JPH06100614A - オレフィン重合用触媒およびこれを用いるオレフィンの重合方法 - Google Patents

オレフィン重合用触媒およびこれを用いるオレフィンの重合方法

Info

Publication number
JPH06100614A
JPH06100614A JP5171256A JP17125693A JPH06100614A JP H06100614 A JPH06100614 A JP H06100614A JP 5171256 A JP5171256 A JP 5171256A JP 17125693 A JP17125693 A JP 17125693A JP H06100614 A JPH06100614 A JP H06100614A
Authority
JP
Japan
Prior art keywords
compound
catalyst
group
organoaluminum
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5171256A
Other languages
English (en)
Japanese (ja)
Inventor
Tatsumasa Oono
野 龍 昌 大
Toshiyuki Tsutsui
井 俊 之 筒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Petrochemical Industries Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26494048&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JPH06100614(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Priority to JP5171256A priority Critical patent/JPH06100614A/ja
Priority to KR1019930015133A priority patent/KR0178072B1/ko
Priority to DE69331123T priority patent/DE69331123T2/de
Priority to EP93306210A priority patent/EP0582480B1/en
Priority to CA002101965A priority patent/CA2101965C/en
Publication of JPH06100614A publication Critical patent/JPH06100614A/ja
Priority to US08/603,096 priority patent/US5840645A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
JP5171256A 1992-08-06 1993-06-17 オレフィン重合用触媒およびこれを用いるオレフィンの重合方法 Pending JPH06100614A (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP5171256A JPH06100614A (ja) 1992-08-06 1993-06-17 オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
KR1019930015133A KR0178072B1 (ko) 1992-08-06 1993-08-04 올레핀 중합용 촉매 및 그를 사용한 올레핀 중합방법
DE69331123T DE69331123T2 (de) 1992-08-06 1993-08-05 Olefinpolymerisationskatalysatoren und diese verwendendes Olefinpolymerisationsverfahren
EP93306210A EP0582480B1 (en) 1992-08-06 1993-08-05 Olefin polymerization catalyst and method for the polymerization of olefin using said polymerization catalyst
CA002101965A CA2101965C (en) 1992-08-06 1993-08-05 Olefin polymerization catalyst and method for the polymerization of olefin using said olefin polymerization catalyst
US08/603,096 US5840645A (en) 1992-08-06 1996-02-20 Olefin polymerization catalyst and method for the polymerization of olefin using said olefin polymerization catalyst

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP21040892 1992-08-06
JP4-210408 1992-08-06
JP5171256A JPH06100614A (ja) 1992-08-06 1993-06-17 オレフィン重合用触媒およびこれを用いるオレフィンの重合方法

Publications (1)

Publication Number Publication Date
JPH06100614A true JPH06100614A (ja) 1994-04-12

Family

ID=26494048

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5171256A Pending JPH06100614A (ja) 1992-08-06 1993-06-17 オレフィン重合用触媒およびこれを用いるオレフィンの重合方法

Country Status (6)

Country Link
US (1) US5840645A (enExample)
EP (1) EP0582480B1 (enExample)
JP (1) JPH06100614A (enExample)
KR (1) KR0178072B1 (enExample)
CA (1) CA2101965C (enExample)
DE (1) DE69331123T2 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7345119B2 (en) 2003-12-01 2008-03-18 Maruzen Petrochemical Company, Limited Olefin polymerization catalyst and olefin polymerization method using the same
JP2012149188A (ja) * 2011-01-20 2012-08-09 Mitsui Chemicals Inc オレフィン重合体の製造方法

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2193888A1 (en) * 1994-06-24 1996-01-04 Howard Curtis Welborn Jr. (Deceased) Polymerization process and catalyst systems useful therein
TR28720A (tr) * 1994-07-11 1997-02-18 Montell Technology Company Bv Olefinlerin polimerizasyonu icin desteklenmis katalizörler.
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
DE69529230T2 (de) * 1994-11-17 2003-09-04 Dow Global Technologies, Inc. Trägerkatalysatorkomponent, Trägerkatalysator, ihre Herstellung und Additionspolymerisationsverfahren
US6043180A (en) * 1994-11-17 2000-03-28 The Dow Chemical Company Supported catalyst component, supported catalyst, their preparation, and addition polymerization process
US5569746A (en) * 1995-01-23 1996-10-29 Albemarle Corporation Process for preparing alkylsubstituted cyclopentadienyl metallocene compounds
DE59503159D1 (de) * 1995-02-17 1998-09-17 Witco Gmbh Verfahren zur Herstellung von Übergangsmetallkomplexen mit 1,3-disubstituierten Cyclopentadienyl-Liganden
US5756416A (en) 1995-11-28 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition having improved comonomer reactivity
DE19621838A1 (de) * 1996-05-31 1997-12-04 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶2¶-Alkenen unter Zusatz eines Reaktionsverzögerers
KR20050085684A (ko) 2002-12-16 2005-08-29 바젤 폴리올레핀 게엠베하 알루미녹산 함량이 감소된, 지지된 촉매계의 제조방법
EP1910431B1 (en) 2005-07-19 2013-11-27 ExxonMobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
US9272965B2 (en) * 2009-12-22 2016-03-01 Catalytic Distillation Technologies Process for the conversion of alcohols to olefins
BR112015020451A2 (pt) * 2013-02-27 2017-07-18 Mitsui Chemicals Inc catalisador para multimerização de olefina e método para produzir multímero de olefina na presença de um catalisador para multimerização de olefina
KR102116476B1 (ko) 2019-01-18 2020-05-28 대림산업 주식회사 폴리올레핀 중합 촉매 조성물, 폴리올레핀의 제조 방법 및 폴리올레핀 수지
KR102676768B1 (ko) 2022-08-11 2024-06-18 백창목 백셋 조절이 가능한 데드볼트용 래치

