman Chemical Company | Polymer blends with improved rheology and improved unnotched impact strength |
US7326659B2 (en) * | 2004-02-16 | 2008-02-05 | Conwed Plastics Llc | Biodegradable netting |
US7776020B2 (en) * | 2004-03-19 | 2010-08-17 | Kimberly-Clark Worldwide, Inc. | Absorbent articles having an aliphatic-aromatic copolyester film |
US7153569B2 (en) * | 2004-03-19 | 2006-12-26 | Kimberly-Clark Worldwide, Inc. | Biodegradable aliphatic-aromatic copolyester films |
ITMI20040720A1 (it) * | 2004-04-09 | 2004-07-09 | Novamont Spa | Sacco da film biodegradabile ad elevata respirabilita' |
US6955850B1 (en) * | 2004-04-29 | 2005-10-18 | The Procter & Gamble Company | Polymeric structures and method for making same |
US6977116B2 (en) * | 2004-04-29 | 2005-12-20 | The Procter & Gamble Company | Polymeric structures and method for making same |
US20070095747A1 (en) * | 2004-05-07 | 2007-05-03 | Profile Products L.L.C. | Composite fiber environmental filtration media containing flocculant |
ITMI20041125A1 (it) * | 2004-06-03 | 2004-09-03 | Novamont Spa | Sistema ventilato per sacchi biodegradabili |
KR20070033344A (ko) * | 2004-06-03 | 2007-03-26 | 노바몬트 에스.피.에이. | 유기성 폐기물 수거용 통풍 시스템 |
DE102004027673B3 (de) * | 2004-06-07 | 2006-01-19 | Universität Ulm | Biodegradables Verbundsystem und dessen Verwendung sowie Verfahren zur Herstellung eines bioabbaubaren Block-copolyesterurethans |
US7244443B2 (en) | 2004-08-31 | 2007-07-17 | Advanced Cardiovascular Systems, Inc. | Polymers of fluorinated monomers and hydrophilic monomers |
US7629405B2 (en) * | 2004-11-19 | 2009-12-08 | Board Of Trustees Of Michigan State University | Starch-polyester biodegradable graft copolyers and a method of preparation thereof |
US20090160095A1 (en) * | 2004-11-19 | 2009-06-25 | Board Of Trustees Of Michigan State University | Biodegradable thermoplasticized starch-polyester reactive blends for thermoforming applications |
US20070021515A1 (en) * | 2005-07-19 | 2007-01-25 | United States (as represented by the Secretary of Agriculture) | Expandable starch-based beads and method of manufacturing molded articles therefrom |
US7989524B2 (en) * | 2005-07-19 | 2011-08-02 | The United States Of America, As Represented By The Secretary Of Agriculture | Fiber-reinforced starch-based compositions and methods of manufacture and use |
US20070128459A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) films |
US7666501B2 (en) * | 2005-12-07 | 2010-02-23 | E. I. Du Pont De Nemours And Company | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) bi-constituent filaments |
US20070129503A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) molded, shaped articles |
CN104802481A (zh) * | 2006-04-14 | 2015-07-29 | 生物技术天然包装两合公司 | 多层膜和其制造方法 |
US9028859B2 (en) | 2006-07-07 | 2015-05-12 | Advanced Cardiovascular Systems, Inc. | Phase-separated block copolymer coatings for implantable medical devices |
JP5030501B2 (ja) * | 2006-07-31 | 2012-09-19 | 関西ペイント株式会社 | 澱粉系塗料組成物 |
US7909003B2 (en) * | 2006-08-07 | 2011-03-22 | J. W. Pet Company, Inc. | Chew toys comprising biologically degradable material |
EP2057209A1 (en) * | 2006-08-31 | 2009-05-13 | Kimberly-Clark Worldwide, Inc. | Highly breathable biodegradable films |
US8592641B2 (en) | 2006-12-15 | 2013-11-26 | Kimberly-Clark Worldwide, Inc. | Water-sensitive biodegradable film |
CN101563392B (zh) * | 2006-12-15 | 2013-02-13 | 金伯利-克拉克环球有限公司 | 用于形成纤维的生物可降解聚酯 |
WO2008089098A1 (en) * | 2007-01-12 | 2008-07-24 | L & P Property Management Company | Environmentally friendly polymeric textile coating |
DE102007037166A1 (de) | 2007-08-07 | 2009-02-19 | Endress + Hauser Flowtec Ag | Meßgerät |
US8950614B2 (en) * | 2007-08-14 | 2015-02-10 | Toyo Seikan Kaisha, Ltd. | Biodegradable resin container with a vacuum-evaporated film and method of forming a vacuum-evaporated film |
US8329977B2 (en) | 2007-08-22 | 2012-12-11 | Kimberly-Clark Worldwide, Inc. | Biodegradable water-sensitive films |
CA2688516A1 (en) * | 2007-10-03 | 2009-04-09 | Universidad De Concepcion | Biodegradable composition, preparation method and their application in the manufacture of functional containers for agricultural and/or forestry use |
