JPH0133485B2 - - Google Patents
Info
- Publication number
- JPH0133485B2 JPH0133485B2 JP59264634A JP26463484A JPH0133485B2 JP H0133485 B2 JPH0133485 B2 JP H0133485B2 JP 59264634 A JP59264634 A JP 59264634A JP 26463484 A JP26463484 A JP 26463484A JP H0133485 B2 JPH0133485 B2 JP H0133485B2
- Authority
- JP
- Japan
- Prior art keywords
- styrene
- weight
- resin composition
- rubber
- blocked
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 122
- 229920001971 elastomer Polymers 0.000 claims description 52
- 239000005060 rubber Substances 0.000 claims description 51
- 239000011342 resin composition Substances 0.000 claims description 41
- 229920005990 polystyrene resin Polymers 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 23
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 17
- 239000004793 Polystyrene Substances 0.000 claims description 12
- 229920002223 polystyrene Polymers 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000010526 radical polymerization reaction Methods 0.000 claims description 3
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 3
- 239000012745 toughening agent Substances 0.000 description 18
- 238000006116 polymerization reaction Methods 0.000 description 15
- 238000000034 method Methods 0.000 description 11
- 238000012662 bulk polymerization Methods 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 7
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 229920005669 high impact polystyrene Polymers 0.000 description 6
- 239000004797 high-impact polystyrene Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 238000010557 suspension polymerization reaction Methods 0.000 description 6
- 229920000428 triblock copolymer Polymers 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 125000001979 organolithium group Chemical group 0.000 description 2
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005063 High cis polybutadiene Substances 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- 239000005064 Low cis polybutadiene Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- PBGVMIDTGGTBFS-UHFFFAOYSA-N but-3-enylbenzene Chemical compound C=CCCC1=CC=CC=C1 PBGVMIDTGGTBFS-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- -1 etc. Chemical compound 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26463484A JPS61143415A (ja) | 1984-12-17 | 1984-12-17 | 耐衝撃性に優れるポリスチレン系樹脂組成物およびその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26463484A JPS61143415A (ja) | 1984-12-17 | 1984-12-17 | 耐衝撃性に優れるポリスチレン系樹脂組成物およびその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61143415A JPS61143415A (ja) | 1986-07-01 |
| JPH0133485B2 true JPH0133485B2 (de) | 1989-07-13 |
Family
ID=17406068
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26463484A Granted JPS61143415A (ja) | 1984-12-17 | 1984-12-17 | 耐衝撃性に優れるポリスチレン系樹脂組成物およびその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61143415A (de) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2650902B2 (ja) * | 1987-02-16 | 1997-09-10 | 三井東圧化学株式会社 | ゴム変性スチレン系共重合樹脂組成物 |
| JP2630955B2 (ja) * | 1987-09-16 | 1997-07-16 | 日本エラストマー株式会社 | ブタジエンースチレンブロック共重合体 |
| JPS6474209A (en) * | 1987-09-17 | 1989-03-20 | Nippon Elastomer Kk | Impact-resistant styrenic resin and manufacture thereof |
| JP2662962B2 (ja) * | 1987-12-28 | 1997-10-15 | 日本エラストマー株式会社 | 耐衝撃性スチレン系樹脂及びその製造方法 |
| JPH0216139A (ja) * | 1988-07-05 | 1990-01-19 | Mitsui Toatsu Chem Inc | アニオン重合ゴム変性スチレン系共重合体 |
| JP2658295B2 (ja) * | 1988-11-11 | 1997-09-30 | 日本合成ゴム株式会社 | 耐衝撃性芳香族ビニル系樹脂の製造方法 |
| JPH085939B2 (ja) * | 1989-03-10 | 1996-01-24 | 出光石油化学株式会社 | ゴム変性スチレン系樹脂組成物の製造方法 |
| JP2608481B2 (ja) * | 1989-03-31 | 1997-05-07 | 出光石油化学株式会社 | スチレン系樹脂組成物 |
| JPH0372510A (ja) * | 1989-08-11 | 1991-03-27 | Japan Synthetic Rubber Co Ltd | 耐衝撃性芳香族ビニル系樹脂の製造方法 |
| JP4920145B2 (ja) * | 2001-08-06 | 2012-04-18 | 電気化学工業株式会社 | ゴム変性芳香族ビニル系共重合樹脂組成物およびその製造方法 |
| JP6258088B2 (ja) * | 2014-03-17 | 2018-01-10 | Ｐｓジャパン株式会社 | 二軸延伸シート |
| JP6262577B2 (ja) * | 2014-03-17 | 2018-01-17 | Ｐｓジャパン株式会社 | 二軸延伸シート |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5271549A (en) * | 1975-12-11 | 1977-06-15 | Asahi Chem Ind Co Ltd | Preparation of high-impact polystyrene compositions |
-
1984
- 1984-12-17 JP JP26463484A patent/JPS61143415A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5271549A (en) * | 1975-12-11 | 1977-06-15 | Asahi Chem Ind Co Ltd | Preparation of high-impact polystyrene compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61143415A (ja) | 1986-07-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |