CA2101965C - Olefin polymerization catalyst and method for the polymerization of olefin using said olefin polymerization catalyst - Google Patents

Olefin polymerization catalyst and method for the polymerization of olefin using said olefin polymerization catalyst

Info

Publication number
CA2101965C
CA2101965C CA002101965A CA2101965A CA2101965C CA 2101965 C CA2101965 C CA 2101965C CA 002101965 A CA002101965 A CA 002101965A CA 2101965 A CA2101965 A CA 2101965A CA 2101965 C CA2101965 C CA 2101965C
Authority
CA
Canada
Prior art keywords
group
compound
olefin
catalyst
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA002101965A
Other languages
English (en)
French (fr)
Other versions
CA2101965A1 (en
Inventor
Ryosuke Ohno
Toshiyuki Tsutsui
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Petrochemical Industries Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26494048&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2101965(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Publication of CA2101965A1 publication Critical patent/CA2101965A1/en
Application granted granted Critical
Publication of CA2101965C publication Critical patent/CA2101965C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CA002101965A 1992-08-06 1993-08-05 Olefin polymerization catalyst and method for the polymerization of olefin using said olefin polymerization catalyst Expired - Lifetime CA2101965C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP210408/1992 1992-08-06
JP21040892 1992-08-06
JP5171256A JPH06100614A (ja) 1992-08-06 1993-06-17 オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
JP171256/1993 1993-06-17

Publications (2)

Publication Number Publication Date
CA2101965A1 CA2101965A1 (en) 1994-02-07
CA2101965C true CA2101965C (en) 1998-01-06

Family

ID=26494048

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002101965A Expired - Lifetime CA2101965C (en) 1992-08-06 1993-08-05 Olefin polymerization catalyst and method for the polymerization of olefin using said olefin polymerization catalyst

Country Status (6)

Country Link
US (1) US5840645A (enExample)
EP (1) EP0582480B1 (enExample)
JP (1) JPH06100614A (enExample)
KR (1) KR0178072B1 (enExample)
CA (1) CA2101965C (enExample)
DE (1) DE69331123T2 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2193888A1 (en) * 1994-06-24 1996-01-04 Howard Curtis Welborn Jr. (Deceased) Polymerization process and catalyst systems useful therein
TR28720A (tr) * 1994-07-11 1997-02-18 Montell Technology Company Bv Olefinlerin polimerizasyonu icin desteklenmis katalizörler.
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
DE69529230T2 (de) * 1994-11-17 2003-09-04 Dow Global Technologies, Inc. Trägerkatalysatorkomponent, Trägerkatalysator, ihre Herstellung und Additionspolymerisationsverfahren
US6043180A (en) * 1994-11-17 2000-03-28 The Dow Chemical Company Supported catalyst component, supported catalyst, their preparation, and addition polymerization process
US5569746A (en) * 1995-01-23 1996-10-29 Albemarle Corporation Process for preparing alkylsubstituted cyclopentadienyl metallocene compounds
DE59503159D1 (de) * 1995-02-17 1998-09-17 Witco Gmbh Verfahren zur Herstellung von Übergangsmetallkomplexen mit 1,3-disubstituierten Cyclopentadienyl-Liganden
US5756416A (en) 1995-11-28 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition having improved comonomer reactivity
DE19621838A1 (de) * 1996-05-31 1997-12-04 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶2¶-Alkenen unter Zusatz eines Reaktionsverzögerers
KR20050085684A (ko) 2002-12-16 2005-08-29 바젤 폴리올레핀 게엠베하 알루미녹산 함량이 감소된, 지지된 촉매계의 제조방법
JP4133772B2 (ja) 2003-12-01 2008-08-13 丸善石油化学株式会社 オレフィン重合用触媒及びそれを用いたオレフィンの重合方法
EP1910431B1 (en) 2005-07-19 2013-11-27 ExxonMobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
US9272965B2 (en) * 2009-12-22 2016-03-01 Catalytic Distillation Technologies Process for the conversion of alcohols to olefins
JP5750271B2 (ja) * 2011-01-20 2015-07-15 三井化学株式会社 オレフィン重合体の製造方法
BR112015020451A2 (pt) * 2013-02-27 2017-07-18 Mitsui Chemicals Inc catalisador para multimerização de olefina e método para produzir multímero de olefina na presença de um catalisador para multimerização de olefina
KR102116476B1 (ko) 2019-01-18 2020-05-28 대림산업 주식회사 폴리올레핀 중합 촉매 조성물, 폴리올레핀의 제조 방법 및 폴리올레핀 수지
KR102676768B1 (ko) 2022-08-11 2024-06-18 백창목 백셋 조절이 가능한 데드볼트용 래치

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2538595B2 (ja) * 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
IT8919252A0 (it) * 1989-01-31 1989-01-31 Ilano Catalizzatori per la polimerizzazione di olefine.
JPH02252705A (ja) * 1989-03-28 1990-10-11 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
DE69226564T3 (de) * 1991-05-20 2004-04-08 Mitsui Chemicals, Inc. Katalysator und Verfahren für Olefinpolymerisation
CA2069995C (en) * 1991-05-31 1996-04-09 Mitsui Chemicals, Incorporated Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization
US5409874A (en) * 1991-06-20 1995-04-25 Mitsui Petrochemical Industries, Ltd. Catalyst for olefin polymerization, process for the polymerization of olefin, and transition metal compound employable for the catalyst
KR950014847B1 (ko) * 1992-01-23 1995-12-16 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 에틸렌계 공중합체의 제조방법
TW304963B (enExample) * 1992-01-27 1997-05-11 Hoechst Ag
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5407882A (en) * 1992-08-04 1995-04-18 Tosoh Corporation Olefin polymerization catalyst and olefin polymerization process

Also Published As

Publication number Publication date
DE69331123D1 (de) 2001-12-20
EP0582480A3 (enExample) 1994-03-23
KR0178072B1 (ko) 1999-05-15
EP0582480A2 (en) 1994-02-09
JPH06100614A (ja) 1994-04-12
US5840645A (en) 1998-11-24
DE69331123T2 (de) 2002-04-18
EP0582480B1 (en) 2001-11-14
CA2101965A1 (en) 1994-02-07
KR940005679A (ko) 1994-03-22

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