DE102007050770A1 (de) | 2007-10-22 | 2009-04-23 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | Polymeres Material und Verfahren zu dessen Herstellung |
DE102007057768A1 (de) * | 2007-11-30 | 2009-06-04 | Universität Ulm | Biodegradables Verbundsystem und dessen Verwendung |
US8227658B2 (en) | 2007-12-14 | 2012-07-24 | Kimberly-Clark Worldwide, Inc | Film formed from a blend of biodegradable aliphatic-aromatic copolyesters |
US7998888B2 (en) * | 2008-03-28 | 2011-08-16 | Kimberly-Clark Worldwide, Inc. | Thermoplastic starch for use in melt-extruded substrates |
AU2009241803B2 (en) * | 2008-04-30 | 2013-06-13 | Armstrong World Industries, Inc. | UV/EB curable biobased coating for flooring application |
AU2009241730B2 (en) * | 2008-04-30 | 2014-06-26 | Armstrong World Industries, Inc. | Biobased resilient floor tile |
ES2817544T3 (es) | 2008-05-06 | 2021-04-07 | Cj Cheiljedang Corp | Mezclas de poliéster biodegradables |
US8147965B2 (en) * | 2008-05-14 | 2012-04-03 | Kimberly-Clark Worldwide, Inc. | Water-sensitive film containing thermoplastic polyurethane |
US8338508B2 (en) * | 2008-05-14 | 2012-12-25 | Kimberly-Clark Worldwide, Inc. | Water-sensitive film containing an olefinic elastomer |
US8470222B2 (en) | 2008-06-06 | 2013-06-25 | Kimberly-Clark Worldwide, Inc. | Fibers formed from a blend of a modified aliphatic-aromatic copolyester and thermoplastic starch |
EP2291455B1 (de) * | 2008-06-18 | 2014-04-09 | Basf Se | Additive für polymerblends |
US8927617B2 (en) * | 2008-06-30 | 2015-01-06 | Kimberly-Clark Worldwide, Inc. | Fragranced water-sensitive film |
US8188185B2 (en) * | 2008-06-30 | 2012-05-29 | Kimberly-Clark Worldwide, Inc. | Biodegradable packaging film |
US8759279B2 (en) * | 2008-06-30 | 2014-06-24 | Kimberly-Clark Worldwide, Inc. | Fragranced biodegradable film |
FR2934272B1 (fr) * | 2008-07-24 | 2013-08-16 | Roquette Freres | Procede de preparation de compositions a base de matiere amylacee et de polymere synthetique. |
DE102008042893A1 (de) | 2008-10-16 | 2010-04-29 | Wacker Chemie Ag | Mischungen zur Herstellung von biologisch abbaubaren Formkörpern auf Basis von aliphatischen Polyestern und in Wasser redispergierbaren Polymerpulvern |
US8283006B2 (en) * | 2008-12-18 | 2012-10-09 | Kimberly-Clark Worldwide, Inc. | Injection molding material containing starch and plant protein |
US8329601B2 (en) | 2008-12-18 | 2012-12-11 | Kimberly-Clark Worldwide, Inc. | Biodegradable and renewable film |
CN106046702B (zh) * | 2008-12-26 | 2020-05-26 | 三菱化学株式会社 | 树脂组合物、膜、袋制品和树脂组合物的制造方法 |
AU2009202397A1 (en) * | 2009-06-16 | 2011-01-06 | Because We Care Pty Ltd | Biodegradable Polymeric Compositions |
FR2947557B1 (fr) | 2009-07-03 | 2011-12-09 | Ulice | Procede de production de materiau biodegradable |
JP5519996B2 (ja) * | 2009-10-20 | 2014-06-11 | 日東電工株式会社 | 表面保護用粘着シート |
IT1396597B1 (it) | 2009-11-05 | 2012-12-14 | Novamont Spa | Miscele di poliesteri biodegradabili |
IT1399031B1 (it) | 2009-11-05 | 2013-04-05 | Novamont Spa | Copoliestere alifatico-aromatico biodegradabile |
PT104846A (pt) | 2009-11-26 | 2011-05-26 | Cabopol Ind De Compostos S A | Misturas polim?ricas biocompost?veis |
US8586821B2 (en) * | 2009-12-23 | 2013-11-19 | Kimberly-Clark Worldwide, Inc. | Melt-processed films of thermoplastic cellulose and microbial aliphatic polyester |
CN102115576B (zh) * | 2009-12-31 | 2014-09-17 | 金伯利-克拉克环球有限公司 | 天然生物聚合物热塑性膜 |
FR2957928B1 (fr) | 2010-03-25 | 2013-07-05 | Roquette Freres | Compositions a base de matiere vegetale et procede de preparation de telles compositions |
US9226524B2 (en) | 2010-03-26 | 2016-01-05 | Philip Morris Usa Inc. | Biopolymer foams as filters for smoking articles |
US20120016328A1 (en) * | 2010-07-19 | 2012-01-19 | Bo Shi | Biodegradable films |
US8907155B2 (en) | 2010-11-19 | 2014-12-09 | Kimberly-Clark Worldwide, Inc. | Biodegradable and flushable multi-layered film |
MX2013005770A (es) | 2010-11-23 | 2013-06-18 | Procter & Gamble | Composiciones de almidon termoplastico. |