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2538595B2 (ja) * 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
IT8919252A0 (it) * 1989-01-31 1989-01-31 Ilano Catalizzatori per la polimerizzazione di olefine.
JPH02252705A (ja) * 1989-03-28 1990-10-11 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
DE69226564T3 (de) * 1991-05-20 2004-04-08 Mitsui Chemicals, Inc. Katalysator und Verfahren für Olefinpolymerisation
CA2069995C (en) * 1991-05-31 1996-04-09 Mitsui Chemicals, Incorporated Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization
US5409874A (en) * 1991-06-20 1995-04-25 Mitsui Petrochemical Industries, Ltd. Catalyst for olefin polymerization, process for the polymerization of olefin, and transition metal compound employable for the catalyst
KR950014847B1 (ko) * 1992-01-23 1995-12-16 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 에틸렌계 공중합체의 제조방법
TW304963B (enExample) * 1992-01-27 1997-05-11 Hoechst Ag
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5407882A (en) * 1992-08-04 1995-04-18 Tosoh Corporation Olefin polymerization catalyst and olefin polymerization process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7345119B2 (en) 2003-12-01 2008-03-18 Maruzen Petrochemical Company, Limited Olefin polymerization catalyst and olefin polymerization method using the same
JP2012149188A (ja) * 2011-01-20 2012-08-09 Mitsui Chemicals Inc オレフィン重合体の製造方法

Also Published As

Publication number Publication date
DE69331123D1 (de) 2001-12-20
CA2101965C (en) 1998-01-06
EP0582480A3 (enExample) 1994-03-23
KR0178072B1 (ko) 1999-05-15
EP0582480A2 (en) 1994-02-09
US5840645A (en) 1998-11-24
DE69331123T2 (de) 2002-04-18
EP0582480B1 (en) 2001-11-14
CA2101965A1 (en) 1994-02-07
KR940005679A (ko) 1994-03-22

Similar Documents

Publication Publication Date Title
JP2826362B2 (ja) オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
JP2693517B2 (ja) ベンゼン不溶性の有機アルミニウムオキシ化合物の製造方法
JPH06100614A (ja) オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
JPH06122706A (ja) オレフィンを重合および共重合する為の触媒および方法
JP3230762B2 (ja) オレフィン重合用触媒およびオレフィンの重合方法
JP2807571B2 (ja) オレフィン重合用固体触媒およびオレフィンの重合方法
JP3110156B2 (ja) オレフィン重合触媒およびオレフィンの重合方法
JP3455960B2 (ja) オレフィンのスラリー重合法
JP3910651B2 (ja) 有機アルミニウムオキシ組成物の製造方法
JP2685264B2 (ja) α―オレフィン系ランダム共重合体の製造方法
JP3230763B2 (ja) オレフィン重合用触媒およびオレフィンの重合方法
JP2940966B2 (ja) オレフィンの重合方法
JP2730939B2 (ja) エチレン・α―オレフィンランダム共重合体の製造方法
JP3339019B2 (ja) ポリオレフィンの製造方法
JPH05140224A (ja) オレフイン重合用触媒およびオレフインの重合方法
JP2825911B2 (ja) オレフィン重合用触媒およびオレフィンの重合方法
JP2975409B2 (ja) オレフィン重合用触媒およびオレフィンの重合方法
JPH0411604A (ja) オレフィン重合用触媒およびオレフィンの重合方法
JP4021463B2 (ja) オレフィン重合用触媒および該触媒を用いるオレフィンの重合方法
JPH05339315A (ja) オレフィンの重合方法
JPH06184226A (ja) オレフィン重合用固体触媒成分の調製方法
JP3465309B2 (ja) オレフィン重合触媒の調製方法、オレフィン重合触媒およびオレフィンの重合方法
JP3115661B2 (ja) エチレン系重合体用触媒およびエチレン系重合体の製造方法
JP2795474B2 (ja) オレフィン重合用触媒成分およびオレフィン重合用触媒ならびにオレフィンの重合方法
JPH08157515A (ja) オレフィン重合用触媒およびオレフィンの重合方法