JP6656242B2 - ゼオライト材料の固体熱合成方法及びそれから得られるゼオライト - Google Patents

ゼオライト材料の固体熱合成方法及びそれから得られるゼオライト Download PDF

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JP6656242B2
JP6656242B2 JP2017520902A JP2017520902A JP6656242B2 JP 6656242 B2 JP6656242 B2 JP 6656242B2 JP 2017520902 A JP2017520902 A JP 2017520902A JP 2017520902 A JP2017520902 A JP 2017520902A JP 6656242 B2 JP6656242 B2 JP 6656242B2
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mass
mixture
crystallized
zeolite material
fluoride
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JP2017532282A (ja
JP2017532282A5 (enExample
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マウレル，シュテファン
ミュラー，ウルリヒ
シャオ，フォン−ショウ
モン，シヤンチュー
ウー，チンミン
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BASF SE
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    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7023—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7042—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
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    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/087—Ferrosilicates
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/205—Faujasite type, e.g. type X or Y using at least one organic template directing agent; Hexagonal faujasite; Intergrowth products of cubic and hexagonal faujasite
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/26—Mordenite type
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    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
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    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
JP2017520902A 2014-10-15 2015-10-15 ゼオライト材料の固体熱合成方法及びそれから得られるゼオライト Expired - Fee Related JP6656242B2 (ja)

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CN2014088647 2014-10-15
CNPCT/CN2014/088647 2014-10-15
PCT/CN2015/091979 WO2016058541A1 (en) 2014-10-15 2015-10-15 Solidothermal synthesis of zeolitic materials and zeolites obtained therefrom

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JP2017532282A JP2017532282A (ja) 2017-11-02
JP2017532282A5 JP2017532282A5 (enExample) 2018-11-22
JP6656242B2 true JP6656242B2 (ja) 2020-03-04

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US (1) US10301185B2 (enExample)
EP (1) EP3206991A4 (enExample)
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WO2016058541A1 (en) 2014-10-15 2016-04-21 Basf Se Solidothermal synthesis of zeolitic materials and zeolites obtained therefrom
KR102558113B1 (ko) 2015-02-12 2023-07-24 바스프 에스이 Bea 골격 구조를 갖는 탈알루미늄화된 제올라이트 물질의 제조 방법
JP6741687B2 (ja) 2015-05-04 2020-08-19 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ メロナールの調製方法
US10202323B2 (en) 2015-07-15 2019-02-12 Basf Se Process for preparing an arylpropene
CN108290134A (zh) 2015-11-27 2018-07-17 巴斯夫欧洲公司 金属-有机骨架的超快高空时产率合成
ES2899827T3 (es) 2015-12-08 2022-03-14 Basf Se Material zeolítico que contiene estaño y que tiene una estructura de marco BEA
EP3178788A1 (en) 2015-12-08 2017-06-14 Basf Se A tin-containing zeolitic material having a bea framework structure
JP6786876B2 (ja) * 2016-05-23 2020-11-18 東ソー株式会社 Ｃｈａ型ゼオライトの製造方法
EP3509991B1 (en) * 2016-09-06 2021-12-01 Basf Se Solidothermal synthesis of a boron-containing zeolite with an mww framework structure
WO2018059316A1 (en) * 2016-09-27 2018-04-05 Basf Se Highly efficient solidothermal synthesis of zeolitic materials
EP3830031A1 (en) * 2018-07-27 2021-06-09 Basf Se Process for preparing a zeolitic material having a framework type fer
WO2021052466A1 (en) * 2019-09-20 2021-03-25 Basf Se Synthesis and use of zeolitic material having the ith framework structure type
CN113979448B (zh) * 2020-07-27 2023-05-02 中国石油化工股份有限公司 含氟zsm-35分子筛及其制备方法
JP2024508239A (ja) * 2021-02-03 2024-02-26 ビーエーエスエフ コーポレーション Ｃｈａ様骨格構造を有するゼオライト材料及びその合成
US12428305B2 (en) * 2021-02-09 2025-09-30 Basf Mobile Emissions Catalysts Llc Zeolite structure synthesized using mixtures of organic structure directing agents
US11565943B2 (en) * 2021-02-11 2023-01-31 Chevron U.S.A. Inc. Synthesis of ton framework type molecular sieves
US20220347663A1 (en) * 2021-04-27 2022-11-03 Chevron U.S.A. Inc. Ferrosilicate ssz-70 molcular sieve, its synthesis and use
JP2023156098A (ja) * 2022-04-12 2023-10-24 東ソー株式会社 Ｆａｕ型ゼオライトの製造方法

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CN1214978C (zh) * 2003-03-20 2005-08-17 吉林大学 具有超高水热稳定的有序介孔分子筛材料及其合成方法
WO2008058398A1 (en) * 2006-11-16 2008-05-22 UNIVERSITé LAVAL Nanozeolites and process for preparation thereof
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JP6591740B2 (ja) 2013-10-29 2019-10-16 中国石油化工股▲ふん▼有限公司 完全Ｓｉ分子篩、および、その合成方法
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CN104891520B (zh) 2015-06-02 2017-08-29 中国科学院上海高等研究院 一种固相合成多级孔分子筛的方法

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CN107074566A (zh) 2017-08-18
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JP2017532282A (ja) 2017-11-02
EP3206991A1 (en) 2017-08-23
US10301185B2 (en) 2019-05-28
WO2016058541A1 (en) 2016-04-21
KR20170070052A (ko) 2017-06-21

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