US20120178858A1 (en) | 2011-01-10 | 2012-07-12 | Andrew Julian Wnuk | Isosorbide-Plasticized Starch And Uses Thereof |
WO2012151693A1 (en) * | 2011-05-06 | 2012-11-15 | Cerestech, Inc. | Polymer blends comprising phase-encapsulated thermoplastic starch and process for making the same |
RU2013156462A (ru) | 2011-05-20 | 2015-06-27 | Дзе Проктер Энд Гэмбл Компани | Формованные изделия на основе композиций, содержащих крахмал, полимер, воск и масло |
CN103547715A (zh) | 2011-05-20 | 2014-01-29 | 宝洁公司 | 淀粉-聚合物-油组合物的纤维 |
RU2013147758A (ru) | 2011-05-20 | 2015-06-27 | Дзе Проктер Энд Гэмбл Компани | Пленки, выполненные из композиций, содержащих крахмал, полимер, воск и масло |
CN103635519A (zh) | 2011-05-20 | 2014-03-12 | 宝洁公司 | 淀粉-聚合物-油组合物、其制备和使用方法 |
CN102321249B (zh) | 2011-06-30 | 2013-01-16 | 无锡碧杰生物材料科技有限公司 | 一种热塑性淀粉和生物降解聚酯/淀粉复合材料及其制备 |
CN102295816B (zh) * | 2011-07-05 | 2012-08-08 | 吉林大学 | 一种可完全降解的填充改性聚乳酸复合材料的制备方法 |
US8933162B2 (en) | 2011-07-15 | 2015-01-13 | Saudi Basic Industries Corporation | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
US8877862B2 (en) | 2011-07-15 | 2014-11-04 | Saudi Basic Industries Corporation | Method for color stabilization of poly(butylene-co-adipate terephthalate |
US9334360B2 (en) | 2011-07-15 | 2016-05-10 | Sabic Global Technologies B.V. | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
CN102912475A (zh) * | 2011-08-04 | 2013-02-06 | 周新民 | 一种用多组分凝固浴液生产高强度壳聚糖纤维的制备方法 |
US8946345B2 (en) | 2011-08-30 | 2015-02-03 | Saudi Basic Industries Corporation | Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst |
US9327438B2 (en) * | 2011-12-20 | 2016-05-03 | Kimberly-Clark Worldwide, Inc. | Method for forming a thermoplastic composition that contains a plasticized starch polymer |
US9718258B2 (en) | 2011-12-20 | 2017-08-01 | Kimberly-Clark Worldwide, Inc. | Multi-layered film containing a biopolymer |
US8969506B2 (en) | 2012-02-15 | 2015-03-03 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
US8901273B2 (en) | 2012-02-15 | 2014-12-02 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
US8889820B2 (en) | 2012-02-15 | 2014-11-18 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
US9034983B2 (en) | 2012-03-01 | 2015-05-19 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof |
US8895660B2 (en) | 2012-03-01 | 2014-11-25 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture, and uses thereof |
US8901243B2 (en) | 2012-03-30 | 2014-12-02 | Saudi Basic Industries Corporation | Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
FR2992651B1 (fr) * | 2012-06-27 | 2015-07-17 | Arkema France | Utilisation d'un alliage d'amidon thermoplastique et de pof pour la fabrication d'un film ultra-fin imper-respirant adhesif. |
FR2992652B1 (fr) * | 2012-06-27 | 2014-06-20 | Arkema France | Utilisation d'un alliage d'amidon thermoplastique et de tpe pour la fabrication d'un film ultra-fin imper-respirant adhesif. |
CN104755538B (zh) | 2012-08-17 | 2018-08-31 | Cj 第一制糖株式会社 | 用于聚合物共混物的生物基橡胶改性剂 |
JP6033008B2 (ja) * | 2012-09-03 | 2016-11-30 | 株式会社クレハ | 樹脂組成物およびその用途 |
GB201217207D0 (en) * | 2012-09-26 | 2012-11-07 | Biome Bioplastics Ltd | Bio-resins |
CN102907362B (zh) * | 2012-11-05 | 2014-05-28 | 连云港耐特网具有限公司 | 一种防藻型海洋养殖用网 |
CN104781332A (zh) | 2012-11-20 | 2015-07-15 | 宝洁公司 | 淀粉-热塑性聚合物-油脂组合物及其制备和使用方法 |
US20140142225A1 (en) | 2012-11-20 | 2014-05-22 | The Procter & Gamble Company | Starch-Thermoplastic Polymer-Soap Compositions and Methods of Making and Using the Same |
US20140272370A1 (en) | 2013-03-15 | 2014-09-18 | The Procter & Gamble Company | Renewable Thermoplastic Starch-Polyolefin Compositions Comprising Compatibilizer and Flexible Thin Films Made Therefrom |
CN105246972B (zh) * | 2013-04-10 | 2018-06-08 | 生物天然包装材料研究与开发有限及两合公司 | 聚合物组合物 |
EP2799232A1 (en) | 2013-04-30 | 2014-11-05 | The Procter & Gamble Company | Flexible package |
EP2799231A1 (en) | 2013-04-30 | 2014-11-05 | The Procter & Gamble Company | Flexible package |
WO2014189905A1 (en) | 2013-05-20 | 2014-11-27 | The Procter & Gamble Company | Nonwoven webs with visually distinct bond sites and method of making |
CN105531308B (zh) | 2013-05-30 | 2021-08-10 | Cj 第一制糖株式会社 | 回收物共混物 |
WO2015066588A1 (en) | 2013-11-04 | 2015-05-07 | The Procter & Gamble Company | Thermoplastic polymer compositions having co-continuous plate-like morphology |
WO2015149029A1 (en) | 2014-03-27 | 2015-10-01 | Metabolix, Inc. | Highly filled polymer systems |
CA2945660A1 (en) | 2014-05-12 | 2015-11-19 | The Procter & Gamble Company | Microtextured films with improved tactile impression and/or reduced noise perception |
ES2556680B1 (es) * | 2014-07-18 | 2016-11-03 | Moreda - Riviere Trefilerías, S.A. | Alambre recubierto, procedimiento de obtención del mismo y malla que lo comprende |
CN104212166B (zh) * | 2014-09-05 | 2016-06-29 | 东莞市瀛通电线有限公司 | 一种信号线用可降解材料及其制备方法 |
CN104371173A (zh) * | 2014-11-07 | 2015-02-25 | 苏州维泰生物技术有限公司 | 一种可降解包装材料用母料及其制备方法 |
LT3310405T (lt) | 2015-06-17 | 2019-12-27 | Hollister Incorporated | Vandenyje suyrantis plaunamas kateteris |
CN104877320A (zh) * | 2015-06-18 | 2015-09-02 | 王宏城 | 一种用于包装材料的新型pcl组合物及其制备方法 |
KR20180064535A (ko) | 2015-11-03 | 2018-06-14 | 킴벌리-클라크 월드와이드, 인크. | 고 벌크 및 저 린트를 갖는 페이퍼 티슈 |
CN106544787A (zh) * | 2016-12-12 | 2017-03-29 | 墨宝股份有限公司 | 一种具有降解功能的非织造新材料的生产工艺 |
MY200682A (en) * | 2017-01-20 | 2024-01-11 | Danimer Bioplastics Inc | Biodegradable hot melt adhesives |
CN106967279A (zh) * | 2017-03-22 | 2017-07-21 | 中联西北工程设计研究院有限公司 | 用于3d打印的pla、淀粉复合材料及其制备工艺 |
US20210100260A1 (en) | 2017-04-06 | 2021-04-08 | Cryovac, Llc | Film, package and method for cheese ripening and preservation |
JP7358340B2 (ja) | 2017-05-26 | 2023-10-10 | インフィニット・マテリアル・ソリューションズ,エルエルシー | 水溶性ポリマー組成物 |
EP3466385B1 (en) | 2017-10-06 | 2020-05-27 | The Procter & Gamble Company | Absorbent article or wipe comprising a nonwoven material with bicomponent fibers comprising antimony-free polyethylene terephthalate |
EP3466389B1 (en) | 2017-10-06 | 2020-05-20 | The Procter & Gamble Company | Absorbent article comprising a carded resin-bonded nonwoven web with fibers comprising antimony-free polyethylene terephthalate |
EP3466388B1 (en) | 2017-10-06 | 2020-05-20 | The Procter & Gamble Company | Absorbent article comprising a nonwoven material with antimony-free polyethylene terephthalate |
CN107780041A (zh) * | 2017-10-18 | 2018-03-09 | 芜湖缆胜电缆新材料有限公司 | 一种阻燃型聚丙烯网状填充绳及其制备方法 |
MX2020004101A (es) | 2017-11-29 | 2020-07-24 | Kimberly Clark Co | Lamina fibrosa con propiedades mejoradas. |
CN108517621A (zh) * | 2018-03-30 | 2018-09-11 | 徐冬 | 一种无纺布的制备方法 |
GB2590316B (en) | 2018-07-25 | 2022-06-01 | Kimberly Clark Co | Process for making three-dimensional foam-laid nonwovens |
EP3689955B1 (en) | 2019-02-01 | 2022-11-09 | United Resins - Produção de Resinas S.A. | Improved starch based biodegradable polymers |
CN111038027A (zh) * | 2019-12-21 | 2020-04-21 | 广东顺德贰发毛绒有限公司 | 可生物降解的静电植绒纸产品的生产工艺 |
US11149131B2 (en) * | 2020-01-30 | 2021-10-19 | Edward Showalter | Earth plant compostable biodegradable substrate and method of producing the same |
US10882977B1 (en) * | 2020-01-30 | 2021-01-05 | Edward Showalter | Earth plant compostable biodegradable substrate and method of producing the same |
WO2022253731A1 (de) * | 2021-06-02 | 2022-12-08 | Periplast Werkzeugbau Und Kunststoffverarbeitung Gmbh & Co. Kg | Thermoplastisches material und verfahren zur herstellung eines formkörpers aus einem thermoplastischen material und formkörper |
CN113462021B (zh) * | 2021-07-19 | 2022-05-10 | 江南大学 | 一种天然填料及其高强高韧聚合物复合材料、制备方法和应用 |
CN116695273A (zh) * | 2023-05-17 | 2023-09-05 | 百事基材料(青岛)股份有限公司 | 含雪莲活性成分的锦纶大生物纤维及其制备方法 |
Family Cites Families (84)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3446079A (en) * | 1967-07-17 | 1969-05-27 | Singer General Precision | Linear electrostatic accelerometer |
US3867324A (en) * | 1972-07-28 | 1975-02-18 | Union Carbide Corp | Environmentally degradable-biodegradable blend of an oxyalkanoyl polymer and an environmentally degradable ethylene polymer |
US3850863A (en) * | 1972-07-28 | 1974-11-26 | Union Carbide Corp | Blends of a biodegradable thermoplastic oxyalkanoyl polymer and a naturally occurring biodegradable product |
US3921333A (en) * | 1972-07-28 | 1975-11-25 | Union Carbide Corp | Transplanter containers made from biodegradable-environmentally degradable blends |
US4076846A (en) * | 1974-11-22 | 1978-02-28 | Sumitomo Bakelite Company Limited | Protein-starch binary molding composition and shaped articles obtained therefor |
US3949145A (en) * | 1975-02-27 | 1976-04-06 | The United States Of America As Represented By The Secretary Of Agriculture | Degradable starch-based agricultural mulch film |
US4133784A (en) * | 1977-09-28 | 1979-01-09 | The United States Of America As Represented By The Secretary Of Agriculture | Biodegradable film compositions prepared from starch and copolymers of ethylene and acrylic acid |
JPS6054322B2 (ja) * | 1977-09-30 | 1985-11-29 | 株式会社林原生物化学研究所 | 成形物の製法 |
US4337181A (en) * | 1980-01-17 | 1982-06-29 | The United States Of America As Represented By The Secretary Of Agriculture | Biodegradable starch-based blown films |
ZA815185B (en) * | 1980-08-06 | 1982-09-29 | Coloroll Ltd | Plastics based composition |
US4394930A (en) * | 1981-03-27 | 1983-07-26 | Johnson & Johnson | Absorbent foam products |
US4410571A (en) * | 1980-08-25 | 1983-10-18 | Johnson & Johnson | Absorbent products, process and compositions for immobilization of particulate absorbents |
US4482386A (en) * | 1982-03-26 | 1984-11-13 | Warner-Lambert Company | Method of conditioning a water swellable hydrocolloid |
US4655840A (en) * | 1982-03-26 | 1987-04-07 | Warner-Lambert Company | Hydrophilic polymer compositions for injection molding |
US4454268A (en) * | 1983-06-23 | 1984-06-12 | The United States Of America As Represented By The Secretary Of Agriculture | Starch-based semipermeable films |
US4673438A (en) * | 1984-02-13 | 1987-06-16 | Warner-Lambert Company | Polymer composition for injection molding |
US4846932A (en) * | 1986-12-31 | 1989-07-11 | Kuromatsu Corporation Co., Ltd. | Water setting paper |
GB2205323B (en) * | 1987-03-09 | 1991-01-30 | Warner Lambert Co | Destructurized starch and process for making same |
GB2208651B (en) * | 1987-08-18 | 1991-05-08 | Warner Lambert Co | Shaped articles made from pre-processed starch |
US5095054A (en) * | 1988-02-03 | 1992-03-10 | Warner-Lambert Company | Polymer compositions containing destructurized starch |
GB2214918B (en) * | 1988-02-03 | 1992-10-07 | Warner Lambert Co | Polymeric materials made from starch and at least one synthetic thermoplastic polymeric material |
US5362777A (en) * | 1988-11-03 | 1994-11-08 | Ivan Tomka | Thermoplastically processable starch and a method of making it |
IE66735B1 (en) * | 1988-11-03 | 1996-02-07 | Biotec Biolog Naturverpack | Thermoplastically workable starch and a method for the manufacture thereof |
US5043196A (en) * | 1989-05-17 | 1991-08-27 | National Starch And Chemical Investment Holding Corporation | Biodegradable shaped products and the method of preparation thereof |
US4863655A (en) * | 1988-12-30 | 1989-09-05 | National Starch And Chemical Corporation | Biodegradable packaging material and the method of preparation thereof |
US5035930A (en) * | 1988-12-30 | 1991-07-30 | National Starch And Chemical Investment Holding Corporation | Biodegradable shaped products and the method of preparation thereof |
IL93620A0 (en) * | 1989-03-09 | 1990-12-23 | Butterfly Srl | Biodegradable articles based on starch and process for producing them |
IT1233599B (it) * | 1989-05-30 | 1992-04-06 | Butterfly Srl | Composizioni polimeriche per la produzione di articoli di materiale plastico biodegradabile e procedimenti per la loro preparazione |
US5314754A (en) * | 1989-06-01 | 1994-05-24 | Goodman Fielder Wattie Australia Limited | Starch derived shaped articles |
IL94647A0 (en) * | 1989-07-06 | 1991-04-15 | Warner Lambert Co | Polymer base blend compositions containing destructurized starch |
YU128990A (sh) * | 1989-07-11 | 1993-05-28 | Warner-Lambert Co. | Preparati polimernih smeša koji sadrže destrukturisani skrob |
IL94966A (en) * | 1989-07-11 | 1994-11-28 | Warner Lambert Co | Polymeric base blend preparations containing starch whose structure has been destroyed |
IE66345B1 (en) * | 1989-07-18 | 1995-12-27 | Warner Lambert Co | Polymer base blend compositions containing destructurized starch |
YU134490A (sh) * | 1989-07-18 | 1992-09-07 | Warner-Labmert Company | Preparati polimernih smeša koji sadrže destrukturisani skrob |
US5288765A (en) * | 1989-08-03 | 1994-02-22 | Spherilene S.R.L. | Expanded articles of biodegradable plastics materials and a method for their production |
IT1232910B (it) * | 1989-08-07 | 1992-03-05 | Butterfly Srl | Composizioni polimeriche per la produzione di articoli di materiale plastico biodegradabile e procedimenti per la loro preparazione |
US5059642A (en) * | 1989-09-14 | 1991-10-22 | Iowa State University Research Foundation, Inc. | Degradable plastics from octenyl succinate starch |
JPH03199245A (ja) * | 1989-12-27 | 1991-08-30 | Agency Of Ind Science & Technol | 微生物崩壊性熱可塑性樹脂発泡体及びその製造方法 |
DE69125965T2 (de) * | 1990-02-28 | 1997-09-25 | Agency Ind Science Techn | Verfahren zur Herstellung eines bioabbaubaren, formbaren Materials |
US5108807A (en) * | 1990-03-14 | 1992-04-28 | First Brands Corporation | Degradable multilayer thermoplastic articles |
US5219646A (en) * | 1990-05-11 | 1993-06-15 | E. I. Du Pont De Nemours And Company | Polyester blends and their use in compostable products such as disposable diapers |
US5115000A (en) * | 1990-06-19 | 1992-05-19 | Iowa State University Research Foundation, Inc. | Biodegradable starch plastics incorporating modified polyethylene |
IT1240503B (it) * | 1990-07-25 | 1993-12-17 | Butterfly Srl | Miscela polimerica amidacea particolarmente per la produzione di film e simili e procedimento per la sua produzione. |
GB9017300D0 (en) * | 1990-08-07 | 1990-09-19 | Cerestar Holding Bv | Starch treatment process |
JP3362040B2 (ja) * | 1990-11-30 | 2003-01-07 | イーストマン ケミカル カンパニー | 脂肪族−芳香族コポリエステル |
US5046730A (en) * | 1990-12-10 | 1991-09-10 | Bio Dynamics, Ltd. | Golf tee |
US5292782A (en) * | 1991-02-20 | 1994-03-08 | Novamont S.P.A. | Biodegradable polymeric compositions based on starch and thermoplastic polymers |
US5186990A (en) * | 1991-04-05 | 1993-02-16 | Eagle Scientific Co. | Biodegradable and water soluble packaging material |
IT1256693B (it) * | 1992-03-10 | 1995-12-12 | Novamont Spa | Composizione polimerica amidacea filmabile, ed articoli sagomati, particolarmente film e foglie ottenibili da tale composizione, aventi elevato effetto barriera e procedimento relativo. |
US5412005A (en) * | 1991-05-03 | 1995-05-02 | Novamont S.P.A. | Biodegradable polymeric compositions based on starch and thermoplastic polymers |
HU216971B (hu) * | 1991-05-03 | 1999-10-28 | Novamont S.P.A. | Keményítő- és hőrelágyulóműanyag-alapú, biológiailag lebomló polimerkompozíciók |
EP0525245A1 (en) * | 1991-08-01 | 1993-02-03 | NOVAMONT S.p.A. | Disposable absorbent articles |
DE4116404A1 (de) * | 1991-05-18 | 1992-11-19 | Tomka Ivan | Polymermischung fuer die herstellung von folien |
SK147693A3 (en) * | 1991-06-26 | 1994-09-07 | Procter & Gamble | Biodegradable, liquid impervious film |
DE4122212C2 (de) * | 1991-07-04 | 1994-06-16 | Inventa Ag | Thermoplastisch verarbeitbare Masse aus Stärke und Acrylatcopolymeren |
EP0524920B1 (de) * | 1991-07-26 | 1996-05-29 | Mundigler, Norbert, Dipl.-Ing. | Neuartige Formkörper |
US5256711A (en) * | 1991-10-04 | 1993-10-26 | Director-General Of Agency Of Industrial Science | Starch-containing biodegradable plastic and method of producing same |
DE4133335C2 (de) * | 1991-10-08 | 1995-11-02 | Inventa Ag | Stärkemischung, Verfahren zu ihrer Herstellung sowie Verwendung derselben |
DE4134190A1 (de) * | 1991-10-16 | 1993-04-22 | Tomka Ivan | Verfahren zur verbesserung der mechanischen eigenschaften von ein- oder mehrschichtfolien |
US5252271A (en) * | 1991-10-22 | 1993-10-12 | Bio-Products International | Biodegradable packaging foam and method of preparation |
SG47625A1 (en) * | 1991-11-14 | 1998-04-17 | Bio Tech Biolog Naturverparkun | Biodegradable mould material |
US5248702A (en) * | 1992-01-21 | 1993-09-28 | Kansas State University Research Foundation | Starch-based, biodegradable packing filler and method of preparing same |
US5208267A (en) * | 1992-01-21 | 1993-05-04 | Univ Kansas State | Starch-based, biodegradable packing filler and method of preparing same |
US5185382A (en) * | 1992-01-21 | 1993-02-09 | Kansas State University Research Foundation | Starch-based, biodegradable packing filler and method of preparing same |
US5427614A (en) * | 1992-02-14 | 1995-06-27 | Warner-Lambert Company | Starch based formulations |
US5266368A (en) * | 1992-04-16 | 1993-11-30 | International Grain & Milling Company | Biodegradable packing material and method |
US5372877A (en) * | 1992-04-16 | 1994-12-13 | Sealed Air | Biodegradable cushioning product |
DE4228016C1 (de) * | 1992-08-24 | 1994-03-31 | Biotec Biolog Naturverpack | Verfahren zum Herstellen von biologisch abbaubaren Folien aus pflanzlichen Rohstoffen |
US5308879A (en) * | 1992-09-07 | 1994-05-03 | Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha | Process for preparing biodegradable resin foam |
JP3019631B2 (ja) | 1992-11-04 | 2000-03-13 | 松下電器産業株式会社 | 文書画像印字装置 |
US5844023A (en) * | 1992-11-06 | 1998-12-01 | Bio-Tec Biologische Naturverpackungen Gmbh | Biologically degradable polymer mixture |
DE4237535C2 (de) * | 1992-11-06 | 2000-05-25 | Biotec Biolog Naturverpack | Biologisch abbaubare Polymermischung, ein Verfahren und eine Folie |
US5272181A (en) * | 1992-11-18 | 1993-12-21 | Evergreen Solutions, Inc. | Biodegradable expanded foam material |
US5393804A (en) * | 1992-11-24 | 1995-02-28 | Parke, Davis & Company | Biodegradable compositions comprising starch and alkenol polymers |
KR950006538B1 (ko) * | 1992-12-31 | 1995-06-16 | 김두현 | 일회용 용기의 제조방법 |
DE4400330C2 (de) * | 1993-03-24 | 1997-10-02 | Naturpack Gmbh Verpackungen Au | Verfahren zum Herstellen eines geschäumten Produktes oder Schaumstoffmaterials aus nichtmodifizierter Stärke sowie Einrichtung zum Durchführen des Verfahrens |
US5512090A (en) * | 1993-06-24 | 1996-04-30 | Free-Flow Packaging Corporation | Compositions for resilient biodegradable packaging material products |
US5288318A (en) * | 1993-07-01 | 1994-02-22 | The United States Of America As Represented By The Secretary Of The Army | Cellulose acetate and starch based biodegradable injection molded plastics compositions and methods of manufacture |
DE4327024A1 (de) * | 1993-08-12 | 1995-02-16 | Bayer Ag | Thermoplastisch verarbeitbare und biologisch abbaubare aliphatische Polyesteramide |
US5397834A (en) * | 1993-09-03 | 1995-03-14 | Iowa State University Research Foundation, Inc. | Biodegradable thermoplastic composition of aldehyde starch and protein |
DE4335983A1 (de) * | 1993-10-21 | 1995-04-27 | Inventa Ag | Verfahren zur Erhöhung der Transparenz von Formkörpern oder Folien aus thermoplastischer Stärke oder thermoplastischem Stärke-Polymer-Blend |
US5500465A (en) * | 1994-03-10 | 1996-03-19 | Board Of Trustees Operating Michigan State University | Biodegradable multi-component polymeric materials based on unmodified starch-like polysaccharides |
DE19500756A1 (de) * | 1995-01-13 | 1996-07-18 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
DE19536505A1 (de) * | 1995-09-29 | 1997-04-10 | Biotec Biolog Naturverpack | Biologisch abbaubares Filtermaterial und Verfahren zu seiner Herstellung |
-
1996
- 1996-04-02 US US08/930,748 patent/US6096809A/en not_active Expired - Lifetime
- 1996-04-02 DE DE59610506T patent/DE59610506D1/de not_active Expired - Lifetime
- 1996-04-02 CA CA002217541A patent/CA2217541A1/en not_active Abandoned
- 1996-04-02 AT AT96905977T patent/ATE242295T1/de active
- 1996-04-02 AU AU49522/96A patent/AU705499B2/en not_active Ceased
- 1996-04-02 PT PT96905977T patent/PT819147E/pt unknown
- 1996-04-02 ES ES96905977T patent/ES2201173T3/es not_active Expired - Lifetime
- 1996-04-02 DK DK96905977T patent/DK0819147T3/da active
- 1996-04-02 JP JP08525223A patent/JP3107830B2/ja not_active Expired - Lifetime
- 1996-04-02 EP EP96905977A patent/EP0819147B1/de not_active Expired - Lifetime
- 1996-04-02 CN CN96193126A patent/CN1181098A/zh active Pending
- 1996-04-02 WO PCT/IB1996/000275 patent/WO1996031561A1/de active IP Right Grant
-
1999
- 1999-10-27 US US09/428,512 patent/US6235816B1/en not_active Expired - Lifetime
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6515054B1 (en) | 1999-11-02 | 2003-02-04 | Nippon Shokubai Co., Ltd. | Biodegradable resin composition and its molded product |
JP4809215B2 (ja) * | 2003-06-03 | 2011-11-09 | ビオテック ビオローギッシュ ナチューフェアパックンゲン ゲーエムベーハー ウント コンパニ カーゲー | 生分解性重合体又は重合体ブレンドで被覆又は含浸された繊維シート |
JP2006526064A (ja) * | 2003-06-06 | 2006-11-16 | ザ プロクター アンド ギャンブル カンパニー | ヒドロキシル・ポリマーのための架橋系 |
JP2008536961A (ja) * | 2005-03-18 | 2008-09-11 | ノバモント・ソシエタ・ペル・アチオニ | 生分解性の脂肪−芳香族ポリエステル |
JP2009511765A (ja) * | 2005-10-11 | 2009-03-19 | ザ プロクター アンド ギャンブル カンパニー | デンプンを含む水安定性繊維及び物品並びにその製造方法 |
JP2009511766A (ja) * | 2005-10-11 | 2009-03-19 | ザ プロクター アンド ギャンブル カンパニー | デンプンを含む水安定性繊維及び物品並びにその製造方法 |
JP2011500934A (ja) * | 2007-10-22 | 2011-01-06 | バイオ−テック ビオローギッシュ ナチューフェアパックンゲン ゲーエムベーハー ウント コンパニ カーゲー | ポリマー材料およびその生産のための方法 |
JP2009155531A (ja) * | 2007-12-27 | 2009-07-16 | Mitsubishi Chemicals Corp | 樹脂組成物及びその製造方法並びに該樹脂組成物からなるフィルム |
JP2011516719A (ja) * | 2009-03-31 | 2011-05-26 | 武▲漢華麗▼生物材料有限公司 | 環境分解性高分子複合材料及びその製造方法 |
JP2015518499A (ja) * | 2012-03-28 | 2015-07-02 | テューリンギッシェス・インスティトゥート・フューア・テクスティル−ウント・クンストストッフ−フォルシュング・エー・ファウ | 液体形態で適用することができる多官能性コーティングフィルム |
Also Published As
Publication number | Publication date |
---|---|
DE59610506D1 (de) | 2003-07-10 |
EP0819147B1 (de) | 2003-06-04 |
AU4952296A (en) | 1996-10-23 |
CA2217541A1 (en) | 1996-10-10 |
US6096809A (en) | 2000-08-01 |
WO1996031561A1 (de) | 1996-10-10 |
PT819147E (pt) | 2003-10-31 |
ES2201173T3 (es) | 2004-03-16 |
US6235816B1 (en) | 2001-05-22 |
ATE242295T1 (de) | 2003-06-15 |
JP3107830B2 (ja) | 2000-11-13 |
DK0819147T3 (da) | 2003-09-29 |
AU705499B2 (en) | 1999-05-27 |
EP0819147A1 (de) | 1998-01-21 |
CN1181098A (zh) | 1998-05-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP3107830B2 (ja) | 生物学的に分解可能なポリマー混合物 | |
AU724636B2 (en) | Biodegradable material essentially consisting of, or based on, thermoplastic starch | |
KR100893840B1 (ko) | 생분해성 폴리에스테르의 삼원성 혼합물 및 이로부터제조된 제품 | |
JP4842502B2 (ja) | 生分解性ポリエステル類の三成分混合物とそれから製造された製品 | |
JP5589377B2 (ja) | 樹脂組成物、フィルム、袋製品、および、樹脂組成物の製造方法 | |
US6284838B1 (en) | Biodegradable composition | |
JP3923094B2 (ja) | 溶融加工可能な生物分解性組成物およびその製品 | |
JP3423320B2 (ja) | 生物学的に分解可能なポリマー、その製造法ならびに該ポリマーから得ることができる複合可能な成形体、接着剤、生物学的に分解可能な配合物、生物学的に分解可能なフォームおよび紙加工用組成物 | |
CA2775181C (en) | Biodegradable composition comprising polymers of natural origin and aliphatic-aromatic copolyesters | |
WO1996031561B1 (de) | Biologisch abbaubare polymermischung | |
KR101000749B1 (ko) | 생분해성 수지 조성물, 그의 제조방법 및 그로부터 제조되는 생분해성 필름 | |
JP2000017164A (ja) | ポリ乳酸ステレオコンプレックスポリマー製造用ペレット、及びステレオコンプレックスポリマー成型物の製造方法 | |
JPH11500762A (ja) | 生物学的に分解可能なポリマー、その製法、並びに生物分解可能な成形体の製造のためのその使用 | |
JPH06504799A (ja) | 乳酸からの包装用熱可塑性プラスチック | |
JPH11500761A (ja) | 生分解可能なポリマー、その製造方法並びに生分解可能な成形体の製造のためのその使用 | |
JP2001261797A (ja) | 脂肪族ポリエステル樹脂および成形品 | |
JP5200208B2 (ja) | 脂肪族芳香族ポリエステル及び樹脂組成物 | |
JPH11241008A (ja) | ポリ乳酸系樹脂組成物 | |
KR101132382B1 (ko) | 생분해성 수지 조성물, 그의 제조방법 및 그로부터 제조되는 생분해성 필름 | |
JP2001323056A (ja) | 脂肪族ポリエステル樹脂および成形品 | |
JPH11241009A (ja) | ポリ乳酸系樹脂組成物 | |
JP2000345012A (ja) | 樹脂組成物 | |
Ariff et al. | Advances in Polylactic Acid Composites with Biofiller as 3D Printing Filaments in Biomedical Applications | |
DE19513237A1 (de) | Biologisch abbaubare Polymermischung | |
JP2000129035A (ja) | 樹脂組成物およびその成形品 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080908 Year of fee payment: 8 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090908 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090908 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100908 Year of fee payment: 10 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110908 Year of fee payment: 11 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110908 Year of fee payment: 11 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120908 Year of fee payment: 12 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120908 Year of fee payment: 12 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130908 Year of fee payment: 13 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
EXPY | Cancellation because of completion of term |